EP2593223A4 - COPPER WITH A ZSM 34, OFF AND / OR ERI ZEOLITE MATERIAL FOR SELECTIVE NOX REDUCTION - Google Patents

COPPER WITH A ZSM 34, OFF AND / OR ERI ZEOLITE MATERIAL FOR SELECTIVE NOX REDUCTION

Info

Publication number
EP2593223A4
EP2593223A4 EP20110806375 EP11806375A EP2593223A4 EP 2593223 A4 EP2593223 A4 EP 2593223A4 EP 20110806375 EP20110806375 EP 20110806375 EP 11806375 A EP11806375 A EP 11806375A EP 2593223 A4 EP2593223 A4 EP 2593223A4
Authority
EP
European Patent Office
Prior art keywords
offerability
material used
nox reduction
copper containing
containing zsm
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP20110806375
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2593223A1 (en
Inventor
Ivor Bull
Ulrich Mueller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP20110806375 priority Critical patent/EP2593223A4/en
Publication of EP2593223A1 publication Critical patent/EP2593223A1/en
Publication of EP2593223A4 publication Critical patent/EP2593223A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9413Processes characterised by a specific catalyst
    • B01D53/9418Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B01J29/52Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952 containing iron group metals, noble metals or copper
    • B01J29/56Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80Mixtures of different zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • B01J37/0246Coatings comprising a zeolite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00Heat treatments such as Calcining; Fusing ; Pyrolysis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2067Urea
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/202Alkali metals
    • B01D2255/2022Potassium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20761Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/50Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/01Engine exhaust gases
    • B01D2258/012Diesel engines and lean burn gasoline engines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Biomedical Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
EP20110806375 2010-07-15 2011-07-05 COPPER WITH A ZSM 34, OFF AND / OR ERI ZEOLITE MATERIAL FOR SELECTIVE NOX REDUCTION Withdrawn EP2593223A4 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP20110806375 EP2593223A4 (en) 2010-07-15 2011-07-05 COPPER WITH A ZSM 34, OFF AND / OR ERI ZEOLITE MATERIAL FOR SELECTIVE NOX REDUCTION

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10169676 2010-07-15
EP20110806375 EP2593223A4 (en) 2010-07-15 2011-07-05 COPPER WITH A ZSM 34, OFF AND / OR ERI ZEOLITE MATERIAL FOR SELECTIVE NOX REDUCTION
PCT/IB2011/052980 WO2012007874A1 (en) 2010-07-15 2011-07-05 Copper containing zsm-34, off and/or eri zeolitic material for selective reduction of nox

Publications (2)

Publication Number Publication Date
EP2593223A1 EP2593223A1 (en) 2013-05-22
EP2593223A4 true EP2593223A4 (en) 2014-02-12

Family

ID=45468997

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20110806375 Withdrawn EP2593223A4 (en) 2010-07-15 2011-07-05 COPPER WITH A ZSM 34, OFF AND / OR ERI ZEOLITE MATERIAL FOR SELECTIVE NOX REDUCTION

Country Status (6)

Country Link
EP (1) EP2593223A4 (cg-RX-API-DMAC7.html)
JP (1) JP2013533804A (cg-RX-API-DMAC7.html)
KR (1) KR20130044322A (cg-RX-API-DMAC7.html)
CN (1) CN103180041A (cg-RX-API-DMAC7.html)
BR (1) BR112013001046A2 (cg-RX-API-DMAC7.html)
WO (1) WO2012007874A1 (cg-RX-API-DMAC7.html)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9527751B2 (en) 2011-11-11 2016-12-27 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material of the CHA-type structure
JP6416096B2 (ja) * 2012-09-28 2018-10-31 パシフィック インダストリアル デベロップメント コーポレイション 選択触媒還元反応における触媒として使用するためのstt型ゼオライトの調製方法
JP6894704B2 (ja) * 2014-03-24 2021-06-30 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Public Limited Company 排気ガス処理のための方法及びシステム
US9925492B2 (en) 2014-03-24 2018-03-27 Mellanox Technologies, Ltd. Remote transactional memory
CN107427777A (zh) * 2015-03-25 2017-12-01 庄信万丰股份有限公司 包含贵金属和具有OFF骨架类型的分子筛的被动NOx吸附剂
JP6980698B2 (ja) * 2016-05-03 2021-12-15 ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフトUmicore AG & Co.KG 活性scr触媒
CN110997138A (zh) * 2017-06-09 2020-04-10 巴斯夫公司 用于NOx减排的具有受控孔隙率的催化洗涂层
JP7603200B2 (ja) * 2018-10-30 2024-12-20 ビーエーエスエフ モバイル エミッションズ カタリスツ エルエルシー 前交換した銅ゼオライト材料におけるin-situ銅イオン交換
CN115138391B (zh) * 2021-03-29 2025-05-09 高化学株式会社 低温羰基化分子筛催化剂及其用途
CN113198525B (zh) * 2021-05-08 2023-05-09 北京工业大学 一种低温条件下笑气分解和NOx催化还原协同净化的催化剂及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008132452A2 (en) * 2007-04-26 2008-11-06 Johnson Matthey Public Limited Company Transition metal/zeolite scr catalysts

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2671551B2 (ja) * 1990-03-16 1997-10-29 トヨタ自動車株式会社 排気浄化用触媒の製造方法
JP3276678B2 (ja) * 1992-07-02 2002-04-22 出光興産株式会社 排ガス浄化用触媒及びこれを使用した排ガスの浄化方法
US5254322A (en) * 1992-08-10 1993-10-19 Mobil Oil Corporation Method for reducing automotive NOx emissions in lean burn internal combustion engine exhaust using a transition metal-containing zeolite catalyst which is in-situ crystallized
CN100515561C (zh) * 2003-12-16 2009-07-22 广东工业大学 一种高效净化汽车尾气催化剂及制备方法
BRPI0619944B8 (pt) * 2005-12-14 2018-03-20 Basf Catalysts Llc método para preparar um catalisador de zeólito promovido por metal, catalisador de zeólito, e, método para reduzir nox em uma corrente de gás de exaustão ou gás combustível

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008132452A2 (en) * 2007-04-26 2008-11-06 Johnson Matthey Public Limited Company Transition metal/zeolite scr catalysts

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
No further relevant documents disclosed *
See also references of WO2012007874A1 *

Also Published As

Publication number Publication date
JP2013533804A (ja) 2013-08-29
CN103180041A (zh) 2013-06-26
KR20130044322A (ko) 2013-05-02
BR112013001046A2 (pt) 2016-05-24
EP2593223A1 (en) 2013-05-22
WO2012007874A1 (en) 2012-01-19

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Effective date: 20140110

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