EP2692842B1 - Concentrated liquid detergent compositions - Google Patents

Concentrated liquid detergent compositions Download PDF

Info

Publication number
EP2692842B1
EP2692842B1 EP12178620.6A EP12178620A EP2692842B1 EP 2692842 B1 EP2692842 B1 EP 2692842B1 EP 12178620 A EP12178620 A EP 12178620A EP 2692842 B1 EP2692842 B1 EP 2692842B1
Authority
EP
European Patent Office
Prior art keywords
composition according
surfactant
moieties
soil release
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP12178620.6A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2692842A1 (en
Inventor
Julie Unilever R&D Port Sunlight BENNETT
Alyn James Unilever R&D Port Sunlight PARRY
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to EP12178620.6A priority Critical patent/EP2692842B1/en
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Priority to AU2013298898A priority patent/AU2013298898B2/en
Priority to BR112015001487-9A priority patent/BR112015001487B1/pt
Priority to ES13733305.0T priority patent/ES2569375T3/es
Priority to IN104MUN2015 priority patent/IN2015MN00104A/en
Priority to PL13733305.0T priority patent/PL2880143T3/pl
Priority to CN201380040587.2A priority patent/CN104508104B/zh
Priority to EP13733305.0A priority patent/EP2880143B1/en
Priority to MX2015000894A priority patent/MX2015000894A/es
Priority to PCT/EP2013/063967 priority patent/WO2014019792A1/en
Priority to ARP130102693A priority patent/AR091933A1/es
Publication of EP2692842A1 publication Critical patent/EP2692842A1/en
Application granted granted Critical
Publication of EP2692842B1 publication Critical patent/EP2692842B1/en
Priority to ZA2015/00456A priority patent/ZA201500456B/en
Priority to PH12015500129A priority patent/PH12015500129A1/en
Priority to CL2015000213A priority patent/CL2015000213A1/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3715—Polyesters or polycarbonates

Definitions

  • the terminal end cap X on the EO blocks is preferably as small as possible.
  • X is preferably methyl, ethyl, or n-butyl and most preferably methyl or n-butyl.
  • the mid block may be formed by condensation of methyl esters of terephthalic acid with the appropriate aliphatic diol, preferably using an excess of one of them as set forth in more detail in the following examples. If the dicarboxylic acid is used in alkyl ester form, the reaction is suitably carried out in the presence of a base catalyst, at an elevated temperature, for example, 120 to 180°C, and, if desired, under reduced pressure.
  • the lower alcohol, normally methanol, generated during the reaction is distilled off.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
EP12178620.6A 2012-07-31 2012-07-31 Concentrated liquid detergent compositions Active EP2692842B1 (en)

Priority Applications (14)

Application Number Priority Date Filing Date Title
EP12178620.6A EP2692842B1 (en) 2012-07-31 2012-07-31 Concentrated liquid detergent compositions
PCT/EP2013/063967 WO2014019792A1 (en) 2012-07-31 2013-07-02 Concentrated liquid detergent compositions
ES13733305.0T ES2569375T3 (es) 2012-07-31 2013-07-02 Composiciones detergentes líquidas concentradas
IN104MUN2015 IN2015MN00104A (cs) 2012-07-31 2013-07-02
PL13733305.0T PL2880143T3 (pl) 2012-07-31 2013-07-02 Skoncentrowane ciekłe detergentowe kompozycje
CN201380040587.2A CN104508104B (zh) 2012-07-31 2013-07-02 浓缩液体洗涤剂组合物
EP13733305.0A EP2880143B1 (en) 2012-07-31 2013-07-02 Concentrated liquid detergent compositions
MX2015000894A MX2015000894A (es) 2012-07-31 2013-07-02 Composiciones detergentes liquidas concentradas.
AU2013298898A AU2013298898B2 (en) 2012-07-31 2013-07-02 Concentrated liquid detergent compositions
BR112015001487-9A BR112015001487B1 (pt) 2012-07-31 2013-07-02 composição detergente líquida alcalina concentrada
ARP130102693A AR091933A1 (es) 2012-07-31 2013-07-30 Composiciones detergentes liquidas concentradas
ZA2015/00456A ZA201500456B (en) 2012-07-31 2015-01-22 Concentrated liquid detergent compositions
PH12015500129A PH12015500129A1 (en) 2012-07-31 2015-01-22 Concentrated liquid detergent compositions
CL2015000213A CL2015000213A1 (es) 2012-07-31 2015-01-28 Composiciones detergentes líquidas concentradas que comprende al menos el 0,25% en peso de polimero de liberacion de la suciedad.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP12178620.6A EP2692842B1 (en) 2012-07-31 2012-07-31 Concentrated liquid detergent compositions

Publications (2)

Publication Number Publication Date
EP2692842A1 EP2692842A1 (en) 2014-02-05
EP2692842B1 true EP2692842B1 (en) 2014-07-30

Family

ID=48745955

Family Applications (2)

Application Number Title Priority Date Filing Date
EP12178620.6A Active EP2692842B1 (en) 2012-07-31 2012-07-31 Concentrated liquid detergent compositions
EP13733305.0A Active EP2880143B1 (en) 2012-07-31 2013-07-02 Concentrated liquid detergent compositions

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP13733305.0A Active EP2880143B1 (en) 2012-07-31 2013-07-02 Concentrated liquid detergent compositions

Country Status (13)

Country Link
EP (2) EP2692842B1 (cs)
CN (1) CN104508104B (cs)
AR (1) AR091933A1 (cs)
AU (1) AU2013298898B2 (cs)
BR (1) BR112015001487B1 (cs)
CL (1) CL2015000213A1 (cs)
ES (1) ES2569375T3 (cs)
IN (1) IN2015MN00104A (cs)
MX (1) MX2015000894A (cs)
PH (1) PH12015500129A1 (cs)
PL (1) PL2880143T3 (cs)
WO (1) WO2014019792A1 (cs)
ZA (1) ZA201500456B (cs)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11046919B2 (en) 2018-06-26 2021-06-29 The Procter & Gamble Company Liquid laundry detergent composition
EP4003603A1 (en) * 2019-07-24 2022-06-01 Basf Se Collector composition

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX380468B (es) 2012-07-31 2025-03-12 Clariant Int Ltd Poliésteres.
BR112015001754B1 (pt) 2012-07-31 2021-03-16 Unilever Ip Holdings B.V. composição detergente líquida alcalina para lavar roupa
ES2728001T3 (es) 2013-03-28 2019-10-21 Procter & Gamble Composiciones de limpieza que contienen una polieteramina
CN106471111B (zh) * 2014-07-09 2020-04-07 荷兰联合利华有限公司 洗衣液组合物
EP2987848A1 (en) 2014-08-19 2016-02-24 The Procter & Gamble Company Method of laundering a fabric
US9617502B2 (en) 2014-09-15 2017-04-11 The Procter & Gamble Company Detergent compositions containing salts of polyetheramines and polymeric acid
JP6399704B2 (ja) * 2014-12-26 2018-10-03 ライオン株式会社 繊維製品用の液体洗浄剤
JP6521507B2 (ja) * 2014-12-29 2019-05-29 ライオン株式会社 繊維製品用の液体洗浄剤
CA2973502A1 (en) * 2015-01-21 2016-07-28 Basf Se Cleaning composition and method of forming the same
JP6638133B2 (ja) * 2015-10-02 2020-01-29 ライオン株式会社 衣料用液体洗浄剤
EP3371292B1 (en) 2015-11-02 2021-04-14 Colgate-Palmolive Company Hard surface cleaning compositions
EP3433346B1 (en) 2016-03-21 2020-12-30 Unilever PLC Laundry detergent composition
EP3440172B1 (en) 2016-04-08 2019-08-21 Unilever PLC Laundry detergent composition
WO2018108382A1 (en) 2016-12-15 2018-06-21 Unilever Plc Laundry detergent composition
CN110914397B (zh) 2017-05-10 2021-04-13 荷兰联合利华有限公司 洗衣洗涤剂组合物
EP3622045B1 (en) 2017-05-10 2021-03-10 Unilever PLC, a company registered in England and Wales under company no. 41424 of Laundry detergent composition
EP3802765B1 (en) 2018-05-24 2024-12-18 Clariant International Ltd Soil release polyesters for use in detergent compositions
CN108949394B (zh) * 2018-08-14 2020-09-11 广州立白企业集团有限公司 一种基本不含增溶剂的浓缩型液体洗涤剂组合物
WO2020109227A1 (en) 2018-11-28 2020-06-04 Unilever N.V. Large particles
BR112022018106A2 (pt) 2020-03-11 2022-10-25 Unilever Ip Holdings B V Composição sólida de limpeza, método para redução do número de enxágues e uso de uma combinação
WO2022043269A1 (en) 2020-08-26 2022-03-03 Unilever Ip Holdings B.V. Detergent composition comprising isethionate surfactant
WO2025045966A1 (en) 2023-08-30 2025-03-06 Unilever Ip Holdings B.V. Solid laundry composition
WO2025045980A1 (en) 2023-08-30 2025-03-06 Unilever Ip Holdings B.V. Solid laundry composition
WO2025045955A1 (en) 2023-08-30 2025-03-06 Unilever Ip Holdings B.V. Solid laundry composition
WO2025045923A1 (en) 2023-08-30 2025-03-06 Unilever Ip Holdings B.V. Solid laundry composition
WO2025045870A1 (en) 2023-08-30 2025-03-06 Unilever Ip Holdings B.V. Solid laundry composition
WO2025045942A1 (en) 2023-08-30 2025-03-06 Unilever Ip Holdings B.V. Solid laundry composition

Family Cites Families (15)

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US2182306A (en) 1935-05-10 1939-12-05 Ig Farbenindustrie Ag Polymerization of ethylene imines
US2208095A (en) 1937-01-05 1940-07-16 Ig Farbenindustrie Ag Process of producing insoluble condensation products containing sulphur and nitrogen
US2553696A (en) 1944-01-12 1951-05-22 Union Carbide & Carbon Corp Method for making water-soluble polymers of lower alkylene imines
US2806839A (en) 1953-02-24 1957-09-17 Arnold Hoffman & Co Inc Preparation of polyimines from 2-oxazolidone
BE615597A (cs) 1958-06-19
CA1049367A (en) * 1974-06-25 1979-02-27 The Procter And Gamble Company Liquid detergent compositions having soil release properties
US4702857A (en) 1984-12-21 1987-10-27 The Procter & Gamble Company Block polyesters and like compounds useful as soil release agents in detergent compositions
US4759876A (en) 1985-03-19 1988-07-26 Colgate-Palmolive Company Stable soil release promoting enzymatic liquid detergent composition
US4711730A (en) 1986-04-15 1987-12-08 The Procter & Gamble Company Capped 1,2-propylene terephthalate-polyoxyethylene terephthalate polyesters useful as soil release agents
DE69208549T3 (de) * 1991-07-17 1999-04-22 Unilever N.V., Rotterdam Wasserlösliches oder in Wasser dispergierbares Copolymer mit UV-Strahlen absorbierendem Monomer enthaltendes Wäschepflegemittel
DE102004056785A1 (de) 2004-11-24 2006-06-01 Sasol Germany Gmbh Fließfähige, amphiphile und nichtionische Oligoester
WO2007138053A1 (en) 2006-05-31 2007-12-06 Basf Se Amphiphilic graft polymers based on polyalkylene oxides and vinyl esters
DE602006020853D1 (de) * 2006-07-07 2011-05-05 Procter & Gamble Waschmittelzusammensetzungen
EP2300586B1 (en) 2008-06-16 2015-04-08 Unilever PLC Improvements relating to fabric cleaning
BR112013019386B1 (pt) * 2011-01-31 2021-04-06 Unilever Ip Holdings B.V. Composição aquosa líquida detergente concentrada isotrópica alcalina

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11046919B2 (en) 2018-06-26 2021-06-29 The Procter & Gamble Company Liquid laundry detergent composition
EP4003603A1 (en) * 2019-07-24 2022-06-01 Basf Se Collector composition

Also Published As

Publication number Publication date
WO2014019792A1 (en) 2014-02-06
CL2015000213A1 (es) 2015-06-12
ZA201500456B (en) 2016-09-28
AR091933A1 (es) 2015-03-11
BR112015001487A2 (pt) 2017-07-04
MX2015000894A (es) 2015-04-17
CN104508104B (zh) 2017-09-22
CN104508104A (zh) 2015-04-08
AU2013298898B2 (en) 2015-05-14
EP2692842A1 (en) 2014-02-05
EP2880143A1 (en) 2015-06-10
ES2569375T3 (es) 2016-05-10
IN2015MN00104A (cs) 2015-10-16
EP2880143B1 (en) 2016-03-23
AU2013298898A1 (en) 2015-02-05
BR112015001487B1 (pt) 2021-05-04
PH12015500129A1 (en) 2015-03-02
PL2880143T3 (pl) 2016-09-30

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