EP2513346A2 - Procédé de fabrication d'un produit en acier plat facilement formable et procédé de fabrication d'une pièce à partir d'un tel produit en acier plat - Google Patents

Procédé de fabrication d'un produit en acier plat facilement formable et procédé de fabrication d'une pièce à partir d'un tel produit en acier plat

Info

Publication number
EP2513346A2
EP2513346A2 EP10787425A EP10787425A EP2513346A2 EP 2513346 A2 EP2513346 A2 EP 2513346A2 EP 10787425 A EP10787425 A EP 10787425A EP 10787425 A EP10787425 A EP 10787425A EP 2513346 A2 EP2513346 A2 EP 2513346A2
Authority
EP
European Patent Office
Prior art keywords
steel product
flat steel
flat
annealing
product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP10787425A
Other languages
German (de)
English (en)
Other versions
EP2513346B1 (fr
Inventor
Wilhelm Warnecke
Manfred Meurer
Jens Kondratiuk
Marc Blumenau
Martin Norden
Thiemo Wuttke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp Steel Europe AG
Original Assignee
ThyssenKrupp Steel Europe AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by ThyssenKrupp Steel Europe AG filed Critical ThyssenKrupp Steel Europe AG
Publication of EP2513346A2 publication Critical patent/EP2513346A2/fr
Application granted granted Critical
Publication of EP2513346B1 publication Critical patent/EP2513346B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D31/00Other methods for working sheet metal, metal tubes, metal profiles
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/74Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
    • C21D1/76Adjusting the composition of the atmosphere
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0257Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment with diffusion of elements, e.g. decarburising, nitriding
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese

Definitions

  • the invention relates to a process for producing a readily deformable, a C content of 0.1 to 0.4 wt .-% having flat steel product, wherein the
  • the invention relates to a correspondingly produced flat steel product and method for
  • Corrosion protection coating provided steel sheet for the hot forming and a possibly subsequently or in combination with the hot working performed hardening are heated to a temperature which is above the melting temperature of the metal of the protective coating, there is the danger of so-called
  • JP 60-159120 A It is generally known from JP 60-159120 A that the bending properties of a steel sheet can be improved by a decarburization treatment which produces a near-surface, 20-100 ⁇ m thick surface layer with a reduced C content in relation to the core region of the steel sheet.
  • this measure is not associated with this prior art Nor does it concern higher or high strength steels having C-contents of at least 0.1% by weight.
  • decarburization is carried out according to the Boudouard equilibrium reactions according to the following
  • decarburization can improve certain properties of a steel product.
  • GB 1 189 464 proposes the "open-coil" method.
  • a hard-rolled, cold-rolled strip is wound loosely into a coil such that a free space exists between the individual winding layers of the coil. That at the subsequent
  • Annealing treatment in a hood furnace flowing through the free spaces annealing gas then sweeps over the entire
  • the steel strip can be provided with a hot dip coating to improve its corrosion resistance.
  • the steel sheet obtained in this way has a particularly good deformability. However, its strength values do not match those
  • Automotive bodies should be shaped.
  • the steel strip treated accordingly has an increased deformability compared to the base material, which reduces the risk of brittle fracture under high external load.
  • DE 102007061489 A1 has proposed a process in which a ductile boundary layer which is advantageous for the forming is produced on a steel sheet by carrying out a selective oxidation of the solidifying alloying elements. In the process, every decarburization is deliberately counteracted.
  • the object of the invention was to provide a method which makes it possible in an economical manner to produce a readily deformable, high-strength or very high-strength steel flat product.
  • Components are given from such a flat steel product.
  • the above-stated object has been achieved according to the invention in that, in the production of a flat steel product, the steps specified in claim 1 are completed.
  • the process according to the invention for producing a readily deformable flat steel product which has a C content of 0.1-0.4% by weight, in particular less than 0.4% by weight, is based on the idea of the relevant flat steel product in a continuous furnace one
  • the annealing treatment according to the invention is carried out under an annealing atmosphere, the 0.1 - 25 vol .-% H 2 , H 2 0 and the balance N 2 and
  • the dew point of the annealing atmosphere is in the range of -20 ° C and +60 ° C. At the same time is in the
  • the flat steel product is further inventively in the course of annealing to a 600 - 1100 ° C.
  • Wt .-% in particular up to 0.38 wt .-%, contains carbon, adjust by an annealing treatment, which leads to a Randentkohlung of the steel material. This edge decarburization causes a ductilization of the
  • the invention is thus based on the idea of a
  • Hot-forming steel flat products i.
  • Steel surface can run off for a subsequent application of a corrosion protection layer, but has a decoupled reaction mechanism.
  • the inventive method is characterized in particular by the fact that it can be carried out in a particularly economical manner using a continuous furnace. This makes it possible to use the method according to the invention in
  • Anticorrosive coating are hot-dip coated.
  • the invention makes use of the knowledge that the risk of liquid metal embrittlement can be minimized by the fact that it can be controlled by a specific method
  • Flat steel product of the susceptible to liquid metal embrittlement temperature range can be shifted so that it does not coincide with the typical for the hot forming temperature interval.
  • the annealing treatment in this case may include edge decarburization, surface conditioning and recrystallization of the base material and then the
  • Procedure can be performed in-line following the annealing treatment.
  • produced flat steel product can on the steel substrate known coating systems which are based on Zn, Al, Zn-Al, Zn-Mg, Zn-Ni, Al-Mg, Al-Si or Zn-Al-Mg.
  • Hot dip finishing can be a steel strip which has been provided in accordance with the invention in a continuous annealing with a ductile decarburized boundary layer,
  • a metallic, a metallic ⁇ inorganic or a metallic-organic coating by electrolytically, for example, with a Zn, a ZnNi or a ZnFe coating, PVD or CVD deposition or by means of another metal-organic or metal inorganic coating method is coated.
  • the invention thus provides that the flat steel product is hot-dip coated in a work step carried out continuously following the annealing treatment. It can the
  • oxidation of the surface of the flat steel product can be carried out before the fire coating.
  • the annealing treatment according to the invention can be carried out in a conventional manner
  • a method according to the invention is produced
  • Core layer of the flat steel product has increased ductility.
  • the thickness of the ductile layer can be determined in a customary manner in accordance with DIN EN ISO 3887
  • Total carbonation depth The distance from the surface to the point where the content of carbon corresponds to that of the unaffected core region. In this way, in the near-surface region, a hardness in the decarburized surface layer region which is not higher than 75% of the hardness of the core region, i.
  • Flat steel product is characterized at least near its free surface typically by a ferritic microstructure. This is true for a multiphase
  • decarburized edge layer sets a ferritic near-surface microstructure, just as for a single-phase, typically ferritic steel, in which the decarburization invention results in a ductilization of the near-surface ferrite.
  • a flat steel product produced according to the invention is suitable in the same way for cold and hot forming, wherein its particular advantages in particular in the hot forming of provided with a metallic protective layer, in particular a galvanized steel sheets or bands show.
  • Cold forming steels typically have a tensile strength of 500-1500 MPa.
  • Hot working can be inventively steels
  • the flat steel product according to the invention may first be heated to a heating temperature above its Acl temperature and then hot formed into the component.
  • the steel flat product according to the invention can also be heated without problems to a heating temperature which is at least equal to the Ac3 temperature of the flat steel product. Even with such a high
  • Heating temperature is minimized in a steel flat product according to the invention, the risk of embrittlement even if the flat steel product is provided with a metallic coating whose
  • Melting temperature is less than or equal to
  • Heating temperature is.
  • the ductility of the surface layer achieved by the surface layer decarburization according to the invention prevents cracking and thus ensures that no molten metal of the coating in the
  • Flat steel products are particularly advantageous for hot forming. This is achieved in that, according to the invention, a decarburization is induced by a targeted annealing gas-metal reaction in a continuous furnace, through which a ductile,
  • the invention is based on
  • Figure 1 is a vertical section of a surface according to the invention decarburized steel sample.
  • FIG. 2 shows a vertical section of a conventionally annealed comparative sample
  • hard-cold-rolled strip samples are in each case a multi-phase steel "MP” and a steel used commonly for hot forming “WU” has been produced.
  • the compositions of steels MP and WU are given in Table 1.
  • Hot-dip galvanizing is performed.
  • FIG. 1 shows the micrograph of the sample produced from the steel MP and annealed according to the invention. It can be clearly seen that, as a consequence of the procedure according to the invention, a decarburised, near-surface microstructure region (boundary layer "R")
  • Discharge Optical Emission Spectrometre is a standard method for the rapid detection of a concentration profile of coatings. It is
  • Carbon distribution of the conventionally treated sample and the solid line represents the carbon distribution of the invention treated sample.
  • Fig. 3 clearly shows that the sample treated according to the invention has a pronounced decarburized edge layer R whose thickness is about 40 ⁇ .
  • a surface layer is not present in the conventionally treated sample.
  • Edge region R has a microhardness of 163 HV and the non-decarburized core region K has a hardness of 255 HV.
  • The% ratio Hv R / Hv K of hardness Hv R of the decarburized edge region R to hardness Hv K of the core region K was thus 64%, which was well below that according to the invention for this ratio predetermined value of 75%.
  • the sample is symbolized by the black and the bending angle Bw of the conventionally generated sample by the white bar.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
  • Coating With Molten Metal (AREA)

Abstract

L'invention concerne un procédé permettant d'obtenir de manière économique un produit en acier plat facilement formable présentant une teneur en C allant de 0,1 à 0,4 % en poids. Selon l'invention, on effectue pour cela un traitement de recuit sous une atmosphère de recuit qui contient 0,1 à 25 % en volume de H2, de l'H2O et comme reste du N2, ainsi que des impuretés techniquement inévitables et qui présente un point de rosée compris entre -20 °C et +60 °C, le rapport H2O/H2 de l'atmosphère de recuit étant tout au plus égal à 0,957. Au cours du traitement de recuit, le produit en acier plat est chauffé à une température de maintien allant de 600 à 1100 °C, à laquelle il est maintenu pendant un temps de maintien de 10 à 360 s, de telle sorte que le produit en acier plat obtenu après le traitement de recuit présente une couche de bordure ductile (R) d'une épaisseur allant de 10 à 200 µm attenante à sa surface libre, avec une ductilité qui est plus grande que celle de la couche de cœur (K) intérieure du produit en acier plat, recouverte par la couche de bordure. L'invention concerne également un produit en acier plat de constitution correspondante, particulièrement approprié pour le formage à chaud ou à froid, et des procédés pour la fabrication de pièces à partir d'un tel produit en acier plat.
EP10787425.7A 2009-12-10 2010-12-03 Procédé de fabrication d'un produit en acier plat facilement formable Active EP2513346B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009044861A DE102009044861B3 (de) 2009-12-10 2009-12-10 Verfahren zum Herstellen eines gut umformbaren Stahlflachprodukts, Stahlflachprodukt und Verfahren zur Herstellung eines Bauteils aus einem solchen Stahlflachprodukt
PCT/EP2010/068831 WO2011069906A2 (fr) 2009-12-10 2010-12-03 Procédé de fabrication d'un produit en acier plat facilement formable et procédé de fabrication d'une pièce à partir d'un tel produit en acier plat

Publications (2)

Publication Number Publication Date
EP2513346A2 true EP2513346A2 (fr) 2012-10-24
EP2513346B1 EP2513346B1 (fr) 2017-06-07

Family

ID=44121379

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10787425.7A Active EP2513346B1 (fr) 2009-12-10 2010-12-03 Procédé de fabrication d'un produit en acier plat facilement formable

Country Status (6)

Country Link
US (1) US9234253B2 (fr)
EP (1) EP2513346B1 (fr)
JP (2) JP2013513725A (fr)
CN (1) CN102652177B (fr)
DE (1) DE102009044861B3 (fr)
WO (1) WO2011069906A2 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2513346B1 (fr) 2009-12-10 2017-06-07 ThyssenKrupp Steel Europe AG Procédé de fabrication d'un produit en acier plat facilement formable
EP3751016A4 (fr) * 2018-03-02 2021-09-01 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Tôle d'acier plaquée zinc pour l'estampage à chaud et son procédé de production

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2513346B1 (fr) 2009-12-10 2017-06-07 ThyssenKrupp Steel Europe AG Procédé de fabrication d'un produit en acier plat facilement formable
EP3751016A4 (fr) * 2018-03-02 2021-09-01 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Tôle d'acier plaquée zinc pour l'estampage à chaud et son procédé de production

Also Published As

Publication number Publication date
CN102652177B (zh) 2015-01-21
CN102652177A (zh) 2012-08-29
US9234253B2 (en) 2016-01-12
JP6298439B2 (ja) 2018-03-20
JP2016117948A (ja) 2016-06-30
WO2011069906A3 (fr) 2011-08-18
WO2011069906A2 (fr) 2011-06-16
JP2013513725A (ja) 2013-04-22
US20130180305A1 (en) 2013-07-18
EP2513346B1 (fr) 2017-06-07
DE102009044861B3 (de) 2011-06-22

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