EP2891771B1 - Procédé d'enrichissement de lignite brut - Google Patents

Procédé d'enrichissement de lignite brut Download PDF

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Publication number
EP2891771B1
EP2891771B1 EP14185476.0A EP14185476A EP2891771B1 EP 2891771 B1 EP2891771 B1 EP 2891771B1 EP 14185476 A EP14185476 A EP 14185476A EP 2891771 B1 EP2891771 B1 EP 2891771B1
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EP
European Patent Office
Prior art keywords
steam
drying
lignite
raw lignite
comminution
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EP14185476.0A
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German (de)
English (en)
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EP2891771A1 (fr
Inventor
Hans Michael Hübner
Ralf Ackermann
Stephan Schwinn
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RWE Power AG
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RWE Power AG
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Publication of EP2891771A1 publication Critical patent/EP2891771A1/fr
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C19/00Other disintegrating devices or methods
    • B02C19/06Jet mills
    • B02C19/068Jet mills of the fluidised-bed type
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/02Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
    • C10L5/04Raw material of mineral origin to be used; Pretreatment thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K17/00Using steam or condensate extracted or exhausted from steam engine plant
    • F01K17/06Returning energy of steam, in exchanged form, to process, e.g. use of exhaust steam for drying solid fuel or plant
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23KFEEDING FUEL TO COMBUSTION APPARATUS
    • F23K1/00Preparation of lump or pulverulent fuel in readiness for delivery to combustion apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23KFEEDING FUEL TO COMBUSTION APPARATUS
    • F23K1/00Preparation of lump or pulverulent fuel in readiness for delivery to combustion apparatus
    • F23K1/04Heating fuel prior to delivery to combustion apparatus
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/08Drying or removing water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/14Injection, e.g. in a reactor or a fuel stream during fuel production
    • C10L2290/148Injection, e.g. in a reactor or a fuel stream during fuel production of steam
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/28Cutting, disintegrating, shredding or grinding
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23KFEEDING FUEL TO COMBUSTION APPARATUS
    • F23K2201/00Pretreatment of solid fuel
    • F23K2201/10Pulverizing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23KFEEDING FUEL TO COMBUSTION APPARATUS
    • F23K2201/00Pretreatment of solid fuel
    • F23K2201/10Pulverizing
    • F23K2201/103Pulverizing with hot gas supply
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23KFEEDING FUEL TO COMBUSTION APPARATUS
    • F23K2201/00Pretreatment of solid fuel
    • F23K2201/20Drying

Definitions

  • the invention relates to a method for refining raw lignite comprising pre-comminuting the humidified raw lignite as well as grinding and drying directly downstream of the pre-comminution to dry lignite, steam being removed from a coupled power plant process with at least one steam generator and being used at least partially to dry the mine-moist raw lignite.
  • Refining lignite in the sense of the present invention means at least drying and grinding the lignite for the purpose of producing a marketable product that can be used outside the power plant process.
  • Refinement can include at least the production of a dried, powdery or granular end product, which is subjected to thermal recycling in a power plant or a further refinement for the enrichment of carbon in the end product.
  • a further refinement step for example, the production of hearth furnace coke, liquefaction, gasification or the production of fuel pellets can be provided.
  • Mine-moist raw lignite in the sense of the present invention is to be understood as the mined and not prepared raw lignite, which can have a moisture content between 40% by weight and 60% by weight, depending on the conditions of the deposit or storage time before refining.
  • the raw lignite When lignite is converted into electricity, the raw lignite is usually fed to a beater mill which has been rendered inert with flue gas. The raw lignite is crushed in the mill. The flue gas is used to dry the moist coal and transports the lignite dust generated as a carrier gas through a classifier to the boiler's burner.
  • the refining of lignite requires a possibly multi-stage grinding and separate drying of the raw lignite in a separate drying unit.
  • Tube dryers, fluidized bed dryers or roller bowl mills are used as drying units.
  • multi-stage pre-comminution and / or grinding of the raw lignite is usually provided.
  • fluidized bed dryers can only be operated with a relatively narrow feed belt, since otherwise the fluidized bed would collapse.
  • the operation of tube dryers is energy-intensive. These are usually operated with steam from a coupled power plant process.
  • the specific steam volume required to operate a tube dryer is approximately 1.35 kg steam per kilogram of raw coal.
  • the pit-moist raw lignite can be dried and ground in roller bowl mills inertized with flue gas, although the investment costs for roller bowl mills are considerable.
  • the invention is therefore based on the object of a method for refining raw lignite comprising the comminution and drying of the raw lignite to provide dry lignite, which requires energy-efficient drying with relatively little equipment.
  • a method according to the invention comprises pre-comminution of the mine-moist raw lignite as well as drying to dry lignite, which is preferably immediately downstream of the pre-comminution, steam being extracted from a coupled power plant process with at least one steam generator and this steam being used at least partially for drying the mine-moist raw lignite, the method being used comprises grinding and drying in a single process step, preferably fine grinding and drying in a single process step, the raw lignite still pre-crushed from the mine being crushed as ground material by means of at least one steam jet from the steam generation, which is introduced into a ground material bed fluidized with steam, is crushed and broken .
  • the raw lignite itself is used as grinding media within a correspondingly configured unit.
  • the steam jet entering the regrind bed comprising the pre-broken or pre-comminuted raw lignite as regrind, interacts with the fluid bed surrounding it in such a way that an exchange of impulses takes place between the steam jet and the regrind, which leads to comminution of the regrind and at the same time to drying it in the Steam atmosphere leads.
  • the steam jet, together with part of the regrind is accelerated into the fluidized regrind bed and this is done in such a way that particle collisions within the regrind bed occur.
  • the individual lignite particles are exposed to an impact, which leads to comminution without the use of grinding media or impact internals within the unit concerned.
  • several Steam jets introduced into the regrind bed in opposite directions, for example in such a way that steam jets meet.
  • the comminution and drying can be carried out in at least one, preferably in a plurality of hydraulic jet mills connected in parallel, preferably in fluid bed counter-jet mills.
  • a fluidized bed counter-jet mill at least two or more steam jets, each loaded with regrind, are directed towards one another in order to achieve particle collisions to the greatest extent possible.
  • Such comminution is particularly advantageous if the upgrading process is coupled to a power plant process, in which case appropriately conditioned steam from the power plant process or steam generation process is available.
  • a part of the dry brown coal is thermally utilized in the power plant process, the rest of the power plant process preferably being operated with raw brown coal as fuel.
  • the steam can be introduced into the regrind bed, for example, at a temperature of between 180 ° C. and 330 ° C., preferably with a temperature between 200 ° C. and 300 ° C. and a steam pressure between 4 bar and 6 bar, preferably with a steam pressure of 5 bar will.
  • both water and volatile constituents of the raw brown coal are expelled as fuel gas from the raw brown coal during the drying, the fuel gas being stored and / or separately thermally utilized.
  • volatile constituents or volatile gaseous constituents in the sense of the present invention are to be understood exclusively as hydrocarbons, but not the roughly capillary bound water of the raw lignite.
  • a further process variant according to the invention provides that the grinding and drying take place in two stages, the grinding and drying taking place in one stage by means of at least one steam jet at a first low temperature and in a second stage using at least one steam jet at a second higher temperature,
  • the low temperature may be on the order of 200 ° C
  • the higher temperature may be on the order of 300 ° C.
  • the ground material When a steam jet is introduced at a temperature of approximately 200 ° C. and a pressure of approximately 5 bar, the ground material is only finely comminuted and dried, the dried ground material then preferably having a residual water content of approximately 2% by weight to 4% by weight. can have. In this case, the product obtained still contains significant amounts of volatile gaseous components.
  • steam can be supplied at a temperature of approximately 300 ° C., which results in the volatile gaseous components being expelled from the raw lignite.
  • volatile constituents can, for example, be stored separately and / or sent for thermal recycling.
  • the steam generator is supplied with a portion of the dry lignite from which the volatile constituents have already been driven off.
  • the volatile constituents can be compressed as fuel gas and fed to a natural gas network or a natural gas storage facility.
  • steam with a relatively high energy content is required, which is no longer available to generate electricity at the turbine power plant.
  • the partial stream of dry lignite not supplied for thermal utilization can be coked, for example, in a further upgrading step to hearth furnace coke if and to the extent that this dry lignite still contains gaseous volatile constituents. If the volatile components are completely expelled in the second stage of fine grinding, the finished, dried product is already in the form of a high-quality coke.
  • Tapped steam from a turbine of the coupled power plant process is preferably provided as steam.
  • the steam can be drawn off between the low-pressure part and the medium-pressure part of a three-stage turbine.
  • FIG. 1 A lignite refinement coupled with a power plant process is shown, the refinement comprising a pre-comminution 1 and a fine comminution with drying 2.
  • the pre-shredding 1 for raw lignite from the mine can only lead to a pre-crushing of mined mine moisture Include raw lignite using conventional crushers / pre-shredders.
  • the raw lignite may have been pre-crushed to a grain size of ⁇ 0 mm and ⁇ 10 mm.
  • the pre-crushed raw lignite can have a moisture content of 54% by weight, for example.
  • the moisture content is only given here as an example, naturally the moisture content of the raw lignite can fluctuate depending on the storage conditions and deposit conditions.
  • an arrangement of parallel fluidized bed jet mills in which the feed grain from 0 mm to 10 mm to a target grain of ⁇ 1 mm with simultaneous drying to a moisture content of about 2% by weight to 3% by weight. is obtained.
  • a hydraulic jet mill suitable for carrying out the method can comprise, for example, a regrind in which several jet tubes are immersed.
  • the jet pipes both introduce steam and, if appropriate, introduce regrind that has previously been withdrawn from the regrind bed or a regrind inlet.
  • a regrind can be discharged, for example, via a classifier arranged inside the regrind room.
  • a partial stream A of the ground material stream discharged from the fine comminution and drying 2 in the form of dry brown coal is fed to a steam generator 3, which is designed, for example, as a boiler which is essentially fired with raw brown coal. It can be provided, for example, that the steam generator 3 is fired at 75% with raw lignite and 25% with dry lignite.
  • the superheated steam generated in the steam generator 3 drives a turbine 4, which in turn drives a generator 5, which feeds into a power grid 6.
  • Another partial stream B of dry lignite is fed to a second upgrading stage 7, the goal of which is the production of a high-quality, marketable fuel. Coking, gasification or liquefaction of the lignite can, for example, be provided as the second upgrading stage 7.
  • a partial stream of steam C is withdrawn from the turbine 4.
  • this partial stream steam C is introduced as a steam jet into the drying units provided there.
  • this partial stream steam C is used for fluidizing the regrind bed provided within the drying units.
  • the steam is drawn off between the low-pressure part and the medium-pressure part of the turbine 4 at a pressure of about 5 bar at a temperature of about 200 ° C., about 0.95 kg of steam being required per kilogram of raw brown coal used as regrind.
  • ORC process Organic Rankine Cycle
  • the variant of the method according to the invention shown differs essentially from that in FIG Figure 1 variant shown that the fine comminution and drying 2 is operated in one or more stages, but with a partial stream steam C, which has a higher energy content or a higher temperature, namely about 300 ° C at a pressure of about 5 bar.
  • a partial stream steam C which has a higher energy content or a higher temperature, namely about 300 ° C at a pressure of about 5 bar.
  • a coke-like product with an increased carbon content is obtained as the finished product from the fine comminution and drying 2, of which a partial stream A in the steam generator 3 can be thermally utilized, whereas another partial stream B is obtained as a finished product.
  • the vapors D from the fine grinding and drying 2 can as in the previously described method variant, are condensed in the vapor condenser 8 for the purpose of utilizing waste heat.
  • the fine comminution and drying 2 can comprise two grinding and drying stages, it being possible in a first stage to provide fine comminution and drying or grinding and drying with steam of lower energy content. This can take place, for example, during peak periods of the power grid, since in this case the maximum amount of steam must be available at the turbine 4.
  • a second grinding and drying stage can be provided, which is operated with steam having a higher energy content, steam then being able to be drawn off from the turbine 4 at a temperature of approximately 300 ° C. Only in this load case would methane E be driven out of the raw lignite and be used separately as fuel gas.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Food Science & Technology (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Drying Of Solid Materials (AREA)

Claims (9)

  1. Procédé permettant le raffinage de lignite brut humide de la mine, comprenant un prébroyage (1) du lignite brut humide de la mine ainsi qu'un broyage et un séchage en lignite sec immédiatement après le prébroyage (1), la vapeur étant éliminée d'un processus de centrale électrique couplée à l'aide d'au moins un générateur de vapeur (3), et étant utilisée au moins partiellement pour sécher le lignite brut humide de la mine, le broyage et le séchage étant réalisés en une seule étape de procédé, le lignite brut préconcassé encore humide de la mine étant introduit dans un lit fluidisé de matière à broyer sous forme de matière à broyer, et étant finement broyé et séché dans le lit de matière à broyer au moyen d'au moins un jet de vapeur, le lignite brut étant finement broyé dans le lit de matière à broyer au moyen de plusieurs jets de vapeur dirigés en sens contraire, caractérisé en ce qu'au moins des parties du lignite brut sont introduites dans la matière à broyer à l'aide des jets de vapeur.
  2. Procédé selon la revendication 1, caractérisé en ce que le broyage fin et le séchage sont réalisés dans au moins un, de préférence dans plusieurs broyeurs à jets hydrauliques connectés en parallèle, de préférence dans des broyeurs à jets opposés à lit fluidisé.
  3. Procédé selon l'une des revendications 1 ou 2, caractérisé en ce que l'au moins un jet de vapeur est introduit dans le lit de matière à broyer à une température comprise entre 180 °C et 330 °C et à une pression de vapeur comprise entre 4 bar et 6 bar.
  4. Procédé selon l'une des revendications 1 à 3, caractérisé en ce que, pendant le séchage, de l'eau et des composants gazeux volatils tels que du méthane sont expulsés du lignite brut sous forme de gaz combustible, le gaz combustible étant stocké et/ou utilisé thermiquement séparément.
  5. Procédé selon l'une des revendications 1 à 4, caractérisé en ce qu'une partie du lignite sec est utilisée thermiquement dans le processus de la centrale électrique, laquelle est par ailleurs de préférence exploitée avec du lignite brut comme combustible.
  6. Procédé selon l'une des revendications 4 ou 5, caractérisé en ce que le broyage fin et le séchage sont effectués en deux étapes, le broyage fin et le séchage (2) étant effectués, dans une première étape, au moyen d'au moins un jet de vapeur à une première température plus basse, et étant effectués, dans une seconde étape, au moyen d'au moins un jet de vapeur à une seconde température plus élevée.
  7. Procédé selon la revendication 6, caractérisé en ce que la seconde étape de broyage fin et de séchage (2) est effectuée en fonction de la charge du générateur de vapeur (3).
  8. Procédé selon l'une des revendications 1 à 7, caractérisé en ce que la chaleur résiduelle issue du broyage fin et du séchage (2) du lignite brut est utilisée pour la génération de vapeur.
  9. Procédé selon l'une des revendications 1 à 8, caractérisé en ce que la vapeur de soutirage issue d'une turbine (4) du processus de la centrale électrique couplée est fournie sous forme de vapeur.
EP14185476.0A 2013-09-20 2014-09-19 Procédé d'enrichissement de lignite brut Active EP2891771B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE201310015579 DE102013015579A1 (de) 2013-09-20 2013-09-20 Verfahren zur Veredelung von Rohbraunkohle

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EP2891771A1 EP2891771A1 (fr) 2015-07-08
EP2891771B1 true EP2891771B1 (fr) 2020-05-20

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CN116218579B (zh) * 2023-04-24 2023-07-18 羚羊环保科技有限公司 一种高硫高水分褐煤脱硫脱水生产装置

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Publication number Priority date Publication date Assignee Title
DD283676A5 (de) * 1988-03-03 1990-10-17 Gagarin Hoeeroemue Vallalat,Hu Verfahren zur vorbereitung von braunkohle zwecks weiterer verarbeitung
DE19728382C2 (de) * 1997-07-03 2003-03-13 Hosokawa Alpine Ag & Co Verfahren und Vorrichtung zur Fließbett-Strahlmahlung
DE19824062A1 (de) * 1998-05-29 1999-12-02 Roland Nied Mahlverfahren unter Verwendung einer Strahlmühle
DE10050520A1 (de) * 2000-10-12 2002-04-18 Karl Strauss Verfahren und Vorrichtung zum Betrieb einer Gasturbine
DE102007023336A1 (de) * 2007-05-16 2008-11-20 Rwe Power Ag Verfahren zum Betreiben eines Dampfturbinenkraftwerks sowie Vorrichtung zum Erzeugen von Dampf
WO2012133549A1 (fr) * 2011-03-31 2012-10-04 三菱重工業株式会社 Unité d'alimentation en matériau humide et système de production d'énergie composite par gazéification utilisant ledit matériau humide

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EP2891771A1 (fr) 2015-07-08
DE102013015579A1 (de) 2015-03-26

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