EP2756059A1 - Hochtemperaturfett - Google Patents
HochtemperaturfettInfo
- Publication number
- EP2756059A1 EP2756059A1 EP12755795.7A EP12755795A EP2756059A1 EP 2756059 A1 EP2756059 A1 EP 2756059A1 EP 12755795 A EP12755795 A EP 12755795A EP 2756059 A1 EP2756059 A1 EP 2756059A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alkylated
- additives
- group
- temperature
- combination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
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- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
- C10M105/32—Esters
- C10M105/40—Esters containing free hydroxy or carboxyl groups
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- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/02—Well-defined hydrocarbons
- C10M105/06—Well-defined hydrocarbons aromatic
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
- C10M2219/068—Thiocarbamate metal salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/12—Groups 6 or 16
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/02—Bearings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
Definitions
- the invention relates to a fluorine-free high-temperature grease, which is used inter alia in corrugated board plants.
- the paper of the wave web is brought under pressure and hot water vapor by corrugating to the desired shape.
- the corrugating rolls are therefore exposed to high temperatures, so that the greases used must meet high requirements.
- the corrugating roller is the critical lubrication point in the corrugated cardboard plants, since high temperatures must be used to bond the paper webs at high pressure and at high temperatures.
- the corrugating roll is a steam-heated roll in which the typical working temperatures of the rolls are in the range of 150 to 180 ° C.
- oil lubrication is carried out by means of circulation lubrication. This is a complicated process in which a lot of oil is consumed.
- mineral oil greases can also be used; here, too, the fat consumption is very high due to the continuous relubrication.
- the object of the present invention is therefore to provide fats which are free of fluorinated base oils, in particular free from PFPE-containing base oils. These fats should be inexpensive to produce and minimize the environmental impact, since it can be dispensed with the use of fluorinated base oils. Also, the relubrication intervals should not be shortened. This object is achieved, surprisingly, by the provision of a high-temperature fat in which an alkylated naphthalene or a dipentaerythritol ester and mixtures thereof are used as the base oil and the use of fluorinated base oils is dispensed with.
- the high-temperature fat according to the invention comprises:
- a particularly preferred high temperature grease comprises:
- the component (A) used as the base oil is selected from the group consisting of alkylated naphthalene, dipentaerythritol ester or mixtures thereof.
- alkylated naphthalene is used as component (A) for the production of a corrugator. If a high temperature grease is made for tire segment pushers, it is recommended to use as component (A) dipentaerythritol ester.
- component (B) PTFE, metallic soaps such as lithium complex soaps, aluminum complex soaps, sodium complex soaps, boron nitride, aerosil, silicates such as bentonite, high-temperature organic polymers such as polyimides and polyamide-imides are used singly or in combination.
- component (C) additives against wear, oxidation, corrosion and additives for reducing friction or improving high-pressure properties are used.
- Antioxidants used in particular as antioxidants are those which may contain sulfur and / or nitrogen and / or phosphorus in the molecule. These are selected from the group consisting of aromatic amine antioxidants such as alkylated phenyl-alpha-naphthylamine, dialkyldiphenylamine, aralkylated diphenylamines, hindered phenols such as butylated hydroxytoluene (BHT), phenolic antioxidants with thioether groups, Zn or Mo or W dialkyl dithiophosphates and phosphites used singly or in combination.
- aromatic amine antioxidants such as alkylated phenyl-alpha-naphthylamine, dialkyldiphenylamine, aralkylated diphenylamines, hindered phenols such as butylated hydroxytoluene (BHT), phenolic antioxidants with thioether groups, Zn or Mo or W dialkyl dithiophosphat
- the anti-wear agent is selected from the group consisting of diphenyl cresyl phosphate-based anti-wear additives, amine-neutralized phosphates, alkylated and non-alkylated triaryl phosphates, alkylated and non-alkylated triaryl thiophosphates, zinc or Mo or dialkyldithiophosphates, carbamates, thiocarbamates, zinc or Mo or W dithiocarbamates, dimercapto thiadiazole, calcium sulfonates and benzotriazole derivatives used singly or in combination.
- the corrosion inhibitor is selected from the group consisting of additives based on "overbased" Ca sulfonates having a TBN of 100 to 300 mg KOH / g, amine-neutralized phosphates, alkylated Ca naphthalenesulfonates, oxazoline derivatives, imidazole derivatives, succinic acid half esters, N-alkylated benzotriazoles used singly or in combination.
- olefin component (D) compounds selected from the group consisting of esters, synthetic hydrocarbons, native oils, group III oils, used singly or in combination.
- Group III oils refer to specially processed mineral oils.
- mineral oils polyglycols, silicone oils or alkylated benzenes can be used.
- the high-temperature grease according to the invention can be used not only for the lubrication of corrugating rolls in corrugated board plants, but also for high-temperature applications in rolling bearings and sliding points for permanent lubrication, in which temperatures of up to 200 ° C can be achieved. Furthermore, the high temperature grease according to the invention can be used in Reifensegementschiebern.
- the high-temperature fat according to the invention is characterized in more detail by the following examples.
- these are lubricating greases with a shear viscosity between approximately 5,000 and 10,000 mPas, measured at a shear rate of 300 1 / s in the cone / plate geometry.
- the PFPE reference samples used were examples 5 and 6, of which example 6 is frequently used for the lubrication of corrugating rolls in corrugating machines.
- the dynamic viscosities at 40 ° C. between 160 mPas and 550 mPas were selected.
- the alkylated naphthalene and the ester are heated in a kettle to about 100 ° C. Thereafter, the antioxidant is added and stirred until a clear solution is obtained. The contents of the kettle are cooled and then the metal soap and the PTFE are stirred in homogeneously. Finally, the fat is homogenized on a three-roll mill.
- the ester is heated in a kettle to about 100 ° C. Thereafter, the antioxidant is added and stirred until a clear solution is obtained. The contents of the kettle are cooled and then the metal soap and the PTFE are stirred in homogeneously. Finally, the fat is homogenized on a three-roll mill.
- the alkylated naphthalene is heated in a boiler to about 100 ° C. Thereafter, the antioxidant is added and stirred until a clear solution is obtained. The contents of the kettle are cooled and then the Metal soap and the boron nitride are stirred in homogeneously. Finally, the fat is homogenized on a three-roll mill.
- PFPE, PTFE and metal soap are stirred homogeneously and the resulting fat is homogenized on a three-roll mill.
- the metal soap is stirred into the PFPE and the resulting fat homogenized on a three-roll mill.
- the urea fat is stirred homogeneously with PTFE and PFPE and the resulting fat homogenized on a three-roll mill.
- Table 1 The urea fat is stirred homogeneously with PTFE and PFPE and the resulting fat homogenized on a three-roll mill.
- Base oil 180 est 290 est 400cst 180cst viscosity (40 ° C)
- Dyn Base Oil 190 mPas 450 mPas 550 mPas Viscosity (40 ° C)
- Example Fats 1 to 4 which were determined after 30 hours at 180 ° C, were significantly lower in all cases than the oil separation values of the PFPE greases according to Comparative Examples 1 and 2 or equivalent to the oil deposit of Comparative Example 3. Low oil separation values result a lower oil leakage in the camp and are favorable for long-term lubrication.
- example fat 1 came very close to the excellent friction conditions of certain PFPE-containing fats such as Comparative Example 2 or 3 or was even superior to Comparative Example 1.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Lubricants (AREA)
- Paper (AREA)
- Rolling Contact Bearings (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011113499 | 2011-09-15 | ||
DE102012007673 | 2012-04-16 | ||
DE201210015648 DE102012015648A1 (de) | 2012-04-16 | 2012-07-31 | Hochtemperaturfett |
PCT/EP2012/003600 WO2013037456A1 (de) | 2011-09-15 | 2012-08-27 | Hochtemperaturfett |
Publications (1)
Publication Number | Publication Date |
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EP2756059A1 true EP2756059A1 (de) | 2014-07-23 |
Family
ID=50473915
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP12755795.7A Withdrawn EP2756059A1 (de) | 2011-09-15 | 2012-08-27 | Hochtemperaturfett |
Country Status (10)
Country | Link |
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US (1) | US9334461B2 (ja) |
EP (1) | EP2756059A1 (ja) |
JP (1) | JP5930343B2 (ja) |
CN (1) | CN103946354B (ja) |
BR (1) | BR112014006050A2 (ja) |
CA (1) | CA2847709C (ja) |
CL (1) | CL2014000483A1 (ja) |
MX (1) | MX358375B (ja) |
RU (1) | RU2014114597A (ja) |
WO (1) | WO2013037456A1 (ja) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6269122B2 (ja) * | 2014-02-06 | 2018-01-31 | Nokクリューバー株式会社 | 潤滑グリース組成物 |
DE102014018719A1 (de) * | 2014-12-17 | 2016-06-23 | Klüber Lubrication München Se & Co. Kg | Hochtemperaturschmierstoff für die Lebensmittelindustrie |
DE102014018718A1 (de) * | 2014-12-17 | 2016-06-23 | Klüber Lubrication München Se & Co. Kg | Hochtemperaturschmierstoffe |
US20190048283A1 (en) * | 2015-09-28 | 2019-02-14 | Autonetworks Technologies, Ltd. | Anticorrosive agent and terminal fitted electric wire |
CN106833845B (zh) * | 2017-01-23 | 2020-02-11 | 上海帕卡兴产化工有限公司 | 一种连轧硅钢高清净性轧制油及其制备方法 |
CN111205914A (zh) * | 2020-02-24 | 2020-05-29 | 惠州迪赛恩润滑科技有限公司 | 高温不碳化抗磨膏 |
CN115697933A (zh) | 2020-06-03 | 2023-02-03 | 康宁股份有限公司 | 涂覆了基于二氧化硅的脱模剂的玻璃制品及其陶瓷化方法 |
CN113528221B (zh) * | 2021-06-11 | 2022-10-18 | 深圳市艾润克润滑科技有限公司 | 一种瓦楞纸板线轴承润滑脂及其制备方法 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4298481A (en) | 1979-02-23 | 1981-11-03 | Tenneco Chemicals, Inc. | High temperature grease compositions |
US4604491A (en) * | 1984-11-26 | 1986-08-05 | Koppers Company, Inc. | Synthetic oils |
DE19653589B4 (de) * | 1995-12-20 | 2006-01-05 | Nsk Ltd. | Wälzlager |
JP3238634B2 (ja) * | 1996-09-30 | 2001-12-17 | 電気化学工業株式会社 | グリース組成物 |
US6331509B1 (en) * | 1997-01-31 | 2001-12-18 | Elisha Technologies Co Llc | Corrosion resistant lubricants, greases, and gels |
US5891830A (en) * | 1997-01-31 | 1999-04-06 | Baker Hughes Incorporated | Lubricating grease |
JP2003049074A (ja) * | 2001-05-31 | 2003-02-21 | Nippon Petrochemicals Co Ltd | 熱硬化性樹脂組成物 |
US7312185B2 (en) | 2002-10-31 | 2007-12-25 | Tomlin Scientific Inc. | Rock bit grease composition |
JP2005132900A (ja) * | 2003-10-29 | 2005-05-26 | Nsk Ltd | グリース組成物及び転がり軸受 |
DE102004021812A1 (de) | 2004-04-30 | 2005-12-08 | KLüBER LUBRICATION MüNCHEN KG | Schmierfett, Verfahren zu dessen Herstellung und dessen Verwendung |
CN100358986C (zh) * | 2005-08-05 | 2008-01-02 | 鞍山海华油脂化学有限公司 | 复合高温脲基脂 |
JP2007238755A (ja) * | 2006-03-08 | 2007-09-20 | Kyodo Yushi Co Ltd | グリース組成物及び軸受 |
JP2008239706A (ja) * | 2007-03-26 | 2008-10-09 | Kyodo Yushi Co Ltd | グリース組成物及び軸受 |
CA2687149C (en) * | 2007-06-20 | 2016-01-12 | Kluber Lubrication Munchen Kg | Lubricating grease compositions containing ionic liquids |
DE102009022593A1 (de) * | 2008-06-13 | 2009-12-17 | KLüBER LUBRICATION MüNCHEN KG | Schmierstoffzusammensetzung auf der Basis natürlicher und nachwachsender Rohstoffe |
JP5604061B2 (ja) * | 2009-06-22 | 2014-10-08 | 出光興産株式会社 | グリース組成物 |
CN101880582A (zh) * | 2010-06-29 | 2010-11-10 | 濮阳市航天化工有限公司 | 高温润滑脂及其制备方法 |
-
2012
- 2012-08-27 JP JP2014530108A patent/JP5930343B2/ja not_active Expired - Fee Related
- 2012-08-27 RU RU2014114597/04A patent/RU2014114597A/ru unknown
- 2012-08-27 WO PCT/EP2012/003600 patent/WO2013037456A1/de active Application Filing
- 2012-08-27 CN CN201280044077.8A patent/CN103946354B/zh active Active
- 2012-08-27 MX MX2014002352A patent/MX358375B/es active IP Right Grant
- 2012-08-27 US US14/343,921 patent/US9334461B2/en active Active
- 2012-08-27 CA CA2847709A patent/CA2847709C/en not_active Expired - Fee Related
- 2012-08-27 EP EP12755795.7A patent/EP2756059A1/de not_active Withdrawn
- 2012-08-27 BR BR112014006050A patent/BR112014006050A2/pt not_active Application Discontinuation
-
2014
- 2014-02-27 CL CL2014000483A patent/CL2014000483A1/es unknown
Also Published As
Publication number | Publication date |
---|---|
CN103946354B (zh) | 2016-08-24 |
CN103946354A (zh) | 2014-07-23 |
US20140213492A1 (en) | 2014-07-31 |
CA2847709C (en) | 2016-01-12 |
BR112014006050A2 (pt) | 2017-04-04 |
RU2014114597A (ru) | 2015-10-20 |
US9334461B2 (en) | 2016-05-10 |
CA2847709A1 (en) | 2013-03-21 |
MX2014002352A (es) | 2014-04-25 |
CL2014000483A1 (es) | 2014-08-29 |
JP2014526578A (ja) | 2014-10-06 |
WO2013037456A1 (de) | 2013-03-21 |
JP5930343B2 (ja) | 2016-06-08 |
MX358375B (es) | 2018-08-16 |
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