EP3050997B1 - Method for diffusion coating heat-resistant metal member with creep reinforcement material, and creep-strength-enhanced heat-resistant metal member - Google Patents
Method for diffusion coating heat-resistant metal member with creep reinforcement material, and creep-strength-enhanced heat-resistant metal member Download PDFInfo
- Publication number
- EP3050997B1 EP3050997B1 EP13894771.8A EP13894771A EP3050997B1 EP 3050997 B1 EP3050997 B1 EP 3050997B1 EP 13894771 A EP13894771 A EP 13894771A EP 3050997 B1 EP3050997 B1 EP 3050997B1
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- EP
- European Patent Office
- Prior art keywords
- heat
- steel
- metal member
- resistant metal
- resistant
- Prior art date
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- 229910052751 metal Inorganic materials 0.000 title claims description 87
- 239000002184 metal Substances 0.000 title claims description 87
- 239000000463 material Substances 0.000 title claims description 47
- 230000002787 reinforcement Effects 0.000 title claims description 44
- 238000000034 method Methods 0.000 title claims description 23
- 239000011248 coating agent Substances 0.000 title claims description 6
- 238000000576 coating method Methods 0.000 title claims description 5
- 238000009792 diffusion process Methods 0.000 title 1
- 229910000831 Steel Inorganic materials 0.000 claims description 51
- 239000010959 steel Substances 0.000 claims description 51
- 238000010438 heat treatment Methods 0.000 claims description 15
- 239000000956 alloy Substances 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 6
- 230000009466 transformation Effects 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 229910052735 hafnium Inorganic materials 0.000 claims description 3
- 229910052758 niobium Inorganic materials 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims 1
- 239000007769 metal material Substances 0.000 description 5
- 238000005728 strengthening Methods 0.000 description 5
- 239000003779 heat-resistant material Substances 0.000 description 4
- 239000011651 chromium Substances 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 239000010955 niobium Substances 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- -1 sialon Chemical compound 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 238000005480 shot peening Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/18—After-treatment
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/10—Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/10—Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
- C23C4/11—Oxides
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/14—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying for coating elongate material
- C23C4/16—Wires; Tubes
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2251/00—Treating composite or clad material
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/08—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/50—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for welded joints
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12576—Boride, carbide or nitride component
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12583—Component contains compound of adjacent metal
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12583—Component contains compound of adjacent metal
- Y10T428/1259—Oxide
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12931—Co-, Fe-, or Ni-base components, alternative to each other
Definitions
- the present invention relates to a method for diffusing and permeating a creep reinforcement material into a heat-resistant metal member, and to a heat-resistant metal member with creep strength enhanced by such a method.
- US2013/0220523 discloses e.g. in example 4 a 430 steel foil was spray coated with a composition comprising e.g. Cr, Mo and B. Then the sprayed foil was put inside a steel pipe i.e. covered by the pipe. The steel foil was pressed against the pipe and the assembly was heat treated in vacuum under 1190-1225 C for 15 to 30 min.
- An object of the present invention is to provide a method capable of efficiently diffusing and permeating a material that enhances creep strength (hereinafter referred to as a "creep reinforcement material") into a member manufactured using a heat-resistant metal material (hereinafter referred to as a "heat-resistant metal member”), and to provide a heat-resistant metal member with creep strength enhanced by such a method.
- the present invention enables provision of a method capable of efficiently diffusing and permeating a creep reinforcement material into a heat-resistant metal member, and provision of a heat-resistant metal member with creep strength enhanced by such a method.
- Fig. 1 is a schematic diagram illustrating a method for diffusing and permeating a creep reinforcement material into a heat-resistant metal member, to explain an embodiment of the present invention.
- Fig. 2 is a schematic cross-section illustrating a cross-section of Fig. 1 , to explain an embodiment of the present invention.
- explanation is of an example of a case in which an already installed (including repaired cases thereof) or unused, or a degraded, high temperature pipe manufactured using a heat-resistant metal material, is employed as a heat-resistant metal member 10, however, there is no limitation thereto.
- the heat-resistant metal member 10 may be another high temperature member manufactured using a heat-resistant metal material, such as an already installed (including repaired cases thereof) or unused, or a degraded, turbine.
- the creep reinforcement material is coated or thermally sprayed onto a surface of the heat-resistant metal member 10. Then a section 25 onto which the creep reinforcement material has been coated or thermally sprayed is covered by a heat-resistant covering member 30, and the heat-resistant covering member 30 is secured so as to make contact with the section 25. Next, the heat-resistant metal member 10 covered by the heat-resistant covering member 30 is heated for a specific duration at a temperature of 1000°C or greater using a heater 40.
- the heat-resistant metal member 10 coated or thermally sprayed with the creep reinforcement material is covered by the heat-resistant covering member 30 and is heated to a temperature of 1000°C or greater, and thus compressive force acts on the heat-resistant metal member as it thermally expands in a direction toward an outer periphery, restraining thermal expansion of the heat-resistant metal member in the direction toward the outer periphery, and enabling the creep reinforcement material on the surface of the heat-resistant metal member 10 to be efficiently diffused and permeated into the heat-resistant metal member 10.
- the heat-resistant metal member 10 is a degraded member or an already installed member
- creep voids and cracks in the heat-resistant metal member 10 and a weld 20 thereof are efficiently repaired, enabling regeneration of the heat-resistant metal member 10 and the weld 20 thereof to be achieved.
- structural strengthening of the heat-resistant metal member 10 and the weld 20 thereof can be achieved accompanying restoration of the structure of the heat-resistant metal member 10 and the weld 20 thereof.
- the creep strength is accordingly enhanced, enabling the lifespan to be extended to that of a new member or greater.
- etching treatment or shot peening and etching treatment, may be performed on the section 25 to be coated or thermally sprayed with the creep reinforcement material prior to coating or thermally spraying the creep reinforcement material on the surface of the heat-resistant metal member 10.
- Such processing enables work hardening of the surface layer of the heat-resistant metal member 10 to be performed by plastic deformation, enables residual compressive stress to be imparted to the surface of the heat-resistant metal member 10, and enables any oxidized film on the surface of the heat-resistant metal member 10 to be removed.
- processing to remove (reduce) residual stress may be performed after the heat-resistant metal member 10 covered by the heat-resistant covering member 30 has been heated to a temperature of 1000°C or greater using the heater 40.
- the heat-resistant metal member 10 may be first cooled to room temperature, then reheated to a temperature of an A 1 transformation point or greater (preferably from 10°C to 100°C above 1000°C) for a specific duration (for example, from approximately several hours to approximately 24 hours).
- the heat-resistant metal member 10 in order to restrict thermal expansion of the heat-resistant metal member 10 toward the outside in the length direction thereof (in directions toward the ends of the heat-resistant metal member 10) occurring when the heat-resistant metal member 10, which has been coated or thermally sprayed with the creep reinforcement material, is covered by the heat-resistant covering member 30 and heated by the heater 40, the heat-resistant metal member 10 may be secured in sections not being heated by the heater 40, by, for example, two clamps so as to sandwich the section being heated by the heater 40.
- the heat-resistant metal of the member 10 is made of 0.3Mo steel, 0.5Mo steel, 0.5Cr-0.5Mo steel, 1Cr-0.2Mo steel, 1Cr-0.5Mo steel, 1.25Cr-0.5Mo steel, 2.25Cr-1Mo steel, 5Cr-0.5Mo steel, 7Cr-0.5Mo steel, 9Cr-1Mo steel, 0.3Cr-Mo-V steel, 0.5Cr-Mo-V steel, 9Cr-Mo-V steel, 12Cr-Mo-V steel, 1Cr-1.25Mo-0.25V steel, 9Cr-1Mo-W steel, SUS304, SUS304L, SUS316, SUS316L, SUS316TI, SUS317, SUS321, SUS347H, SUS310S, Super304, SUS904L, NCF600, NCF601, NCF800, and NCF800H.
- the creep reinforcement material needs to contain an element which has a melting point of 1000°C or greater and in which precipitation strengthening and solid solution strengthening occur upon heating to a temperature of 1000°C or greater so as to enable creep strength to be enhanced.
- the heat-resistant metal member 10 the creep reinforcement material contains one or a plurality of elements appropriately selected from B (boron), W (tungsten), Cr (Chromium), Mo (molybdenum), Nb (niobium), V (vanadium), Hf (hafnium), Zr (zirconium), Ti (titanium), Cu (copper), and Co (cobalt).
- the creep reinforcement material is coated on the surface of the heat-resistant metal member 10
- powdered creep reinforcement material may be employed as it is, or a coating agent of the creep reinforcement material in a liquid form or paste form using a binder, solvent, adhesive or the like may be employed.
- a known thermal spray method may be appropriately employed, such as a plasma spraying method using powdered creep reinforcement material. Note that coating or thermally spraying of the creep reinforcement material on the surface of the heat-resistant metal member 10 may be performed over the entire outer peripheral surface of the heat-resistant metal member 10 as in the present embodiment, or may be performed on a part of the surface of the heat-resistant metal member 10.
- the heat-resistant covering member 30 needs to be capable of covering the section 25 coated or thermally sprayed with the creep reinforcement material so as to make contact with the section 25, as long as it is made from a heat-resistant material that restrains thermal expansion in the section 25 in the direction toward the outer periphery of the heat-resistant metal member 10 occurring when heated to the heating temperature mentioned above, and is able to maintain the approximate profile of the heat-resistant metal member 10 at the section 25.
- a material having a lower thermal expansion coefficient than the heat-resistant metal member 10 at temperatures of the heating temperature mentioned above or greater is preferably employed for the heat-resistant covering member 30.
- the heat-resistant covering member 30 is configured from a heat-resistant material different from that of the heat-resistant metal member 10, yet having a thermal expansion coefficient of about the same as the heat-resistant metal member 10, or from a heat resistant material having a higher thermal expansion coefficient than the heat-resistant metal member 10, in order to restrain the thermal expansion of the heat-resistant covering member 30 occurring when heated to the heating temperature mentioned above, the outer periphery of the heat-resistant covering member 30 may be secured by a member of a heat-resistant material having a lower thermal expansion coefficient than the heat-resistant metal member 10 at or above the heating temperature mentioned above, so as to maintain the profile of the heat-resistant covering member 30.
- the heat-resistant covering member 30 being a ceramic or an alloy, including ceramics such as alumina, zirconia, aluminum nitride, silicon carbide, silicon nitride, cordierite, sialon, zircon, and mullite, and alloys such as Alloy 903, Alloy 909, and HRA 929.
- the heat-resistant covering member 30 is, for example, of a cord, plate, or clamp shape. Securing of the above may be performed by, for example, wrapping a cord-shaped or plate-shaped heat-resistant covering member 30 around the outer periphery of the heat-resistant metal member 10 at the section 25 coated or thermally sprayed with the creep reinforcement material, by attaching a clamp-shaped heat-resistant covering member 30 to the outer periphery of the heat-resistant metal member 10 at the section 25 coated or thermally sprayed with the creep reinforcement material, or by attaching a heat-resistant covering member 30 formed in a plate shape or the like to the outer periphery of a heat-resistant metal member 10 at the section 25 coated or thermally sprayed with the creep reinforcement material using fasteners, such as clamps or screws.
- the heat-resistant covering member 30 is made from fittings including two substantially semi-circular arc cross-section shapes.
- the heat-resistant covering member 30 is then secured to the surface of the heat-resistant metal member 10 using threaded members 35 attached to flanges of these fittings, such that the inner face of the fittings contact the outer periphery of the heat-resistant metal member 10 at the section 25 coated or thermally sprayed with the creep reinforcement material.
- the threaded members 35 are manufactured, for example, from the same material as the heat-resistant covering member 30.
- the heating temperature of the heat-resistant metal member 10 coated or thermally sprayed with the creep reinforcement material is a temperature of 1000°C or greater.
- the heat-resistant metal member 10 is heated at a temperature of, or greater than, an A 3 transformation point of the component of the heat-resistant metal material of the member 10 or the creep reinforcement material having the highest A 3 transformation point (preferably from 10°C to 100°C above 1000°C) for a specific duration (for example, from approximately several hours to approximately 24 hours) .
- the present embodiment employs, as a heating device, the high frequency heater 40, which is capable of heating the heat-resistant metal member 10 coated or thermally sprayed with the creep reinforcement material, from the outer periphery thereof, there is no particular limitation thereto, as long as a heating device capable of heating the heat-resistant metal member 10 at the section 25 coated or thermally sprayed with the creep reinforcement material.
- the product of diffusing and permeating the creep reinforcement material into the heat-resistant metal member 10 by the method described above is useful as a heat-resistant metal member with enhanced creep strength due to the creep strength being enhanced as described above.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Coating By Spraying Or Casting (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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PL13894771T PL3050997T3 (pl) | 2013-09-25 | 2013-09-25 | Sposób powlekania dyfuzujnego żaroodpornego elementu metalowego materiałem wzmacniającym przed pełzaniem, oraz żaroodporny element metalowy o zwiększonej wytrzymałości na pełzanie |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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PCT/JP2013/075927 WO2015045038A1 (ja) | 2013-09-25 | 2013-09-25 | 耐熱金属材料部材に対するクリープ強化材の拡散浸透方法、及びクリープ強度を強化させた耐熱金属材料部材 |
Publications (3)
Publication Number | Publication Date |
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EP3050997A1 EP3050997A1 (en) | 2016-08-03 |
EP3050997A4 EP3050997A4 (en) | 2016-09-21 |
EP3050997B1 true EP3050997B1 (en) | 2018-07-18 |
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EP13894771.8A Active EP3050997B1 (en) | 2013-09-25 | 2013-09-25 | Method for diffusion coating heat-resistant metal member with creep reinforcement material, and creep-strength-enhanced heat-resistant metal member |
Country Status (8)
Country | Link |
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US (1) | US20160230262A1 (ja) |
EP (1) | EP3050997B1 (ja) |
JP (1) | JP5925958B2 (ja) |
KR (1) | KR20160043033A (ja) |
CN (1) | CN105555988A (ja) |
CA (1) | CA2924624C (ja) |
PL (1) | PL3050997T3 (ja) |
WO (1) | WO2015045038A1 (ja) |
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KR102155888B1 (ko) * | 2017-09-11 | 2020-09-14 | 주식회사 엘지화학 | 레이저 용접 지그 및 이를 포함하는 레이저 용접 장치 |
CN108161209B (zh) * | 2017-12-23 | 2021-06-15 | 河南瀚银光电科技股份有限公司 | 铝基复合材料及其制备方法 |
WO2020065817A1 (ja) * | 2018-09-27 | 2020-04-02 | 中国電力株式会社 | 耐熱合金製部品の補修方法 |
CN112094997B (zh) * | 2020-09-15 | 2022-02-15 | 中南大学 | 一种改善低合金超高强钢焊件耐腐蚀性能的方法 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
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DE3907625C1 (ja) * | 1989-03-09 | 1990-02-15 | Mtu Muenchen Gmbh | |
JPH04176856A (ja) * | 1990-04-19 | 1992-06-24 | Nkk Corp | 耐摩耗性複合材料及びその製造方法 |
JPH0794705B2 (ja) * | 1990-04-19 | 1995-10-11 | 日本鋼管株式会社 | 耐摩耗性複合材料及びその製造方法 |
JP2733016B2 (ja) * | 1994-04-06 | 1998-03-30 | 新日本製鐵株式会社 | 酸化雰囲気中で接合可能な耐熱材料用液相拡散接合合金箔 |
CA2152525C (en) * | 1994-06-24 | 1999-03-23 | Thomas Alan Taylor | A process for producing carbide particles dispersed in a mcraly-based coating |
JPH1137864A (ja) * | 1997-07-23 | 1999-02-12 | Aisin Seiki Co Ltd | 磁歪式トルクセンサの磁歪膜の製造方法 |
JP2002257163A (ja) * | 2001-02-28 | 2002-09-11 | Daido Seimitsu Kogyo Kk | ブレーキ装置及びブレーキ装置のバックラッシュ低減方法 |
JP3793966B2 (ja) | 2002-08-30 | 2006-07-05 | 中国電力株式会社 | 耐熱材料の改質強化処理方法及び溶接熱影響部のクリープ特性を強化した高温用部材 |
US8133595B2 (en) * | 2006-11-16 | 2012-03-13 | National University Corporation Hokkaido University | Multilayer alloy coating film, heat-resistant metal member having the same, and method for producing multilayer alloy coating film |
US7900458B2 (en) * | 2007-05-29 | 2011-03-08 | Siemens Energy, Inc. | Turbine airfoils with near surface cooling passages and method of making same |
US20110244138A1 (en) * | 2010-03-30 | 2011-10-06 | Schlichting Kevin W | Metallic coating for non-line of sight areas |
JP5859305B2 (ja) * | 2011-12-27 | 2016-02-10 | 三菱重工業株式会社 | 大口径の金属管のクリープ部の再生装置及び該再生装置を用いた再生方法 |
US20130220523A1 (en) * | 2012-02-29 | 2013-08-29 | c/o Chevron Corporation | Coating compositions, applications thereof, and methods of forming |
-
2013
- 2013-09-25 CN CN201380079648.6A patent/CN105555988A/zh active Pending
- 2013-09-25 KR KR1020167006489A patent/KR20160043033A/ko active IP Right Grant
- 2013-09-25 EP EP13894771.8A patent/EP3050997B1/en active Active
- 2013-09-25 CA CA2924624A patent/CA2924624C/en active Active
- 2013-09-25 WO PCT/JP2013/075927 patent/WO2015045038A1/ja active Application Filing
- 2013-09-25 PL PL13894771T patent/PL3050997T3/pl unknown
- 2013-09-25 JP JP2015512426A patent/JP5925958B2/ja active Active
- 2013-09-25 US US15/022,948 patent/US20160230262A1/en not_active Abandoned
Non-Patent Citations (1)
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None * |
Also Published As
Publication number | Publication date |
---|---|
US20160230262A1 (en) | 2016-08-11 |
KR20160043033A (ko) | 2016-04-20 |
WO2015045038A1 (ja) | 2015-04-02 |
PL3050997T3 (pl) | 2018-12-31 |
JP5925958B2 (ja) | 2016-05-25 |
JPWO2015045038A1 (ja) | 2017-03-02 |
CN105555988A (zh) | 2016-05-04 |
CA2924624A1 (en) | 2015-04-02 |
CA2924624C (en) | 2017-12-12 |
EP3050997A1 (en) | 2016-08-03 |
EP3050997A4 (en) | 2016-09-21 |
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