EP2432905A1 - Ferritisch martensitische eisenbasislegierung, ein bauteil und ein verfahren - Google Patents
Ferritisch martensitische eisenbasislegierung, ein bauteil und ein verfahrenInfo
- Publication number
- EP2432905A1 EP2432905A1 EP09776639A EP09776639A EP2432905A1 EP 2432905 A1 EP2432905 A1 EP 2432905A1 EP 09776639 A EP09776639 A EP 09776639A EP 09776639 A EP09776639 A EP 09776639A EP 2432905 A1 EP2432905 A1 EP 2432905A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alloy
- alloy according
- carbon
- cobalt
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 47
- 239000000956 alloy Substances 0.000 title claims abstract description 47
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 6
- 229910000734 martensite Inorganic materials 0.000 title abstract description 9
- 238000000034 method Methods 0.000 title description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 22
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 18
- 229910052799 carbon Inorganic materials 0.000 claims description 16
- 239000010949 copper Substances 0.000 claims description 14
- 239000011572 manganese Substances 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 239000011651 chromium Substances 0.000 claims description 13
- 239000010955 niobium Substances 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- 239000010941 cobalt Substances 0.000 claims description 10
- 229910017052 cobalt Inorganic materials 0.000 claims description 10
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 10
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 10
- 229910052721 tungsten Inorganic materials 0.000 claims description 10
- 239000010937 tungsten Substances 0.000 claims description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 8
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052802 copper Inorganic materials 0.000 claims description 8
- 229910052748 manganese Inorganic materials 0.000 claims description 8
- 229910052759 nickel Inorganic materials 0.000 claims description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims description 8
- 239000011574 phosphorus Substances 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- 229910052796 boron Inorganic materials 0.000 claims description 7
- 239000011593 sulfur Substances 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 6
- 229910052758 niobium Inorganic materials 0.000 claims description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 229910052787 antimony Inorganic materials 0.000 claims description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052785 arsenic Inorganic materials 0.000 claims description 4
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 238000005266 casting Methods 0.000 claims 1
- 229910052735 hafnium Inorganic materials 0.000 claims 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 claims 1
- 230000007774 longterm Effects 0.000 description 7
- 229910001566 austenite Inorganic materials 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 230000009466 transformation Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910001068 laves phase Inorganic materials 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 229910000601 superalloy Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 230000003334 potential effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
Definitions
- Ferritic martensitic iron-based alloy a component and a method
- the invention relates to a ferritic martensitic alloy, a component and a method.
- the object is achieved by an alloy according to claim 1, by a component according to claim 32 and a method according to claim 33.
- Figure 1, 2, 3 embodiments, Figure 4 shows a steam turbine.
- the new ferritic martensitic alloy preferably dispenses with the addition of tungsten (W) except for the commercial impurities, which are significantly below 0, 1 wt%, in particular below 0.01 wt%.
- the iron-based alloy has not been conclusive
- the alloy consists of these elements.
- the boron content gives a very good long-term stability at elevated temperatures.
- the boron content with the required nitrogen content is optimized to prevent the formation of Boron nitrides to avoid. This results in a good balance of skill and tenacity.
- the nickel content gives good forgeability.
- the content of nickel is lowered because of the improvement of the creep strength by reducing the diffusion coefficients in the microstructure.
- a compensation of the changed through temperability takes place by adding carbon (C) and cobalt (Co).
- the content of carbon (C) is lowered because of balance with other elements to obtain a martensite structure with high toughness. Due to the lowered carbon content, a complete transformation of the austenite on cooling to room temperature (no retained austenite) can be achieved, resulting in a high microstructure homogeneity, good martensite lath structure, high toughness, fine carbide formation of M23C6 in order to achieve a good creep rupture strength. Carbon is required to form M23C6.
- carbon contents> 0.13wt% are used.
- nitrogen contents> 150 ppm are used.
- the content of silicon is lowered because of the thereby improved long-term ability and reduction of nucleation for Laves phase precipitation (see under tungsten).
- the content of manganese is lowered because of the positive influence on increasing the creep rupture strength by increasing the Acl temperature, which allows a higher use temperature without microstructure or structural transformation of ferrite / martensite austenite:
- the levels of phosphorus, sulfur, copper are lowered to improve the initial toughness of the structure and ensure high long-term capability.
- Titanium is preferably not used because otherwise nitrogen would be bound as TiN and thus would miss the MX particles of the form (V, Nb) N required for creep rupture.
- the use temperature for components is increased by this alloy, with toughness / ductility remaining at lower temperatures.
- the minimum contents in the claims are each preferably 0, lwt% for cobalt (Co), 0.01wt% for silicon (Si), 0.001wt% for phosphorus (P), 0.05wt% for manganese (Mn), 0.01wt % for copper (Cu); these are well above the detection limits for these elements and their degree of contamination.
- the steam turbine has a high-pressure turbine section 300 and a medium-pressure turbine section 303, each having an inner housing 312 and an outer housing 315 enclosing this.
- the high-pressure turbine part 300 is designed, for example, in Topfbauart.
- the medium-pressure turbine part 303 is designed, for example, double-flow. It is also possible for the medium-pressure turbine section 303 to be single-flow.
- the turbine shaft 309 is composed, for example, of two sub-turbine shafts 309a and 309b, which are firmly connected to one another in the region of the bearing 318.
- Each turbine shaft 309a, 309b has a cooling line 372 formed as a central bore 372a along the axis of rotation 306.
- the cooling line 372 is connected to the steam outlet region 351 via an inflow line 375 having a radial bore 375a.
- the coolant line 372 is connected to a cavity not shown below the shaft shield.
- the feed lines 375 are designed as a radial bore 375a, whereby "cold" steam can flow from the high-pressure turbine section 300 into the central bore 372a the medium-pressure turbine section 303 and there to the mantle surface 330 of the turbine shaft 309 in the Dampfeinström Suite 333.
- the flowing through the cooling line steam has a much lower temperature than the in the Dampfeinström Scheme 333 incoming reheated steam, so that an effective cooling of the first rotor blade rows 342 of the medium-pressure turbine section 303 and of the jacket surface 330 in the region of these rotor blade rows 342 is ensured.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Abstract
Description
Claims
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/EP2009/003640 WO2010133244A1 (de) | 2009-05-22 | 2009-05-22 | Ferritisch martensitische eisenbasislegierung, ein bauteil und ein verfahren |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2432905A1 true EP2432905A1 (de) | 2012-03-28 |
EP2432905B1 EP2432905B1 (de) | 2016-04-13 |
Family
ID=42173351
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09776639.8A Active EP2432905B1 (de) | 2009-05-22 | 2009-05-22 | Ferritisch martensitische eisenbasislegierung, ein bauteil und ein verfahren |
Country Status (4)
Country | Link |
---|---|
US (1) | US20120070329A1 (de) |
EP (1) | EP2432905B1 (de) |
CN (1) | CN102428197B (de) |
WO (1) | WO2010133244A1 (de) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9039365B2 (en) * | 2012-01-06 | 2015-05-26 | General Electric Company | Rotor, a steam turbine and a method for producing a rotor |
JP6317542B2 (ja) * | 2012-02-27 | 2018-04-25 | 三菱日立パワーシステムズ株式会社 | 蒸気タービンロータ |
EP2653587A1 (de) | 2012-04-16 | 2013-10-23 | Siemens Aktiengesellschaft | Strömungsmaschinenkomponente mit einer Funktionsbeschichtung |
US9175637B2 (en) * | 2013-09-13 | 2015-11-03 | Federal-Mogul Corporation | Hot gasket with stainless steel |
CN104372262B (zh) * | 2014-11-10 | 2016-05-04 | 苏州蔻美新材料有限公司 | 一种医疗器械用不锈钢及其制备方法 |
CN105438637A (zh) * | 2015-12-24 | 2016-03-30 | 常熟市新冶机械制造有限公司 | 摩根线材打捆机 |
CN110997960B (zh) * | 2017-09-21 | 2021-11-02 | 三菱动力株式会社 | 燃气轮机盘材料以及其热处理方法 |
CN108342661A (zh) * | 2018-01-22 | 2018-07-31 | 江苏理工学院 | 一种火电机组用耐热钢合金材料及其制造工艺 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3387145B2 (ja) * | 1993-04-08 | 2003-03-17 | 住友金属工業株式会社 | 高温延性および高温強度に優れた高Crフェライト鋼 |
DE19607736A1 (de) * | 1996-02-29 | 1997-09-04 | Siemens Ag | Turbinenwelle |
JPH09296258A (ja) * | 1996-05-07 | 1997-11-18 | Hitachi Ltd | 耐熱鋼及び蒸気タービン用ロータシャフト |
CA2449604C (en) * | 2001-06-06 | 2008-04-01 | Nippon Steel Corporation | High-strength hot-dip galvanized steel sheet and hot-dip galvannealed steel sheet having fatigue resistance, corrosion resistance, ductility and plating adhesion, after severe deformation, and a method of producing the same |
US7491910B2 (en) * | 2005-01-24 | 2009-02-17 | Lincoln Global, Inc. | Hardfacing electrode |
-
2009
- 2009-05-22 US US13/321,196 patent/US20120070329A1/en not_active Abandoned
- 2009-05-22 WO PCT/EP2009/003640 patent/WO2010133244A1/de active Application Filing
- 2009-05-22 EP EP09776639.8A patent/EP2432905B1/de active Active
- 2009-05-22 CN CN2009801593641A patent/CN102428197B/zh active Active
Non-Patent Citations (1)
Title |
---|
See references of WO2010133244A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO2010133244A1 (de) | 2010-11-25 |
EP2432905B1 (de) | 2016-04-13 |
CN102428197B (zh) | 2013-12-11 |
CN102428197A (zh) | 2012-04-25 |
US20120070329A1 (en) | 2012-03-22 |
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