EP2879969B1 - Emballage contenant des sachets en film soluble dans l'eau remplis de produit de lavage ou de nettoyage liquide - Google Patents

Emballage contenant des sachets en film soluble dans l'eau remplis de produit de lavage ou de nettoyage liquide Download PDF

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Publication number
EP2879969B1
EP2879969B1 EP13705171.0A EP13705171A EP2879969B1 EP 2879969 B1 EP2879969 B1 EP 2879969B1 EP 13705171 A EP13705171 A EP 13705171A EP 2879969 B1 EP2879969 B1 EP 2879969B1
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EP
European Patent Office
Prior art keywords
water
packaging
bag
soluble film
soluble
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP13705171.0A
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German (de)
English (en)
Other versions
EP2879969A1 (fr
Inventor
Matthias Sunder
Frank Meier
Helmut SANDMÜLLER
Frank Pessel
Andreas Bauer
Carsten Bertram
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
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Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP2879969A1 publication Critical patent/EP2879969A1/fr
Application granted granted Critical
Publication of EP2879969B1 publication Critical patent/EP2879969B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/043—Liquid or thixotropic (gel) compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes

Definitions

  • the present invention relates to a package containing water-soluble foil bags filled with liquid washing or cleaning agent, according to the preamble of claim 1.
  • portioned dosage forms such as tablets or foil pouches.
  • portioned dosage forms such as tablets or foil pouches.
  • EP 879 874 Pre-portioned bags filled with detergent.
  • Foil bags filled with detergents and cleaning agents are frequently formed by means of water-soluble films, which has the advantage for the consumer of having to dispense a corresponding bag without opening it, for example, in a washing machine.
  • this dosage form there is regularly the problem that the fragrances of the preparations stored in the foil bags do not pass through the water-soluble foils, so that the consumer can not directly determine the later fragrance impression of the washed laundry on such a foil pouch.
  • revealed EP 1256 623 A1 a foil bag which is filled with detergent and also comprises fragrances.
  • the object of the invention is therefore to provide a package for water-soluble film bag, which avoids or reduces the aforementioned disadvantages.
  • This object is achieved in accordance with the invention by providing a package containing water-soluble film bags filled with liquid detergent or cleaning agent, wherein the water-soluble film bags are formed wholly or partially from PVA, the washing or cleaning agent contains a source of at least one amine compound, within the Packing at least one fragrance emission source is arranged, which releases fragrances having a boiling point of> 70 ° C, in the package at least one ventilation opening is provided, the amount of a Ventilationsö Stamms vom-boiling point ratio based on amine compounds between 0.8-50 mm 2 / ° C. , preferably between 1-20 mm 2 / ° C, particularly preferably between 1.1-10 mm 2 / ° C.
  • the water-soluble film bag comprises at least one source of dimethylamine.
  • at least one ventilation opening is provided in the package, which in terms of magnitude has a ventilation opening area boiling point ratio based on dimethylamine of 1.1-10 mm 2 / ° C.
  • the packaging is a plastic bag.
  • the ventilation opening or ventilation openings in the packaging are / are arranged above the filling level (H) of the film bags.
  • the fragrance emission source be located at the bottom of the package.
  • a water-soluble film bag comprises a water-soluble envelope.
  • the water-soluble coating is preferably formed by a water-soluble film material.
  • the foil bag can be formed dimensionally stable or deformable.
  • the water-soluble film bag is formed according to a first preferred embodiment as a dimensionally stable container, for example in the form of a capsule or a container.
  • the water-soluble film bag as a non-dimensionally stable container, for example as a bag.
  • the shape of such a foil bag can be largely adapted to the conditions of use.
  • plastic foils or sheets worked and / or processed in various forms (such as hoses, cushions, cylinders, bottles, disks or the like) and other conceivable forms come into question.
  • Particularly preferred according to the invention are films which can be glued and / or sealed to hoses, cushions or the like, for example, after they have been filled with detergent or cleaning agent preparation.
  • the water soluble package may include one or more chambers for storing one or more agents.
  • the water-soluble packaging preferably has between 2 and 5 chambers.
  • the water-soluble envelope of the film bag contains polyvinyl alcohol or a polyvinyl alcohol copolymer.
  • Water-soluble coatings containing polyvinyl alcohol or a polyvinyl alcohol copolymer have a good stability with a sufficiently high water solubility, in particular cold water solubility on.
  • the water-soluble coating is preferably formed from a water-soluble film material selected from the group consisting of polymers or polymer blends.
  • the wrapper may be formed of one or two or more layers of the water-soluble film material.
  • the water-soluble film material of the first layer and the further layers, if present, may be the same or different.
  • the water-soluble coating contains polyvinyl alcohol or a polyvinyl alcohol copolymer.
  • Suitable water-soluble films for producing the water-soluble coating are preferably based on a polyvinyl alcohol or a polyvinyl alcohol copolymer whose molecular weight is in the range of 10,000 to 1,000,000 gmol-1, preferably 20,000 to 500,000 gmol-1, more preferably 30,000 to 100,000 gmol-1 and especially from 40,000 to 80,000 gmol-1.
  • polyvinyl alcohol is usually carried out by hydrolysis of polyvinyl acetate, since the direct synthesis route is not possible. The same applies to polyvinyl alcohol copolymers prepared from polyvinyl acetate copolymers become. It is preferred if at least one layer of the water-soluble coating comprises a polyvinyl alcohol whose degree of hydrolysis makes up 70 to 100 mol%, preferably 80 to 90 mol%, particularly preferably 81 to 89 mol% and in particular 82 to 88 mol%.
  • a polymer selected from the group consisting of acrylic acid-containing polymers, polyacrylamides, oxazoline polymers, polystyrene sulfonates, polyurethanes, polyesters, polyether polylactic acid or mixtures of the above polymers may be added to a film material suitable for producing the water-soluble coating.
  • Preferred polyvinyl alcohol copolymers include, in addition to vinyl alcohol, dicarboxylic acids as further monomers.
  • Suitable dicarboxylic acids are itaconic acid, malonic acid, succinic acid and mixtures thereof, with itaconic acid being preferred.
  • polyvinyl alcohol copolymers include, in addition to vinyl alcohol, an ethylenically unsaturated carboxylic acid, its salt or its esters.
  • Such polyvinyl alcohol copolymers particularly preferably contain, in addition to vinyl alcohol, acrylic acid, methacrylic acid, acrylates, methacrylates or mixtures thereof.
  • Suitable water-soluble films for use in the casings of the water-soluble packaging according to the invention are films sold by the company MonoSol LLC, for example under the designation M8630, C8400 or M8900.
  • Other suitable films include films named Solublon® PT, Solublon® GA, Solublon® KC or Solublon® KL from Aicello Chemical Europe GmbH or the films VF-HP from Kuraray.
  • a water-soluble bag preferably has a length between 50-80 mm, a width between 40-70 mm and a height between 15-45 mm.
  • the filling volume of the bag is between 20-50 ml.
  • the surface of a water-soluble bag is preferably between 5,000-10,000 mm 2.
  • the filling volume of the packaging is preferably between 1-10 liters.
  • One or more washing and cleaning agents are stored in the water-soluble foil bag. These detergents and cleaners are liquid to gel.
  • suspensions or dispersions are conceivable in the present detergent or cleaning agent preparations and encompassed by the invention, which alone, combined with other liquid detergent compositions or combined with solid detergent compositions in a single enclosure or in a combination of several, optionally interconnected enclosures are provided can.
  • the agent contains ingredients that do not destroy the structural integrity of the water-soluble wrapper.
  • the agent used is a liquid detergent or cleaning agent, it may contain one or more substances from the group of surfactants, builders, bleaches, enzymes, electrolytes, pH adjusters, perfumes, perfume carriers, fluorescers, dyes, hydrotopes, foam inhibitors, silicone oils, antiredeposition agents, Graying inhibitors, anti-shrinkage agents, anti-wrinkling agents, color transfer inhibitors, antimicrobial agents, non-aqueous solvents, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, antistatic agents, bittering agents, ironing aids, repellents and impregnating agents, skin-care agents, swelling and anti-slip agents, softening components and UV absorber included.
  • the washing or cleaning agents may contain water, wherein the content of water is less than 10 wt .-%, and more preferably less than 8 wt .-%, each based on the total liquid detergent or cleaning agent.
  • the packaging according to the invention comprises a closable container, which is designed to receive, in particular, a plurality of water-soluble foil bags.
  • a container in the sense of this application is a device which is intended to cover a plurality of water-soluble film bags in such a way that they can be shipped, stored and / or sold.
  • the container usually has a bottom and a lateral surface, through which a volume for receiving the foil bag is formed. Furthermore, the container regularly has an opening for removing the foil bag from the container, wherein the opening is closable by a closure.
  • the container for receiving the water-soluble film bag on the lowest possible water vapor permeability in order to protect the stored in him water-soluble film bag from unwanted exposure to water vapor.
  • the container is formed according to a first preferred embodiment as a dimensionally stable container, for example in the form of a closable box, box, bottle or box.
  • the container is also possible in principle to mold the container as a non-dimensionally stable container, for example as a bag or a bag.
  • a non-dimensionally stable container for example as a bag or a bag.
  • the container is preferably formed from a plastic. It is also possible to form the container from a pulp-containing material such as paper, cardboard or cardboard. Of course, the container may also be made of multi-layer materials comprising plastics, pulp-containing materials and / or metallic materials. Composite materials consisting of a cellulose-containing carrier material, which is laminated with plastic and / or metallic films, are suitable here.
  • cans may be a pruned can, a can, a can lid, a retracted can, a fold lid can, a fold lid fill can, a folded can, a drawn can, a can, a siphon, a tearing can, a sippy can, a slip lid can, or a stepped can.
  • a bottle may be a check bottle, ale bottle, goitre bag, goitre bottle, flail bottle, stony bottle, stubby bottle, vichy bottle, wide neck bottle, and mega plate bottle, squeeze bottle, dropper bottle, or as a packaging bottle like a bottle.
  • a flexible container is a packaging material which substantially alters its shape even under light load when used as intended.
  • the flexible packaging is designed as a bag.
  • the bag can be selected, for example, from the group of bottom bags, block bags, block bags, block bottom bags, block bottom bags, floor bags, bottom fold bag, cross bottom bag, round bottom bag, stand-up bag, double bag, window bag, flat bag, flap bag, flap bag, conical bag, tube bag, gusseted bag, pleated bag, sealed edge bag , Tri-seal bag, two-seam bag, flap flap bag, carrying bag and / or valve bag.
  • At least one ventilation opening is provided in the package, the amount of which is a ventilation opening area boiling point ratio based on amine compounds between 0.8-50 mm 2 / ° C, preferably between 1-20 mm 2 / ° C, particularly preferably between 1.1 -10 mm 2 / ° C.
  • the vent area boiling point ratio is the sum of the vent areas in the otherwise sealed package, based on the boiling point of one or a group of amine compounds.
  • Ventilation opening surfaces in the sense of this application are openings for removing foil bags from the packaging. Ventilation openings are consequently smaller than the foil bags stored in the packaging, so that the foil bags can not be removed through a ventilation opening.
  • the boiling point of the amine compound which has the lowest boiling point and which is present with at least 5% by weight in the group of the underlying amine compounds results from the determination of the ventilation opening surface boiling point ratio.
  • the ventilation opening can be introduced, for example by punching, slitting or by melting by means of a hot needle in the package.
  • the ventilation opening or ventilation openings in the packaging are preferably arranged above the filling level (H) of the film bags.
  • the ventilation opening has a different basic shape from the foil bags.
  • At least one fragrance emission source is arranged in the packaging.
  • the fragrance emission source releases fragrances with a boiling point of> 70 ° C.
  • the fragrance emission source is located freely in the container, i. it can be removed from the container by a user as needed.
  • the fragrance emission source is located at the bottom of the container.
  • the fragrance emission source may be formed, for example, as a scented paper or board card. It is also conceivable to produce fragrance carriers of other suitable materials, such as plastic or adhesive masses.
  • Fig. 1 shows a package 1, which is formed in the example shown as a stand-up pouch.
  • a plurality of foil bags 3 filled with liquid detergent or cleaning agent 2 are stored in a loose bed.
  • the water-soluble film bags 3 are formed from a PVA film, wherein the water-soluble film bag 3 and / or the washing and cleaning agent preparation 2 comprises a source of at least one amine compound
  • the foil pouches 3 have the bulk height H inside the packaging. Above the bed height H, a ventilation opening 5 is arranged.
  • the solvent and the aminote is greatly reduced, on the other hand, the perfume odor generated by the fragrance card is retained.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Packages (AREA)
  • Wrappers (AREA)
  • Detergent Compositions (AREA)
  • Mechanical Engineering (AREA)

Claims (7)

  1. Emballage (1) contenant des poches pelliculaires (3) solubles dans l'eau et remplies un agent de lavage ou de nettoyage liquide (2),
    - les poches pelliculaires (3) solubles dans l'eau étant entièrement ou partiellement constituées d'alcool de polyvinyle et
    - la poche pelliculaire (3) soluble dans l'eau et/ou la composition d'agent de lavage et de nettoyage comportant une source d'au moins un composé aminé,
    - au moins une source d'émission de substance odorante (4) étant disposée à l'intérieur de l'emballage, laquelle source libère des substances odorantes ayant un point d'ébullition supérieur à 70°C,
    caractérisé en ce que
    l'emballage (1) comporte au moins un orifice d'aération (5) qui a un rapport aire d'orifice d'aération sur point d'ébullition, sur la base des composés aminés, compris entre 0,8 et 50 mm2/°C, de préférence entre 1-20 mm2/°C, en particulier de préférence entre 1,1 et 10 mm2/°C.
  2. Emballage selon la revendication 1, caractérisé en ce que la poche pelliculaire (3) soluble dans l'eau comporte au moins une source d'alkylamines volatils.
  3. Emballage selon la revendication 1, caractérisé en ce que l'emballage (1) est une poche en matière plastique.
  4. Emballage selon la revendication 1, caractérisé en ce que l'emballage (1) est une boîte en matière plastique.
  5. Emballage selon l'une des revendications précédentes, caractérisé en ce que l'orifice d'aération (5) ou les orifices d'aération ménagés dans l'emballage (1) sont disposés au-dessus de la hauteur de remplissage (H) de la poche pelliculaire (2).
  6. Emballage selon l'une des revendications précédentes, caractérisé en ce qu'entre un et quatre orifices d'aération (5) sont ménagés dans l'emballage (1).
  7. Emballage selon l'une des revendications précédentes, caractérisé en ce que la source d'émission de substances odorantes (5) est disposée au fond de l'emballage (1).
EP13705171.0A 2012-07-30 2013-02-20 Emballage contenant des sachets en film soluble dans l'eau remplis de produit de lavage ou de nettoyage liquide Active EP2879969B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102012213301.1A DE102012213301A1 (de) 2012-07-30 2012-07-30 Verpackung enthaltend mit flüssigem Wasch- oder Reinigungsmittel befüllte wasserlösliche Folienbeutel
PCT/EP2013/053339 WO2014019715A1 (fr) 2012-07-30 2013-02-20 Emballage contenant des sachets en film soluble dans l'eau remplis de produit de lavage ou de nettoyage liquide

Publications (2)

Publication Number Publication Date
EP2879969A1 EP2879969A1 (fr) 2015-06-10
EP2879969B1 true EP2879969B1 (fr) 2016-09-07

Family

ID=47740959

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13705171.0A Active EP2879969B1 (fr) 2012-07-30 2013-02-20 Emballage contenant des sachets en film soluble dans l'eau remplis de produit de lavage ou de nettoyage liquide

Country Status (7)

Country Link
US (1) US20150136636A1 (fr)
EP (1) EP2879969B1 (fr)
KR (1) KR101997953B1 (fr)
DE (1) DE102012213301A1 (fr)
ES (1) ES2598138T3 (fr)
PL (1) PL2879969T3 (fr)
WO (1) WO2014019715A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014206037B3 (de) * 2014-03-31 2015-08-06 Henkel Ag & Co. Kgaa Verpackung mit Behälter und Portionspackungen sowie Verfahren zur Detektion ausgelaufener Portionspackungen
DE102014206093A1 (de) * 2014-03-31 2015-10-01 Henkel Ag & Co. Kgaa Verpackung mit einem wenigstens eine Dünnstelle aufweisenden Behälter und mit mehreren Portionspackungen sowie Verfahren zur Detektion ausgelaufener Portionspackungen
EP3138897A1 (fr) * 2015-09-04 2017-03-08 The Procter and Gamble Company Films d'au moins 80 microns comprenant des agents répulsifs ou d'amertume, pour compositions d´étergentes en dose unitaire, leurs utilisations et procédés associés
WO2017062561A1 (fr) * 2015-10-06 2017-04-13 The Procter & Gamble Company Sac de boîte souple comprenant un sachet de détergent en dose unitaire soluble
EP3153425B1 (fr) * 2015-10-06 2018-07-04 The Procter and Gamble Company Sac de boîte flexible comprenant une poudre détergente et une pelle
WO2020254406A1 (fr) * 2019-06-18 2020-12-24 Unilever Plc Emballage contenant des capsules hydrosolubles
EP3763806A1 (fr) * 2019-07-11 2021-01-13 The Procter & Gamble Company Produit de consommation contenant une bande adhésive
US20230058562A1 (en) * 2021-08-03 2023-02-23 The Procter & Gamble Company Product-Shipping Assembly

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US5351831A (en) * 1990-07-18 1994-10-04 Rhone-Poulenc Inc. Bag in a bag for containerization of toxic or hazardous material
US5253759A (en) * 1991-04-02 1993-10-19 Rhone-Poulenc Inc. Containerization system
US5817403A (en) * 1994-04-13 1998-10-06 E. I. Du Pont De Nemours And Company Nonwoven fabric
US6548134B1 (en) * 1996-06-26 2003-04-15 The Procter & Gamble Company Vented container containing a liquid product with particulate solids
GB2369094A (en) * 2000-11-17 2002-05-22 Procter & Gamble Packaging assembly for sheets of water-soluble sachets
EP1721838A3 (fr) * 2001-05-08 2007-03-07 The Procter and Gamble Company Kit de sachets solubles ou dispersables dans l'eau
GB0128946D0 (en) * 2001-12-03 2002-01-23 Unilever Plc Package for a water-soluble capsule
US20040175404A1 (en) * 2002-04-15 2004-09-09 Adi Shefer Moisture triggered sealed release system
GB0409642D0 (en) * 2004-04-30 2004-06-02 Unilever Plc Package for odorant compositions
ATE496113T1 (de) * 2004-06-08 2011-02-15 Procter & Gamble Waschmittelpackung
CA2621179A1 (fr) * 2005-09-02 2007-03-08 The Procter & Gamble Company Personnalisation de l'odeur d'une lessive
KR20080005693A (ko) * 2006-07-10 2008-01-15 엘지전자 주식회사 데이터 방송 신호, 이를 처리하는 방법 및 수신하는 장치
ES2338582T5 (es) * 2006-09-28 2014-12-19 The Procter & Gamble Company Envase de detergente
CN102149781B (zh) * 2008-09-12 2014-05-21 巴斯夫欧洲公司 用于无增塑剂的、自粘合的、可再分离的标签的粘合剂组合物

Also Published As

Publication number Publication date
DE102012213301A1 (de) 2014-02-20
KR101997953B1 (ko) 2019-07-08
PL2879969T3 (pl) 2017-03-31
WO2014019715A1 (fr) 2014-02-06
ES2598138T3 (es) 2017-01-25
US20150136636A1 (en) 2015-05-21
EP2879969A1 (fr) 2015-06-10
KR20150037902A (ko) 2015-04-08

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