EP2850215B1 - Acier à coût réduit pour la technique de l'hydrogène, à haute résistance contre la fragilisation induite par de l'hydrogène - Google Patents
Acier à coût réduit pour la technique de l'hydrogène, à haute résistance contre la fragilisation induite par de l'hydrogène Download PDFInfo
- Publication number
- EP2850215B1 EP2850215B1 EP13731695.6A EP13731695A EP2850215B1 EP 2850215 B1 EP2850215 B1 EP 2850215B1 EP 13731695 A EP13731695 A EP 13731695A EP 2850215 B1 EP2850215 B1 EP 2850215B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- hydrogen
- steel
- mass
- percent
- induced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/001—Heat treatment of ferrous alloys containing Ni
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M21/00—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form
- F02M21/02—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels
- F02M21/0203—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels characterised by the type of gaseous fuel
- F02M21/0206—Non-hydrocarbon fuels, e.g. hydrogen, ammonia or carbon monoxide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M21/00—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form
- F02M21/02—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels
- F02M21/0218—Details on the gaseous fuel supply system, e.g. tanks, valves, pipes, pumps, rails, injectors or mixers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M21/00—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form
- F02M21/02—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels
- F02M21/0218—Details on the gaseous fuel supply system, e.g. tanks, valves, pipes, pumps, rails, injectors or mixers
- F02M21/0296—Manufacturing or assembly; Materials, e.g. coatings
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
Definitions
- the invention relates to the use of an austenitic stainless steel for hydrogen technology in motor vehicles with high resistance to hydrogen-induced embrittlement, in particular in the temperature range between -100 ° C and room temperature (+ 25 ° C). It is suitable for all hydrogen in contact with metallic components of a motor vehicle, such as hydrogen tanks, valves, pipes, fittings, Boss, liner springs, heat exchangers or bellows.
- US 2009/0159602 A1 is an austenitic steel having a composition according to the formula - 120 ⁇ Md 30 ⁇ 20 with Md30 (° C): 551-462 (C + N) -9.2Si-8, lMn-13.7Cr-29 (Ni + Cu) -18.2Mo.
- the object of the invention is to provide for use for the hydrogen technology in motor vehicles, a cost-effective steel that is resistant to hydrogen-induced embrittlement throughout the temperature range between at least + 100 ° C and -253 ° C and high pressure resistant, has corrosion resistance and good warm and cold forming and welding.
- the melting-related steel accompanying elements comprise further customary production-related elements (eg sulfur and phosphorus) as well as other elements which are not specifically added.
- the phosphorus content is preferably ⁇ 0.05 mass%, the sulfur content ⁇ 0.4 mass%, in particular ⁇ 0.04 mass%.
- the content of all other melting-related steel accompanying elements is maximum per element. 0.3 mass%.
- the costs can be reduced.
- the steel Despite the decrease in the nickel content and the low molybdenum content or lack of molybdenum (ie without molybdenum additive), the steel has very good mechanical properties in a hydrogen atmosphere over the entire temperature range of -253 to at least + 100 ° C and pressure range from 0.1 to 100 MPa.
- the steel in the solution-annealed condition (AT) at a test temperature of -50 ° C and a gas pressure of 40 MPa hydrogen in the tensile test at a strain rate of 5x10-5 1 / s, a Relative Reduction of Area (RAA) or relative Brucheinschnürung ( Fractional Z in air or helium / Fractional Z in hydrogen x 100%) of at least 90%.
- R_Rm, relative yield strength R_Rp0.2 and relative elongation at break R_A5 are also at least 90%.
- the high yield strength of the steel of 300 to 400 MPa is essential.
- the steel can be solution annealed (AT). It can also be cold formed, in particular cold drawn or cold rolled used.
- the steel has a very good weldability and good corrosion resistance.
- the steel has a high resistance to hydrogen embrittlement in the entire temperature range from -253 ° C to at least + 100 ° C and pressure range from 0.1 to 100 MPa.
- the steel thus represents a cost-effective hydrogen-resistant material for hydrogen technology.
- the steel can be used in the hydrogen technology of automobiles for devices and components of systems for generating, storing, distributing and using hydrogen, especially when the devices come into contact with hydrogen.
- a (high) pressure vessel for hydrogen storage, a (high) pressure vessel, a cryogenic (high) pressure vessel, or a liquid hydrogen tank from the steel can be used.
- the steel has a stable austenitic structure.
- the ⁇ -ferrite content of the steels is less than 5% by volume, preferably even no ⁇ -ferrite is present.
- the yield strength Rp0.2 in the tensile test at a strain rate of 5x10-5 is 1 / s at -50 ° C in a hydrogen atmosphere of 40 MPa for Steel No. 1 200 to 300 MPa and for Steel No. 2 300 to 400 MPa.
- the steel Due to the relatively low nickel content of up to 9% by mass and the absence of molybdenum, the steel is very cost-effective.
- the steel with stable austenitic structure thus represents a cost-effective hydrogen-resistant material for hydrogen technology in motor vehicles.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- General Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
- Heat Treatment Of Steel (AREA)
- Electric Propulsion And Braking For Vehicles (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Heat Treatment Of Articles (AREA)
Claims (1)
- Utilisation d'un acier austénitique présentant la composition suivante :0,01 -0,12 % en masse de carbone,0,05 - 0,5 % en masse de silicium,9 - 13 % en masse de manganèse,16 - 20 % en masse de chrome,6 - 9 % en masse de nickel0,01 - 0,5 % en masse d'aluminium1 - 4 % en masse de cuivre,≤ 0,04 % en masse de bore,un reste de fer et des éléments d'accompagnement de l'acier dus à la fusion pour la technologie de l'hydrogène dans des véhicules dans la plage de température de -253°C à +100°C et dans la gamme de pression de 0,1 à 100 MPa.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102012104260A DE102012104260A1 (de) | 2012-05-16 | 2012-05-16 | Kostenreduzierter Stahl für die Wasserstofftechnik mit hoher Beständigkeit gegen wasserstoffinduzierte Versprödung |
PCT/EP2013/060084 WO2013171277A1 (fr) | 2012-05-16 | 2013-05-15 | Acier à coût réduit pour la technique de l'hydrogène, à haute résistance contre la fragilisation induite par de l'hydrogène |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2850215A1 EP2850215A1 (fr) | 2015-03-25 |
EP2850215B1 true EP2850215B1 (fr) | 2018-01-03 |
Family
ID=48699725
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13731695.6A Active EP2850215B1 (fr) | 2012-05-16 | 2013-05-15 | Acier à coût réduit pour la technique de l'hydrogène, à haute résistance contre la fragilisation induite par de l'hydrogène |
Country Status (5)
Country | Link |
---|---|
US (1) | US10513764B2 (fr) |
EP (1) | EP2850215B1 (fr) |
CN (1) | CN104302790A (fr) |
DE (1) | DE102012104260A1 (fr) |
WO (1) | WO2013171277A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP4032999A1 (fr) | 2021-01-20 | 2022-07-27 | Poppe & Potthoff GmbH | Système de distribution d'hydrogène et composants de faible poids |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6148188B2 (ja) | 2014-02-13 | 2017-06-14 | トヨタ自動車株式会社 | オーステナイト系耐熱鋳鋼 |
WO2016195106A1 (fr) * | 2015-06-05 | 2016-12-08 | 新日鐵住金株式会社 | Acier inoxydable austénitique |
KR20180104509A (ko) * | 2017-03-13 | 2018-09-21 | 엘지전자 주식회사 | 공기 조화기 |
KR20180104520A (ko) * | 2017-03-13 | 2018-09-21 | 엘지전자 주식회사 | 공기 조화기 |
CN110462082B (zh) * | 2017-03-30 | 2021-04-30 | 日铁不锈钢株式会社 | 焊接性优良的氢用高Mn奥氏体系不锈钢、使用该不锈钢的焊接接头和氢用设备、以及焊接接头的制造方法 |
KR20180111417A (ko) * | 2017-03-31 | 2018-10-11 | 엘지전자 주식회사 | 연성 스테인리스 강관 |
DE102017114262A1 (de) * | 2017-06-27 | 2018-12-27 | Salzgitter Flachstahl Gmbh | Stahllegierung mit verbesserter Korrisionsbeständigkeit bei Hochtemperaturbeanspruchung und Verfahren zur Herstellung von Stahlband aus dieser Stahllegierung |
RU2680557C1 (ru) * | 2017-11-28 | 2019-02-22 | Российская Федерация, от имени которой выступает Министерство промышленности и торговли Российской Федерации (Минпромторг России) | Экономнолегированная хладостойкая высокопрочная сталь |
JP7262172B2 (ja) * | 2018-02-23 | 2023-04-21 | 日鉄ステンレス株式会社 | 高Mnオーステナイト系ステンレス鋼 |
CN110499475B (zh) * | 2019-08-19 | 2020-07-28 | 广东省材料与加工研究所 | 一种奥氏体耐热钢及其制备方法和应用 |
JP7339123B2 (ja) | 2019-10-30 | 2023-09-05 | 山陽特殊製鋼株式会社 | 高硬度耐水素脆化鋼 |
CN113832400A (zh) * | 2021-09-24 | 2021-12-24 | 中国船舶重工集团公司第七0四研究所 | 一种扭矩传感器用不锈钢弹性体材料及热处理方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090159602A1 (en) * | 2005-11-01 | 2009-06-25 | Masaharu Hatano | Austenitic High Mn Stainless Steel for High Pressure Hydrogen Gas |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR743179A (fr) * | 1933-03-25 | |||
AT76445B (de) | 1912-02-27 | 1919-05-10 | Ferdinand Fiala | Gitter aus einander durchdringenden Stäben mit mindestens einem Hohlprofil. |
SE8102015L (sv) * | 1980-04-07 | 1981-10-08 | Armco Inc | Ferritfritt utskiljningsherdbart rostfritt stal |
US4828630A (en) * | 1988-02-04 | 1989-05-09 | Armco Advanced Materials Corporation | Duplex stainless steel with high manganese |
FR2743179B1 (fr) * | 1995-12-29 | 1998-02-13 | Avenir Havas Media | Dispositif support d'appareillage d'eclairage et panneau d'affichage comportant un tel dispositif |
US20040258554A1 (en) * | 2002-01-09 | 2004-12-23 | Roman Radon | High-chromium nitrogen containing castable alloy |
CN100567542C (zh) * | 2003-03-20 | 2009-12-09 | 住友金属工业株式会社 | 高压氢气用不锈钢、由该钢制作的容器以及器具 |
KR100617465B1 (ko) * | 2003-03-20 | 2006-09-01 | 수미도모 메탈 인더스트리즈, 리미티드 | 고압 수소 가스용 스테인레스강, 그 강으로 이루어지는 용기 및 기기 |
CN1833043B (zh) * | 2003-06-10 | 2010-09-22 | 住友金属工业株式会社 | 氢气用奥氏体不锈钢及其制造方法 |
US7754305B2 (en) * | 2007-01-04 | 2010-07-13 | Ut-Battelle, Llc | High Mn austenitic stainless steel |
JP5388589B2 (ja) * | 2008-01-22 | 2014-01-15 | 新日鐵住金ステンレス株式会社 | 加工性と衝撃吸収特性に優れた構造部材用フェライト・オーステナイト系ステンレス鋼板およびその製造方法 |
KR101387767B1 (ko) * | 2008-10-07 | 2014-04-21 | 신닛테츠스미킨 카부시키카이샤 | 고체 고분자형 연료 전지의 세퍼레이터용 스테인리스강판 및 그것을 이용한 고체 고분자형 연료 전지 |
WO2012043877A1 (fr) * | 2010-09-29 | 2012-04-05 | 新日鐵住金ステンレス株式会社 | Acier austénitique inoxydable à forte teneur en manganèse, procédé de fabrication correspondant, et élément utilisant cet acier |
-
2012
- 2012-05-16 DE DE102012104260A patent/DE102012104260A1/de not_active Withdrawn
-
2013
- 2013-05-15 EP EP13731695.6A patent/EP2850215B1/fr active Active
- 2013-05-15 WO PCT/EP2013/060084 patent/WO2013171277A1/fr active Application Filing
- 2013-05-15 CN CN201380025169.6A patent/CN104302790A/zh active Pending
-
2014
- 2014-11-14 US US14/541,420 patent/US10513764B2/en active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090159602A1 (en) * | 2005-11-01 | 2009-06-25 | Masaharu Hatano | Austenitic High Mn Stainless Steel for High Pressure Hydrogen Gas |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP4032999A1 (fr) | 2021-01-20 | 2022-07-27 | Poppe & Potthoff GmbH | Système de distribution d'hydrogène et composants de faible poids |
WO2022157247A1 (fr) | 2021-01-20 | 2022-07-28 | Poppe + Potthoff Gmbh | Système de distribution d'hydrogène et éléments à faible poids |
Also Published As
Publication number | Publication date |
---|---|
EP2850215A1 (fr) | 2015-03-25 |
DE102012104260A1 (de) | 2013-11-21 |
US20150167134A1 (en) | 2015-06-18 |
WO2013171277A1 (fr) | 2013-11-21 |
US10513764B2 (en) | 2019-12-24 |
CN104302790A (zh) | 2015-01-21 |
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