EP2683793B1 - Utilisation d'un stabilisant pour la production de compositions de revêtement ignifuges exemptes d'halogène, renfermant un polyphosphate d'ammonium - Google Patents

Utilisation d'un stabilisant pour la production de compositions de revêtement ignifuges exemptes d'halogène, renfermant un polyphosphate d'ammonium Download PDF

Info

Publication number
EP2683793B1
EP2683793B1 EP12707235.3A EP12707235A EP2683793B1 EP 2683793 B1 EP2683793 B1 EP 2683793B1 EP 12707235 A EP12707235 A EP 12707235A EP 2683793 B1 EP2683793 B1 EP 2683793B1
Authority
EP
European Patent Office
Prior art keywords
ammonium polyphosphate
flame
binder
bis
contained
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP12707235.3A
Other languages
German (de)
English (en)
Other versions
EP2683793A1 (fr
Inventor
Thomas Staffel
Jürgen STRAUB
Michael Schmitt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BK Giulini GmbH
Original Assignee
BK Giulini GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BK Giulini GmbH filed Critical BK Giulini GmbH
Priority to PL12707235T priority Critical patent/PL2683793T3/pl
Publication of EP2683793A1 publication Critical patent/EP2683793A1/fr
Application granted granted Critical
Publication of EP2683793B1 publication Critical patent/EP2683793B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/02—Inorganic materials
    • C09K21/04—Inorganic materials containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/72—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with metaphosphoric acids or their salts; with polyphosphoric acids or their salts; with perphosphoric acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/568—Reaction products of isocyanates with polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties

Definitions

  • This invention relates to the use of a stabilizer which significantly improves the compatibility of the binder (polymer dispersion) with the liquid ammonium polyphosphate, APP for short, in a flame retardant coating composition.
  • the liquid ammonium polyphosphate acts in this Flame retardant coating composition as an active flame retardant agent.
  • the flame retardant coating compositions are well suited for all types of textiles, but also for paper, leather and fiber materials.
  • Burning textiles are a common phenomenon, such. B. in apartments where carpets furniture or home textiles are. But even clothing, especially by firefighters, children or kitchen staff is very often exposed to the risk of fire. In many industrial processes, textiles play a major role, which must be fireproof. Also in public transport, the flame resistance of seat covers and upholstery and flooring is a very important safety requirement.
  • Pulse erasers which is often sodium bicarbonate under carbon dioxide pressure delete.
  • the mechanism of the extinguishing here is the suffocation of the flame by liberated carbon dioxide, the is formed by the thermal decomposition of sodium bicarbonate.
  • the flame-retardant effect of phosphorus-containing flame retardants is generated mainly by the formation of a cover layer and elimination of water in the condensed phase.
  • Intumescent paints containing powdered ammonium polyphosphate function primarily by forming a heat-insulating foam.
  • compositions for flame retardant coatings for textiles or materials as mentioned above contain besides a e.g. halogen-containing active flame retardant a binder.
  • the binder is usually an aqueous polymer dispersion consisting of z. B. from the polymers polyurethane, polyacrylate or vinyl chloride copolymers.
  • these compositions contain adjuvants, such as crosslinkers, foam stabilizers, thickeners and active flame retardant agents, e.g. organic bromine and / or chlorine compounds.
  • brominated flame retardants which include polybrominated diphenyl ethers (PBDE), tetrabromobisphenol A (TBBPA) and hexabromocyclododecane (HBCD). They have long been in use in the environment, but chemically difficult to decompose and sometimes bioaccumulating, that is, they accumulate in living things. TBBPA and HBCD are toxic to aquatic organisms. DecaBDE, TBBPA and HBCD have already been detected in breast milk and in human blood. DecaBDE and HBCD are suspected of having long-term toxic effects. Several legislative decrees have been initiated to push these funds out of the market.
  • PBDE polybrominated diphenyl ethers
  • TBBPA tetrabromobisphenol A
  • HBCD hexabromocyclododecane
  • flame retardants are used, for example, in soft and hard polyurethane foams, such as in upholstered furniture, vehicle seats or building materials.
  • Ammonium polyphosphate solutions have also been known as active flame retardants.
  • Soluble ammonium polyphosphate solutions are presented. These solutions are very well suited for the aforementioned purpose namely fireproofing textiles of all kinds. Alone as an aqueous solution applied to the textiles, but they can not penetrate deeply enough into the fibers and also, even if you treat the textiles, they would be very stiff and heavy, would be spotty and would have very poor wearing properties. Over time, the ammonium polyphosphate is washed out of the textile structures over time by washing.
  • a suitable flame retardant coating composition for the treatment of textiles including but not limited to the binder (polymer dispersion) and a liquid ammonium polyphosphate.
  • the essential starting materials are plastic monomers, protective colloid and / or emulsifier, initiator. Polymerization of the monomers gives the corresponding binders in the form of a polymer dispersion. These binders are responsible for the improved adhesion of the flame retardant coating composition to the substrates.
  • the binders (polymer dispersions) based on polyurethane, vinyl acetate or Polyäcrylatbasis are incompatible with the liquid ammonium polyphosphate, there is an irreversible coagulation or flocculation. Presumably, this coagulation is done by damaging the stabilizer system consisting of protective colloid or emulsifier.
  • liquid ammonium polyphosphate means only those compounds which have been prepared in the liquid form, i. no solutions that result from the dissolution of a powdery, solid ammonium polyphosphate in water, because the solubility is very low, it is only 1%.
  • alkyl benzene sulfonates stabilize the binder (polymer dispersion) against coagulation in the flame retardant coating compositions.
  • the invention generally relates to the finishing of textiles of all kinds, such as woven, knitted, knitted, scrim and nonwoven fabrics of natural fibers such as, vegetable fibers, cellulose fibers, vegetable protein fibers, pulp paper fibers, rubber fibers and alginate fibers, and animal fibers such as wool and hair, leather and leather fibers, fibers based on chemical fibers, polymerizing fibers, polycondensation fibers and polyaddition fibers.
  • p-cumenesulfonic acid in the form of its Na and / or K salts is preferably suitable as stabilizer for the binder (polymer dispersion) in the flame-retardant coating compositions .
  • Equal sized strips of cotton fabric were impregnated with the different solutions and then dried.
  • the dry strips were exposed to a strong gas flame at a temperature of over 500 ° C and held for about 1 minute in the gas burner flame at about 450 to 600 ° C.
  • the flame retardant properties of the liquid ammonium polyphosphate are not affected.
  • the system consisting of liquid APP, binder and the stabilizer of the invention, e.g. p-Cumolsulfonat, can be incorporated into the flame retardant coating compositions outstanding and such compositions can be homogeneously and easily applied to the substrates.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Fireproofing Substances (AREA)
  • Paints Or Removers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Claims (4)

  1. Utilisation de sel de sodium, de sel de potassium et/ou de sel d'ammonium issus de l'acide cumènesulfonique-p comme stabilisateur de liant dans des compositions d'agents ignifuges contenant du polyphosphate d'ammonium liquide sans halogène, tout en tenant compte que les sels mentionnés concernant le liant (dispersion de polymères) sont contenus dans les compositions dans une proportion de 1:10 à 1:30.
  2. Utilisation selon revendication 1, caractérisée par le fait que la proportion entre le liant (dispersion de polymères) et le polyphsophate d'ammonium (PPA) liquide dans la dispersion est de 1,3:1 à 1:5.
  3. Utilisation selon revendication 1, caractérisée par le fait que le polyphosphate d'ammonium liquide (PPA) est disponible en mélangeant un acide polyphosphorique de la composition (Hn+2 Pn O3n+1 avec n= 1 jusqu'à 50) et une répartition de ions phosphate de P1 à P3 avec 20 % de pourcentage en poids et de P4 à P50 avec 70 à 90 % de pourcentage en poids avec une solution aqueuse d'ammoniac de 10 à 30 de pourcentage en poids et/ou avec du gaz d'ammoniac, jusqu'à une température de 60°C et jusqu'à obtention d'un pH dans une plage de 6,5 à 7,5. La solution ainsi obtenu devra refroidir à température ambiante de sorte qu'il en résulte un polyphosphate d'ammonium clair et liquide avec la formule (NH4PO3)n, avec n=1 à 50 et avec une teneur en matières solides jusqu'à 50 de pourcentage en poids avec un pH de 6,5 à 7,5 et une densité de 1,1 à 1,3 g/ml et un taux P4 à P50 de 60 à 90 de pourcentage en poids, tout en privilégiant 70 à 80 de pourcentage en poids.
  4. Utilisation de la composition du revêtement ignifuge selon les revendications 1 à 3 caractérisée par le fait que la présente composition peut être appliquée par imprégnation, vaporisation, immersion, imprégnation ou enduction à la racle dans un volume de 10 à 500 g/m2 sur les substrats.
EP12707235.3A 2011-03-05 2012-02-29 Utilisation d'un stabilisant pour la production de compositions de revêtement ignifuges exemptes d'halogène, renfermant un polyphosphate d'ammonium Active EP2683793B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL12707235T PL2683793T3 (pl) 2011-03-05 2012-02-29 Zastosowanie stabilizatora do wytwarzania bezhalogenowych formulacji powłok ogniochronnych zawierających polifosforan amonu

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102011013222A DE102011013222B4 (de) 2011-03-05 2011-03-05 Verwendung eines p-Cumolsulfonat-Stabilisators für die Herstellung von halogenfreien, Ammoniumpolyphosphat enthaltenden Flammschutzbeschichtungszusammensetzungen
PCT/EP2012/000868 WO2012119717A1 (fr) 2011-03-05 2012-02-29 Utilisation d'un stabilisant pour la production de compositions de revêtement ignifuges exemptes d'halogène, renfermant un polyphosphate d'ammonium

Publications (2)

Publication Number Publication Date
EP2683793A1 EP2683793A1 (fr) 2014-01-15
EP2683793B1 true EP2683793B1 (fr) 2016-12-14

Family

ID=46671411

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12707235.3A Active EP2683793B1 (fr) 2011-03-05 2012-02-29 Utilisation d'un stabilisant pour la production de compositions de revêtement ignifuges exemptes d'halogène, renfermant un polyphosphate d'ammonium

Country Status (12)

Country Link
US (1) US9045652B2 (fr)
EP (1) EP2683793B1 (fr)
JP (1) JP5859029B2 (fr)
KR (1) KR101593522B1 (fr)
CN (1) CN103562348B (fr)
DE (1) DE102011013222B4 (fr)
DK (1) DK2683793T3 (fr)
ES (1) ES2609781T3 (fr)
PL (1) PL2683793T3 (fr)
PT (1) PT2683793T (fr)
WO (1) WO2012119717A1 (fr)
ZA (1) ZA201305634B (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014215943B4 (de) 2014-08-12 2016-05-19 Bk Giulini Gmbh Verfahren zur Herstellung von Polyphosphatlösungen und deren Verwendung im Flammschutz
DE102020124334A1 (de) 2020-09-17 2022-03-17 Chemische Fabrik Budenheim Kg Zusammensetzung umfassend Ammoniumpolyphosphat
CN113604086A (zh) * 2021-08-18 2021-11-05 沈阳浩丰科技有限公司 一种保温防火涂料的制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1384241A (en) * 1971-02-23 1975-02-19 Albright & Wilson Manufacture of ammonium polyphosphate
GB2243846B (en) * 1990-03-26 1993-05-12 Albright & Wilson Flame retardant treatment of fabrics
US5212272A (en) * 1990-10-31 1993-05-18 Peach State Labs, Inc. Polyacrylic acid compositions for textile processing
US5629376A (en) * 1990-10-31 1997-05-13 Peach State Labs, Inc. Polyacrylic acid compositions for textile processing
JP3030906B2 (ja) * 1991-04-01 2000-04-10 ジェイエスアール株式会社 水性被覆組成物
JP4578803B2 (ja) * 2003-12-25 2010-11-10 日本合成化学工業株式会社 難燃性水性樹脂組成物
DE102008021027A1 (de) * 2008-04-25 2009-10-29 Bk Giulini Gmbh Verfahren zur Herstellung von Flammschutzmitteln und ihre Verwendung in Textilien

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Also Published As

Publication number Publication date
PT2683793T (pt) 2017-01-12
US9045652B2 (en) 2015-06-02
KR101593522B1 (ko) 2016-02-15
EP2683793A1 (fr) 2014-01-15
JP5859029B2 (ja) 2016-02-10
DK2683793T3 (en) 2017-01-23
DE102011013222B4 (de) 2012-11-08
WO2012119717A1 (fr) 2012-09-13
CN103562348B (zh) 2015-11-25
JP2014511422A (ja) 2014-05-15
DE102011013222A1 (de) 2012-09-06
KR20140015423A (ko) 2014-02-06
CN103562348A (zh) 2014-02-05
US20140212588A1 (en) 2014-07-31
ZA201305634B (en) 2014-05-28
ES2609781T3 (es) 2017-04-24
PL2683793T3 (pl) 2019-07-31

Similar Documents

Publication Publication Date Title
EP1048778B1 (fr) Matériaux fibreux avec un revêtement ignifugeant
CN101466533B (zh) 耐洗的抑制阴燃的组合物
EP2683793B1 (fr) Utilisation d'un stabilisant pour la production de compositions de revêtement ignifuges exemptes d'halogène, renfermant un polyphosphate d'ammonium
EP2112123B1 (fr) Procédé de fabrication de moyens ignifuges et leur utilisation dans des textiles
KR101989968B1 (ko) 방염조성물 및 이의 제조방법
EP0656438A1 (fr) Composition pour le traitement ignifuge de matériaux fibreux
EP0263570A1 (fr) Solution extinctrice pour éteindre les incendies du phosphore et des métaux
DE2401222A1 (de) Antistatische beschichtungsmasse und verfahren zu ihrer herstellung
DE2107373A1 (de) Wässrige Athylencopolymensatdispersion und Verwendung derselben zum Beschichten von Polyestertextilstoffen
DE102013008446A1 (de) Flammschutzmittel
DE1941060A1 (de) Feuerloeschpulver
DE102014215943B4 (de) Verfahren zur Herstellung von Polyphosphatlösungen und deren Verwendung im Flammschutz
EP1038915B1 (fr) Compositions retardatrices au feu contenant de bore, phosphore et polymère
DE1923982A1 (de) Verfahren zur Herstellung von flammwidrigen Polyurethanhartschaeumen
EP1423487B1 (fr) Agent ignifugeant et utilisation
DE4101539A1 (de) Zusammensetzung zur flammfestausruestung von fasermaterialien
EP3444318B1 (fr) Composition, agent ignifuge comportant ladite composition et agent d'extinction comportant ladite composition
DE102009045465A1 (de) Wolle-Imprägniermittel
DE3525684A1 (de) Brandbekaempfungsmittel zum aufspruehen
WO2015189810A1 (fr) Composition ignifuge liquide
WO2004024806A2 (fr) Mousses de polymethacrylimide peu inflammables et procedes de production associes
US20110223824A1 (en) Flame-retardant compositions and related processes, fabrics, textiles, plastics, and articles of manufacture
DE10034823A1 (de) Wäßrige Zusammensetzungen für Flammschutzausrüstung

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20130917

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

DAX Request for extension of the european patent (deleted)
17Q First examination report despatched

Effective date: 20140703

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20160920

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: PT

Ref legal event code: SC4A

Ref document number: 2683793

Country of ref document: PT

Date of ref document: 20170112

Kind code of ref document: T

Free format text: AVAILABILITY OF NATIONAL TRANSLATION

Effective date: 20170104

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 853585

Country of ref document: AT

Kind code of ref document: T

Effective date: 20170115

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

Effective date: 20170119

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502012009021

Country of ref document: DE

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 6

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20161214

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2609781

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20170424

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170315

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170314

REG Reference to a national code

Ref country code: RO

Ref legal event code: EPE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170414

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170314

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 502012009021

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170228

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170228

26N No opposition filed

Effective date: 20170915

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170228

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170228

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20120229

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20161214

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161214

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20220221

Year of fee payment: 11

Ref country code: DK

Payment date: 20220221

Year of fee payment: 11

Ref country code: DE

Payment date: 20220217

Year of fee payment: 11

Ref country code: AT

Payment date: 20220215

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: RO

Payment date: 20220221

Year of fee payment: 11

Ref country code: PT

Payment date: 20220218

Year of fee payment: 11

Ref country code: PL

Payment date: 20220224

Year of fee payment: 11

Ref country code: FR

Payment date: 20220221

Year of fee payment: 11

Ref country code: ES

Payment date: 20220318

Year of fee payment: 11

Ref country code: BE

Payment date: 20220216

Year of fee payment: 11

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 502012009021

Country of ref document: DE

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

Effective date: 20230228

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 853585

Country of ref document: AT

Kind code of ref document: T

Effective date: 20230228

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20230228

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20230228

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RO

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230301

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230831

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230228

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230228

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230228

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230228

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230228

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230901

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230228

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230301

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20240426

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20230301