EP2524079A1 - Dosiersystem zur verwendung in verbindung mit einem wasserführenden haushaltsgerät wie eine waschmaschine, spülmaschine, wäschetrockner oder dergleichen - Google Patents
Dosiersystem zur verwendung in verbindung mit einem wasserführenden haushaltsgerät wie eine waschmaschine, spülmaschine, wäschetrockner oder dergleichenInfo
- Publication number
- EP2524079A1 EP2524079A1 EP10778963A EP10778963A EP2524079A1 EP 2524079 A1 EP2524079 A1 EP 2524079A1 EP 10778963 A EP10778963 A EP 10778963A EP 10778963 A EP10778963 A EP 10778963A EP 2524079 A1 EP2524079 A1 EP 2524079A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- chamber
- household appliance
- dosing
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005406 washing Methods 0.000 title claims abstract description 75
- 238000002360 preparation method Methods 0.000 claims abstract description 172
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 67
- 238000003860 storage Methods 0.000 claims abstract description 62
- 239000012530 fluid Substances 0.000 claims abstract description 50
- 230000009969 flowable effect Effects 0.000 claims abstract description 11
- 102000004190 Enzymes Human genes 0.000 claims description 56
- 108090000790 Enzymes Proteins 0.000 claims description 56
- 229940088598 enzyme Drugs 0.000 claims description 51
- 239000004094 surface-active agent Substances 0.000 claims description 29
- 230000003287 optical effect Effects 0.000 claims description 23
- 108091005804 Peptidases Proteins 0.000 claims description 22
- 239000004365 Protease Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 19
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 18
- 239000008139 complexing agent Substances 0.000 claims description 18
- 239000003381 stabilizer Substances 0.000 claims description 15
- 239000007844 bleaching agent Substances 0.000 claims description 13
- -1 mananases Proteins 0.000 claims description 12
- 108090001060 Lipase Proteins 0.000 claims description 9
- 102000004882 Lipase Human genes 0.000 claims description 9
- 239000004367 Lipase Substances 0.000 claims description 9
- 239000003205 fragrance Substances 0.000 claims description 9
- 235000019421 lipase Nutrition 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- 108010084185 Cellulases Proteins 0.000 claims description 8
- 102000005575 Cellulases Human genes 0.000 claims description 8
- 108010065511 Amylases Proteins 0.000 claims description 7
- 102000013142 Amylases Human genes 0.000 claims description 7
- 235000019418 amylase Nutrition 0.000 claims description 7
- 229940025131 amylases Drugs 0.000 claims description 5
- 238000004891 communication Methods 0.000 claims description 5
- 238000004061 bleaching Methods 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 108010087558 pectate lyase Proteins 0.000 claims description 3
- 239000002304 perfume Substances 0.000 claims description 2
- 230000001960 triggered effect Effects 0.000 claims 2
- 239000003112 inhibitor Substances 0.000 description 17
- 235000019419 proteases Nutrition 0.000 description 15
- 239000002904 solvent Substances 0.000 description 12
- 239000003599 detergent Substances 0.000 description 11
- 238000005259 measurement Methods 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 11
- 239000007789 gas Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 230000005540 biological transmission Effects 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 230000002378 acidificating effect Effects 0.000 description 7
- 239000011521 glass Substances 0.000 description 7
- 230000002366 lipolytic effect Effects 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- 230000007935 neutral effect Effects 0.000 description 6
- 238000012546 transfer Methods 0.000 description 6
- 108010059892 Cellulase Proteins 0.000 description 5
- 239000004599 antimicrobial Substances 0.000 description 5
- 238000011161 development Methods 0.000 description 5
- 239000006260 foam Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 238000012544 monitoring process Methods 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 102000004157 Hydrolases Human genes 0.000 description 4
- 108090000604 Hydrolases Proteins 0.000 description 4
- 102000035195 Peptidases Human genes 0.000 description 4
- 239000003570 air Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000009529 body temperature measurement Methods 0.000 description 4
- 210000004027 cell Anatomy 0.000 description 4
- 229940106157 cellulase Drugs 0.000 description 4
- 239000000645 desinfectant Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000011010 flushing procedure Methods 0.000 description 4
- 238000005755 formation reaction Methods 0.000 description 4
- 238000010409 ironing Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000005086 pumping Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 150000003751 zinc Chemical class 0.000 description 4
- 102000004316 Oxidoreductases Human genes 0.000 description 3
- 108090000854 Oxidoreductases Proteins 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004382 Amylase Substances 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 108700020962 Peroxidase Proteins 0.000 description 2
- 102000003992 Peroxidases Human genes 0.000 description 2
- 108010059820 Polygalacturonase Proteins 0.000 description 2
- 108090000637 alpha-Amylases Proteins 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 2
- 238000004851 dishwashing Methods 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 108010093305 exopolygalacturonase Proteins 0.000 description 2
- 125000003147 glycosyl group Chemical group 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000006199 nebulizer Substances 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- VQJMAIZOEPPELO-KYGIZGOZSA-N (1S,2S,6R,14R,15R,16R)-5-(cyclopropylmethyl)-16-(2-hydroxy-5-methylhexan-2-yl)-15-methoxy-13-oxa-5-azahexacyclo[13.2.2.12,8.01,6.02,14.012,20]icosa-8(20),9,11-trien-11-ol hydrochloride Chemical compound Cl.CO[C@]12CC[C@@]3(C[C@@H]1C(C)(O)CCC(C)C)[C@H]1Cc4ccc(O)c5O[C@@H]2[C@]3(CCN1CC1CC1)c45 VQJMAIZOEPPELO-KYGIZGOZSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- 241000193422 Bacillus lentus Species 0.000 description 1
- 241000194108 Bacillus licheniformis Species 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- 102100032487 Beta-mannosidase Human genes 0.000 description 1
- 108010053835 Catalase Proteins 0.000 description 1
- 102000016938 Catalase Human genes 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004155 Chlorine dioxide Substances 0.000 description 1
- 238000000018 DNA microarray Methods 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 101710121765 Endo-1,4-beta-xylanase Proteins 0.000 description 1
- 108090000371 Esterases Proteins 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241001480714 Humicola insolens Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 108010028688 Isoamylase Proteins 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 101100269674 Mus musculus Alyref2 gene Proteins 0.000 description 1
- 241000158147 Sator Species 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- ZRXYMHTYEQQBLN-UHFFFAOYSA-N [Br].[Zn] Chemical compound [Br].[Zn] ZRXYMHTYEQQBLN-UHFFFAOYSA-N 0.000 description 1
- BPKGOZPBGXJDEP-UHFFFAOYSA-N [C].[Zn] Chemical compound [C].[Zn] BPKGOZPBGXJDEP-UHFFFAOYSA-N 0.000 description 1
- TWLBWHPWXLPSNU-UHFFFAOYSA-L [Na].[Cl-].[Cl-].[Ni++] Chemical compound [Na].[Cl-].[Cl-].[Ni++] TWLBWHPWXLPSNU-UHFFFAOYSA-L 0.000 description 1
- OSOVKCSKTAIGGF-UHFFFAOYSA-N [Ni].OOO Chemical compound [Ni].OOO OSOVKCSKTAIGGF-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 102000004139 alpha-Amylases Human genes 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 239000012753 anti-shrinkage agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000011001 backwashing Methods 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 108010047754 beta-Glucosidase Proteins 0.000 description 1
- 102000006995 beta-Glucosidase Human genes 0.000 description 1
- 108010055059 beta-Mannosidase Proteins 0.000 description 1
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 108010085318 carboxymethylcellulase Proteins 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 235000019398 chlorine dioxide Nutrition 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 108010005400 cutinase Proteins 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 229940079919 digestives enzyme preparation Drugs 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000012729 immediate-release (IR) formulation Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 1
- 238000002032 lab-on-a-chip Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- LWRYTNDOEJYQME-UHFFFAOYSA-N lithium;sulfanylideneiron Chemical compound [Li].[Fe]=S LWRYTNDOEJYQME-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 210000001724 microfibril Anatomy 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910000483 nickel oxide hydroxide Inorganic materials 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 230000003534 oscillatory effect Effects 0.000 description 1
- 238000009896 oxidative bleaching Methods 0.000 description 1
- SJEFKIVIMJHMLR-UHFFFAOYSA-N oxomercury;zinc Chemical compound [Zn].[Hg]=O SJEFKIVIMJHMLR-UHFFFAOYSA-N 0.000 description 1
- HTQOEHYNHFXMJJ-UHFFFAOYSA-N oxosilver zinc Chemical compound [Zn].[Ag]=O HTQOEHYNHFXMJJ-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000008237 rinsing water Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- BSWGGJHLVUUXTL-UHFFFAOYSA-N silver zinc Chemical compound [Zn].[Ag] BSWGGJHLVUUXTL-UHFFFAOYSA-N 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000010897 surface acoustic wave method Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F39/00—Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00
- D06F39/02—Devices for adding soap or other washing agents
- D06F39/022—Devices for adding soap or other washing agents in a liquid state
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F33/00—Control of operations performed in washing machines or washer-dryers
- D06F33/30—Control of washing machines characterised by the purpose or target of the control
- D06F33/32—Control of operational steps, e.g. optimisation or improvement of operational steps depending on the condition of the laundry
- D06F33/37—Control of operational steps, e.g. optimisation or improvement of operational steps depending on the condition of the laundry of metering of detergents or additives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F2103/00—Parameters monitored or detected for the control of domestic laundry washing machines, washer-dryers or laundry dryers
- D06F2103/20—Washing liquid condition, e.g. turbidity
- D06F2103/22—Content of detergent or additives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F2105/00—Systems or parameters controlled or affected by the control systems of washing machines, washer-dryers or laundry dryers
- D06F2105/42—Detergent or additive supply
Definitions
- Dosing apparatus for use in connection with a water-conducting domestic appliance such as a washing machine, dishwasher, tumble dryer or the like
- the invention relates to a metering system for use in conjunction with a water-conducting household appliance such as a washing machine, dishwasher, tumble dryer or the like, which is provided for positioning outside the treatment room of the water-conducting household appliance and has no connection to a water-carrying pipe of the water-conducting household appliance.
- the invention relates to a metering system with at least one fluid line, which connects the metering system with the treatment chamber of the water-conducting household appliance via an opening in communication with the treatment room.
- Machine washing and dishwashing detergents are available to the consumer in a variety of forms. These machine washing and dishwashing agents are typically offered to the consumer in solid form, for example as powders or as tablets, but increasingly also in liquid or gel form. For some time now, the main focus has been on the dosage of detergents and cleaning agents and the simplification of the steps necessary to carry out a washing or cleaning process.
- laundry detergents and cleaners were preferably added to new ingredients, for example more active surfactants, polymers, enzymes or bleaches.
- new ingredients for example more active surfactants, polymers, enzymes or bleaches.
- the object of the invention is to provide a metering system for a water-conducting household appliance that provides an improved dosage of a plurality of preparations in the treatment room of the water-conducting household appliance.
- At least one storage container for storing a plurality of dosing portions of at least one flowable preparation
- At least one dosing device At least one dosing device
- At least one sensor that at least detects the presence of water in the water-bearing household appliance
- At least one pump which causes a conveyance of preparation from the storage container or metering device
- At least one control unit which interacts with the sensor and the pump in such a way that, when a defined sensor signal, at least one preparation from the storage container or metering device is conveyed by means of the pump, as well as
- At least one fluid line which connects the reservoir or the dosing device with the treatment chamber of the water-bearing household appliance, so that a preparation from outside the treatment room of the water-bearing Household appliance positioned dosing over a communicating with the treatment room opening of the water-conducting household appliance in the treatment room of the water-bearing household appliance can be fed.
- the dosing system according to the invention can be used with existing water-conducting household appliances without having to structurally change existing water-conducting domestic appliances. Furthermore, it is possible to integrate the dosing system in the water-conducting household appliance, that the fluid line preferably for the user is not visible within the water-bearing household appliance. Furthermore, the dosing system, in particular the preparation contained reservoir, positioned outside of the treatment room, so that it is no mechanical, hydraulic or thermal influences that usually prevail in a treatment room (rotating laundry drum, hot water, steam, etc.) is exposed.
- the dosing system permits precise and appropriate dosing, in particular of preparations which are not storage-stable with one another.
- the invention makes it possible to deliver liquid detergent composition in a time-optimized manner to a washing process, so that excellent washing performance can be achieved with minimal use of raw materials, in particular in the area of enzymatically degradable and bleachable soils in connection with a very appealing perfuming on the laundry.
- the metering system comprises a metering device and at least one storage container which can be coupled to the metering device and contains at least one flowable preparation, preferably with a plurality of chambers, in particular preferably with 3-4 chambers.
- the metering device is configured such that it can meter a plurality of preparations from the chambers of a storage container and / or from several storage containers into the interior of a washing machine.
- at least one actuator and / or at least one closure element and / or at least one control unit and / or at least one sensor and / or at least one energy source can be provided in the dosing device.
- the dosing device can be fixed with a water-conducting household appliance, eg. B. a washing machine be installed.
- the dosing device is not permanently installed with the water-conducting household appliance, but freely movable in, on or on a water-bearing household appliance by a user positionable. It is particularly preferred that the dosing device comprises at least a first interface which cooperates with a corresponding interface formed in or on a water-conducting domestic appliance in such a way that transmission of electrical energy and / or signals from the water-conducting domestic appliance to the dosing device and / or or is realized by the metering device for water-conducting household appliance.
- the interfaces are formed by connectors.
- the interface cells can be designed in such a way that a wireless transmission of electrical energy and / or electrical and / or optical signals is effected.
- the interfaces provided for the transmission of electrical energy are inductive transmitters or receivers of electromagnetic waves.
- the interface of a water-conducting domestic appliance, as an alternating current-operated transmitter coil with iron core and the interface of the dosing device can be designed as a receiver coil with iron core.
- the transmission of electrical energy can also be provided by means of an interface, the home appliance side an electrically operated light source and dosier confuse smell a light sensor, such as a photodiode or a solar cell comprises.
- a light sensor such as a photodiode or a solar cell comprises.
- the light emitted by the light source is converted by the light sensor into electrical energy, which in turn feeds, for example, a metering device side accumulator.
- such an interface can be designed such that a wireless transmission of electrical energy and / or electromagnetic and / or optical signals is effected. It is particularly preferred that the interface is configured to transmit and / or receive optical signals. It is very particularly preferred that the interface is configured to emit or receive light in the visible range. It has proven particularly advantageous to use wavelengths between 600-800 nm in the visible spectrum.
- the interface is configured to emit or receive infrared signals.
- the interface is configured for transmitting or receiving infrared signals in the near infrared range (780nm-3,000nm).
- the interface comprises at least one LED.
- the interface comprises at least two LEDs. It is also possible according to a further preferred embodiment of the invention to provide at least two LEDs which emit light in a mutually different wavelength. This makes it possible, for example, to define different signal bands on which information can be sent or received.
- At least one LED is an RGB LED whose wavelength is adjustable.
- an LED can be used to define different signal bands that emit signals at different wavelengths.
- an optical signal is designed as a signal pulse with a pulse duration between 1 ms and 10 seconds, preferably between 5 ms and 100 ms seconds.
- the signal emitted and / or received by the interface is in particular a carrier of information, in particular a control signal or a signal representing an operating state of the dosing device and / or the water-conducting domestic appliance.
- the dosing device may comprise at least one optical receiving unit.
- the dosing device can receive signals from an optical transmission unit arranged in the water-conducting domestic appliance.
- This can be realized by any suitable optical receiving unit, such as photocells, photomultipliers, semiconductor detectors, photodiodes, photoresistors, solar cells, phototransistors, CCD and / or CMOS image sensors. It is particularly preferred that the optical receiving unit is suitable for receiving light in the wavelength range of 600-800 nm.
- the optical receiving unit on the dosing device can also be embodied such that the signals which can be coupled by the transmitting unit into a cartridge coupled to the dosing device can be decoupled from the cartridge and detected by the optical receiving unit of the dosing device.
- the signals emitted by the transmitting unit into the surroundings of the metering device may preferably represent information regarding operating conditions or control commands.
- the dosing device is arranged outside the washing machine in a preferred embodiment.
- the metering device may be designed so that it can be coupled with a container Vorratsbe and is provided for positioning outside the treatment chamber of the water-conducting household appliance and has no connection to a water-carrying pipe of the water-conducting household appliance.
- such a dosing device comprises at least one sensor which detects at least the presence of water in the water-conducting domestic appliance and / or the operation of a water-conducting domestic appliance, at least one pump which effects a delivery of preparation from the storage container or dosing apparatus, at least one control unit , which cooperates with the sensor and the pump in such a way that in the presence of a defined sensor signal, at least one preparation from the reservoir or metering device is conveyed by means of the pump, and at least one fluid line, the reservoir or the dosing device with connects the treatment room of the water-conducting household appliance, so that a preparation from the outside of the treatment room of the water-conducting household appliance positioned dosing over a communicating with the treatment room opening of the water-conducting household appliance in the treatment room of water-conducting household appliance can be supplied.
- a sensor is a measuring sensor or measuring sensor which can quantitatively record certain physical or chemical properties and / or the material quality of its environment qualitatively or as a measured variable.
- the dosing system preferably has at least one sensor which is suitable for detecting a temperature.
- the temperature sensor is designed in particular for detecting a water temperature. It is further preferred that the dosing system comprises a sensor for detecting the conductivity, whereby in particular the presence, the flushing and / or the spraying of water in a water-conducting domestic appliance is / are detected.
- a sensor from the group of timers, temperature sensors, infrared sensors, brightness sensors, motion sensors, strain sensors, speed sensors, proximity sensors, flow sensors, color sensors, gas sensors, vibration sensors, pressure sensors, conductivity sensors, turbidity sensors, sound pressure sensors, "lab-on-a-chip” Sensors, force sensors, acceleration sensors, inclination sensors, pH sensors, moisture sensors, magnetic field sensors, RFID sensors, Hall sensors, biochips, odor sensors, hydrogen sulfide sensors, position sensors, gyro sensors, optical, electrical and / or mechanical displacement sensors, and / or MEMS sensors selected.
- At least two sensors for measuring mutually different parameters are provided in or on the dosing system, wherein very particularly preferably one sensor is a conductivity sensor and another sensor is a temperature sensor.
- the sensors are in particular adapted to detect the beginning, course and end of a treatment program of a water-conducting household appliance, such as a washing or rinsing program.
- a treatment program of a water-conducting household appliance such as a washing or rinsing program.
- the sensor combinations listed in the following table can be used
- Vibration sensor temperature sensor By means of the conductivity sensor can be detected, for example, whether the conductivity sensor is wetted by water, so that can thus determine, for example, whether water is in the water-bearing household appliance or flushed.
- Treatment programs in water-bearing household appliances such as washing and rinsing programs, usually have a characteristic temperature profile, the u. a. is determined by the heating of the washing or rinsing water, which can be detected by a temperature sensor.
- the light penetration into the interior of a dishwasher can be detected when the dishwasher door is opened, resulting in e.g. indicates an end to the washing program.
- a vibration sensor By means of a vibration sensor, it is for example possible to detect natural oscillations or the resonance of a household appliance with a rotating treatment room, for example, if the washing drum is accelerated to spin the laundry to correspondingly high numbers of revolutions. Thus, it is conceivable to detect by means of a vibration sensor the beginning or the end of a spin cycle.
- a turbidity sensor can also be provided. From this it is also possible, for example, to select a dosing program in the dosing system which is appropriate for the identified contamination situation. It is also conceivable to recognize the course of a treatment program of a water-conducting domestic appliance with the aid of at least one sound sensor, by recording specific sound and / or vibration emissions, e.g. when pumping or pumping out of water, are detected.
- the data line between the sensor and the control unit can be realized via an electrically conductive cable or wirelessly.
- a wirelessly formed data line is in particular due to the transmis- formed electromagnetic wave or light. It is preferable to form a wireless data line according to standardized standards such as Bluetooth, IrDA, IEEE 802, GSM, UMTS, etc.
- At least one sensor is arranged on the distal end of the fluid line projecting into the treatment space.
- the sensor is in particular configured such that it is suitable for detecting the operation of the water-conducting domestic appliance and / or the flushing of water into the water-conducting domestic appliance.
- the sensor on the distal end of the fluid line projecting into the treatment space is a conductance and / or a temperature sensor and / or a sound or vibration sensor. pump
- the dosing system preferably comprises at least one pump and / or at least one atomizer or nebulizer for conveying or dispensing preparation from the dosing system into the treatment chamber of a water-conducting domestic appliance.
- a pump in the sense of this application is a fluid energy machine for moving or conveying a fluid by converting a mechanical drive power into a flow rate.
- fluids are liquids and gases, as well as mixtures thereof and solids.
- the pump can be selected from the group of positive displacement pumps, oscillatory pumps, diaphragm pumps, piston pumps, rotary pumps, dynamic pumps, centrifugal pumps, electrohydrodynamic pumps, electroosmotic pumps, magnetohydrodynamic pumps, surface acoustic wave pumps, capillary force pumps, electrowetting Pumps, thermo-capillary pumps.
- a fluid such as air
- the container may, for example, have a pressure compensation valve that releases the product flow from the storage container or from the metering system when a defined pressure in the storage container is exceeded.
- the dosing system has at least one vibrating atomizer, via which it is possible to transfer a preparation into the gas phase or to keep it in the gas phase.
- a preparation into the gas phase or to keep it in the gas phase.
- This embodiment is particularly advantageous when used in a washing machine, where a corresponding release of preparation into the gas phase takes place in a closable washroom.
- the introduced into the gas phase preparation can be evenly distributed in the washroom and reflected on the laundry located in the washing.
- the preparation released by the vibrating atomizer may be selected from the group of surfactant-containing preparations, enzyme-containing preparations, odor-neutralizing preparations, biocidal preparations, antibacterial preparations.
- a suitable preparation can suppress the formation of bad odors through biological decomposition processes.
- a corresponding preparation can cause a "softening" of the soiling possibly adhering to the laundry, so that they can easily and completely be removed in the washing program of the washing machine, in particular in the case of low-temperature programs.
- a preparation by means of the vibrating atomizer on the laundry after completion of a washing program.
- This may be, for example, an antibacterial preparation or a preparation for the modification of textile surfaces.
- the vibrating atomizer is formed as a piezoelectric element.
- the dosing device can be configured such that a control unit is provided, which is connected to the energy source, a sensor unit, a delivery element and a sound transducer, wherein ⁇ the sensor unit is a piezoelectric element, which is suitable to absorb vibrations, in particular sound waves in a frequency range of 1 kHz - 300 kHz, preferably 20-25 kHz and / or structure-borne noise from the environment of the dosing and convert it into a sensor signal which in the Control unit is converted into a control signal, in particular for the delivery element,
- the delivery element is a piezoelectric element that is supplied with electrical signals by the control unit and that sprays at least one first preparation from at least one chamber of the cartridge, which is communicatively connected to the delivery element,
- the sensor unit and the discharge element are formed as a component.
- the electrical signals which cause the spraying of a preparation have a frequency of 70-400 kHz, preferably 80-90 kHz.
- the dosing device can be configured such that a control unit is provided, which is connected to the energy source, a sensor unit, a delivery element and a sound transducer, wherein
- the sensor unit is a piezoelectric element, which is suitable to absorb vibrations, in particular sound waves in a frequency range of 1 kHz - 300 kHz, preferably 20-25 kHz and / or structure-borne noise from the environment of the dosing and convert it into a sensor signal which in the Control unit is converted into a control signal, in particular for the delivery element,
- the delivery element is a piezoelectric element that is supplied with electrical signals by the control unit and that sprays at least one first preparation from at least one chamber of the cartridge, which is communicatively connected to the delivery element,
- the transducer is a piezoelectric element that is applied by the control unit with electrical signals and the piezoelectric element in audible acoustic signals in a frequency range of 20 Hz to 20 kHz, preferably 5 - 15 kHz, particularly preferably 7 - 10 kHz walks and
- the sensor unit, the delivery element and the sound transducer are designed as a component.
- the electrical signals which cause the spraying of a preparation have a frequency of 70-400 kHz, preferably 80-90 kHz, and the electrical signals which cause the generation of an audible acoustic signal a frequency of 20 Hz - 20 kHz, preferably 5 - have 15 kHz and more preferably 7 - 10 kHz.
- the electrical signals that cause the spraying of a preparation and the generation of an audible acoustic signal can be applied to the piezoelectric element by the control unit at the same time and / or with a time delay.
- the above-described piezoelectric element provides a method of operating a metering system comprising:
- a sensor unit which is a piezoelectric element, receives vibrations, in particular sound waves in a frequency range of 1 kHz - 300 kHz, preferably 20-25 kHz, and / or structure-borne noise from the environment of the dispenser and in a
- a delivery element which is a piezoelectric element, from the control unit in the presence of a defined sensor signal, which in particular the presence of water and / or the operation of the washing machine, is supplied with electrical signals, so that at least a first preparation of at least one
- Chamber of the cartridge which is communicatively connected to the discharge element, in particular into the interior of the washing machine, preferably sprayed into the treatment room of the washing machine and / or is atomized,
- a sound transducer which is a piezoelectric element, from the control unit
- the piezoelectric element is particularly preferably configured in such a way that it detects the natural frequency or a multiple of the natural frequency of the washing machine, in particular during spin processes.
- the preparation released by the piezoelectric atomizer may in particular be selected from the group of surfactant-containing preparations, enzyme-containing preparations, odor-neutralizing preparations, biocidal preparations, antibacterial preparations.
- each preparation is metered in each case via a vibrating atomizer assigned to the corresponding preparation. It is of course possible to dose a preparation by means of a vibrating atomizer and another preparation by means of a pump, a valve or gravitationally effected in the interior of a water-conducting household appliance. The person skilled in the art will here select a suitable combination of the listed delivery elements for the corresponding preparations.
- a storage container is understood as meaning a packaging material which is suitable for wrapping or holding together at least one flowable preparation and which can be coupled to a metering device for dispensing at least one preparation.
- the storage container is provided for storing a plurality of dosing portions of at least one flowable preparation.
- the storage container for storing 10 to 50, more preferably 15 to 30, most preferably 20 to 25 Dosierportionen formed.
- the reservoir has at least three, preferably dimensionally stable chambers for storing mutually different preparations.
- each of the chambers is designed to store from 10 to 50, particularly preferably 15 to 30, very particularly preferably 20 to 25 metering portions.
- the storage container has a preferably rigid chamber for storing a preparation.
- a reservoir can also comprise a plurality of chambers which can be filled with mutually different preparations.
- the storage container has at least one outlet opening which is arranged such that a gravity-induced release of preparation from the storage container in the position of use of the dosing device can be effected.
- conveying means such as e.g. Pumps omitted.
- At least one second chamber is provided for receiving at least one second preparation, wherein the second chamber has at least one outlet opening which is arranged such that a gravity-induced product release from the second chamber in the position of use of the dosing device can be effected.
- the arrangement of a second chamber is particularly advantageous if in the separate chambers of the reservoir preparations are stored, which are usually not stable to each other, such as bleaching agents and enzymes.
- one of the chambers can also be designed for the delivery of volatile preparations, such as a fragrance to the environment.
- the reservoir is formed integrally.
- the storage container in particular by suitable blow molding, cost-effectively trained in a manufacturing step.
- the chambers of a storage container can be separated from one another, for example, by webs or material bridges, which are formed during or after the blow molding process.
- the reservoir can also be formed in several pieces by injection molded and then assembled components. Furthermore, it is conceivable that the storage container is formed in such a multi-piece, that at least one chamber, preferably all chambers, can be removed individually from the metering device or inserted into the metering device. This makes it possible, with a different consumption of a preparation from a chamber to exchange an already empty chamber, while the rest, which may still be filled with preparation, remain in the metering device. Thus, a targeted and needs-based refilling the individual chambers or their preparations can be achieved.
- the chambers can be coupled to one another or to the dosing device in only one specific position or position, thereby avoiding a user having to move a chamber in a position not intended for this purpose.
- the dosing unit connects.
- the chamber walls can in particular be shaped such that they can be positively connected to one another.
- a storage container formed from at least three chambers it is shaped in such a way that the chambers can be positively connected to one another only in a specific defined position relative to one another.
- the chambers of a storage container can be fixed to each other by suitable connection methods, so that a container unit is formed.
- the chambers can be fixed by a suitable form-fitting, non-positive or cohesive connection releasably or permanently against each other.
- the fixation can be achieved by one or more of the types of connections from the group of snap-in connections, Velcro connections, press connections, fusible links, glued connections, welded connections, soldered connections. conditions, screw connections, wedge connections, clamp connections or bounce connections.
- the fixation can also be formed by a heat-shrinkable tube (so-called SIeeve), which is pulled in a heated state over the entire or sections of the storage container and firmly encloses the chambers or the storage container in the cooled state.
- the reservoir can also be designed asymmetrically. It is particularly preferred to form the asymmetry of the reservoir so that the reservoir can be coupled only in a predefined position in with the dosing device, whereby an otherwise possible incorrect operation is prevented by the user.
- a metering chamber may be formed in a gravity-induced flow direction of the preparation in front of the outlet opening of a chamber. Through the metering chamber, the preparation amount that is to be released in the release of preparation from the chamber to the environment, set. This is particularly advantageous if the closure element of the dosing device, which causes the preparation output from a chamber to the environment, can only be put into a dispensing and a closure state without measuring or controlling the dispensing quantity. It is then ensured by the metering chamber that a predefined amount of preparation is released without an immediate feedback of the currently discharged, outflowing preparation amount.
- a storage container with a plurality of chambers, which preferably contain mutually different preparations, is provided.
- a plurality of storage containers are coupled to the dosing device.
- the metering system has at least one fluid line which connects the storage container or the metering device to the treatment chamber of the water-bearing household appliance, so that a preparation from the metering device positioned outside the treatment chamber of the water-conducting domestic appliance has a connection with the treatment room Opening the water-conducting household appliance in the treatment room of the water-conducting household appliance can be fed. It is particularly preferred that in each case a fluid line for each preparation is present.
- the fluid line may be formed, for example, of a flexible hose. However, it is also conceivable to form the fluid line as a dimensionally stable channel.
- the opening of the water-conducting domestic appliance which is in communication with the treatment chamber is the dispenser drawer of a washing machine.
- the opening of the water-conducting household appliance that is in communication with the treatment chamber is the washing machine or dishwasher door.
- the opening associated with the treatment room is formed as an interface between the water-conducting household appliance and the metering system.
- a control unit in the sense of this application is a device which is suitable for influencing the transport of material, energy and / or information.
- the control unit influences at least one actuator with the aid of information, in particular of measuring signals of the sensor unit, which processes it in the sense of the control target.
- at least one sensor is connected to the control unit, wherein it is particularly preferred that the sensor sends a signal to the control unit that represents the presence of water, for example in the washing machine and / or the operation of the washing machine.
- control unit may be a programmable microprocessor.
- a plurality of dosing programs is stored on the microprocessor, which are selectable and executable in a particularly preferred embodiment according to the container coupled to the dosing device.
- the control unit has, in a preferred embodiment, no connection to the possibly existing control of the household appliance. Accordingly, no formations, in particular electrical, optical or electromagnetic signals, exchanged directly between the control unit and the control of the household appliance.
- control unit is coupled to the existing control of the household appliance.
- this coupling is wireless.
- a transmitter on or in a dishwasher preferably on or at the dosing chamber embedded in the door of the dishwasher, which wirelessly transmits a signal to the dosing unit when the control of the domestic appliance controls the dosing of, for example, a detergent from the dosing unit Dosing or rinse aid causes.
- the delivery of preparations from the dosing device can be controlled by the control unit, sequentially or simultaneously.
- a signal which represents the presence of water and / or the operation of a domestic water-conducting appliance such as a washing machine, this signal allowing the dosage of at least one first preparation into the treatment room e.g. a washing machine triggers.
- the sensor signal can be provided in particular by means of a conductivity sensor, temperature sensor, sound sensor, vibration sensor, motion sensor and / or turbidity sensor - and any combination of the aforementioned sensors.
- a particularly preferred method for controlling a metering device for use in the metering system comprises a metering device with at least one temperature sensor and / or a conductivity sensor, wherein the temperature sensor and / or the conductivity sensor can be arranged in and / or on and / or outside of the metering device , and a dispensing means for releasing a preparation from the dispenser inside the dishwasher, comprising the measurement of a first resistor R, wherein when the condition R ⁇ R Re f, where R Re f is a predefined reference resistance, the presence of water on Leitwertsensor represents a release of at least one volume V1 of a first preparation from the metering device takes place inside the water-bearing household appliance.
- a measurement of a first temperature Ti inside the water-bearing household appliance by means of the temperature sensor and measurement of the resistance R at the conductivity sensor wherein in the presence of the conditions Ti> T Re fi, where T Re fi is a predefined, first reference temperature which is at least 21 ° C., preferably at least 30 ° C., and wherein, when the condition R ⁇ R Re f, where R Re f is a predefined reference resistance representing the presence of water at the conductivity sensor, is one Release of at least one volume V1 of a first preparation from the metering device takes place inside the water-bearing household appliance.
- temperature and conductivity information prevents, among other things, that the dosing device in a warm environment, such as during transport, initiates an undesired dosing process, which could happen by the sole use of temperature information for the control of the dosing device.
- the temperature T-i and the resistance R at the conductivity sensor can be measured one after the other or at the same time. It is preferred that first the temperature T-i and subsequently the resistance R is measured. However, it is also conceivable first to measure the resistance R and then the temperature T-i.
- a first volume V1 of a first preparation and a second volume V2 of a second preparation can also be dosed substantially simultaneously, wherein it is particularly preferred that the preparations are different from one another.
- a temperature rise which is detected in the heating phase of the water-conducting household appliance, in particular in the pre-washing or Haupt Hughes- or washing section of a rinsing or washing program.
- a renewed temperature measurement of the first temperature Ti is carried out after a preliminary -defined time t dif, especially after 2-10 min, preferably 3-7 min, particularly preferably initiated 4-6 min.
- the temperature is preferably measured not continuously, but at predefined time intervals.
- a second reference temperature T Re f2 which is greater than the first reference temperature T. Re fi is exceeded.
- a second reference temperature which is at least 35 ° C, preferably at least 40 ° C, is a measurement of the resistance R takes place at the conductivity sensor and in the presence of the condition R ⁇ R Re f, where R Re f is a predefined reference resistance representing the presence of water at the conductivity sensor, an immediate release of at least one volume V1 of a first preparation from the metering device into the interior of the water-conducting household appliance.
- condition R> R Ref where R Ref is a predefined reference resistance which represents the presence of water on the conductivity sensor, is a renewed temperature measurement of the first temperature Ti after a predefined time t dif . in particular after 10-600 sec, preferably after 30-240 sec, particularly preferably 45-100 sec.
- this time interval is less than or equal to the time interval that is before the measurement of the first temperature Ti in the presence of the condition Ti ⁇ T Re fi.
- the dosing device is switched by shortened monitoring intervals in the measurement of the first temperature Ti in a tightened monitoring mode, so that by the shortened monitoring intervals a timely detection of water in water-bearing household appliance is made possible.
- a second volume V2 of a second preparation from the metering device is introduced into the interior of the water-bearing domestic appliance, the first preparation being different from the second preparation and between the dosage of V1 and V2 is a predefined time interval t diff , preferably between 30-300 sec, more preferably between 60-240 sec, most preferably between 60-150 sec.
- t diff preferably between 30-300 sec, more preferably between 60-240 sec, most preferably between 60-150 sec.
- the first preparation is an enzyme-containing preparation and the second preparation is an alkaline and / or bleach-containing preparation.
- the first preparation is a first enzyme-containing preparation and the second preparation is a second enzyme-containing preparation, wherein the first and the second enzyme-containing preparation are different from each other.
- the method according to the invention further develop in such a way that after the metering of the first volume V1 and the second volume V2, the metering of a third volume V3 of a third preparation from the metering device takes place inside the washing machine, the third preparation is different from the first and the second preparation.
- the third preparation is, for example, fragrance-containing preparation.
- the metering of the third volume V3 takes place after the start of a wash program section in a wash program.
- the beginning of a wash program section is characterized in particular by the fact that after the main wash cycle has ended and before the start of the wash program section, a water change takes place in the washing machine, in which normally heated water is pumped off and cold wash water is fed to the wash process. This can be sensed by a conductivity measurement in connection with a temperature measurement, for example. Of course, other possible metrologically detectable characteristics that represent such a water change can be used.
- the metering of the third volume V3 takes place after a delay of 0.5 to 30 minutes, preferably 1 to 20 minutes, particularly preferably 5 to 15 minutes after the start of a washing program section in a washing program.
- the discharge quantities of the first volume V1, of the second volume V2 and of the third volume V3 preferably have a ratio of 1: 4: 1, wherein the first volume V1 particularly preferably contains an enzyme-containing preparation, the second volume V2 an alkaline detergent preparation and the third volume a fragrance-containing preparation is.
- the term "energy source” is understood to mean a component of the dosing system which is suitable for operating a dosing system or dosing system. appropriate energy.
- the energy source is designed such that the dosing system is self-sufficient.
- the energy source provides electrical energy.
- the energy source may be, for example, a battery, an accumulator, a power supply, solar cells or the like.
- a battery may be selected from the group of alkaline manganese batteries, zinc carbon batteries, nickel oxyhydroxide batteries, lithium batteries, lithium iron sulfide batteries, zinc air batteries, zinc chloride batteries, Mercury oxide zinc batteries and / or silver oxide zinc batteries.
- Lead accumulators lead dioxide / lead
- nickel-cadmium batteries nickel-metal hydride batteries
- lithium-ion batteries lithium-polymer batteries
- alkaline-manganese batteries silver-zinc batteries
- nickel batteries etc.
- Hydrogen batteries zinc bromine batteries, sodium nickel chloride batteries and / or nickel-iron batteries.
- the accumulator can in particular be designed in such a way that it can be recharged by induction.
- mechanical energy sources consisting of one or more coil spring, torsion spring or torsion bar spring, spiral spring, air spring / gas spring and / or elastomer spring.
- the energy source is dimensioned such that the dosing device can pass through about 1000 dosing cycles before the energy source is exhausted. It is particularly preferred that the energy source can run between 1 and 1000 dosing cycles, most preferably between 10 and 500, more preferably between 100 and 300, before the energy source is exhausted.
- the preparations stored in the storage container or in the chambers of the storage containers are free-flowing, preferably they have a viscosity of between 10 and 10,000 mPas (Brookfield viscometer RVD-VII at 20 rpm and 20 ° C., spindle 3).
- the preparations in the chambers or the storage containers are different from each other. The possible constituents of the preparations are explained in more detail below.
- At least one of the preparations stored in the cartridge chambers contains at least one enzyme, in particular e.g. from the group of proteases, amylases, catalases, peroxidases, cellulases, mannanase, polyesterases, xylanases, carrageenases, perhydrolases, pectinases, pectate lyases, oxidases, e.g.
- Glycose oxidases and / or lipases, and / or enzyme stabilizers preferably in amounts of 0 to 50 wt .-%, preferably 5-30 wt .-%, particularly preferably 10-25 wt .-% in each case based on the total agent.
- Particularly suitable enzymes are those from the classes of hydrolases such as the proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases and mixtures of the enzymes mentioned. All of these hydrolases in the wash contribute to the removal of stains such as proteinaceous, greasy or starchy stains and graying. In addition, cellulases and other glycosyl hydrolases may contribute to color retention and to enhancing the softness of the fabric by removing pilling and microfibrils. Oxireductases can also be used for bleaching or inhibiting color transfer.
- hydrolases such as the proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases and mixtures of the enzymes mentioned. All of these hydrolases in the wash contribute to the removal of stains such as proteinaceous, greasy or starchy stains and graying.
- subtilisin-type proteases and in particular proteases derived from Bacillus lentus are used.
- Enzyme mixtures are, for example, from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or, respectively.
- lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular interest.
- lipolytic enzymes are the known cutinases.
- Peroxidases or oxidases have also proved suitable in some cases.
- Suitable amylases include in particular ⁇ -amylases, iso-amylases, pullulanases and pectinases.
- Cellulases used are preferably cellobiohydroases, endoglucanases and .beta.-glucosideas, which are also cellobiases, or mixtures thereof. Since different cellulase types differ in their CMCase and avicelase activities, targeted mixtures of the cellulases can be used to set the desired activities. bleaching
- At least one of the preparations stored in the chambers or storage containers contains at least one bleach.
- any oxidizing agent can be used, e.g. Perborates, percarbonates, hydrogen peroxide, sodium hypochlorite, dichromate, dithionite, permanganate, chlorine, concentrated sulfuric acid, organic peracids, hypochlorite, chlorine dioxide, peroxides, etc ..
- the oxidizing agent is an oxidative bleaching agent, preferably based on oxygen, with particular preference being given to peroxycarboxylic acids.
- At least one of the preparations stored in the chambers or storage containers contains at least one surfactant.
- At least one preparation contains at least 0.1% by weight of surfactants.
- the surfactant content of the entire composition is preferably 0, 1-60% by weight.
- Glaskorrosioninhibitoren prevent the occurrence of turbidity, streaks and scratches but also iridescence of the glass surface of glasses, as used in particular for washing machine doors.
- Preferred glass corrosion inhibitors come from the group of magnesium and zinc salts and magnesium and zinc complexes.
- At least one zinc salt of an organic carboxylic acid is used as the glass corrosion inhibitor.
- the content of zinc salt in detergents or cleaners is preferably between 0.1 and 5% by weight, based on the total weight of the glass corrosion inhibitor-containing agent.
- the preparations may contain further ingredients which further improve the performance and / or aesthetic properties of the preparation.
- the preparations may additionally contain one or more substances from the group of builders, bleach catalysts, sators, bleach activators, enzyme stabilizers, electrolytes, solvents, pH adjusters, perfume carriers, fluorescers, dyes, hydrotopes, foam inhibitors, silicone oils, anti-redeposition agents, grayness inhibitors, anti-shrinkage agents, crease inhibitors, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, preservatives , Corrosion inhibitors (including glass corrosion inhibitors), antistatic agents, bittering agents, ironing aids, repellents and impregnating agents, swelling and anti-slip agents, textile softening components, complexing agents, fragrances, optical brighteners, foam inhibitors, UV absorbers and other conditioning have.
- Example 1 shows in the following table a first assignment of three storage containers and / or chambers of a storage container.
- the first chamber is designed as an enzyme chamber, the second chamber as a bleaching chamber and the third chamber as a fragrance chamber. Further components of the respective chamber can be taken from the following table.
- the chamber 1 has a substantially neutral pH between 6-8, the chamber 2 has a substantially alkaline pH of 8-12, preferably 8-1 1, more preferably 8-10, and the chamber has a essentially neutral pH between 6-8.
- the chamber 1 is dosed in a time interval immediately at the beginning up to 15 minutes after the start of a washing program.
- the second chamber is dosed between 10 and 30 minutes after the start of a wash program, it being preferred that the release of the first chamber and the second chamber is not simultaneous.
- a time interval of 0.5-30 minutes, preferably 1-15 minutes, particularly preferably 5-15 minutes.
- the third chamber is dosed after the beginning of a rinse program section.
- the third chamber is dosed for 0.5-30 minutes, preferably 1-15 minutes, more preferably 5-15 minutes after the beginning of a rinse program section.
- Example 2 differs from Example 1 in that chamber 3 additionally contains a component for improving the softness in the form of at least one surfactant, preferably a cationic surfactant.
- a surfactant preferably a cationic surfactant.
- suitable polymers can also be used as fabric softening compounds.
- Example 3 differs from Example 1 in that in chamber 3 additionally an antimicrobial compound, for. As a disinfectant contains. In this course, an acidic pH of 1 -3 is set in chamber 3.
- Example 4 differs from Example 1 in that in chamber 3 additionally contains an optical brightener.
- Example 5 differs from Example 1 in that chamber 3 additionally contains an antimicrobial compound, e.g. As a disinfectant, and contains an optical brightener.
- an antimicrobial compound e.g. As a disinfectant, and contains an optical brightener.
- Example 6 differs from Example 1 in that chamber 2 additionally contains a bleach catalyst.
- Example 7 differs from Example 1 in that in chamber 1 and chamber 2 additionally a foam inhibitor is present.
- Example 8 differs from Example 1 in that in chamber 1 and chamber 2 additionally a color transfer inhibitor is present.
- Example 9 differs from Example 1 in that there is additionally an ironing aid in chamber 3.
- Example 10 differs from Example 1 in that the preparation stored in chamber 1 has a substantially acidic pH of 3-7, preferably 3-6.
- the dosage of a first, acidic preparation can prevent the formation and the setting of poorly soluble deocomponents (aluminum salts) by high pH values, so that such soiling can be easily removed by the surfactants and enzymes contained in an acidic environment.
- Example 1 differs from Example 1 in that the lead-containing preparation stored in chamber 2 is metered into the washing process at two different times.
- the bleach-containing preparation is dosed a first time between 10 and 30 minutes after the start of a wash program and a second time after the beginning of a wash program section, preferably 0.5-30 minutes, preferably 1-15 minutes, more preferably 5-15 minutes after the start of a Rinse program section dosed. It is very particularly preferred to dispense the bleach-containing preparation from the second chamber not at the same time but with a time delay to the fragrance-containing preparation from the third chamber after the beginning of the rinse program section.
- Example 12 shows in the following table a first allocation of three storage containers and / or chambers of a storage container.
- the first chamber is used as the first enzyme chamber, the second chamber as the second enzyme chamber, wherein the enzyme preparations of the first and second chambers are different from each other and the third chamber formed as a fragrance chamber.
- the chamber 1 has a substantially neutral pH between 6-8
- the chamber 2 preferably has a substantially neutral pH of 6-8
- the chamber has a substantially neutral pH between 6-8.
- the chamber 1 is dosed in a time interval immediately at the beginning up to 15 minutes after the start of a washing program.
- the second chamber is dosed between 10 and 30 minutes after the start of a wash program, it being preferred that the release of the first chamber and the second chamber is not simultaneous.
- a time interval of 0.5-30 minutes, preferably 1-15 minutes, particularly preferably 5-15 minutes.
- the third chamber is dosed after the beginning of a rinse program section.
- the third chamber is dosed for 0.5-30 minutes, preferably 1-15 minutes, more preferably 5-15 minutes after the beginning of a rinse program section.
- Example 13 differs from Example 12 in that in chamber 3 additionally a component for improving the softness in the form of at least one surfactant, preferably a cationic surfactant, is present.
- a component for improving the softness in the form of at least one surfactant preferably a cationic surfactant
- suitable polymers may be used to improve the softness.
- Example 14 differs from Example 12 in that chamber 3 additionally contains an anti-microbial compound, e.g. As a disinfectant contains.
- an anti-microbial compound e.g. As a disinfectant contains.
- Example 15 differs from Example 12 in that chamber 3 additionally contains an optical brightener.
- Example 16 differs from Example 12 in that chamber 3 additionally contains an anti-microbial compound, e.g. As a disinfectant, and contains an optical brightener.
- an anti-microbial compound e.g. As a disinfectant, and contains an optical brightener.
- Example 17 differs from Example 12 in that in chamber 1 and chamber 2 additionally a foam inhibitor is present.
- Example 18 differs from Example 12 in that in chamber 1 and chamber 2 additionally a color transfer inhibitor is present.
- Example 19 differs from Example 12 in that in chamber 3 additionally an ironing aid is present.
- Example 20 differs from Example 12 in that the preparation stored in chamber 1 has a substantially acidic pH of 3-7, preferably 3-6.
- the dosage of a first, acidic preparation can prevent the formation and the setting of poorly soluble deocomponents (aluminum salts) by high pH values, so that such soiling can be easily removed by the surfactants and enzymes contained in an acidic environment.
- Example 21 differs from Example 12 in that the preparation of the first chamber has a substantially neutral pH, while the preparation of the second chamber is made alkaline at a pH of 8-12.
- Example 22 differs from Example 12 in that the preparation of the second compartment is alkaline at pH 8-12 and compartment 2 contains a bleach.
- FIG. 1 shows a metering system for a washing machine with a fluid line opening into the dispensing drawer of the washing machine
- FIG. 2 shows a metering system for a washing machine with fluid lines opening in the dispensing drawer of the washing machine
- FIG. 3 shows a metering system for a washing machine with a plurality of dosing devices
- Fig. 4 shows an adapter for coupling the dosing with a Ein Actuallyschublade a
- FIG. 5 shows a metering system for a washing machine with a fluid line, which is guided through the washing machine door in the treatment room.
- FIG. 6 shows a washing machine with an interface for the metering system according to the invention
- Figure 7 is a schematic sectional view of the dosing system with reservoir on the suction side of the pump.
- FIG. 8 shows a schematic sectional view of the metering system with reservoir on the pressure side of the pump
- the metering system 1 shows a first possible embodiment of the metering system 1 according to the invention.
- the metering system 1 consists of a metering device 5 which is detachably coupled to a plurality of storage containers 3a, 3b, 3c.
- the storage containers 3a, 3b, 3c can be removed individually from the dosing device 5. It is also conceivable to form the storage containers 3a, 3b, 3c as a cartridge which has three chambers 3a, 3b, 3c, the chambers 3a, 3b, 3c being fixed to one another in a separable or inseparable manner.
- a control unit for controlling the dosing device 5, an energy source, preferably as a battery, accumulator or power plug and a pump that promotes the preparations from the reservoirs 3a, 3b, 3c.
- an energy source preferably as a battery, accumulator or power plug
- a pump that promotes the preparations from the reservoirs 3a, 3b, 3c.
- a fluid line 7 is arranged, through which the pumped by the pump preparation to Ein istschublade 8 of the washing machine 2 are passed.
- the free, distal end of the fluid line 7 is positioned in the dispenser drawer 8. It is also possible to couple the fluid line 7 with the Ein effetschublade 8 by means of an adapter provided for this purpose. This will be discussed in more detail elsewhere.
- a preparation dosed by the dosing device 5 reaches the treatment chamber 6 of the washing machine 2.
- the dosing device 5 doses at least one of the preparations from the storage containers 3a, 3b, 3c in accordance with a dosing program stored in the control unit.
- the fluid line 7 may in particular be formed of a flexible hose, preferably of plastic.
- the fluid conduit 7 can be positioned in the Ein effetschublade 8 in a manner that is simple for a user.
- the fluid line 7 can additionally be designed that it is pinch-proof, that is, the line cross-section is substantially maintained, even if the fluid line 7 is squeezed off, for example, by the Ein effetschublade 8 of an object standing on the line. It is also conceivable to form the fluid line 7 as a rigid channel.
- a vibrating atomizer may be provided, which is in particular configured so that it can spray preparation and detect vibrations and / or sound from the environment.
- FIG. 2 shows the metering system 1 known from FIG. 1, wherein a separate fluid line 7a, 7b, 7c is provided for each of the preparations to be released from the storage containers 3a, 3b, 3c.
- the free distal ends of the fluid lines 7a, 7b, 7c can be positioned in a dispensing chamber of the dispensing drawer 8 or in different dispensing chambers of the dispensing drawer 8.
- each dosing device 5a, 5b, 5c in each case a storage container 3a, 3b, 3c is coupled to preparations which are different from one another.
- a storage container 3a, 3b, 3c is coupled to preparations which are different from one another.
- FIG. 3 Each of the dosing devices 5a, 5b, 5c has in each case a fluid line 7a, 7b, 7c whose free, distal end open into in each case different dispensing chambers 8a, 8b, 8c of the dispensing drawer 8.
- the fluid line 7 is designed in particular as a squeeze-proof hose.
- the distal end of the fluid conduit 7 is fixed to the inside of the washing machine door, for example by a suction cup or an adhesive.
- a vibrating atomizer which is configured to spray preparation and to detect vibrations and / or sound from the environment.
- Fig. 5 can be dispensed with the use of a pump, since due to the geodetic difference in height between the dosing device and the vibrating atomizer at the distal end of the fluid conduit 7 preparation is always present at the distal end of the fluid conduit 7.
- interfaces 10a, 10b, 10c are provided on the washing machine 2, which allow a coupling with the dosing device 5 in such a way that a fluid connection via the interfaces 10, 10b, 10c between a preferably rigid fluid line 7a, 7b, 7c of the metering device 5 and the treatment chamber 6 of the washing machine can be produced.
- FIG. 7 shows the metering system 1 according to the invention, which consists of the metering device 5 and a reservoir 3 connected to the metering device 5 and containing a preparation 4.
- the dosing device 5 comprises an energy source 13, a control unit 14, a sensor 15 and a pump 12, these components preferably being integrated in a housing.
- the pump 12 is connected to the power source 13 via the control unit 14.
- the control unit 14 in turn is connected to the sensor 15, which conducts measurement signals to the control unit 14.
- the pump 12 has a pressure-side fluid line 7 and a suction line 16, wherein the suction line 16 is connected to the reservoir 4 containing the preparation 4.
- the pump 12 thus promotes the flowable preparation 4 via the suction line 16 from the reservoir 3 into the pressure-side fluid line 7 from where the preparation 4 is discharged into the treatment chamber 6 of the water-conducting household appliance 2.
- the reservoir 3 may have a pressure compensation valve 17, which causes a pressure equalization between the environment and the interior of the reservoir 3, when the pump 12 pumping preparation 4 from the reservoir 3 out.
- the pump 12 can be controlled by the control unit 4 such that the conveying direction of the pump 12 is reversed and in the pump 12 and the lines 7 and 16 still located preparation 4 are returned to the reservoir 3.
- This backwashing can be particularly advantageous if the preparation 4, for example, for thickening and thus for bonding the lines 7 or 16 tends.
- FIG. 8 shows a further embodiment of the metering system known from FIG. 7, in which the storage container 3 is connected to the pump 12 on the pressure side.
- the pump 12 builds up a pressure in the reservoir 3 by pumping ambient air into the reservoir 3.
- a valve 17b may be provided that releases the preparation 4 from the storage container 3 only when a defined pressure in the storage container 3 is reached.
- a check valve 17 a may be arranged, which prevents the built-up in the reservoir 3 pressure escapes at standstill of the pump 12 through the pressure line 7.
- the preparation output side of the container 3 is connected via a fluid line, which is not shown, with the treatment chamber 6 of a water-conducting household appliance.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Detail Structures Of Washing Machines And Dryers (AREA)
- Washing And Drying Of Tableware (AREA)
- Control Of Washing Machine And Dryer (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102010027991A DE102010027991A1 (de) | 2010-04-20 | 2010-04-20 | Dosiersystem zur Verwendung in Verbindung mit einem wasserführenden Haushaltsgerät wie eine Waschmaschine, Spülmaschine, Wäschetrockner oder dergleichen |
PCT/EP2010/066771 WO2011131260A1 (de) | 2010-04-20 | 2010-11-04 | Dosiersystem zur verwendung in verbindung mit einem wasserführenden haushaltsgerät wie eine waschmaschine, spülmaschine, wäschetrockner oder dergleichen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2524079A1 true EP2524079A1 (de) | 2012-11-21 |
EP2524079B1 EP2524079B1 (de) | 2018-04-11 |
Family
ID=43567600
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10778963.8A Active EP2524079B1 (de) | 2010-04-20 | 2010-11-04 | Dosiersystem zur verwendung in verbindung mit einem wasserführenden haushaltsgerät wie eine waschmaschine, spülmaschine, wäschetrockner oder dergleichen |
Country Status (5)
Country | Link |
---|---|
US (1) | US20130042652A1 (de) |
EP (1) | EP2524079B1 (de) |
KR (1) | KR20130062271A (de) |
DE (1) | DE102010027991A1 (de) |
WO (1) | WO2011131260A1 (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105350261A (zh) * | 2015-11-20 | 2016-02-24 | Tcl家用电器(合肥)有限公司 | 洗涤剂投放系统和洗衣机 |
IT201900022392A1 (it) | 2019-11-28 | 2021-05-28 | Salros S R L | Composizione di lavaggio liquida a componenti separati, per bucato in macchine lavatrici automatiche |
Families Citing this family (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010002048A1 (de) * | 2010-02-17 | 2011-08-18 | BSH Bosch und Siemens Hausgeräte GmbH, 81739 | Verfahren zur Einstellung einer Schleuderdrehzahl einer Trommel eines Hausgeräts zur Pflege von Wäschestücken |
DE102010027992A1 (de) * | 2010-04-20 | 2011-10-20 | Henkel Ag & Co. Kgaa | Dosiersystem zur Freisetzung von wenigstens drei unterschiedlichen Zubereitungen während eines Waschprogramms einer Waschmaschine |
GB2496857A (en) * | 2011-11-22 | 2013-05-29 | Reckitt & Colman Overseas | A method and device for dispensing detergent in a washing machine |
DE102011089122A1 (de) * | 2011-12-20 | 2013-06-20 | BSH Bosch und Siemens Hausgeräte GmbH | Haushaltsgerät mit einer Nebelquelle und einem Kreislauf zur Medienführung |
EP2703544B1 (de) | 2012-08-28 | 2016-06-08 | Miele & Cie. KG | Dosierbehältnis für Reinigungsmittel und Verfahren zur Dosierung von Reinigungsmittel |
AT515709A1 (de) * | 2014-04-30 | 2015-11-15 | Hans Georg Hagleitner | Dosiersystem zur dosierten Abgabe von in Gebinden gelagerten chemischen Substanzen an eine Geschirrspülmaschine oder Waschmaschine |
CN104047146A (zh) * | 2014-06-13 | 2014-09-17 | 合肥荣事达三洋电器股份有限公司 | 一种洗衣机用自动投放洗涤剂装置 |
DE102015209824A1 (de) | 2015-05-28 | 2016-12-01 | BSH Hausgeräte GmbH | Vorrichtung und Verfahren zur Bestimmung der Schmutzfracht in einer Spül- oder Waschflotte |
DE102015111045A1 (de) * | 2015-07-08 | 2017-01-12 | Miele & Cie. Kg | Dosiervorrichtung sowie Verfahren zum Hinzufügen zumindest eines Waschzusatzes in einen Laugenbehälter einer Maschine zum Waschen von Wäsche |
EP3387125B1 (de) | 2015-12-07 | 2022-10-12 | Henkel AG & Co. KGaA | Geschirrspülmittel enthaltend polypeptide mit beta-glucanase-aktivität und verwendungen davon |
CN105442263B (zh) * | 2015-12-09 | 2019-08-23 | 无锡小天鹅电器有限公司 | 自动投放装置及其控制方法和具有它的洗衣机 |
CN106854813A (zh) * | 2015-12-09 | 2017-06-16 | 无锡小天鹅股份有限公司 | 洗衣机 |
CN106854814A (zh) * | 2015-12-09 | 2017-06-16 | 无锡小天鹅股份有限公司 | 自动投放衣物处理剂的洗衣机 |
CN106854815A (zh) * | 2015-12-09 | 2017-06-16 | 无锡小天鹅股份有限公司 | 自动投放衣物处理剂的洗衣机 |
US9988754B2 (en) * | 2016-03-24 | 2018-06-05 | Whirlpool Corporation | Apparatus and method for identifying treating chemistry in a laundry treating appliance dispensing assembly |
BR112018075525B1 (pt) | 2016-06-09 | 2022-11-29 | Unilever Ip Holdings B.V. | Dispositivo para fornecer uma dose do produto para lavagem de tecidos |
US10982373B2 (en) | 2016-06-09 | 2021-04-20 | Conopco, Inc. | Laundry liquid mixing apparatus |
IT201600086018A1 (it) * | 2016-08-18 | 2018-02-18 | Illinois Tool Works | Dispositivo ausiliario per l'erogazione di liquidi di lavaggio ad una lavatrice |
CN106283530A (zh) * | 2016-09-30 | 2017-01-04 | 无锡小天鹅股份有限公司 | 用于洗衣机的自动投放装置和洗衣机 |
US20190264364A1 (en) * | 2016-10-28 | 2019-08-29 | Conopco, Inc., D/B/A Unilever | Washing machine drawer insert dispenser |
EP3571344A1 (de) * | 2017-01-20 | 2019-11-27 | Unilever PLC | Vorrichtung zur bereitstellung eines waschmittels und spülzykluspflegemittelzusammensetzungen |
GB2562799B (en) * | 2017-05-26 | 2020-02-05 | Hydro Systems Europe Ltd | Control system for a liquid dosing apparatus |
BR112019026011A2 (pt) * | 2017-06-09 | 2020-06-23 | Unilever N.V. | Sistema de dispensação de líquido para lavagem de tecidos e recipiente para uso com o sistema de dispensação |
CN107657759A (zh) * | 2017-09-08 | 2018-02-02 | 青岛海尔滚筒洗衣机有限公司 | 一种用于自助洗涤设备的外置自动投放装置及控制方法 |
WO2019063691A1 (en) * | 2017-09-29 | 2019-04-04 | Unilever Plc | APPARATUS FOR MIXING LAUNDRY FLUIDS |
WO2019063798A1 (en) * | 2017-09-29 | 2019-04-04 | Unilever Plc | APPARATUS FOR MIXING LAUNDRY FLUIDS |
DE112018004426T5 (de) | 2017-10-05 | 2020-05-20 | Unilever N.V. | Verfahren und Vorrichtungen für individualisierte Wäsche |
GB2567693A (en) | 2017-10-23 | 2019-04-24 | Selden Res Ltd | A chemical dosing system |
CN111247283B (zh) * | 2017-10-25 | 2023-05-30 | E.G.O.电气设备制造股份有限公司 | 洗衣机贮槽、洗衣机和用于操作洗衣机的方法 |
GB2571336A (en) | 2018-02-26 | 2019-08-28 | Unilever Plc | Methods and system for monitoring and replenishing one or more laundry components |
DE102018203586A1 (de) * | 2018-03-09 | 2019-09-12 | Henkel Ag & Co. Kgaa | Vorrichtung mit Ausgabemodul und/oder Sensormodul |
CN110747598A (zh) * | 2018-07-05 | 2020-02-04 | 青岛海尔滚筒洗衣机有限公司 | 一种衣物处理装置的控制方法 |
CA3110505A1 (en) | 2018-08-27 | 2020-03-05 | Ecolab Usa Inc. | System and technique for extracting particulate-containing liquid samples without filtration |
CN113785039B (zh) | 2019-04-03 | 2024-06-18 | 诺维信公司 | 具有β-葡聚糖酶活性的多肽、编码其的多核苷酸及其在清洁和洗涤剂组合物中的用途 |
KR102657349B1 (ko) | 2019-04-12 | 2024-04-12 | 엘지전자 주식회사 | 세탁기 및 세탁기의 제어방법 |
WO2020209687A1 (en) * | 2019-04-12 | 2020-10-15 | Lg Electronics Inc. | Washing machine |
KR102638183B1 (ko) | 2019-04-12 | 2024-02-16 | 엘지전자 주식회사 | 세탁기 및 그 제어방법 |
KR102643589B1 (ko) | 2019-04-12 | 2024-03-04 | 엘지전자 주식회사 | 세탁기 및 세탁기의 제어방법 |
KR102604690B1 (ko) | 2019-04-12 | 2023-11-20 | 엘지전자 주식회사 | 세탁기 및 세탁기의 제어방법 |
KR102704631B1 (ko) | 2019-04-12 | 2024-09-06 | 엘지전자 주식회사 | 세탁기 및 세탁기의 제어방법 |
KR102638184B1 (ko) | 2019-04-12 | 2024-02-16 | 엘지전자 주식회사 | 세탁기 및 그 제어방법 |
KR102604689B1 (ko) * | 2019-04-12 | 2023-11-20 | 엘지전자 주식회사 | 세탁기 |
KR102644821B1 (ko) | 2019-04-12 | 2024-03-06 | 엘지전자 주식회사 | 세탁기 |
DE102019214481A1 (de) * | 2019-09-23 | 2021-03-25 | E.G.O. Elektro-Gerätebau GmbH | Ventileinrichtung für eine Dosiereinrichtung, Dosiereinrichtung und Haushaltsgerät |
US11910982B2 (en) | 2019-11-01 | 2024-02-27 | Conopco Inc. | Recyclable auto-dosing container |
CN111041781A (zh) * | 2019-12-31 | 2020-04-21 | 广州立白企业集团有限公司 | 一种外置式洗衣机自动投放的蠕动泵装置及自动投放方法 |
US11352730B2 (en) * | 2020-02-13 | 2022-06-07 | Haier Us Appliance Solutions, Inc. | Additive dispenser for varying the types of additives within a washing machine appliance |
US11959217B1 (en) * | 2021-10-05 | 2024-04-16 | Aliya Widener | Portable clothes-washing machine |
EP4162856A1 (de) * | 2021-10-07 | 2023-04-12 | Michael Saier | Dosiereinrichtung |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5392618A (en) * | 1993-09-14 | 1995-02-28 | Diversey Corporation | Low cost liquid chemical dispenser for laundry machines |
DE19654090C1 (de) * | 1996-12-23 | 1998-03-05 | Henkel Ecolab Gmbh & Co Ohg | Unabhängige Dosiersteuerung für Waschmaschinen |
DE10062111C1 (de) * | 2000-12-13 | 2002-07-25 | Miele & Cie | Verfahren zum Dosieren von Waschmittel |
US6792637B2 (en) * | 2002-01-08 | 2004-09-21 | U.S. Chemical Corporation | Automatic detergent dispensing system for a warewasher |
GB2386129B (en) | 2002-03-06 | 2004-12-01 | Reckitt Benckiser Nv | Detergent dosing device |
US7481081B2 (en) * | 2004-11-23 | 2009-01-27 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Automatic stand-alone dispensing device for laundry care composition |
US20070044820A1 (en) * | 2005-08-30 | 2007-03-01 | Johnsondiversey, Inc. | Automatically configurable chemical dispensing system for cleaning equipment |
DE102005062479A1 (de) | 2005-12-27 | 2007-07-05 | BSH Bosch und Siemens Hausgeräte GmbH | Dosiervorrichtung für die Zugabe eines Zuschlagmittels in einen Behandlungsraum und Geschirrspülmaschine mit einer Dosiervorrichtung |
CA2912081C (en) * | 2006-03-30 | 2017-09-26 | Diversey, Inc. | Powdered and liquid chemical dispensing and distribution system |
DE102006026800A1 (de) * | 2006-06-07 | 2007-12-13 | Henkel Kgaa | Dosiervorrichtung für fließfähige Zusammensetzungen |
DE202008001532U1 (de) * | 2008-02-01 | 2008-04-10 | Weber, Lothar Ernst Wilhelm | Vorrichtung zum Waschen oder Reinigen von Gegenständen |
DE102008007429A1 (de) * | 2008-02-01 | 2009-08-13 | Lothar Ernst Wilhelm Weber | Vorrichtung zum Waschen oder Reinigen von Gegenständen |
KR101482111B1 (ko) * | 2008-05-23 | 2015-01-13 | 엘지전자 주식회사 | 세탁기 |
KR101482108B1 (ko) * | 2008-05-23 | 2015-01-13 | 엘지전자 주식회사 | 세탁기 |
US8555678B2 (en) * | 2008-12-09 | 2013-10-15 | Lg Electronics Inc. | Washing machine system and washing method |
EP2395898A1 (de) * | 2009-02-16 | 2011-12-21 | Henkel AG & Co. KGaA | Kartusche |
JP2012525923A (ja) * | 2009-05-06 | 2012-10-25 | ディバーシー・インコーポレーテッド | 静電容量センサーアセンブリを用いる材料分注システム及び方法 |
DE102009045580A1 (de) * | 2009-10-12 | 2011-04-14 | Henkel Ag & Co. Kgaa | Tür zum flüssigkeitsdichten Verschluss einer Wäscheaufgabe- bzw. Entnahmeöffnung eines Wäschebehandlungsgeräts insbesondere einer Waschmaschine und/oder eines Wäschetrockners |
-
2010
- 2010-04-20 DE DE102010027991A patent/DE102010027991A1/de not_active Withdrawn
- 2010-11-04 EP EP10778963.8A patent/EP2524079B1/de active Active
- 2010-11-04 KR KR1020127027409A patent/KR20130062271A/ko not_active Application Discontinuation
- 2010-11-04 WO PCT/EP2010/066771 patent/WO2011131260A1/de active Application Filing
-
2012
- 2012-10-19 US US13/655,891 patent/US20130042652A1/en not_active Abandoned
Non-Patent Citations (1)
Title |
---|
See references of WO2011131260A1 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105350261A (zh) * | 2015-11-20 | 2016-02-24 | Tcl家用电器(合肥)有限公司 | 洗涤剂投放系统和洗衣机 |
CN105350261B (zh) * | 2015-11-20 | 2018-07-13 | Tcl家用电器(合肥)有限公司 | 洗涤剂投放系统和洗衣机 |
IT201900022392A1 (it) | 2019-11-28 | 2021-05-28 | Salros S R L | Composizione di lavaggio liquida a componenti separati, per bucato in macchine lavatrici automatiche |
EP4386072A2 (de) | 2019-11-28 | 2024-06-19 | Salros S.R.L. | Flüssige waschmittelzusammensetzung mit getrennten komponenten für wäsche und kit dafür und waschverfahren für automatische waschmaschinen |
Also Published As
Publication number | Publication date |
---|---|
DE102010027991A1 (de) | 2011-10-20 |
KR20130062271A (ko) | 2013-06-12 |
EP2524079B1 (de) | 2018-04-11 |
US20130042652A1 (en) | 2013-02-21 |
WO2011131260A1 (de) | 2011-10-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2524079B1 (de) | Dosiersystem zur verwendung in verbindung mit einem wasserführenden haushaltsgerät wie eine waschmaschine, spülmaschine, wäschetrockner oder dergleichen | |
EP2521810B1 (de) | Dosiersystem zur freisetzung von wenigstens drei unterschiedlichen zubereitungen während eines waschprogramms einer waschmaschine | |
EP2521811B1 (de) | Dosiersystem zur freisetzung von wenigstens drei unterschiedlichen zubereitungen während eines waschprogramms einer waschmaschine | |
WO2011134690A1 (de) | Dosiersystem zur verwendung in verbindung mit einem wasserführenden haushaltsgerät wie eine waschmaschine, spülmaschine, wäschetrockner oder dergleichen | |
EP2299892B1 (de) | Koppelbares dosiergerät | |
EP2303091B1 (de) | Anordnung zur Kopplung eines Dosiersystems mit einer wasserführenden Leitung einer Geschirrspülmaschine | |
WO2018114359A1 (de) | Nachrüstbare sensoreinheit zur steuerung einer dosiervorrichtung | |
EP2296522A1 (de) | Dosiersystem mit bauelementträger | |
WO2011045108A1 (de) | Tür zum flüssigkeitsdichten verschluss einer wäscheaufgabe- bzw. entnahmeöffnung eines wäschebehandlungsgeräts insbesondere einer waschmaschine und/oder eines wäschetrockners | |
EP2296520A2 (de) | Dosiersystem für eine geschirrspülmaschine | |
WO2010091782A1 (de) | Kartusche | |
EP3558082A1 (de) | Dosiergerät für reinigungsmaschine | |
EP2398952A1 (de) | Verfahren zum betrieb eines in einem haushaltsgerät angeordneten dosiergeräts, dosiergerät und haushaltsgerät hierzu | |
DE102009002693A1 (de) | Dosiersystem | |
DE102010002750A1 (de) | Verfahren zur Steuerung eines im Inneren eines wasserführenden Haushaltsgeräts positionierbaren Dosiersystems | |
EP2528487B1 (de) | Dosiergerät für eine geschirrspülmaschine mit optischer sende- und/oder empfangseinheit | |
WO2010149697A1 (de) | Maschinelles reinigungsmittel | |
EP2398371A1 (de) | Abgabevorrichtung mit sende- und/oder empfangseinheit zur drahtlosen übermittlung von signalen | |
WO2010007049A1 (de) | Dosiersystem mit abgabe einer zubereitung in die gasphase | |
EP2398373B1 (de) | Dosiergerät mit dosierkammer | |
WO2010094386A1 (de) | Dosiergerät zur abgabe von wenigstens einer wasch- und/oder reinigungsmittelzubereitung ins innere eines haushaltsgeräts | |
EP2545216B1 (de) | Verfahren zum betrieb eines dosiersystems im inneren eines wasserführenden haushaltsgeräts |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20120718 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: NITSCH, CHRISTIAN Inventor name: BRUECKNER, ERIK Inventor name: KESSLER, ARND |
|
DAX | Request for extension of the european patent (deleted) | ||
17Q | First examination report despatched |
Effective date: 20160728 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
INTG | Intention to grant announced |
Effective date: 20171117 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 988146 Country of ref document: AT Kind code of ref document: T Effective date: 20180415 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 502010014856 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20180411 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180711 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180711 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180712 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180813 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 502010014856 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 |
|
26N | No opposition filed |
Effective date: 20190114 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181104 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20181130 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181130 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181130 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181104 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181130 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MM01 Ref document number: 988146 Country of ref document: AT Kind code of ref document: T Effective date: 20181104 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20181104 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180411 Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20101104 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180411 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180811 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230531 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20231123 Year of fee payment: 14 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20231120 Year of fee payment: 14 Ref country code: DE Payment date: 20231121 Year of fee payment: 14 |