EP2681441A1 - Système de soupape permettant la commande ou le dosage d'un fluide - Google Patents

Système de soupape permettant la commande ou le dosage d'un fluide

Info

Publication number
EP2681441A1
EP2681441A1 EP12700461.2A EP12700461A EP2681441A1 EP 2681441 A1 EP2681441 A1 EP 2681441A1 EP 12700461 A EP12700461 A EP 12700461A EP 2681441 A1 EP2681441 A1 EP 2681441A1
Authority
EP
European Patent Office
Prior art keywords
valve device
valve
sealing
baffle
flow channel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP12700461.2A
Other languages
German (de)
English (en)
Other versions
EP2681441B1 (fr
Inventor
Heiko Roth
Dominik Brunner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Robert Bosch GmbH
Original Assignee
Robert Bosch GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Robert Bosch GmbH filed Critical Robert Bosch GmbH
Publication of EP2681441A1 publication Critical patent/EP2681441A1/fr
Application granted granted Critical
Publication of EP2681441B1 publication Critical patent/EP2681441B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M59/00—Pumps specially adapted for fuel-injection and not provided for in groups F02M39/00 -F02M57/00, e.g. rotary cylinder-block type of pumps
    • F02M59/20—Varying fuel delivery in quantity or timing
    • F02M59/36—Varying fuel delivery in quantity or timing by variably-timed valves controlling fuel passages to pumping elements or overflow passages
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M59/00—Pumps specially adapted for fuel-injection and not provided for in groups F02M39/00 -F02M57/00, e.g. rotary cylinder-block type of pumps
    • F02M59/44—Details, components parts, or accessories not provided for in, or of interest apart from, the apparatus of groups F02M59/02 - F02M59/42; Pumps having transducers, e.g. to measure displacement of pump rack or piston
    • F02M59/46—Valves
    • F02M59/466—Electrically operated valves, e.g. using electromagnetic or piezoelectric operating means
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M59/00—Pumps specially adapted for fuel-injection and not provided for in groups F02M39/00 -F02M57/00, e.g. rotary cylinder-block type of pumps
    • F02M59/20—Varying fuel delivery in quantity or timing
    • F02M59/36—Varying fuel delivery in quantity or timing by variably-timed valves controlling fuel passages to pumping elements or overflow passages
    • F02M59/366—Valves being actuated electrically
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M59/00—Pumps specially adapted for fuel-injection and not provided for in groups F02M39/00 -F02M57/00, e.g. rotary cylinder-block type of pumps
    • F02M59/20—Varying fuel delivery in quantity or timing
    • F02M59/36—Varying fuel delivery in quantity or timing by variably-timed valves controlling fuel passages to pumping elements or overflow passages
    • F02M59/366—Valves being actuated electrically
    • F02M59/367—Pump inlet valves of the check valve type being open when actuated
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M59/00—Pumps specially adapted for fuel-injection and not provided for in groups F02M39/00 -F02M57/00, e.g. rotary cylinder-block type of pumps
    • F02M59/44—Details, components parts, or accessories not provided for in, or of interest apart from, the apparatus of groups F02M59/02 - F02M59/42; Pumps having transducers, e.g. to measure displacement of pump rack or piston
    • F02M59/46—Valves
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M59/00—Pumps specially adapted for fuel-injection and not provided for in groups F02M39/00 -F02M57/00, e.g. rotary cylinder-block type of pumps
    • F02M59/44—Details, components parts, or accessories not provided for in, or of interest apart from, the apparatus of groups F02M59/02 - F02M59/42; Pumps having transducers, e.g. to measure displacement of pump rack or piston
    • F02M59/46—Valves
    • F02M59/462—Delivery valves
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M63/00—Other fuel-injection apparatus having pertinent characteristics not provided for in groups F02M39/00 - F02M57/00 or F02M67/00; Details, component parts, or accessories of fuel-injection apparatus, not provided for in, or of interest apart from, the apparatus of groups F02M39/00 - F02M61/00 or F02M67/00; Combination of fuel pump with other devices, e.g. lubricating oil pump
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M63/00—Other fuel-injection apparatus having pertinent characteristics not provided for in groups F02M39/00 - F02M57/00 or F02M67/00; Details, component parts, or accessories of fuel-injection apparatus, not provided for in, or of interest apart from, the apparatus of groups F02M39/00 - F02M61/00 or F02M67/00; Combination of fuel pump with other devices, e.g. lubricating oil pump
    • F02M63/0012—Valves
    • F02M63/007—Details not provided for in, or of interest apart from, the apparatus of the groups F02M63/0014 - F02M63/0059
    • F02M63/0077—Valve seat details
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M63/00—Other fuel-injection apparatus having pertinent characteristics not provided for in groups F02M39/00 - F02M57/00 or F02M67/00; Details, component parts, or accessories of fuel-injection apparatus, not provided for in, or of interest apart from, the apparatus of groups F02M39/00 - F02M61/00 or F02M67/00; Combination of fuel pump with other devices, e.g. lubricating oil pump
    • F02M63/0012—Valves
    • F02M63/007—Details not provided for in, or of interest apart from, the apparatus of the groups F02M63/0014 - F02M63/0059
    • F02M63/0078—Valve member details, e.g. special shape, hollow or fuel passages in the valve member

Definitions

  • valve devices such as quantity control valves of a fuel system of an internal combustion engine, are known from the market. Often, such valve devices have a valve body which abut against a sealing section against a housing-side sealing seat and thus close the valve means.
  • the sealing seat is formed, for example, flat, cylindrical, spherical or conical. In the closed state of the valve device can in the connected to the valve device hydraulic
  • the invention is based on the consideration that a high
  • Sealing portion and a sealing seat formed sealing area on the one hand, and a high flow coefficient of the valve device on the other hand, can be conflicting requirements. Although it is possible by means of the sealing area upstream immediately upstream chamfers or curves
  • valve device Flow coefficient of the valve device - with unchanged valve lift - to increase.
  • closed valve means a wedge-like cross-section gap between the sealing portion and the sealing seat.
  • the bubbles of the fluid formed as a result of cavitation effects-depending on the particular pressure-are decayed last in this gap and thus comparatively quickly, as a result of which erosion of the sealing section and / or of the sealing seat can occur.
  • the valve device in a flow channel immediately upstream of the sealing area when closed
  • a boundary wall of the decomposition space is formed by a baffle, which adjoins the sealing area, wherein the baffle is at least partially tilted against the direction normal to the sealing region with an angle of at most 15 ° in the flow direction to a maximum of 60 ° against the flow direction.
  • a further boundary wall of the decomposition space runs, for example, approximately parallel to the sealing region, so that an upstream shoulder results upstream of the sealing region.
  • An embodiment of the invention provides that the baffle wall at least partially opposite to the sealing region normal with an angle of at most 5 ° in the flow direction to a maximum of 20 ° against the
  • Flow direction is tilted, more preferably that the baffle at least partially opposite to the sealing region normal with a Wnkel of a maximum of 2 ° in the flow direction to a maximum of 10 ° against the
  • baffle is at least partially disposed at right angles with respect to the sealing area.
  • areas for a spatial orientation of the baffle are described in which a particularly favorable ratio of low cavitation erosion on the one hand, and a high
  • the invention provides that the baffle wall is formed on a housing and / or on a valve body of the valve device.
  • the decomposition space can also be designed alternatively or even simultaneously on the housing or on the valve body.
  • the valve device can be designed constructively in many ways.
  • the flow coefficient of the valve device can be improved if a boundary wall of the flow channel upstream of and close to the baffle wall has a rounding or chamfer. This can be the
  • Flow rate in the sealing area can be further increased without the cavitation erosion increases.
  • a boundary wall of the flow channel immediately upstream of the rounding has an angle with respect to a longitudinal axis of the flow channel of a maximum of +/- 15 ° degrees.
  • an undercut is present.
  • the valve device When the valve device is closed, the hydraulic end of the upstream fluid region and thus the location of the disintegration of the cavitation bubbles can be kept away from the sealing region.
  • valve body is plate-shaped, cylindrical, spherical or conical or it is a conical-cone valve.
  • the invention can be used advantageously.
  • the manufacture of the valve device can be simplified and cheapened if the housing is multi-part in the baffle wall.
  • the above-described diverse geometries of the valve device upstream of the sealing region can optionally be produced by separate elements and thus simpler.
  • FIG. 1 is a simplified schematic of a Kraftstoffsytems with a
  • FIG. 2 is a simplified sectional view of a first embodiment of the valve device of Figure 1 in the open state;
  • FIG. 3 shows the valve device of FIG. 2 in the closed state;
  • Figure 4 is a simplified sectional view of a second embodiment of the valve device;
  • Figure 5 is a simplified sectional view of a third embodiment of
  • Valve means is a simplified sectional view of a fourth embodiment of the valve device;
  • Figure 7 is a simplified sectional view of a fifth embodiment of
  • Figure 8 is a simplified sectional view of a sixth embodiment of the valve device.
  • Figure 9 is a simplified sectional view of a seventh embodiment of the valve device.
  • FIG. 10 is a simplified sectional view of an eighth embodiment of the valve device.
  • Figure 1 1 is a simplified sectional view of a ninth embodiment of the valve device.
  • Figure 12 is a simplified sectional view of a tenth embodiment of the valve device.
  • FIG. 1 shows a fuel system 10 of an internal combustion engine in a greatly simplified representation. From a fuel tank 12 is fuel via a suction line 14, by means of a prefeed pump 16, via a low pressure line 18, and via an actuatable by an electromagnet 20 valve means
  • High pressure pump 24 is connected via a high pressure line 26 to a high pressure accumulator 28.
  • Other elements, such as outlet valves of the high-pressure pump 24, are not shown in FIG. It is understood that the valve device 22 and the quantity control valve 22 as a unit with the High pressure pump 24 may be formed. For example, that can
  • Quantity control valve 22 may be an inlet valve of the high-pressure pump 24.
  • Actuating device as the electromagnet 20 for example, a piezoelectric actuator or a hydraulic actuator.
  • the prefeed pump 16 delivers fuel from the fuel tank 12 into the low-pressure line 18
  • Quantity control valve 22 the delivery chamber of the high pressure pump 24 supplied amount of fuel.
  • FIG. 2 shows a first embodiment of the valve device 22 of Figure 1 in a simplified sectional view.
  • the elements of the valve device 22 shown in the drawing are designed substantially rotationally symmetrical about a longitudinal axis 29 and comprise a housing 30 with a
  • Sealing seat 32 on which a sealing portion 34 of a valve body 36 may rest when the valve device 22 is closed.
  • FIG 2 is the figure 2
  • Valve device 22 however, open, that is, the valve body 36 is lifted from the sealing seat 32 axially.
  • a flow channel 38 is formed, through which in the open position shown fluid - present
  • the sealing seat 32 and the sealing portion 34 are flat and parallel to each other and together form a sealing region 42. Upstream of the sealing region 42 is by means of a step-like recess in the housing
  • a decay space 44 is formed, which is bounded by an extending from the sealing region 42 and its plane at right angles extending baffle 46.
  • Two dashed lines 48 along the flow channel 38 define a cross section of the flow channel 38 with a particularly high
  • the distance between the two dashed lines 48 is characterized by a measure 50 downstream of the sealing region 42.
  • the fuel flows substantially from left to right in the drawing of FIG. 2, the flow first extending approximately horizontally and then being deflected radially outward in front of the valve body 36.
  • the deflection of the flow takes place downstream of a Edge 52 comparatively early and low loss by means of the hydraulic action of the decomposition space 44.
  • the dimension 50 is only slightly smaller than the axial distance between the sealing seat 32 and the sealing portion 34, so that the fuel can flow relatively quickly through the sealing region 42 and the flow coefficient of Valve device 22 is correspondingly good.
  • FIG. 3 shows the valve device 22 of FIG. 2 in the closed state.
  • the valve body 36 abuts with the sealing portion 34 on the sealing seat 32, so that a flow of fluid substantially does not take place.
  • Valve body 36 is a region of vapor bubbles 54 shown, which have formed due to cavitation effects as a result of pressure pulsations.
  • the vapor bubbles 54 rest against or are at least closely adjacent to the valve body 36 with a comparatively large area.
  • valve device 22 in a vicinity of the vapor bubble 54, no narrowing (wedge-like) space sections, which may be particularly prone to cavitation erosion.
  • FIG. 4 shows a further embodiment of the valve device 22, the disintegration space 44 being widened by an undercut 56. In this way, the imploding vapor bubble (s) 54 can still further from
  • Sealing area 42 kept away and thus the risk of cavitation erosion at the sealing seat 32 and the sealing portion 34 are further reduced.
  • FIG. 5 shows a further embodiment of the valve device 22, the baffle 46 being opposite a sealing region 42 or its plane
  • Normal 58 is tilted by a Wnkel W1 of 15 ° in the flow direction.
  • the angle W1 can also be less than 15 °, whereby the valve device 22 can be even more resistant to cavitation erosion.
  • FIG. 6 shows a further embodiment of the valve device 22, wherein the baffle wall 46 is tilted counter to the flow direction with respect to the normal to the sealing region 42 by an angle W2 of 15 °. This can further reduce the risk of cavitation erosion.
  • the Wnkel W2 can also be up to 60 °. This is not shown in FIG.
  • Figure 7 shows a further embodiment of the valve means 22, wherein a boundary wall of the flow channel 38 upstream of and close to the baffle 46 in place of the edge 52 has a rounding 60 with a radius R1.
  • the baffle 46 may also be tilted at a maximum of 15 ° in the flow direction or alternatively at most 60 ° counter to the direction of flow relative to the sealing region 42 normal 58. Both alternatives are indicated in FIG. 7 by auxiliary lines.
  • Rounding 60 may be tilted with respect to the longitudinal axis 29 by a W3 W3 of +/- 15 °.
  • FIG. 8 shows a further embodiment of the valve device 22, wherein a boundary wall of the flow channel 38 upstream of and close to the
  • Baffle 46 instead of the edge 52 has a chamfer 62.
  • the baffle wall 46 can also be tilted with respect to the sealing area by a wedge W1 or by a wedge W2 (compare FIGS. 5, 6 and 7).
  • FIG. 9 shows an embodiment comparable to FIG. 8
  • Valve device 22 wherein the housing 30 in the region of the baffle 46 is made of several parts.
  • the chamfer 62 is arranged on a housing element 64.
  • FIG. 10 shows a first variant of a second group of embodiments of the valve device 22, in which the baffle wall 46 is formed on the valve body 36. This is done by the decomposition space 44 at the
  • Valve body 36 is made by means of a recess (no reference numeral). Similar to FIG. 7, the boundary wall of the flow channel 38 has a rounding 60 upstream of and close to the baffle 46.
  • One Angle W4 in a corner of the boundary wall of the flow channel 38 and the baffle 46 is 90 °, whereby a wedge-like end portion of the
  • the angle W4 can also be between 75 ° and 105 ° and / or the rounding 60 can be replaced by a chamfer 62. This is not shown in FIG.
  • Figure 1 1 shows a second variant of the second group of embodiments, wherein an undercut 66 is disposed in the valve body 36. This results in similar flow characteristics as in the embodiment of FIG. 4.
  • An upstream upstream edge 52 on the housing 30 is dispensable in the valve device 22 of FIG.
  • FIG. 12 shows the valve device 22 in a design as a conical-cone valve.
  • this embodiment is similar to that of FIGS. 2 and 3, respectively.
  • the baffle 46 is oriented approximately at right angles with respect to the sealing portion 34.
  • the planes of the sealing seat 32 and the sealing portion 34 and the baffle 46 in comparison to the figure 2 and 3, however, by a certain angle - in this case approximately at 45 ° - tilted against the longitudinal axis 29. Accordingly, the angle at the edge 52 is approximately 135 °.
  • valve body 36 can be plate-shaped or cone-shaped. Alternatively, however, the valve body 36 may also be cylindrical or spherical, from which further variants of the valve device 22 may result.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Lift Valve (AREA)
  • Details Of Valves (AREA)
  • Fuel-Injection Apparatus (AREA)

Abstract

L'invention concerne un système de soupape (22) permettant la commande ou le dosage d'un fluide, ledit système comportant un boîtier (30), un canal d'écoulement (38) et un corps de soupape (36) agencé dans le canal d'écoulement (38), lequel corps de soupape présente une section d'étanchéité (34) qui repose sur un siège d'étanchéité (32) côté boîtier lorsque le système de soupape (22) est fermé, la section d'étanchéité (34) et le siège d'étanchéité (32) formant ensemble une zone d'étanchéité (42) et un espace de dissociation (44) étant présent immédiatement en amont de la zone d'étanchéité (42) dans le canal d'écoulement (38) lorsque le système de soupape (22) est fermé. Ledit espace de dissociation est délimité par une paroi d'impact (46), la paroi d'impact (46) étant inclinée par rapport aux perpendiculaires (58) à la zone d'étanchéité (42) selon un angle allant d'un maximum de 15° dans le sens de l'écoulement à un maximum de 60° dans le sens opposé au sens de l'écoulement.
EP12700461.2A 2011-03-02 2012-01-04 Système de soupape permettant la commande ou le dosage d'un fluide Active EP2681441B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102011004993A DE102011004993A1 (de) 2011-03-02 2011-03-02 Ventileinrichtung zum Schalten oder Zumessen eines Fluids
PCT/EP2012/050093 WO2012116850A1 (fr) 2011-03-02 2012-01-04 Système de soupape permettant la commande ou le dosage d'un fluide

Publications (2)

Publication Number Publication Date
EP2681441A1 true EP2681441A1 (fr) 2014-01-08
EP2681441B1 EP2681441B1 (fr) 2017-03-15

Family

ID=45497982

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12700461.2A Active EP2681441B1 (fr) 2011-03-02 2012-01-04 Système de soupape permettant la commande ou le dosage d'un fluide

Country Status (8)

Country Link
US (1) US10393079B2 (fr)
EP (1) EP2681441B1 (fr)
JP (1) JP5826295B2 (fr)
KR (1) KR101504495B1 (fr)
CN (1) CN103403337B (fr)
DE (1) DE102011004993A1 (fr)
ES (1) ES2628064T3 (fr)
WO (1) WO2012116850A1 (fr)

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JP6135437B2 (ja) * 2013-10-07 2017-05-31 トヨタ自動車株式会社 高圧燃料ポンプ
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DE102015201520A1 (de) 2015-01-29 2016-08-04 Robert Bosch Gmbh Verstelleinrichtung und Brennstoffeinspritzanlage mit einer Verstelleinrichtung
DE102015118001A1 (de) * 2015-10-22 2017-04-27 Vag-Armaturen Gmbh Absperrarmaturengehäuse

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JP4569825B2 (ja) * 2005-04-26 2010-10-27 株式会社デンソー 高圧燃料ポンプ
US8925579B2 (en) * 2006-03-02 2015-01-06 Pacific Bag, Inc. Pressure relief valve
JP4237781B2 (ja) * 2006-06-29 2009-03-11 シーケーディ株式会社 流量制御弁
EP1914458A1 (fr) * 2006-10-18 2008-04-23 Varian B.V. Vanne avec amortisseur de vibration
DE102007004553A1 (de) * 2007-01-30 2008-07-31 Robert Bosch Gmbh Kugelsitzventil mit verringertem Erosionsverhalten
US8333336B2 (en) * 2007-03-06 2012-12-18 Caterpillar Inc. Cavitation erosion reduction strategy for valve member and fuel injector utilizing same
JP2008248788A (ja) 2007-03-30 2008-10-16 Denso Corp 高圧燃料ポンプ
DE102008000658B4 (de) * 2007-03-29 2018-09-27 Denso Corporation Hydraulische Pumpe
JP5492210B2 (ja) * 2008-09-09 2014-05-14 アルテミス インテリジェント パワー リミティド バルブアセンブリ
JP5180365B2 (ja) * 2009-02-20 2013-04-10 日立オートモティブシステムズ株式会社 高圧燃料供給ポンプ及びそれに用いる吐出弁ユニット

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CN103403337B (zh) 2017-06-06
DE102011004993A1 (de) 2012-09-06
WO2012116850A1 (fr) 2012-09-07
CN103403337A (zh) 2013-11-20
KR101504495B1 (ko) 2015-03-20
EP2681441B1 (fr) 2017-03-15
JP2014506976A (ja) 2014-03-20
KR20140007421A (ko) 2014-01-17
US10393079B2 (en) 2019-08-27
JP5826295B2 (ja) 2015-12-02
US20140048043A1 (en) 2014-02-20
ES2628064T3 (es) 2017-08-01

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