EP2707543B1 - Rouleau de guidage avec revêtement résistant à la corrosion - Google Patents

Rouleau de guidage avec revêtement résistant à la corrosion Download PDF

Info

Publication number
EP2707543B1
EP2707543B1 EP12715055.5A EP12715055A EP2707543B1 EP 2707543 B1 EP2707543 B1 EP 2707543B1 EP 12715055 A EP12715055 A EP 12715055A EP 2707543 B1 EP2707543 B1 EP 2707543B1
Authority
EP
European Patent Office
Prior art keywords
coating
stainless steel
spray coating
guide roll
steel material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP12715055.5A
Other languages
German (de)
English (en)
Other versions
EP2707543A1 (fr
Inventor
Alexander Etschmaier
Jürgen ANGERLER
Hasso Jungklaus
Goar Hesselmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Voith Patent GmbH
Original Assignee
Voith Patent GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Voith Patent GmbH filed Critical Voith Patent GmbH
Publication of EP2707543A1 publication Critical patent/EP2707543A1/fr
Application granted granted Critical
Publication of EP2707543B1 publication Critical patent/EP2707543B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F1/00Wet end of machines for making continuous webs of paper
    • D21F1/36Guiding mechanisms
    • D21F1/40Rolls
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F3/00Press section of machines for making continuous webs of paper
    • D21F3/02Wet presses
    • D21F3/08Pressure rolls
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21GCALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
    • D21G1/00Calenders; Smoothing apparatus
    • D21G1/02Rolls; Their bearings
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21GCALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
    • D21G1/00Calenders; Smoothing apparatus
    • D21G1/02Rolls; Their bearings
    • D21G1/0246Hard rolls
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49544Roller making
    • Y10T29/4956Fabricating and shaping roller work contacting surface element
    • Y10T29/49563Fabricating and shaping roller work contacting surface element with coating or casting about a core
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12014All metal or with adjacent metals having metal particles
    • Y10T428/12028Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
    • Y10T428/12049Nonmetal component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12542More than one such component
    • Y10T428/12549Adjacent to each other
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12556Organic component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12556Organic component
    • Y10T428/12569Synthetic resin

Definitions

  • the present invention relates to corrosion resistant coatings of guide rolls for conducting screens or felts in papermaking machines.
  • US-A-5,283,121 discloses a method of applying an anticorrosive coating to the metal body of a paper machine roll wherein the surface of the body is provided with a thermal spray coating of a stainless steel material and a layer of fluoropolymer applied to the surface of the thermal spray stainless steel coating.
  • the anticorrosive coating of rolls or roll cores currently uses galvanic hard chrome layers and hard metal layers applied by thermal spraying.
  • the galvanic chrome plating offers cost-effective and effective corrosion protection, but is due to the toxicity of the galvanic baths used to classify as polluting process.
  • a mechanical cleaning of hard chromium plating is difficult due to the brittle behavior of chromium.
  • hard metal coatings usually a composite material embedded in a cobalt-nickel matrix tungsten carbide hard materials is used, which with a thermal spraying method, such as. B.
  • HVOF H IgH V elocity- O xygen- F uel, high velocity flame spraying
  • the application of thermal hard metal spray coatings takes place in several strokes, ie in several sub-layers to ensure the physical homogeneity of the coating.
  • Thermally sprayed hard metal coatings are characterized by good corrosion protection and high abrasion resistance.
  • the adhesion of impurities arising during a paper production is comparatively low on hardmetal surfaces, so that they are relatively easy to clean by Beschabtation.
  • the production of thermal hard metal spray coatings is very expensive compared to the chrome plating.
  • Corresponding corrosion protection can be achieved with a method according to claim 1 comprising steps of providing a thermal spray coating apparatus, providing a stainless steel material, coating at least a portion of the surface of the guide roll by applying the stainless steel material using the thermal spray coating apparatus and sealing the applied coating with a polymeric material comprising an epoxy resin.
  • An inexpensively and environmentally produced corrosion-resistant guide roll according to claim 16, comprising a metallic base body, a thermal spray coating of a stainless steel material covering at least a portion of the surface of the metallic base body and a polymeric sealing layer applied to the surface of the thermal spray stainless steel coating polymeric sealant layer comprises an epoxy resin.
  • the provided thermal spray coating apparatus is configured to perform high velocity flame spraying or laser spraying. These thermal spray processes do not lead to any significant metallurgical change of the spray material, so that the metallurgical Composition of thermal spray coatings prepared by these methods corresponds to the starting material used for the coating.
  • the stainless steel material used as the starting material for the coating is provided in the form of fine powder whose particles plastically deform on impact with the surface to be coated, whereby very dense layers of low porosity can be produced in a simple manner.
  • the provided apparatus for thermal spray coating for performing arc spraying is formed in which the coating starting material is melted in an arc and transferred by means of a carrier gas to the workpiece to be coated.
  • Arc spraying is particularly suitable for applying very well-adhering layers with thicknesses of more than 200 microns to several millimeters on large surfaces.
  • the stainless steel material is preferably provided in wire form for ease of feeding.
  • a stainless steel material is preferably used, which is formed by a chromium-nickel steel having a composition according to one of the material numbers 1.4401, 1.4404, 1.4406, 1.4435, 1.44036 or 1.4440.
  • Stainless steels of this material number also meet the standards 316 L and 316 of the American Iron and Steel Institute (AISI).
  • AISI American Iron and Steel Institute
  • Very dense, low-porous coatings are advantageous by applying the stainless steel material on a surface of the roll component in several strokes, ie by means of achieved several successive successive deposited sublayers. Dense thermal coatings with thicknesses of about 50 to 200 ⁇ m can already be achieved with 4 to 6 strokes.
  • the further material being a carbide, boride or nitride or a mixture thereof or a mixture can be with a metal of the 4th, 5th or 6th subgroup.
  • the coating can be applied by the same coating methods as the stainless steel layer, wherein the thickness can be a further 1 to 3 strokes. As a result, a coating which, although not closed, but serving at least one compacting purpose, is formed on the stainless steel, which ensures increased corrosion resistance.
  • the polymeric material for sealing the spray coating comprises an epoxy resin, which wets a stainless steel surface in the non-crosslinked as well as in the partially crosslinked state well and thus guarantees a solid cohesive connection. Furthermore, the good wettability also ensures that the resin penetrates into the recesses of the surface and completely fills it, so that no voids form at the interface of the spray coating with the polymeric sealing layer.
  • the polymeric material for sealing the sprayed coating comprises a silicone-polyester resin which combines good wetting of stainless steel sprayed layers with a non-stick and dirt-repellent action.
  • fillers can also be embedded in the polymeric material of the sealant layer for improvement the non-stick and dirt-repellent properties to achieve their surface.
  • materials which contain polyfluoroethylene and in particular polytetrafluoroethylene are preferably used for the fillers.
  • the fillers in the form of particles and in particular in the form of particles with average diameters in the range of 0.1 to 5 microns are embedded in the polymeric base material of the seal.
  • Figures 1A and 1B is for illustrative purposes only and does not represent a representation of a real component. Sizes and ratios of the individual components are therefore selected with regard to a clear presentation of the circumstances and differ from those of an actual embodiment.
  • FIG. 1A shows a detail of a roll component 10 provided with a corrosion-protected surface.
  • the illustrated embodiment of a roll component has a roll core 1, on the surface of which a corrosion protection layer 5 formed by a spray coating 4 and a seal 3 applied thereon is arranged.
  • the anticorrosion layer 5 preferably covers all Surface areas of the roll component 10, which are exposed to the corrosive media occurring during normal use of the roller.
  • the spray coating 4 is constructed in the illustrated embodiment of individual stainless steel particles 2, which adjoin one another positively to form a closed and thus dense layer.
  • a suitably corrosion-protected roller is suitable for use as a guide roller for screens or felts in papermaking machines.
  • the stainless steel material of the spray coating 4 is preferably a stainless chromium-nickel steel having a composition according to one of the material numbers 1.4401 (short name: X5CrNiMo17-12-2), 1.4404 (short name: X2CrNiMo17-12-2), 1.4406 (short name: X2CrNiMoN17-11 -2), 1.4435 (short name: X2CrNiMo18-14-3), 1.4436 (short name: X3CrNiMo17-13-3) or 1.4440 (short name: X2CrNiMo19-12), which are distinguished by their high resistance to corrosion and acids.
  • the steel types mentioned also meet the standards 316 and 316 L of the American Iron and Steel Institute (AISI).
  • a thermal spraying method is preferably used, the basic steps in FIG. 2A are presented.
  • Thermal spray coating is to be understood as a surface coating process in which the coating material is ab-, on or melted and accelerated as a spray particle is accelerated via a gas stream in the direction of the surface to be coated.
  • the surface of the workpiece to be coated is only slightly thermally loaded. When hitting the workpiece surface, the spray particles are usually flattened and connect by mechanical clamping. As a result, crack-free coatings with a homogeneous microstructure, low porosity and good bonding to the workpiece can be achieved.
  • the melting of the wire-shaped spray or coating material is performed with an electric arc
  • the high-speed flame spraying is the melting of the spray material particles in the fuel-oxygen high-velocity flame and laser spraying with the laser beam.
  • other than the exemplified thermal spray coating methods may be used.
  • step S2 of the in FIG. 2A illustrated method for applying a corrosion protection coating on a roll component of the spray material is provided in the form of a stainless steel material, preferably using stainless stainless steels, such as chromium-nickel steels of AISI standard 316 L or 316, which also with the material numbers 1.4401, 1.4404 , 1.4406, 1.4435, 1.44036 or 1.4440.
  • the form in which the spray material is provided depends on the device used for coating. In arc spraying, the coating material is provided, for example, in wire form, in high-speed flame spraying in powder form.
  • the order of magnitude of the average particle sizes of such powders is selected as a function of the desired coating thickness and can be, for example, about 50 ⁇ m for coating thicknesses of approximately 100 to a few 100 ⁇ m, since the particles are flattened when they hit the workpiece surface.
  • a surface or a part of a surface of the workpiece 10 is coated with the spray material using the apparatus.
  • the application of the spray material is preferably carried out in several strokes.
  • the number of strokes was determined by the process parameters set on the coating apparatus, possibly the size of the powder particles, the distance between the workpiece and the part of the apparatus emitting the spray material and the desired coating thickness. Usually, the number of strokes is determined experimentally.
  • the porosity of the sprayed coating can also be influenced by the process parameters of the coating process, whereby porosities of less than 0.5% can be achieved, in particular with high-speed flame spraying. By porosity here is the area fraction to be understood, which is taken in a penetrating the investigated material transverse grinding of the cavities contained therein.
  • step S3 The stainless steel sprayed coating applied in step S3 is finally sealed in step S4 by application of a polymeric material, whereupon the corrosion protection coating process is completed in step S5, apart from possible surface finishing.
  • Thermal spray coating processes are characterized by the possibility of producing coating layers with very low porosity, ie with few cavities formed in the coating material.
  • the individual cavities are usually not connected to each other, so that the pores create no passages from the surface of the coating to the surface of the base material, via which a penetration of electrolytically acting substances could take place.
  • coatings are therefore dense for the process water and vapors associated with papermaking.
  • the coating surface is sealed with a polymeric material upon completion of the thermal spray coating.
  • the sealing effect is not removed by a possible wear of the sealing layer 3 to the exposure of the upper regions of the spray coating 4, the surface of the spray coating is not ideally flat, but has a spatial contouring, in which the interfaces of adjoining coating particles arranged almost exclusively in depressions are.
  • Suitable polymers are epoxy resins and epoxy resins with filler particles embedded therein, for example of a polyfluoroethylene (PFE) and in particular of polytetrafluoroethylene (PTFE). Since epoxy resin in the non-crosslinked or partially crosslinked state shows good wetting of the coating base material, it can also penetrate into depressions of the coating surface with an unfavorable aspect ratio. The viscosity of the epoxy resin can be reduced by the addition of solvents, such as alcohols or ketones, to adjust the wetting to the surface contour of the coating 4.
  • the sealing process can be done by dipping, by spraying, or by using brushing tools such as a brush. As brushing or filling done.
  • DJ2600 is applied a corresponding one of one of the AISI standard 316 L steel formed spray material in 4 strokes on the surface of a steel roller core to form an approximately 90 micron thick spray coating using a high-speed flame spraying apparatus "Diamond Jet Hybrid ®". The resulting thermal spray coating is then sealed with a colorless two-component epoxy resin-based system.
  • FIG. 1B is in the same view as in Figure 1A a second embodiment of the invention shown.
  • an additional second coating 6 is provided here, which is arranged on the spray coating 4 and provides the function of compacting the stainless steel particles 2. This embodiment is particularly suitable for use in highly loaded positions appropriate.
  • carbides there are in particular carbides, nitrides or borides and mixtures thereof and mixtures with other metals of the 4th, 5th or 6th subgroup of the Periodic Table of the Elements application.
  • a preferred embodiment is tungsten carbide.
  • this hard metal layer does not form a dense, closed layer, it densifies the underlying layer due to the high density, for example of tungsten, in such a way that increased corrosion resistance can be assumed.
  • the invention described enables effective, long-lasting and cost-effective corrosion protection of guide rolls for use in paper machines.

Landscapes

  • Coating By Spraying Or Casting (AREA)
  • Rolls And Other Rotary Bodies (AREA)

Claims (20)

  1. Procédé d'application d'un revêtement anticorrosion sur un rouleau de guidage pour le guidage de tamis ou de feutres dans une machine pour la fabrication d'une bande de matière fibreuse cellulosique telle qu'une bande de papier, carton ou non-tissé, dans lequel le procédé comprend les étapes suivantes :
    - la préparation d'un dispositif pour le revêtement par pulvérisation thermique (S1),
    - la préparation d'un matériau en acier inoxydable (S2),
    - le revêtement d'au moins une partie de la surface du rouleau de guidage par application du matériau en acier inoxydable en utilisant le dispositif pour le revêtement par pulvérisation thermique (S3),
    - le scellage du revêtement (4) appliqué avec un matériau polymère (S4), le matériau polymère comprenant une résine époxyde.
  2. Procédé selon la revendication 1, dans lequel un revêtement (6) supplémentaire en un matériau supplémentaire est appliqué sur le matériau en acier inoxydable (S6).
  3. Procédé selon la revendication 2, dans lequel le matériau supplémentaire est un carbure, un nitrure ou un borure ou un mélange de ceux-ci ou un mélange avec un métal du groupe de transition 4, 5 ou 6.
  4. Procédé selon l'une quelconque des revendications 1 à 3, dans lequel le dispositif préparé pour le revêtement par pulvérisation thermique est configuré pour la réalisation d'une pulvérisation à la flamme à vitesse élevée ou d'une pulvérisation laser.
  5. Procédé selon l'une quelconque des revendications 1 à 4, dans lequel le matériau en acier inoxydable est préparé sous la forme d'une poudre fine.
  6. Procédé selon l'une quelconque des revendications 1 à 3, dans lequel le dispositif préparé pour le revêtement par pulvérisation thermique est configuré pour la réalisation d'une projection à l'arc électrique.
  7. Procédé selon la revendication 1 ou 6, dans lequel le matériau en acier inoxydable est préparé sous la forme de fils.
  8. Procédé selon l'une quelconque des revendications précédentes, dans lequel le matériau en acier inoxydable est formé par un acier au chrome-nickel ayant une composition selon un des numéros de matériau 1,4401, 1,4404, 1,4406, 1,4435, 1,4436 ou 1,4440.
  9. Procédé selon l'une quelconque des revendications précédentes, dans lequel le revêtement d'une surface du rouleau de guidage a lieu par application du matériau en acier inoxydable (S3) et du matériau supplémentaire (S6) en plusieurs courses.
  10. Procédé selon la revendication 9, dans lequel le nombre de courses pour l'application du matériau en acier inoxydable est d'au moins 4 et d'au plus 6.
  11. Procédé selon la revendication 9 ou 10, dans lequel le nombre de courses pour l'application du matériau supplémentaire est d'au moins 1 et d'au plus 3.
  12. Procédé selon l'une quelconque des revendications précédentes, dans lequel le matériau polymère pour le scellage du revêtement pulvérisé (4) comprend une résine de polyester de silicone.
  13. Procédé selon l'une quelconque des revendications précédentes, dans lequel le matériau polymère pour le scellage du revêtement pulvérisé (4) comprend un polymère dans lequel sont incorporées des charges.
  14. Procédé selon la revendication 13, dans lequel des charges contenant du polyfluoroéthylène et notamment du polytétrafluoroéthylène sont utilisées en tant que charges.
  15. Procédé selon la revendication 13 ou 14, dans lequel les charges sont utilisées sous la forme de particules et notamment sous la forme de particules ayant des diamètres moyens dans la plage allant de 0,1 à 5 µm.
  16. Rouleau de guidage pour le guidage de tamis ou de feutres dans une machine pour la fabrication d'une bande de matière fibreuse cellulosique telle qu'une bande de papier, carton ou non-tissé, dans lequel le rouleau de guidage comprend un corps de base métallique (1), un revêtement pulvérisé thermique (4) en un matériau en acier inoxydable recouvrant au moins une partie de la surface du corps de base métallique et une couche de scellage polymère (3) appliquée sur la surface du revêtement pulvérisé thermique en acier inoxydable, le matériau de la couche de scellage polymère (3) comprenant une résine époxyde.
  17. Rouleau de guidage selon la revendication 16, dans lequel un revêtement (6) en un matériau supplémentaire recouvrant au moins une partie de la surface du revêtement pulvérisé thermique en acier inoxydable est prévu.
  18. Rouleau de guidage selon la revendication 17, dans lequel le matériau supplémentaire est un carbure, un borure ou un nitrure ou un mélange de ceux-ci ou un mélange avec un métal du groupe de transition 4, 5 ou 6.
  19. Rouleau de guidage selon l'une quelconque des revendications 16 à 18, dans lequel le matériau en acier inoxydable est formé par un acier au chrome-nickel ayant une composition selon un des numéros de matériau 1,4401, 1,4404, 1,4440 ou 1,4435.
  20. Rouleau de guidage selon l'une quelconque des revendications 17 à 19, dans lequel le matériau de la couche de scellage polymère (3) comprend une résine de polyester de silicone.
EP12715055.5A 2011-05-13 2012-04-10 Rouleau de guidage avec revêtement résistant à la corrosion Active EP2707543B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102011075810A DE102011075810A1 (de) 2011-05-13 2011-05-13 Korrosionsbeständige walzenbeschichtung
PCT/EP2012/056422 WO2012156152A1 (fr) 2011-05-13 2012-04-10 Enduction par rouleau résistante à la corrosion

Publications (2)

Publication Number Publication Date
EP2707543A1 EP2707543A1 (fr) 2014-03-19
EP2707543B1 true EP2707543B1 (fr) 2015-03-04

Family

ID=45976360

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12715055.5A Active EP2707543B1 (fr) 2011-05-13 2012-04-10 Rouleau de guidage avec revêtement résistant à la corrosion

Country Status (5)

Country Link
US (1) US9322132B2 (fr)
EP (1) EP2707543B1 (fr)
CN (1) CN103534410A (fr)
DE (1) DE102011075810A1 (fr)
WO (1) WO2012156152A1 (fr)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012213648A1 (de) * 2012-08-02 2013-09-26 Voith Patent Gmbh Verfahren zum Beschichten einer Walze und Walze
WO2015000642A1 (fr) * 2013-07-04 2015-01-08 Voith Patent Gmbh Garniture de rouleau à faible énergie de surface
US9963395B2 (en) 2013-12-11 2018-05-08 Baker Hughes, A Ge Company, Llc Methods of making carbon composites
US9325012B1 (en) 2014-09-17 2016-04-26 Baker Hughes Incorporated Carbon composites
US10315922B2 (en) 2014-09-29 2019-06-11 Baker Hughes, A Ge Company, Llc Carbon composites and methods of manufacture
US10480288B2 (en) 2014-10-15 2019-11-19 Baker Hughes, A Ge Company, Llc Articles containing carbon composites and methods of manufacture
US9962903B2 (en) 2014-11-13 2018-05-08 Baker Hughes, A Ge Company, Llc Reinforced composites, methods of manufacture, and articles therefrom
US9745451B2 (en) 2014-11-17 2017-08-29 Baker Hughes Incorporated Swellable compositions, articles formed therefrom, and methods of manufacture thereof
US11097511B2 (en) * 2014-11-18 2021-08-24 Baker Hughes, A Ge Company, Llc Methods of forming polymer coatings on metallic substrates
US9726300B2 (en) 2014-11-25 2017-08-08 Baker Hughes Incorporated Self-lubricating flexible carbon composite seal
US10300627B2 (en) 2014-11-25 2019-05-28 Baker Hughes, A Ge Company, Llc Method of forming a flexible carbon composite self-lubricating seal
US9714709B2 (en) 2014-11-25 2017-07-25 Baker Hughes Incorporated Functionally graded articles and methods of manufacture
US9840887B2 (en) 2015-05-13 2017-12-12 Baker Hughes Incorporated Wear-resistant and self-lubricant bore receptacle packoff tool
US10161082B1 (en) * 2015-07-03 2018-12-25 Fluoron Inc. Contact surface having a composite release layer and method of making
CN105625081B (zh) * 2016-03-17 2017-05-10 安徽山鹰纸业股份有限公司 造纸机湿部导辊及其运用
US10125274B2 (en) 2016-05-03 2018-11-13 Baker Hughes, A Ge Company, Llc Coatings containing carbon composite fillers and methods of manufacture
US10344559B2 (en) 2016-05-26 2019-07-09 Baker Hughes, A Ge Company, Llc High temperature high pressure seal for downhole chemical injection applications
CN106111486A (zh) * 2016-07-04 2016-11-16 深圳市星源材质科技股份有限公司 一种防止滚筒表面粘附的处理方法
CN107798204B (zh) * 2017-12-08 2018-10-26 山东大学 一种复杂型面工件切向渐变热喷涂涂层设计方法
CN110552043B (zh) * 2019-09-26 2022-02-22 长安大学 一种高耐蚀镁合金轮毂表面处理方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3526939A (en) * 1968-12-19 1970-09-08 Ahlstroem Oy Method for covering press rolls
FR2156954A5 (fr) * 1971-10-12 1973-06-01 Batteux Armand
US3942230A (en) * 1974-03-05 1976-03-09 Plasma Coatings, Inc. Composite metallic roll with release surface and method of making same
US4856161A (en) * 1985-01-09 1989-08-15 Valmet Oy Press roll
US4609577A (en) * 1985-01-10 1986-09-02 Armco Inc. Method of producing weld overlay of austenitic stainless steel
FI86566C (fi) 1989-10-27 1992-09-10 Valmet Paper Machinery Inc Vals foer anvaendning vid pappersframstaellning och foerfarande foer framstaellning av valsen.
CA2052925C (fr) * 1990-10-08 1996-08-06 Atsuo Watanabe Rouleau presseur pour machine a papier
US5283121A (en) * 1991-11-08 1994-02-01 Bordner Barry A Corrosion and abrasion resistant industrial roll coating with non-sticking properties
US5268045A (en) * 1992-05-29 1993-12-07 John F. Wolpert Method for providing metallurgically bonded thermally sprayed coatings
DE69314966T2 (de) * 1992-10-16 1998-03-26 Beloit Technologies Inc Verfahren zur herstellung einer presswalzenbekleidung
US5268405A (en) * 1993-03-31 1993-12-07 E. I. Du Pont De Nemours And Company Low temperature perfluoroelastomers
US5979314A (en) * 1994-08-19 1999-11-09 Varn Products Company, Inc. Lithographic dampener
US6339883B1 (en) * 2000-02-25 2002-01-22 Voith Sulzer Paper Technology North America, Inc. Method of making a roll for paper-making machine
JP4871610B2 (ja) * 2006-02-27 2012-02-08 ヤマウチ株式会社 セラミックス−樹脂複合ロールおよびその製造方法
CN101443472A (zh) * 2006-05-12 2009-05-27 普莱克斯S.T.技术有限公司 有热喷涂层的工作辊
DE102006023567A1 (de) * 2006-05-19 2007-11-22 Schaeffler Kg Wälzlagerbauteil und Verfahren zur Herstellung eines solchen
CN101134868B (zh) * 2006-08-31 2010-05-12 上海宝钢设备检修有限公司 一种热喷涂涂层封孔剂及其使用方法
JP5803212B2 (ja) * 2011-03-30 2015-11-04 セイコーエプソン株式会社 ノズル吐出量の補正方法、液滴の吐出方法及び有機el素子の製造方法
DE102012213648A1 (de) * 2012-08-02 2013-09-26 Voith Patent Gmbh Verfahren zum Beschichten einer Walze und Walze

Also Published As

Publication number Publication date
EP2707543A1 (fr) 2014-03-19
US20140127526A1 (en) 2014-05-08
DE102011075810A1 (de) 2012-11-15
WO2012156152A1 (fr) 2012-11-22
CN103534410A (zh) 2014-01-22
US9322132B2 (en) 2016-04-26

Similar Documents

Publication Publication Date Title
EP2707543B1 (fr) Rouleau de guidage avec revêtement résistant à la corrosion
DE102006004769B4 (de) Oberflächenkonditionierung für thermische Spritzschichten
DE69020507T2 (de) Ablösung von plasmagespritzten oder gesinterten Beschichtungen mittels eines Wasserstrahls.
DE60111658T2 (de) Beschichtung auf faserverstärkte Verbundmaterialien
EP1943369B1 (fr) Procede de revetement d'un composant
DE102007023418B4 (de) Verfahren zum Aufrauen von Oberflächen für die spätere Aufbringung von Spritzschichten, entspechend aufgeraute Bauteile sowie beschichtete Metallbauteile
DE69016161T2 (de) Walze für die Papiererzeugung und Verfahren zu deren Herstellung.
EP2480720B1 (fr) Couchage à la lame
DE8329109U1 (de) Abstreifmesser oder Schaber
EP2150630A2 (fr) Élément de machine appartenant à une paire coulissante et son procédé de production
EP2651632B1 (fr) Revêtement de lame imprégné
WO2006021507A1 (fr) Surface a microstructure diminuant l'adherence et procede de fabrication associe
DE102010022593A1 (de) Verfahren zum Kaltgasspritzen einer Schicht mit einer metallischen Gefügephase und einer Gefügephase aus Kunststoff, Bauteil mit einer solchen Schicht sowie Verwendungen dieses Bauteils
EP3296054B1 (fr) Procédé de fabrication d'une pièce micro-usinée par érosion au laser
DE19883017B4 (de) Oberflächenbehandlungsverfahren und Elektrode für ein Oberflächenbehandlungsverfahren
EP2994572B1 (fr) Cylindre
EP0836931B1 (fr) Procédé pour la fabrication d'un corps stratifié
EP2729615B2 (fr) Racloir de nettoyage anti-salissures
EP4010176A1 (fr) Procédé de production d'un constituant et constituant de ce dernier
DE202012012592U1 (de) Walze
DE102019213464B4 (de) Verfahren zum Herstellen eines Reibbremskörpers für eine Reibbremse eines Kraftfahrzeugs
DE102004006857B4 (de) Gradientenschicht und Verfahren zu ihrer Herstellung
DE10354507A1 (de) Beschichtung von mit einer Materialbahn in Kontakt tretende Einrichtungen einer Papiermaschine
DE102020202896A1 (de) Auftrags-/Schöpfwalze und Verfahren zu seiner Herstellung
EP3563443B1 (fr) Procédé de fabrication d'une plaque de distribution destinée à une pile à combustible et/ou un électrolyseur

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20131213

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

DAX Request for extension of the european patent (deleted)
GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20141015

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 714031

Country of ref document: AT

Kind code of ref document: T

Effective date: 20150415

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502012002437

Country of ref document: DE

Effective date: 20150416

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20150304

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150604

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150605

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150706

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150704

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 502012002437

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150430

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150430

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20151231

26N No opposition filed

Effective date: 20151207

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150504

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150410

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20160410

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160410

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20120410

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150430

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150410

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 714031

Country of ref document: AT

Kind code of ref document: T

Effective date: 20170410

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170410

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20150304

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20240418

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FI

Payment date: 20240425

Year of fee payment: 13