EP2773741B1 - Système d'emballage doté d'un support pour compositions odorantes - Google Patents

Système d'emballage doté d'un support pour compositions odorantes Download PDF

Info

Publication number
EP2773741B1
EP2773741B1 EP12723690.9A EP12723690A EP2773741B1 EP 2773741 B1 EP2773741 B1 EP 2773741B1 EP 12723690 A EP12723690 A EP 12723690A EP 2773741 B1 EP2773741 B1 EP 2773741B1
Authority
EP
European Patent Office
Prior art keywords
fragrance composition
container
water
carrier
clogp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP12723690.9A
Other languages
German (de)
English (en)
Other versions
EP2773741A1 (fr
Inventor
Matthias Sunder
Frank Meier
Andreas Bauer
Frank Pessel
Helmut SANDMÜLLER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP2773741A1 publication Critical patent/EP2773741A1/fr
Application granted granted Critical
Publication of EP2773741B1 publication Critical patent/EP2773741B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/70—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B5/00—Packaging individual articles in containers or receptacles, e.g. bags, sacks, boxes, cartons, cans, jars
    • B65B5/10—Filling containers or receptacles progressively or in stages by introducing successive articles, or layers of articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B7/00—Closing containers or receptacles after filling
    • B65B7/16—Closing semi-rigid or rigid containers or receptacles not deformed by, or not taking-up shape of, contents, e.g. boxes or cartons
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/043—Liquid or thixotropic (gel) compositions

Definitions

  • the present invention relates to a packaging system for water-soluble film bags containing a fragrance composition-containing detergent and cleaner formulation and a fragrance composition carrier. Furthermore, the present invention relates to a method for packaging and storage of water-soluble plastic bags.
  • washing and cleaning agent filled foil bags are often formed by means of water-soluble films, which has the advantage for the consumer that he has to open a corresponding bag without him, for example, can dose into a washing machine, see, eg EP1905818 and EP1605037 ,
  • fragrance of the preparation which usually contains fragrance compositions. Since the fragrance composition concentration in these free-dosed preparations is usually quite high, the fragrance impression is regularly perceived by the consumer as intense, often as so intense that he is perceived by the consumer as unpleasant. However, the comparatively high perfume composition concentration in detergents and cleaners is necessary in order to leave a perceptible fragrance impression for the consumer on the laundry or ware. Especially the fragrance impression on the freshly treated laundry or ware is perceived by consumers as an essential quality criterion of a washing and cleaning agent. It is thus in the case of the freely dosed washing and cleaning agents, so to speak, in the "nature of the thing" that the fragrance impression or the intensity of the fragrance of the product and the laundry treated with it are significantly different.
  • Water-soluble sachets usually have the property that fragrance compositions are poorly or not at all discharged from the stored in them preparations through the water-soluble film to the environment. Thus, the fragrance impression of such preparations stored in water-soluble sachets can not be perceived by a user. Because such Water-soluble portion bags usually have an unpleasant odor, the fragrance impression of the portion bag is even regularly perceived by the consumer as repugnant.
  • the object of the present invention is therefore to produce a scent impression in the case of a water-soluble film bag, which substantially corresponds to the scent impression of a freshly washed article of laundry stored in the water-soluble film bag.
  • the water-soluble film pouches produce a scent impression by the use of the packaging system according to the invention, which substantially corresponds to the scent impression of a laundry article freshly washed with the preparation stored in the water-soluble film pouch.
  • a perfume composition carrier into a container filled with water-soluble film bag, through which the surfaces of the water-soluble film bags are scented within the container, so that a scent impression is produced on the film bags, which is substantially the scent impression of one with the water-soluble film bag stocked preparation of freshly washed laundry corresponds.
  • This perfume composition has proven to be particularly suitable for effecting a well-perceived fragrance transfer on the one hand from the fragrance composition carrier to the foil pouches and on the other hand from the detergent or cleaner composition to the to be cleaned, especially textile surfaces, so that in a water-soluble foil pouch a fragrance impression is produced, which essentially corresponds to the scent impression of a freshly washed laundry with the preparation stored in the water-soluble film bag.
  • a water-soluble film bag has a perfume composition permeability of ⁇ 0.01 g / m 2 h. Furthermore, it is particularly preferred that the water-soluble film bag is made of a PVA film
  • the perfume composition carrier has a Bendtsen surface roughness between 100-5,000 ml / min, preferably between 200-2,000 ml / min. It is very particularly preferred that the perfume composition carrier is formed from a cellulose-based material.
  • the packaging system according to the invention consists of a closable container for holding a plurality of water-soluble film bags, at least a first group of water-soluble film bags, the at least one perfume composition stored detergent or cleaning agent preparation and at least one freely positionable in the container fragrance composition carrier.
  • the packaging system comprises a closable container which is designed to receive a plurality of water-soluble film bags and at least one fragrance composition carrier which can be freely positioned in the container.
  • a container in the sense of this application is a device which is intended to cover a plurality of water-soluble film bags in such a way that they can be shipped, stored and / or sold.
  • the container usually has a bottom and a lateral surface, through which a volume for receiving the foil bag is formed. Furthermore, the container regularly has an opening for removing the foil bag from the container, wherein the opening is closed by a closure.
  • the water-soluble film bags are, as mentioned above, arranged in a sealable container.
  • the container is in particular designed so that no fragrance release from the container into the environment takes place in the closed state.
  • the container for receiving the water-soluble film bag on the lowest possible water vapor permeability in order to protect the stored in him water-soluble film bag from unwanted exposure to water vapor.
  • the container is formed according to a first preferred embodiment as a dimensionally stable container, for example in the form of a closable box, box, bottle or box.
  • the container is also possible in principle to mold the container as a non-dimensionally stable container, for example as a bag or a bag.
  • a non-dimensionally stable container for example as a bag or a bag.
  • the container is preferably formed from a plastic. It is also possible to form the container from a pulp-containing material such as paper, cardboard or cardboard. Of course, the container may also be made of multi-layer materials comprising plastics, pulp-containing materials and / or metallic materials. Composite materials consisting of a cellulose-containing carrier material, which is laminated with plastic and / or metallic films, are suitable here.
  • cans may be a pruned can, a can, a can lid, a retracted can, a fold lid can, a fold lid fill can, a folded can, a drawn can, a can, a siphon, a tearing can, a sippy can, a slip lid can, or a stepped can.
  • a bottle may be a check bottle, ale bottle, goitre bag, goitre bottle, flail bottle, stony bottle, stubby bottle, vichy bottle, wide neck bottle, and mega plate bottle, squeeze bottle, dropper bottle, or as a packaging bottle like a bottle.
  • a flexible container is a packaging material which substantially alters its shape even under light load when used as intended.
  • the flexible packaging is designed as a bag.
  • the bag can be selected, for example, from the group of bottom bags, block bags, block bags, block bottom bag, block bottom bag, floor bag, bottom fold bag, cross bottom bag, round bottom bag, stand-up bag, double bag, window bag, flat bag, flap bag, flap bag, conical bag, tubular bag, gusseted bag, pleated bag, sealed edge bag , Tri-seal bag, two-seam bag, flap flap bag, carrying bag and / or valve bag.
  • the container may be formed in a further advantageous embodiment of the invention as a two- or multi-chamber container.
  • the chambers then each contain different products from each other. It is thus possible, for example, to stock a first group of water-soluble film bags in one chamber and a second group of water-soluble film bags in another chamber.
  • Liquid in this context means that the corresponding preparations are flowable liquids, pastes or gels.
  • solid means that the corresponding preparations are present in solid form, in powder form or as granules.
  • the different groups of water-soluble film bags can store detergent or cleaner preparations with the same or different fragrance compositions. If different fragrance compositions are present in the different groups of water-soluble film bags from one another, then the respectively corresponding perfume composition carriers are assigned to the corresponding chambers of the container.
  • the container has a perfume composition permeability of ⁇ 0.01 g / m 2 h. It is particularly preferred that the container is impermeable to the perfume composition of the perfume composition carrier. This prevents unwanted release of the perfume composition from the closed container. This is of importance insofar as an uncontrolled scenting of the container environment is regularly perceived by the user as unpleasant, especially when buying and Transport of such packaging together with food. Furthermore, this ensures that the largest possible and as constant as possible amount of fragrance composition for scenting the water-soluble film bag is available.
  • the ratio of internal volume of the container to free volume between the film bags 1-5 preferably 2-4, more preferably 2.7-4.4.
  • the free volume between the foil bags is calculated from the volume of the container minus the sum of the volumes of the individual foil bags in the container.
  • the water-soluble film bags are advantageously arranged as a free bed in the container. This ensures that the largest possible surface of the film bag is uncovered in contact with the gas phase of the inner container volume and the contact surfaces between the film bags and the film bag and the container inner wall are possible.
  • substantially dimensionally stable spherical and pillow-shaped embodiments of the foil bag having a circular, elliptical, square or rectangular basic shape have shown.
  • the packaging system of the present invention further comprises at least a first group of water-soluble film bags storing at least one detergent or cleaning composition containing perfume composition, the at least first group of water-soluble film bags being positioned in a sealable container.
  • a water-soluble film bag according to the present invention has a perfume composition permeability of ⁇ 0.01 g / m 2 h. It is particularly preferred that the film bag is impermeable to the perfume composition of the detergent or cleaner formulation. This ensures that the stored in a water-soluble plastic bags sachet composition is not or only in a user usually olfactometrisch imperceptible amounts to the environment of the film bag and the fragrance impression of the film bag thus essentially by the emission of perfume preparation of the perfume preparation carrier and the precipitate this perfume formulation is determined on the foil bag.
  • a water-soluble film bag consists of one or more enclosures of one or more water-soluble material (s), preferably polymer material (s), which at least partially or completely comprises the detergent or cleaning agent preparation.
  • a water-soluble film bag contains an enclosure of one or more water-soluble polymer Materiali (s) or that more enclosures are included.
  • an enclosure preferred, which brings advantages in the choice of materials and also in view of the requirement that the water-soluble polymer material must be solved without residue in the washing or cleaning liquor.
  • the at least one washing or cleaning agent preparation partially or completely surrounding water-soluble polymer material is a water-soluble film bag.
  • a water-soluble film bag This is understood to mean a surface-shaped part which partially or completely surrounds at least one washing or cleaning agent preparation.
  • the exact shape of such a foil bag is not critical and can be largely adapted to the conditions of use.
  • plastic foils or sheets, capsules and other conceivable forms can be used for various shapes (such as hoses, cushions, cylinders, bottles, disks or the like).
  • Particularly preferred according to the invention are films which, for example, can be glued and / or sealed to packagings such as hoses, cushions or the like after they have been filled with detergent or cleaning agent preparation.
  • water-soluble polymer materials are basically all polymer materials in question, which can completely dissolve in the aqueous phase under the given conditions (temperature, pH, concentration of detergent components).
  • the polymer materials may particularly preferably belong to the groups (acetalised) polyvinyl alcohol, polyvinylpyrrolidone, polyethylene oxide, gelatin, cellulose and derivatives thereof and mixtures of said materials.
  • PVA polyvinyl alcohol
  • PVA films which are soluble at a temperature in a range which corresponds to the temperature range of a wash cycle or cleaning cycle in which at least one washing or cleaning agent preparation is to be used.
  • these are temperatures of about ⁇ 25 ° C. for the prewash, temperatures of about ⁇ 90 ° C. for the main wash and temperatures of about ⁇ 30 ° C. for the afterwash or a fabric softening cycle and, for example, cleaning. or rinse cycles temperatures of about ⁇ 20 ° C for the pre-rinse cycle, temperatures of about ⁇ 55 ° C for the main rinse and temperatures of about ⁇ 65 ° C for rinsing or rinse.
  • the most preferred water-soluble film M8630 from Mono-Sol has been found to be particularly preferred.
  • Fragrances are added to the washing or cleaning preparations in order to improve the aesthetic overall impression of the products and to the consumer in addition to the technical performance (eg softening result) a sensory to provide typical and distinctive product.
  • fragrances individual compounds can be used, for example the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons.
  • Fragrance compounds of the ester type are, for example, benzyl acetate, phenoxyethyl isobutyrate, p-t-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinyl acetate, phenylethyl acetate, linalyl benzoate, benzylformate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate and benzylsalicylate.
  • Ethers include, for example, benzyl ethyl ether.
  • the aldehydes include, for. B. linear alkanals having 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, purple and bourgeonal.
  • the ketones include, for example, the ionones, ⁇ -isomethylionone, and methyl cedryl ketone.
  • the alcohols include, for example, anethole, citronellol, eugenol, geraniol, linalool, phenylethyl alcohol and terpineol.
  • the hydrocarbons mainly include terpenes such as limonene and pinene.
  • fragrance compositions of various fragrances which are coordinated with one another in such a way that together they produce an attractive fragrance note.
  • perfume compositions may also contain natural perfume mixtures as are available from vegetable sources. Examples are pine, citrus, jasmine, patchouli, rose or ylang-ylang oil. Also suitable are nutmeg oil, sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil and labdanum oil and orange blossom oil, neroliol, orange peel oil and sandalwood oil.
  • the fragrance compositions may be incorporated directly into the detergent or cleaning compositions; but it may also be advantageous to apply the fragrances on carriers that enhance the adhesion of the fragrances on the laundry and provide by a slower release of fragrance for long-lasting fragrance of the textiles.
  • carrier materials for example, cyclodextrins have been proven.
  • the cyclodextrin-perfume complexes can additionally be coated with other auxiliaries.
  • Numerous washing or cleaning agent preparation are in the form of powders, powder mixtures or in the form of particulate body, such as balls or granules, so that it is convenient to provide foil bags as single-portion packs or packages of combinations of powdered or particulate components, for example as combinations powdered or particulate components in foil bags with one or more chambers or layers or as individual portions or combinations of powdered components in capsules.
  • the solid, for example powdered, components can be processed to granules or beads and in the form of granules or beads - comparable to the powders - be packaged in bags made of film with multiple layers or chambers or in capsules, in which Form then immediately used for washing or cleaning.
  • the detergent or cleaner formulations may also be in the form of solids compressed into bodies, which may be of any desired shape;
  • Such shaped body such as tablets, blocks, briquettes, rings o. ⁇ .
  • Such moldings can also depressions, hollows, cuts or similar. which serve special purposes of accommodating individual washing preparations.
  • molded articles in combination with powders, in combination with liquids (the latter for example in a closed enclosure of a water-soluble material) or in combination with a washing-active preparation embedded in a fusible matrix are also within the scope of the present invention.
  • the washing or cleaning agent preparations according to the invention contain one or more substances from the group of surfactants, surfactant compounds, builders, bleaching agents, bleach activators, enzymes, foam inhibitors, dyes and fragrances and - in the case that the detergent or cleaning agent preparations at least partially as a shaped body present - binding and disintegration aids.
  • At least one perfume composition carrier is positioned in the container.
  • the fragrance composition carrier is disposed freely in the container, i. it can be removed from the container by a user if necessary.
  • the perfume composition carrier is disposed at the bottom of the container. This can be done for example by a first filling of the container with the fragrance composition carrier and a subsequent filling of the container with the foil bags.
  • the perfume composition carrier has a Bendtsen surface roughness between 100-5,000 ml / min, preferably between 200-2,000 ml / min.
  • the Bendtsen surface roughness is determined according to DIN 53108. It has been found that a perfume composition carrier has a particularly favorable perfume composition release profile and kinetics in these surface roughnesses. Furthermore, an automated loading of such a configured perfume composition carrier is possible because the individual perfume composition carriers still have a sufficient sliding behavior relative to each other. This is particularly important in high-speed automated packaging processes in which the fragrance composition carriers are stacked on top of one another in the containers to provide adequate security against blockages due to unwanted multiple dosages of perfume composition carriers.
  • the stacked perfume composition carriers have been found to abrade the reciprocating perfume composition carriers within the above-mentioned packaging processes, the resulting dust adversely affecting the mechanical reliability of the packaging process, and further may cause a potential explosion safety problem.
  • the perfume composition in and / or on the perfume composition carrier and the perfume composition in at least the first group of water-soluble film pouches are substantially olfactometrically identical.
  • the surface ratio of film bag to perfume composition carrier is in the range from 1 to 200, preferably from 1 to 100, particularly preferably from 1 to 50, particularly preferably from 1 to 20.
  • the weight ratio between the perfume composition in the washing or cleaning agent preparation of a film bag and the perfume composition carrier is in the range 1-300, preferably 1-200, very particularly preferably 1-100, particularly preferably 1-50.
  • the fragrance composition carrier can take any spatial form. However, it is preferred that the perfume composition carrier is plate-shaped.
  • the base area of a plate-shaped perfume composition carrier may in particular be square, rectangular, freckled, circular or elliptical in shape.
  • the particular plate-shaped perfume composition carrier can furthermore be printed on one and / or two sides.
  • the fragrance composition carrier can be made of an absorbent or non-absorbent material.
  • the perfume composition carrier is particularly preferably formed from an absorbent material, since the perfume carrier can be fragranced by its absorbency in a particularly simple and controlled manner without the influence of heat.
  • absorbent material is particularly suitable a pulp-based material such as paper, cardboard or cardboard. It is also possible to use laminates of various papers, boards and / or boxes, which may also contain layers of plastic films and / or metal foils.
  • the absorbent perfume composition carrier may be treated by, for example, spraying, dipping, dropping or knife coating with a perfume composition.
  • a perfume composition In a possible intermediate storage of fragranced, fragrance fragrance composition carrier, which may be up to several weeks, the applied fragrance composition is evenly distributed in the absorbent carrier material.
  • the weight per unit area of such pulp-based materials is preferably 200-2,000 g / m 2 , particularly preferably 250-1,000 g / m 2 , very particularly preferably 275-750 g / m 2 .
  • the perfume composition carrier from a non-absorbent material, for example from a scented plastic or the like.
  • FIG. 1 and Fig. 2 A first preferred embodiment of the invention show Fig. 1 and Fig. 2 , in which Fig. 1 an embodiment of a sealable container without water-soluble film bag and Fig. 2 the out Fig.1 shows known container filled with water-soluble foil bag shows. It can be seen a transparent container 1 having an oval shape in front view for placing a label.
  • the container 1 is molded from a plastic such as PP, PE or PET and has a perfume composition permeability of ⁇ 0.01 g / m 2 h with respect to the perfume composition used in the perfume composition carrier (not shown).
  • the container 1 has an inner volume of 1.9 liters, wherein in the container interior 20 water-soluble foil bags 2 are stored with a single volume of 35 ml.
  • the foil bag 2 have a pillow-shaped design and have a rectangular basic shape of about 55x40 mm.
  • the film bags 2 are made of a film based on polyvinyl alcohol (PVA).
  • PVA polyvinyl alcohol
  • a particularly suitable PVA film is, for example, M8630 from Monosol.
  • a water-soluble film bag 2 has a perfume composition permeability of ⁇ 0.01 g / m 2 h compared to the perfume composition used.
  • the internal pressure of the film bags which are filled with a liquid to gelatinous detergent or cleaning agent preparation, is selected so that the film bags 2 are substantially dimensionally stable.
  • the foil bag 2 are arranged in a loose bed within the container 1, which is well out of the Fig.2 can be seen.
  • the ratio of volume of the container 1 to free volume between the film bags 2 is in this preferred embodiment in about 2.7.
  • a plate-shaped fragrance composition carrier (not visible) formed of a pulp-based laminate.
  • the laminate consists of a pulp-based core on whose outer cover layers bleached, pulp-based layers are arranged.
  • the perfume composition carrier has a Bendtsen surface roughness between 200-2,000 ml / min.
  • the perfume composition in and / or on the perfume composition carrier and the perfume composition in at least the first group of water-soluble film pouches are thus substantially olfactometrically identical.
  • the weight ratio between the perfume composition in the detergent formulation of a film bag and the perfume composition carrier in this preferred embodiment is about 4.2.
  • the perfume composition carrier is plate-shaped, wherein the perfume composition carrier has a square, rectangular, circular or oval basic shape.
  • the one-sided base area of the perfume composition carrier is preferably between 9-25 cm 2 .
  • the perfume composition carrier is preferably added to the container 1 before being filled with the film bags 2.
  • the perfume composition carrier is not fixed to the container so that it can be removed by a user and e.g. can be used as a room freshener.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Wrappers (AREA)
  • Packages (AREA)

Claims (9)

  1. Système d'emballage comprenant
    - un récipient fermable pouvant contenir une pluralité de sachets en film hydrosolubles et au moins un support de composition de parfum positionnable librement dans le récipient,
    - au moins un premier groupe de sachets en film hydrosolubles qui stocke au moins une préparation d'agent de lavage ou de nettoyage contenant une composition de parfum,
    o la composition de parfum étant présente à une concentration située dans la plage allant de 0,1 à 5 % en poids, de préférence de 0,2 à 3 % en poids, et de manière particulièrement préférée de 0,3 à 2 % en poids, dans la préparation d'agent de lavage ou de nettoyage,
    - au moins un support de composition de parfum positionnable dans le récipient,
    o la composition de parfum dans et/ou sur le support de composition de parfum et la composition de parfum dans au moins le premier groupe de sachets en film hydrosolubles étant sensiblement identiques sur le plan olfactométrique,
    o le rapport de surface entre le sachet en film et le support de composition de parfum se situant dans la plage allant de 1 à 200,
    o le rapport en poids entre la composition de parfum dans la préparation d'agent de lavage ou de nettoyage d'un sachet en film et le support de composition de parfum se situant dans la plage allant de 1 à 300, de préférence de 1 à 50 et de manière particulièrement préférée de 1 à 10,
    o le rapport entre le volume du récipient et le volume libre entre les sachets en film se situant dans la plage allant de 1 à 5, de préférence de 2 à 4, et de manière particulièrement préférée de 2,7 à 3,4.
  2. Système d'emballage selon la revendication 1, caractérisé en ce que la composition de parfum est définie comme suit :
    a. Moins de 25 % de la composition de parfum présente une valeur de clogP > 4 et un point d'ébullition > 250 °C,
    b. Moins de 70 % de la composition de parfum présente une valeur de clogP > 3 et un point d'ébullition > 200 °C,
    c. Plus de 30 % de la composition de parfum présente un ODT (seuil de détection des odeurs) < 50 µg/m3.
  3. Système d'emballage selon l'une des revendications précédentes, caractérisé en ce qu'un sachet en film hydrosoluble présente une perméabilité à la composition de parfum < 0,01 g/m2/h.
  4. Système d'emballage selon l'une des revendications précédentes, caractérisé en ce que la composition de parfum du support de composition de parfum est définie comme suit :
    a. Moins de 25 % de la composition de parfum présente une valeur de clogP > 4 et un point d'ébullition > 250 °C,
    b. Moins de 70 % de la composition de parfum présente une valeur de clogP > 3 et un point d'ébullition > 200 °C,
    c. Plus de 10 % de la composition de parfum présente une valeur de clogP < 2, et
    d. Plus de 30 % de la composition de parfum présente un ODT (seuil de détection des odeurs) < 50 µg/m3.
  5. Système d'emballage selon l'une des revendications précédentes, caractérisé en ce que la composition de parfum de la composition d'agent de lavage ou de nettoyage est définie comme suit :
    a. Moins de 25 % de la composition de parfum présente une valeur de clogP > 4 et un point d'ébullition > 250 °C,
    b. Moins de 70 % de la composition de parfum présente une valeur de clogP > 3 et un point d'ébullition > 200 °C,
    c. Moins de 10 % de la composition de parfum présente une valeur de clogP < 2, et
    d. Plus de 30 % de la composition de parfum présente un ODT (seuil de détection des odeurs) < 50 µg/m3.
  6. Système d'emballage selon l'une des revendications précédentes, caractérisé en ce que le support de composition de parfum présente une rugosité de surface Bendtsen comprise entre 100 et 5 000 ml/min, de préférence entre 200 et 2 000 ml/min.
  7. Système d'emballage selon l'une quelconque des revendications précédentes, caractérisé en ce que le sachet en film hydrosoluble est fabriqué à partir d'un film en alcool polyvinylique (PVA).
  8. Système d'emballage selon l'une des revendications précédentes, caractérisé en ce que le support de composition de parfum est formé d'un matériau à base de pâte de cellulose.
  9. Procédé d'emballage et de stockage de sachets en film hydrosolubles dans un système d'emballage, en particulier selon l'une des revendications 1 à 8, dans lequel le système d'emballage comprend :
    • un récipient fermable pouvant contenir une pluralité de sachets en film hydrosolubles et au moins un support de composition de parfum positionnable librement dans le récipient,
    • au moins un premier groupe de sachets en film hydrosolubles qui stocke au moins une préparation d'agent de lavage ou de nettoyage contenant une composition de parfum,
    o la composition de parfum étant présente à une concentration située dans la plage allant de 0,1 à 5 % en poids, de préférence de 0,2 à 3 % en poids, et de manière particulièrement préférée de 0,3 à 2 % en poids, dans la préparation d'agent de lavage ou de nettoyage,
    • au moins un support de composition de parfum positionnable dans le récipient,
    o la composition de parfum dans et/ou sur le support de composition de parfum et la composition de parfum dans au moins le premier groupe de sachets en film hydrosolubles étant sensiblement identiques sur le plan olfactométrique,
    o le rapport de surface entre le sachet en film et le support de composition de parfum se situant dans la plage allant de 1 à 200,
    o le rapport en poids entre la composition de parfum dans la préparation d'agent de lavage ou de nettoyage d'un sachet en film et le support de composition de parfum se situant dans la plage allant de 1 à 300, de préférence de 1 à 50 et de manière particulièrement préférée de 1 à 10,
    o le rapport entre le volume du récipient et le volume libre entre les sachets en film se situant dans la plage allant de 1 à 5, de préférence de 2 à 4, et de manière particulièrement préférée de 2,7 à 3,4.
    comprenant les étapes de procédé suivantes :
    (a.) remplissage du récipient avec au moins le premier groupe de sachets en film hydrosolubles
    (b.) positionnement de l'au moins un support de composition de parfum dans le récipient, les étapes de procédé (a.) et (b.) pouvant être effectuées dans n'importe quel ordre,
    (c.) fermeture du récipient
    (d.) stockage du récipient fermé pendant au moins 24 heures, de préférence au moins 48 heures, et en particulier de préférence au moins 72 heures.
EP12723690.9A 2011-11-04 2012-05-25 Système d'emballage doté d'un support pour compositions odorantes Active EP2773741B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102011085778A DE102011085778A1 (de) 2011-11-04 2011-11-04 Verpackungssystem mit Duftstoffzusammensetzungsträger
PCT/EP2012/059811 WO2013064274A1 (fr) 2011-11-04 2012-05-25 Système d'emballage doté d'un support pour compositions odorantes

Publications (2)

Publication Number Publication Date
EP2773741A1 EP2773741A1 (fr) 2014-09-10
EP2773741B1 true EP2773741B1 (fr) 2019-02-27

Family

ID=46168489

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12723690.9A Active EP2773741B1 (fr) 2011-11-04 2012-05-25 Système d'emballage doté d'un support pour compositions odorantes

Country Status (5)

Country Link
US (1) US20140238889A1 (fr)
EP (1) EP2773741B1 (fr)
KR (1) KR101953084B1 (fr)
DE (1) DE102011085778A1 (fr)
WO (1) WO2013064274A1 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150076248A1 (en) * 2013-06-04 2015-03-19 Rich Brands Llc Fragrance accessories for use with home fashions and consumer products
CN106661509A (zh) * 2014-06-30 2017-05-10 宝洁公司 衣物洗涤剂组合物
DE102015201954A1 (de) 2015-02-04 2016-08-04 Henkel Ag & Co. Kgaa Standbeutel für Vorportionierte Packungen
DE102018101566A1 (de) * 2018-01-24 2019-07-25 Huhtamaki Flexible Packaging Germany Gmbh & Co. Kg Verpackung
US11053047B2 (en) 2018-03-23 2021-07-06 The Procter & Gamble Company Container system with improved messaging structure
WO2019245889A1 (fr) 2018-06-18 2019-12-26 Baker Hughes, A Ge Company, Llc Procédés de fabrication d'agents de réduction de traînée de polyoléfine
US10736815B1 (en) * 2019-01-24 2020-08-11 Scentsational Technologies, Llc Scent releasing insert for confined containers
USD976102S1 (en) 2019-03-22 2023-01-24 The Procter & Gamble Company Messaging structure
USD957251S1 (en) 2019-03-22 2022-07-12 The Procter & Gamble Company Packaging with insert
US11199296B2 (en) 2019-06-14 2021-12-14 Baker Hughes Oilfield Operations Llc Drag reducing agents
US20220025303A1 (en) * 2020-06-30 2022-01-27 The Procter & Gamble Company Process for manufacturing a water-soluble unit dose article
US20230058562A1 (en) * 2021-08-03 2023-02-23 The Procter & Gamble Company Product-Shipping Assembly
WO2024028159A1 (fr) * 2022-08-04 2024-02-08 Unilever Ip Holdings B.V. Produit de soins à domicile emballé

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002096473A1 (fr) * 2001-05-29 2002-12-05 Reckitt Benckiser (Uk) Limited Feuille desodorisante ou purifiante
GB2407327A (en) * 2003-10-24 2005-04-27 Reckitt Benckiser Tear-off odour-reducing sheets

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4510019A (en) * 1981-05-12 1985-04-09 Papeteries De Jeand'heurs Latex containing papers
US5817403A (en) * 1994-04-13 1998-10-06 E. I. Du Pont De Nemours And Company Nonwoven fabric
ES2229343T3 (es) * 1996-03-19 2005-04-16 THE PROCTER &amp; GAMBLE COMPANY Procedimiento para fabricar composiciones para lavavajillas automaticas con mejoradores de la detergencia que contienen perfume de flores.
GB2369094A (en) * 2000-11-17 2002-05-22 Procter & Gamble Packaging assembly for sheets of water-soluble sachets
GB0128946D0 (en) * 2001-12-03 2002-01-23 Unilever Plc Package for a water-soluble capsule
US20040175404A1 (en) 2002-04-15 2004-09-09 Adi Shefer Moisture triggered sealed release system
EP1396440A1 (fr) * 2002-09-05 2004-03-10 The Procter & Gamble Company Produit emballé comprenant des poches flexibles remplies de liquide
EP1605037B1 (fr) * 2004-06-08 2011-01-19 The Procter & Gamble Company Emballage de detergent
WO2007026331A1 (fr) * 2005-09-02 2007-03-08 The Procter & Gamble Company Personnalisation de l'odeur d'une lessive
KR20080005693A (ko) * 2006-07-10 2008-01-15 엘지전자 주식회사 데이터 방송 신호, 이를 처리하는 방법 및 수신하는 장치
ES2338582T5 (es) * 2006-09-28 2014-12-19 The Procter & Gamble Company Envase de detergente
EP2210520A1 (fr) * 2009-01-22 2010-07-28 The Procter & Gamble Company Paquet comprenant un matériau adhésif de fourniture de parfum

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002096473A1 (fr) * 2001-05-29 2002-12-05 Reckitt Benckiser (Uk) Limited Feuille desodorisante ou purifiante
GB2407327A (en) * 2003-10-24 2005-04-27 Reckitt Benckiser Tear-off odour-reducing sheets

Also Published As

Publication number Publication date
KR20140088548A (ko) 2014-07-10
WO2013064274A1 (fr) 2013-05-10
DE102011085778A1 (de) 2013-05-08
US20140238889A1 (en) 2014-08-28
EP2773741A1 (fr) 2014-09-10
KR101953084B1 (ko) 2019-03-04

Similar Documents

Publication Publication Date Title
EP2773741B1 (fr) Système d&#39;emballage doté d&#39;un support pour compositions odorantes
EP2802643B1 (fr) Emballage parfumé soluble dans l&#39;eau
EP2874897B1 (fr) Emballage hydrosoluble comprenant une composition et son procédé de fabrication
EP2879969B1 (fr) Emballage contenant des sachets en film soluble dans l&#39;eau remplis de produit de lavage ou de nettoyage liquide
DE60113867T3 (de) Waschmittel verpackt mit ethoxyliertem polyvinylalkohol
DE60003298T3 (de) Verfahren zum herstellen einer wasserlöslichen verpackung
DE60311830T2 (de) Wasserlöslicher behälter
WO2014016144A1 (fr) Emballage hydrosoluble coloré
WO2015150231A1 (fr) Dose préemballée soluble dans l&#39;eau dotée d&#39;un couvercle de forme stable
DE20220721U1 (de) Wasserlösliche Behälter mit Gasfreisetzungseinrichtungen
WO2001007560A1 (fr) Portion d&#39;agent de lavage ou de nettoyage et emballage pour agent de lavage ou de nettoyage
EP2158132B1 (fr) Emballage avec une barrière à la vapeur d&#39;eau améliorée
WO2017140515A1 (fr) Produit détergent et procédé associé pour fabriquer ce produit détergent
DE10244802B4 (de) Pralle Waschmittelformkörper
DE10244803A1 (de) Geschrumpfte Waschmittelformkörper
DE10310932B4 (de) Verfahren zur Herstellung eines Behälters durch Tiefziehen
DE102004030148B4 (de) Verfahren zur Herstellung von Portionspackungen für wasch- oder reinigungsaktive Substanzen
DE10305799A1 (de) Blasgeformter Waschmittelformkörper
DE10350931B4 (de) Verpackungsverfahren
DE102012214978A1 (de) Verpackung für wasserlösliche, mit Wasch- oder Reinigungsmittel befüllte Folienbeutel
DE102015117056A1 (de) Sichtverpackung für stückförmige Mittel, insbesondere Reinigungsmittel für den Toilettenbereich, und Herstellungsverfahren
EP2027243A2 (fr) Agents de nettoyage ou de lavage enveloppés

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20140317

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

DAX Request for extension of the european patent (deleted)
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

17Q First examination report despatched

Effective date: 20171122

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20180926

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502012014348

Country of ref document: DE

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 1101353

Country of ref document: AT

Kind code of ref document: T

Effective date: 20190315

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20190227

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190627

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190527

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190627

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190528

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190527

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 502012014348

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190531

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190531

26N No opposition filed

Effective date: 20191128

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20190531

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190525

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190525

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190531

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 1101353

Country of ref document: AT

Kind code of ref document: T

Effective date: 20190525

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190525

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20120525

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190227

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230531

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20230526

Year of fee payment: 12

Ref country code: DE

Payment date: 20230519

Year of fee payment: 12

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20230524

Year of fee payment: 12