EP3045480A4 - Vinylalkoholpolymer, verdickungsmittel, stabilisator zur emulsionspolymerisation, stabilisator zur suspensionspolymerisation, beschichtungsmittel, beschichtung, leimungsmittel für fasern, verfahren zur herstellung von geleimtem garn und textilstoff - Google Patents

Vinylalkoholpolymer, verdickungsmittel, stabilisator zur emulsionspolymerisation, stabilisator zur suspensionspolymerisation, beschichtungsmittel, beschichtung, leimungsmittel für fasern, verfahren zur herstellung von geleimtem garn und textilstoff Download PDF

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Publication number
EP3045480A4
EP3045480A4 EP14843527.4A EP14843527A EP3045480A4 EP 3045480 A4 EP3045480 A4 EP 3045480A4 EP 14843527 A EP14843527 A EP 14843527A EP 3045480 A4 EP3045480 A4 EP 3045480A4
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EP
European Patent Office
Prior art keywords
stabilizer
coating
agent
thickener
textile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP14843527.4A
Other languages
English (en)
French (fr)
Other versions
EP3045480A1 (de
EP3045480B1 (de
Inventor
Masaki Kato
Hideki Maki
Keishi HACHIYA
Masako Kawagoe
Yoko Mori
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuraray Co Ltd
Original Assignee
Kuraray Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2013191179A external-priority patent/JP6041776B2/ja
Priority claimed from JP2014039450A external-priority patent/JP6163122B2/ja
Priority claimed from JP2014052636A external-priority patent/JP6339830B2/ja
Priority claimed from JP2014073673A external-priority patent/JP6163130B2/ja
Priority claimed from JP2014149240A external-priority patent/JP6272736B2/ja
Application filed by Kuraray Co Ltd filed Critical Kuraray Co Ltd
Publication of EP3045480A1 publication Critical patent/EP3045480A1/de
Publication of EP3045480A4 publication Critical patent/EP3045480A4/de
Application granted granted Critical
Publication of EP3045480B1 publication Critical patent/EP3045480B1/de
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/02Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an alcohol radical
    • C08F216/04Acyclic compounds
    • C08F216/06Polyvinyl alcohol ; Vinyl alcohol
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/30Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
    • B41M5/337Additives; Binders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/5254Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/42Applications of coated or impregnated materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02Esters of monocarboxylic acids
    • C08F218/04Vinyl esters
    • C08F218/08Vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/12Hydrolysis
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/14Esterification
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D129/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
    • C09D129/02Homopolymers or copolymers of unsaturated alcohols
    • C09D129/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/36Coatings with pigments
    • D21H19/44Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/60Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16Sizing or water-repelling agents
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/001Release paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10Packing paper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M2205/00Printing methods or features related to printing methods; Location or type of the layers
    • B41M2205/02Dye diffusion thermal transfer printing (D2T2)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M2205/00Printing methods or features related to printing methods; Location or type of the layers
    • B41M2205/32Thermal receivers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00Chemical modification of a polymer
    • C08F2810/20Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2429/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2429/02Homopolymers or copolymers of unsaturated alcohols
    • C08J2429/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Textile Engineering (AREA)
  • Optics & Photonics (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
EP14843527.4A 2013-09-13 2014-09-11 Vinylalkoholpolymer, verdickungsmittel, stabilisator zur emulsionspolymerisation, stabilisator zur suspensionspolymerisation, beschichtungsmittel, beschichtung, leimungsmittel für fasern, verfahren zur herstellung von geleimtem garn und textilstoff Active EP3045480B1 (de)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP2013191179A JP6041776B2 (ja) 2013-09-13 2013-09-13 増粘剤、増粘剤の製造方法、ビニルアルコール系重合体、及びビニルアルコール系重合体の製造方法
JP2014039450A JP6163122B2 (ja) 2014-02-28 2014-02-28 乳化重合用安定剤及びその製造方法
JP2014052636A JP6339830B2 (ja) 2014-03-14 2014-03-14 コーティング剤、その製造方法、及び塗工物
JP2014073673A JP6163130B2 (ja) 2014-03-31 2014-03-31 懸濁重合用安定剤及びその製造方法
JP2014149240A JP6272736B2 (ja) 2014-07-22 2014-07-22 繊維用糊剤、繊維用糊剤の製造方法、糊付け糸及び織物の製造方法
PCT/JP2014/074147 WO2015037683A1 (ja) 2013-09-13 2014-09-11 ビニルアルコール系重合体、増粘剤、乳化重合用安定剤、懸濁重合用安定剤、コーティング剤、塗工物、繊維用糊剤、糊付け糸及び織物の製造方法

Publications (3)

Publication Number Publication Date
EP3045480A1 EP3045480A1 (de) 2016-07-20
EP3045480A4 true EP3045480A4 (de) 2017-05-10
EP3045480B1 EP3045480B1 (de) 2021-06-16

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ID=52665783

Family Applications (1)

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EP14843527.4A Active EP3045480B1 (de) 2013-09-13 2014-09-11 Vinylalkoholpolymer, verdickungsmittel, stabilisator zur emulsionspolymerisation, stabilisator zur suspensionspolymerisation, beschichtungsmittel, beschichtung, leimungsmittel für fasern, verfahren zur herstellung von geleimtem garn und textilstoff

Country Status (9)

Country Link
US (1) US9751968B2 (de)
EP (1) EP3045480B1 (de)
CN (1) CN105531292B (de)
BR (1) BR112016005288B1 (de)
CA (1) CA2924175C (de)
MX (1) MX388402B (de)
SG (1) SG11201601871QA (de)
TW (1) TWI637967B (de)
WO (1) WO2015037683A1 (de)

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JP6120745B2 (ja) * 2013-09-30 2017-04-26 三菱鉛筆株式会社 水性ボールペン用インク組成物
JP6730862B2 (ja) * 2016-06-23 2020-07-29 株式会社クラレ ビニルアルコール系重合体水溶液
WO2018061272A1 (ja) * 2016-09-28 2018-04-05 株式会社クラレ メタノール含有量が低減された変性ビニルアルコール系重合体粉末及びその製造方法、並びに水溶性フィルム及び包装体
US11208550B2 (en) * 2016-12-28 2021-12-28 Kuraray Co., Ltd. Polyvinyl alcohol composition and use thereof
JP7153011B2 (ja) * 2017-03-30 2022-10-13 株式会社クラレ 剥離紙原紙及びその製造方法、並びに剥離紙
JP7160897B2 (ja) * 2018-03-08 2022-10-25 株式会社クラレ 農薬用展着剤及び農薬散布液
WO2019181915A1 (ja) * 2018-03-20 2019-09-26 株式会社クラレ 懸濁重合用分散安定剤
WO2019189000A1 (ja) * 2018-03-26 2019-10-03 株式会社クラレ コーティング剤、接着剤及び塗工物
TWI799607B (zh) * 2018-06-29 2023-04-21 日商可樂麗股份有限公司 聚乙烯醇薄膜、偏光薄膜及此等之製造方法、以及薄膜卷
KR102315970B1 (ko) * 2018-12-07 2021-10-20 주식회사 엘지화학 딥 성형용 라텍스 조성물, 이의 제조방법 및 이로부터 성형된 성형품
WO2020137466A1 (ja) * 2018-12-27 2020-07-02 株式会社クラレ 収束糸、水硬性組成物及び成形体
US20220085375A1 (en) * 2019-01-11 2022-03-17 Kuraray Co., Ltd. Non-aqueous electrolyte cell electrode binder, non-aqueous electrolyte cell electrode binder solution, non-aqueous electrolyte cell electrode slurry, non-aqueous electrolyte cell electrode, and non-aqueous electrolyte cell
TWI812855B (zh) * 2019-04-05 2023-08-21 日商可樂麗股份有限公司 水性乳液及使用其之接著劑
WO2021075480A1 (ja) * 2019-10-16 2021-04-22 株式会社クラレ 紙用コーティング剤及びそれを用いた塗工紙
CN113800814B (zh) * 2021-09-16 2022-07-01 中建西部建设建材科学研究院有限公司 一种混凝土废浆浓缩液悬浮稳定剂及其制备方法
WO2023054707A1 (ja) * 2021-09-30 2023-04-06 株式会社クラレ クレーピング用接着剤、クレーピング用接着剤用の粉末、クレーピング用接着剤の製造方法、及びトイレットペーパー、ティシュペーパー、タオルペーパー、キッチンペーパー又はナプキン原紙
WO2024233627A1 (en) * 2023-05-08 2024-11-14 Monosol, Llc Water-soluble film including metal salts

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CN105531292B (zh) 2018-07-03
TWI637967B (zh) 2018-10-11
MX2016003133A (es) 2016-09-07
US20160251466A1 (en) 2016-09-01
EP3045480A1 (de) 2016-07-20
TW201514209A (zh) 2015-04-16
CA2924175A1 (en) 2015-03-19
CA2924175C (en) 2021-10-19
EP3045480B1 (de) 2021-06-16
SG11201601871QA (en) 2016-04-28
CN105531292A (zh) 2016-04-27
BR112016005288A2 (pt) 2022-03-29
BR112016005288B1 (pt) 2022-08-09
MX388402B (es) 2025-03-19
US9751968B2 (en) 2017-09-05

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