EP2965743B1 - Kosmetische wasser-in-öl-emulsionszusammensetzung - Google Patents

Kosmetische wasser-in-öl-emulsionszusammensetzung Download PDF

Info

Publication number
EP2965743B1
EP2965743B1 EP14759951.8A EP14759951A EP2965743B1 EP 2965743 B1 EP2965743 B1 EP 2965743B1 EP 14759951 A EP14759951 A EP 14759951A EP 2965743 B1 EP2965743 B1 EP 2965743B1
Authority
EP
European Patent Office
Prior art keywords
oil
water
mass
cosmetic composition
sample
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP14759951.8A
Other languages
English (en)
French (fr)
Other versions
EP2965743A1 (de
EP2965743A4 (de
Inventor
Masaki Kitajima
Tomoko Sato
Satoshi Yamaki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shiseido Co Ltd
Original Assignee
Shiseido Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Co Ltd filed Critical Shiseido Co Ltd
Publication of EP2965743A1 publication Critical patent/EP2965743A1/de
Publication of EP2965743A4 publication Critical patent/EP2965743A4/de
Application granted granted Critical
Publication of EP2965743B1 publication Critical patent/EP2965743B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/062—Oil-in-water emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin

Definitions

  • the present invention relates to a water-in-oil type emulsion cosmetic composition. More specifically, it relates to a water-in-oil type emulsion cosmetic composition having excellent stability and low viscosity, which does not need to be re-emulsified by shaking at the time of use.
  • water-in-oil type emulsion compositions having an oil phase as an external phase and a water phase as an internal phase are a type of formulation that is suitable for use as formulations for external application to the skin due to their ability to effectively spread oil-soluble active ingredients, such as emollient oils, oil-soluble medicinal agents and UV absorbing agents over the skin, and are widely used in the cosmetic field, such as in skin care creams, milky lotions, and hair care creams.
  • oil-soluble active ingredients such as emollient oils, oil-soluble medicinal agents and UV absorbing agents
  • water-in-oil type emulsion cosmetic compositions are often stabilized by gelling the oils constituting the external phase so as to immobilize water droplets and lower the collision frequency of the particles, thus requiring the viscosity to be raised. For this reason, it was considered to be difficult to achieve both low viscosity and stability in water-in-oil type emulsion cosmetic compositions, and it was difficult to simultaneously improve the stability over time and the spreadability and sensation of use at the time of application.
  • Patent Document 1 proposes the use of a mixed powder combining highly oil-absorbent powders which are powders of different particle sizes (in other words, a powder mixture of a spherical organopolysiloxane elastomer powder and a hydrophobic silica powder) at a specific weight ratio, an oil part comprising 30 wt% or more of a silicone oil, and an organically modified clay mineral as an auxiliary emulsifier.
  • highly oil-absorbent powders which are powders of different particle sizes (in other words, a powder mixture of a spherical organopolysiloxane elastomer powder and a hydrophobic silica powder) at a specific weight ratio, an oil part comprising 30 wt% or more of a silicone oil, and an organically modified clay mineral as an auxiliary emulsifier.
  • Patent Document 2 proposes the use of a specific hydrophobized silica as an emulsion stabilizer, and the use of a specific silicone surfactant as an emulsifier to improve the stability over time of the emulsion state, the feel and the texture.
  • EP2392312 discloses similar compositions with organically modified clay but together with silanized zinc-oxide.
  • the present invention was made in view of the drawbacks of the above-described conventional art, and has the purpose of offering a low-viscosity water-in-oil type emulsion cosmetic composition capable of maintaining excellent stability even when a polar oil is added.
  • a water-in-oil type emulsion cosmetic composition with low viscosity while having excellent stability sufficient to withstand the inclusion of a polar oil can be obtained by blending an organically modified clay mineral and a hydrophobic silica in specific amounts, and further blending an oil component containing a non-polar hydrocarbon oil in specific ratio, a silicone-type surfactant, and a water phase component in specific amounts, thereby achieving the present invention.
  • the gist of the present invention is a water-in-oil type emulsion cosmetic composition comprising:
  • the water-in-oil type cosmetic composition according to the present invention has low viscosity and therefore is not sticky, is capable of providing a spreadable and fresh sensation of use, while simultaneously having good stability and therefore not requiring re-emulsification by shaking at the time of use, so it excels in ease of handling as well. Additionally, since a large quantity of polar oils can be added without sacrificing stability, medicinal agents that do not easily dissolve in non-polar oils can be stably dissolved. For this reason, the choice of medicinal agents that can be added increases, and a cosmetic composition with high medicinal effects can be obtained.
  • the water-in-oil type emulsion cosmetic composition of the present invention is characterized by essentially comprising (A) an organically modified clay mineral, (B) a hydrophobic silica, (C) a silicone-type surfactant, (D) an oil component, and (E) a water phase component.
  • a clay mineral such as a naturally occurring or synthetic (in this case, one wherein the (OH) group in the formula is substituted with a fluorine) substance in the montmorillonite group such as montmorillonite, saponite or hectorite (commercially available products of which include Veegum, Kunipia, and Laponite) or a synthetic mica known by the name of sodium silicic mica or sodium or lithium taeniolite (commercially available products of which include Dimonite from Topy Industries, Ltd.), with a quaternary ammonium salt-type cationic surfactant.
  • a clay mineral such as a naturally occurring or synthetic (in this case, one wherein the (OH) group in the formula is substituted with a fluorine) substance in the montmorillonite group such as montmorillonite, saponite or hectorite (commercially available products of which include Veegum, Kunipia, and Laponite) or a synthetic mica known by the name
  • the quaternary ammonium salt-type cationic surfactant used here is represented by the following general formula (2): where R 1 represents a benzyl group or an alkyl group having 10 to 22 carbon atoms, R 2 represents an alkyl group having 10 to 22 carbon atoms or a methyl group, R 3 and R 4 represent a hydroxyalkyl group or an alkyl group having 1 to 3 carbon atoms, and X represents a halogen atom or a methylsulfate residue.
  • this quaternary ammonium salt-type cationic surfactant examples include dodecyltrimethylammonium chloride, myristyltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, aralkyltrimethylammonium chloride, behenyltrimethylammonium chloride, myristyldimethylethylammonium chloride, cetyldimethylethylammonium chloride, stearyldimethylethylammonium chloride, aralkyldimethylethylammonium chloride, behenyldimethylethylammonium chloride, myristyldiethylmethylammonium chloride, cetyldiethylmethylammonium chloride, stearyldiethylmethylammonium chloride, aralkyldiethylmethylammonium chloride, behenyldiethylmethylammonium chloride
  • organically modified clay minerals are dimethylalkylammonium hectorite, benzyldimethylstearylammonium hectorite and distearlydimethylammonium chloride-treated aluminum magnesium silicate and the like.
  • Bentone 27 benzyldimethylstearylammonium chloride-treated hectorite; product of the National Lead Company
  • Bentone 38 distearlydimethylammonium chloride-treated hectorite; product of the National Lead Company
  • the amount of the organically modified clay mineral to be blended should be 0.1 to 2 mass% with respect to the entire water-in-oil type emulsion cosmetic composition, more preferably 0.2 to 1.5 mass%, and even more preferably 0.4 to 1 mass%. If the amount of the (A) organically modified clay mineral is less than 0.1 mass%, then sufficient stability cannot be obtained, whereas if it is added in excess of 2 mass%, then the viscosity becomes high and there are problems in terms of texture such as the composition not being able to be taken up by the fingers or becoming heavy when trying to spread it over the skin.
  • the (B) hydrophobic silica used in the water-in-oil type emulsion cosmetic composition of the present invention is silica, i.e. silicic anhydride, wherein the silanol groups (hydroxyl groups) on the surface are subjected to a dimethyldichlorosilane treatment, an octylsilane treatment, a hexamethyldisilazane treatment, a dimethylsilicone oil treatment or a methacryloxysilane treatment.
  • those that are subjected to a dimethyldichlorosilane treatment, an octylsilane treatment, a hexamethyldisilazane treatment or a diemthylsilicone oil treatment are preferable for having excellent cosmetic composition stability improving effects.
  • portions of the (B) hydrophobic silica form three-dimensional structures with each other to form gel structures in the water-in-oil type emulsion cosmetic composition, which are believed to aid in stabilization. For this reason, those with a fine primary particle size of 5 to 20 nm which tend to form gel structures are preferred.
  • Examples of commercially available (B) hydrophobic silica products that satisfy the above conditions include the dimethyldichlorosilane-treated products AEROSIL R972, R972V, R972CF, R974, R976 and R976S (products of Nippon Aerosil), the octylsilane-treated product AEROSIL R805 (product of Nippon Aerosil), the hexamethyldisilazane-treated products AEROSIL R812, R812S and RX200 (products of Nippon Aerosil), and the dimethylsilicone oil-treated products AEROSIL R202 and RY200 (products of Nippon Aerosil). In the present invention, one or two or more of these can be added and used.
  • the blended amount of the (B) hydrophobic silica should be 0.1 to 2 mass% with respect to the entire water-in-oil type emulsion cosmetic composition, more preferably 0.5 to 1 mass%. If the amount of (B) hydrophobic silica is less than 0.1 mass% with respect to the cosmetic composition, then sufficient stability cannot be obtained, and if the amount exceeds 2 mass%, a tendency to adversely affect the texture is observed, such as the occurrence of squeakiness.
  • the total amount of the (A) organically modified clay mineral and (B) hydrophobic silica in the water-in-oil type emulsion cosmetic composition of the present invention should be 0.2 to 2 mass% with respect to the entire water-in-oil type emulsion cosmetic composition, more preferably 0.5 to 1.5 mass%. If the total amount of the (A) organically modified clay mineral and (B) hydrophobic silica is less than 0.2 mass%, then sufficient stability may not be obtained and separation may occur, and if they are added in excess of 2 mass%, the viscosity becomes high and there is a tendency toward a degraded sensation of use.
  • the (C) silicone type surfactant used in the present invention has an organopolysiloxane backbone, and has a polyoxyalkylene group and an alkyl group having two or more carbon atoms on a side chain.
  • a poly(oxyethylene/oxypropylene) methylpolysiloxane copolymer or an alkyl chain/silicone chain branched polyoxyethylene methylpolysiloxane copolymer or the like can be used.
  • Examples of commercially available products that can be favorably used include KF-6038 (product of Shin-Etsu Chemical Company) which is a lauryl PEG-9 polydimethylsiloxyethyl dimethicone, ABILEM 90 (product of Evonik Industries) which is a methylpolysiloxane/cetylmethylpolysiloxane/poly(oxyethylene/oxypropylene) methylpolysiloxane copolymer, and 5200 Formulation aid (product of Toray Dow Corning) which is a lauryl PEG/PPG-18/18 dimethicone. In the present invention, one or two or more of these can be added and used.
  • the blended amount of (C) silicone type surfactant should be 2 to 5 mass% with respect to the entire water-in-oil type emulsion cosmetic composition, more preferably 2.5 to 4.5 mass%, and even more preferably 3 to 4 mass%. If the blended amount is less than 2 mass%, then the viscosity becomes high and the sensation of use tends to become worse, while on the other hand, if the amount exceeds 5 mass%, there is a tendency for the stability to be lost, and separation may occur.
  • the (D) oil component used in the water-in-oil type emulsion cosmetic composition of the present invention contains a non-polar hydrocarbon oil in an amount of 10 to 50 mass% with respect to the total oil content. If the proportion of the non-polar hydrocarbon oil in the total oil content lies outside said range, then the stability can be reduced, and separation may occur.
  • non-polar hydrocarbon oil in the present invention, a hydrocarbon oil that is generally known as a non-polar oil or low-polarity oil can be used.
  • non-polar hydrocarbon oils include liquid paraffin, isohexadecane, isododecane, ozokerite, squalane, squalene, pristane, paraffin, isoparaffin, ceresin, vaseline, microcrystalline wax, and hydrogenated polyisobutene.
  • oil components other than the non-polar hydrocarbon oil contained in the (D) oil component any component chosen from among oils and fats, waxes, higher fatty acids, higher alcohols, ester oils and silicone oils can be added, and there are no particular restrictions as long as the effects of the present invention are not lost.
  • a polar oil may be added to the present invention.
  • the amount of polar oil blended should be 90 mass% or less with respect to the total oil content, preferably 70 mass% or les, and more preferably 50 mass% or less. If the amount of polar oil added exceeds 90 mass% with respect to the total oil content, the stability may be reduced. On the other hand, while there is no particular restriction on the lower limit of the amount of the polar oil added, when considering the sensation of use and the stability when dissolving a medicinal agent, it should preferably be at least 20 mass% with respect to the total oil content, and more preferably at least 30 mass%.
  • polar oils are oil components having an IOB value of 0.05 to 0.80, such as isostearic acid, isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyldecyl dimethyloctanoate, isononyl isononanoate, cetyl lactate, myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, cetyl ethylhexanoate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, N-alkylglycol monoisostearate, ne
  • the (E) water phase component used in the water-in-oil type emulsion cosmetic composition of the present invention may contain water (ion exchanged water, purified water, natural water etc.) or an aqueous solvent, as well as those components that can normally be used in cosmetic compositions, within a range not sacrificing the stability of the cosmetic composition.
  • a lower alcohol or polyhydric alcohol may be added.
  • lower alcohols examples include ethanol, methanol, propanol, isopropanol, butanol, isobutanol and t-butanol.
  • polyhydric alcohols examples include dihydric alcohols (e.g., ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3-butylene glycol, pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol and octylene glycol); trihydric alcohols (e.g., glycerin and trimethylol propane); tetrahydric alcohols (e.g., pentaerythritols such as 1,2,6-hexanetriol); pentahydric alcohols (e.g., xylitol); hexahydric alcohols (e.g., sorbitol and mannitol); polyhydric alcohol polymers (e.g., diethylene glycol, dipropylene glycol, triethylene glycol, polypropylene glycol, tetraethylene glycol
  • the blended amount of the (E) water phase component in the present invention in other words, the internal water phase amount of the water-in-oil type emulsion cosmetic composition, is 20 to 60 mass%, preferably 30 to 50 mass%, and more preferably 35 to 45 mass%. If the amount of the water phase component is less than 20 mass%, sufficient stability cannot be obtained and separation may occur. On the other hand, if it is added in excess of 60 mass%, the viscosity tends to become too high, and the sensation of use may become worse.
  • the water-in-oil type emulsion cosmetic composition of the present invention is in the form of a low-viscosity emulsion with a viscosity of 1000 to 10000 mPa ⁇ s (30 °C, B-type viscometer). If the viscosity is less than 1000 mPa ⁇ s, then it tends to become more difficult to obtain sufficient stability, and on the other hand, if the viscosity exceeds 10000 mPa ⁇ s, the viscosity becomes too high, and the composition becomes heavy to spread at the time of application, so a good sensation of use cannot be obtained.
  • the water-in-oil type emulsion cosmetic composition of the present invention may include, as needed, other optional additive ingredients that are normally used in cosmetics, within a range not detracting from the effects of the present invention, e.g., surfactants, metal ion sequestering agents, powder components, sugars, amino acids, organic amines, pH adjusters, UV absorbing agents, skin nutrients, vitamins, antioxidants and fragrances.
  • other optional additive ingredients that are normally used in cosmetics, within a range not detracting from the effects of the present invention, e.g., surfactants, metal ion sequestering agents, powder components, sugars, amino acids, organic amines, pH adjusters, UV absorbing agents, skin nutrients, vitamins, antioxidants and fragrances.
  • the water-in-oil type emulsion cosmetic composition of the present invention can contain large quantities of polar oils, so even UV absorbing agents that do not easily dissolve in non-polar oils can be stably added.
  • the UV absorbing agents that can be added include, for example, cinnamic acid derivatives such as ethylhexyl methoxycinnamate (octylmethoxycinnamate), isopropyl methoxycinnamate and isoamyl methoxycinnamate; para-aminobenzoic acid (hereinafter abbreviated to "PABA") derivatives such as PABA, ethyl PABA, ethyl-dihydroxypropyl PABA, ethylhexyl-dimethyl PABA and glyceryl PABA; salicylic acid derivatives such as homosalate, ethylhexyl salicylate, dipropylene glycol salicylate, and TEA salicylate; be
  • UV absorbing agents water soluble UV absorbing agents having sulfonic acid groups such as phenylbenzimidazole-5-sulfonic acid and salts thereof, and phenylene-bis-benzimidazole-tetrasulfonic acid and salts thereof are also preferable.
  • Basic compounds (neutralizing base) to be used for obtaining the salts include sodium hydroxide, potassium hydroxide, triethanolamine, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1,3-propanediol and sodium N-methyltaurine.
  • the water-in-oil type emulsion cosmetic composition of the present invention can be prepared by a conventional method, and the method of emulsification is not particularly limited. For example, there is a method of respectively heating the water phase and the oil phase to about 70 °C, gradually adding the heated water phase to the oil phase, emulsifying in an emulsifier, and then, cooling to room temperature, but the method is not limited thereto.
  • the water-in-oil type emulsion cosmetic composition according to the present invention can be applied to a wide range of cosmetics, examples of which include products such as sun care cosmetic compositions (sunscreens, sun oils, after-sun lotions, etc.), whitening beauty lotions, milky lotions, creams, makeup base, and emulsified foundations.
  • sun care cosmetic compositions sun care cosmetic compositions (sunscreens, sun oils, after-sun lotions, etc.), whitening beauty lotions, milky lotions, creams, makeup base, and emulsified foundations.
  • a sample that was stored at 30 °C for 1 hour after production was measured using a B-type viscometer (BL-type, Rotor No. 3, 12 rpm). The measurement was not made when separation occurred.
  • (5) to (10) were mixed and homogeneously dispersed (oil phase).
  • (1) to (4) were homogeneously mixed (water phase). The water phase was gradually added to the oil phase, homogeneously dispersed with a homodisper, then the emulsion particles were adjusted to produce a low-viscosity water-in-oil type emulsion.
  • (5) to (13) were mixed and homogeneously dispersed (oil phase).
  • (1) to (4) were homogeneously mixed (water phase). The water phase was gradually added to the oil phase, homogeneously dispersed with a homodisper, then the emulsion particles were adjusted to produce a low-viscosity water-in-oil type emulsion.
  • (5) to (13) were mixed and homogeneously dispersed (oil phase).
  • (1) to (4) were homogeneously mixed (water phase). The water phase was gradually added to the oil phase, homogeneously dispersed with a homodisper, then the emulsion particles were adjusted to produce a low-viscosity water-in-oil type emulsion.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Claims (3)

  1. Kosmetische Emulsionszusammensetzung vom Wasser-in-Öl-Typ, umfassend:
    (A) 0,1 bis 2 Masse% eines organisch modifizierten Tonminerals;
    (B) 0,1 bis 2 Masse% eines hydrophoben Silica;
    (C) 2 bis 5 Masse% eines Tensids vom Silicon-Typ;
    (D) ein Ölkomponente, von der 10 bis 50 Masse% der gesamten Ölkomponente ein nichtpolares Kohlenwasserstoff-Öl ist; und
    (E) 20 bis 60 Masse% einer Wasserphasenkomponente;
    wobei das (A) organisch modifizierte Tonmineral und (B) hydrophobes Silica insgesamt 0,2 bis 2 Masse% ausmachen; und
    eine Viskosität der kosmetischen Zusammensetzung insgesamt 1.000 bis 10.000 mPa·s beträgt (30°C; B-Typ-Viskosimeter).
  2. Kosmetische Emulsionszusammensetzung vom Wasser-in-Öl-Typ nach Anspruch 1, wobei die (D) Ölkomponente ein polares Öl umfasst.
  3. Kosmetische Emulsionszusammensetzung vom Wasser-in-Öl-Typ nach Anspruch 2, wobei die (D) Ölkomponente das polare Öl in einem Bereich von 20 bis 90 Masse% enthält, mit Bezug auf die gesamte Ölkomponente.
EP14759951.8A 2013-03-08 2014-03-06 Kosmetische wasser-in-öl-emulsionszusammensetzung Active EP2965743B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2013046273A JP5834037B2 (ja) 2013-03-08 2013-03-08 油中水型乳化化粧料
PCT/JP2014/055801 WO2014136886A1 (ja) 2013-03-08 2014-03-06 油中水型乳化化粧料

Publications (3)

Publication Number Publication Date
EP2965743A1 EP2965743A1 (de) 2016-01-13
EP2965743A4 EP2965743A4 (de) 2016-12-07
EP2965743B1 true EP2965743B1 (de) 2018-07-25

Family

ID=51491394

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14759951.8A Active EP2965743B1 (de) 2013-03-08 2014-03-06 Kosmetische wasser-in-öl-emulsionszusammensetzung

Country Status (9)

Country Link
US (1) US10434041B2 (de)
EP (1) EP2965743B1 (de)
JP (1) JP5834037B2 (de)
KR (1) KR20150124949A (de)
CN (1) CN105025866B (de)
ES (1) ES2686673T3 (de)
HK (1) HK1212630A1 (de)
TW (1) TWI593427B (de)
WO (1) WO2014136886A1 (de)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7046472B2 (ja) * 2015-03-27 2022-04-04 ロレアル 油中水型エマルション組成物
JP6263244B2 (ja) * 2015-10-09 2018-01-17 株式会社 資生堂 噴霧型日焼け止め化粧料
JP6588345B2 (ja) 2016-01-18 2019-10-09 株式会社 資生堂 油中水型乳化化粧料
US11931435B2 (en) 2016-04-28 2024-03-19 Shiseido Company, Ltd. Water-in-oil type emulsified cosmetic
JP6853037B2 (ja) 2016-12-28 2021-03-31 株式会社 資生堂 油中水型乳化化粧料
KR102269866B1 (ko) * 2020-10-30 2021-06-28 한국콜마주식회사 수분감이 극대화된 유중수형 화장료 조성물

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4164564A (en) 1976-12-23 1979-08-14 E. R. Squibb & Sons, Inc. Ointment and cream bases capable of withstanding elevated temperatures
JP3403223B2 (ja) 1993-08-24 2003-05-06 花王株式会社 油中水型乳化組成物
GB9426313D0 (en) * 1994-12-29 1995-03-01 Dow Corning Sa Water in oil emulsifiers and emulsions made with them
JP3474720B2 (ja) * 1996-10-23 2003-12-08 株式会社資生堂 油中水型乳化化粧料
FR2776183B1 (fr) * 1998-03-17 2004-05-28 Oreal Utilisation d'un tensio-actif silicone du type alkyldimethicone copolyol pour la preparation d'emulsions cosmetiques solides eau-dans-huile et emulsions solides eau-dans-huile ainsi obtenues
EP1200039B1 (de) * 1999-07-20 2006-06-07 Beiersdorf AG Emulgatorfreie feindisperse systeme vom typ wasser-in-öl
JP3930434B2 (ja) * 2003-01-21 2007-06-13 日本メナード化粧品株式会社 油中水型乳化化粧料
US20050271611A1 (en) * 2004-06-08 2005-12-08 Shiseido Co., Ltd. Cosmetic
JP5040008B2 (ja) 2005-06-20 2012-10-03 エス．ヴェー．アー．ツェー． シュミット−ウォルター オートメーション コンサルト ゲーエムベーハー 圧力センサ
JP5240967B2 (ja) * 2006-02-20 2013-07-17 株式会社 資生堂 油中水型乳化日焼け止め化粧料
JP2009137909A (ja) * 2007-12-10 2009-06-25 Shiseido Co Ltd 収斂化粧料
JP4881961B2 (ja) * 2009-01-08 2012-02-22 株式会社トキワ 油中水型日焼け止め化粧料
JP4902752B2 (ja) * 2009-01-27 2012-03-21 株式会社 資生堂 油中水型乳化日焼け止め化粧料
JP5041551B2 (ja) 2009-09-25 2012-10-03 株式会社 資生堂 油中水型乳化皮膚化粧料
US9580600B2 (en) * 2009-10-23 2017-02-28 Dow Conring Toray Co., Ltd. Thickening or gelling agent for oily raw materials
CN102762193A (zh) * 2010-02-12 2012-10-31 株式会社资生堂 W/o型乳化化妆品
JP2012067049A (ja) * 2010-09-27 2012-04-05 Shiseido Co Ltd 油中水型乳化組成物
JP5007369B2 (ja) * 2010-10-12 2012-08-22 株式会社 資生堂 油中水型乳化化粧料
JP2012116757A (ja) * 2010-11-29 2012-06-21 Shiseido Co Ltd 低粘度ｗ／ｏ乳化組成物
WO2013065664A1 (ja) * 2011-10-31 2013-05-10 花王株式会社 化粧料
FR2992215B1 (fr) * 2012-06-21 2014-10-31 Oreal Composition cosmetique anhydre comprenant une huile, des particules d'aerogel de silice hydrophobe, un actif hydrophile et au moins un agent tensioactif

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Also Published As

Publication number Publication date
TWI593427B (zh) 2017-08-01
CN105025866B (zh) 2017-04-19
WO2014136886A1 (ja) 2014-09-12
US10434041B2 (en) 2019-10-08
TW201517925A (zh) 2015-05-16
HK1212630A1 (zh) 2016-06-17
EP2965743A1 (de) 2016-01-13
KR20150124949A (ko) 2015-11-06
CN105025866A (zh) 2015-11-04
JP2014172853A (ja) 2014-09-22
ES2686673T3 (es) 2018-10-19
US20160058677A1 (en) 2016-03-03
JP5834037B2 (ja) 2015-12-16
EP2965743A4 (de) 2016-12-07

Similar Documents

Publication Publication Date Title
EP2965743B1 (de) Kosmetische wasser-in-öl-emulsionszusammensetzung
EP2559426B1 (de) Wasser-in-öl-emulsionsverbindung
EP2529727B1 (de) Emulgierte kosmetische wasser-in-öl-zusammensetzung als sonnenschutz
EP3087970B1 (de) Emulgiertes wasser-in-öl-kosmetikum als sonnenschutz
CN108289812B (zh) 防晒化妆品
JP6878462B2 (ja) 水中油型乳化化粧料
EP3636245A1 (de) Herstellung eines wasser-in-öl-emulsionskosmetikums
EP2609902B1 (de) Herstellung eines wasser-in-öl-emulsionskosmetikums
JPWO2020032243A1 (ja) 乳化化粧料
JP7347993B2 (ja) 日焼け止め用組成物
JP2024099778A (ja) 乳化化粧料
JP6741836B2 (ja) 水中油型乳化化粧料
EP3636246A1 (de) Kosmetikpräparat mit wasser-in-öl-emulsion
US20210386652A1 (en) Oil-in-water emulsion cosmetic
JP2021123590A (ja) 油中水型乳化化粧料
JPWO2020032246A1 (ja) 日やけ止め効果増強剤
JP7381457B2 (ja) 温感化粧料
JP7427592B2 (ja) 化粧料
CN114617784A (zh) 水包油型乳化化妆料
JP2020164524A (ja) 油中水型乳化化粧料

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20150901

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

DAX Request for extension of the european patent (deleted)
A4 Supplementary search report drawn up and despatched

Effective date: 20161107

RIC1 Information provided on ipc code assigned before grant

Ipc: A61K 8/31 20060101ALI20161031BHEP

Ipc: A61K 8/37 20060101ALI20161031BHEP

Ipc: A61K 8/06 20060101AFI20161031BHEP

Ipc: A61Q 1/02 20060101ALI20161031BHEP

Ipc: A61K 8/894 20060101ALI20161031BHEP

Ipc: A61Q 19/00 20060101ALI20161031BHEP

Ipc: A61K 8/25 20060101ALI20161031BHEP

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20180130

GRAJ Information related to disapproval of communication of intention to grant by the applicant or resumption of examination proceedings by the epo deleted

Free format text: ORIGINAL CODE: EPIDOSDIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

GRAR Information related to intention to grant a patent recorded

Free format text: ORIGINAL CODE: EPIDOSNIGR71

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

INTC Intention to grant announced (deleted)
INTG Intention to grant announced

Effective date: 20180614

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 1020978

Country of ref document: AT

Kind code of ref document: T

Effective date: 20180815

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602014029177

Country of ref document: DE

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2686673

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20181019

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20180725

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 1020978

Country of ref document: AT

Kind code of ref document: T

Effective date: 20180725

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181025

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181026

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181125

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181025

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602014029177

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FI

Payment date: 20190321

Year of fee payment: 6

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20190426

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20190424

Year of fee payment: 6

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20190306

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190306

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20190331

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190331

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190331

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190306

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190306

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190331

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20200330

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190306

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20181125

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20210728

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20140306

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602014029177

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200306

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200307

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20211001

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180725

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230517

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20240220

Year of fee payment: 11