EP2396806B1 - Massenanalyseeinrichtung mit grosser winkelannahmefähigkeit mit einem reflektron - Google Patents
Massenanalyseeinrichtung mit grosser winkelannahmefähigkeit mit einem reflektron Download PDFInfo
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- EP2396806B1 EP2396806B1 EP20100703478 EP10703478A EP2396806B1 EP 2396806 B1 EP2396806 B1 EP 2396806B1 EP 20100703478 EP20100703478 EP 20100703478 EP 10703478 A EP10703478 A EP 10703478A EP 2396806 B1 EP2396806 B1 EP 2396806B1
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- 238000004458 analytical method Methods 0.000 title claims description 52
- 150000002500 ions Chemical class 0.000 claims description 121
- 239000000523 sample Substances 0.000 claims description 68
- 230000005686 electrostatic field Effects 0.000 claims description 20
- 238000003795 desorption Methods 0.000 claims description 7
- 238000000605 extraction Methods 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 description 21
- 238000010884 ion-beam technique Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 230000004075 alteration Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/26—Mass spectrometers or separator tubes
- H01J49/34—Dynamic spectrometers
- H01J49/40—Time-of-flight spectrometers
- H01J49/405—Time-of-flight spectrometers characterised by the reflectron, e.g. curved field, electrode shapes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J49/00—Particle spectrometers or separator tubes
- H01J49/0004—Imaging particle spectrometry
Definitions
- the present invention relates to a mass analysis device with wide angular acceptance comprising a reflectron.
- angular acceptance is understood as the capacity for the device integrating the reflectron, to treat ions emitted from a source such as the surface of a sample to be analyzed, with a large angular dispersion.
- the present invention is particularly applicable to the field of time-of-flight spectrometry, and more particularly to mass analysis devices such as mass spectrometers and time-of-flight atomic probes equipped with electrostatic mirrors, or reflectrons.
- a time of flight mass spectrometer or TOF makes it possible to determine the mass of ions torn off from a sample by measuring the flight time of the ions from a given position, real or virtual, from the ion source, to their impact on a detector, through an analysis chamber.
- the time of flight of an ion through an electrostatic field is proportional to the square root of the mass-to-charge ratio of this ion for a given kinetic energy.
- the mass resolution of a time-of-flight spectrometer depends, in addition to the precision with which the start and impact times of the ions can be measured, of the energy dispersion of the ions; Indeed, ions of an identical charge-to-charge mass ratio but with different charge-energy ratios have different flight times from the ion source to the detector.
- a known method making it possible to eliminate, at least in first approximation, the dependence of the flight time of an ion on its energy, and thus to improve the mass resolution of a time-of-flight spectrometer, is to incorporate in the analysis chamber of the mass spectrometer an ion mirror device.
- This method has been proposed for the first time by Alikhanov, and implemented by Mamyrin.
- the ion mirrors used in reflectron time-of-flight mass analyzers typically incorporate homogeneous and uniform homogeneous particle retardation fields, that is homogeneous in defined spatial areas.
- Ionic mirrors commonly consist of a main electrode, a particular geometry and excited by an electrical potential, and a gate electrode of similar geometry and excited by a different electrical potential.
- the electrostatic field generated by these electrodes is contained in the space separating these electrodes, and its characteristics can for example be adjusted as a function of the excitation potentials.
- mass spectrometers rely on various ionic emission methods such as field desorption, laser desorption or secondary ion emission, themselves known from the state of the art.
- a characteristic of the ion beams resulting from these techniques is a strong angular dispersion of emitted ions, which can wait for values of the order of 90 ° or more. It is important not to restrict ion beams with wide angular dispersion in order to maximize the sensitivity of the mass spectrometer.
- the analysis of ions emitted with wide angular dispersion may be of major interest
- the atomic probes also called atomic probe microscopes, in which an increase in the angular acceptance is synonymous with an enlargement of the field of view of the microscope, since different angles of emission correspond to different positions on the surface of the sample to which the ions are torn off.
- Ion mirrors of conventional piecewise homogeneous electrostatic reflectrons can not accept an angular dispersion of the ion beam greater than about 10 °.
- curved geometry mirrors have been proposed in the article. from Vialle et al., Rev. Sci. Instrum., 68 (1997) 2312 .
- a reflectron with curved geometry is proposed in the international patent application WO2006 / 120428 . This type of reflectron performs a transformation of the ion beam diverging from a sample of reduced size into a substantially parallel beam, capable of being admitted by a detector of reasonable dimensions.
- the plane of the detector is substantially perpendicular to the ion beam, in order to avoid increasing the dimensions of the detector, which would otherwise be unavoidable.
- a device In addition to its spatial focusing properties, and focusing in terms of flight time as a function of ion energy, such a device has spatial focusing properties as a function of ion energy, and can thus be used to obtain spatially resolved images of a sample in atomic probe microscopes.
- Such a reflectron has some disadvantages.
- the angular acceptance of such a device can not exceed 90 ° for reasons simply related to the geometry of the device.
- the angular acceptance of such a reflectron is further reduced by an indispensable inclination with respect to the plane of the detector, the surface on which is made the focusing in terms of flight time as a function of energy.
- Another disadvantage of this type of reflectron is related to the fact that the intersection between most of the trajectories of the ions and the direction normal to the input gate electrode of the reflectron mirror is made at relatively open angles, which considerably increases the dispersion of the ions at the local inhomogeneities of electric field generated by the grid.
- WO2006 / 134380 A2 discloses a time-of-flight mass analysis device according to the preamble of claim 1.
- An object of the present invention is to overcome at least the aforementioned drawbacks, by proposing a new reflectron design, capable of allowing a large angular acceptance of ions emitted from the reduced surface of a sample in at least one direction.
- the time-of-flight mass analysis device may be characterized in that the detector is disposed at a distance from the spatial focusing point of the ions emitted from the sample in the first direction. , after reflection by the ion mirror, less than a quarter of the first radius of curvature.
- the time-of-flight mass analysis device may be characterized in that the detector is disposed downstream of the spatial focusing point of the emitted ions of the sample in the first direction, after reflection by the ion mirror.
- the time of flight mass analysis device can be characterized in that the detector is sensitive to the two-dimensional position of the impact of the ions on its surface.
- the time-of-flight mass analysis device can be characterized in that the detector is able to be displaced along the main axis of the mass analysis device.
- the time-of-flight mass analysis device may be characterized in that the ion mirror comprises a rear electrode and a gate electrode, the electrostatic field being formed between the back electrode and the grid electrode.
- the time of flight mass analysis device may be characterized in that the rear electrode and the gate electrode have a cylindrical surface.
- the time-of-flight mass analysis device can be characterized in that the rear electrode and the gate electrode are of spherical surface.
- the time of flight mass analysis device may be characterized in that it comprises additional means capable of varying the electrostatic field produced by the ion mirror.
- the time-of-flight mass analysis device can be characterized in that the sample is able to be moved in all directions and / or to be rotated.
- the time of flight mass analysis device may be characterized in that the ion extraction means pull out the ions from the surface of the sample by means of field desorption and / or or laser desorption, or secondary ion emission.
- a particular reflectron time-of-flight mass analyzer geometry is proposed for this purpose.
- the sample to be analyzed is placed at a distance substantially close to the center of curvature of the curved-field mirror in the direction of the emitted ion field.
- the ions emitted, after reflection on the curved-field mirror, are then focused in the direction considered, at a conjugate point located at an opposite position, with respect to the center of curvature, of the position of the sample.
- the detector can be arranged, depending on the physical problem that arises, either at the point of focus or downstream from this point.
- the angular image of the sample can be resolved at a detector of reasonable dimensions.
- An advantage of the present invention is that these properties remain valid for theoretically unlimited angular dispersion, i.e. up to 180 °.
- Another advantage of the invention lies in the fact that, irrespective of the angular dispersion, the angles of intersection of the ion trajectories with respect to the normal to the surface of the gate-entry electrode of the mirror for the considered direction , remain low, thus allowing a reduction of the angular dispersion of the ions at this level.
- the spatial energy dispersion offered by the reflectron time-of-flight mass analyzer according to the invention is not zero at the detector. Nevertheless, by using the field of a spherical mirror and a small shift between the sample and the center of curvature of the field, this dispersion can be made negligible and tend towards zero. This is because in the case - impractical in practice - where the position of the sample coincides with the center of curvature of the field, ions follow the same paths to the mirror, then back from the mirror, regardless of their kinetic energy.
- a reflectron time-of-flight mass analyzer comprising a spherical mirror field and a detector located downstream of the focusing point, gives properties that are particularly favorable to large acceptance.
- angular beam of the ion beam particularly suitable for use in high resolution and high sensitivity atomic probe microscopes.
- the figure 1 presents the sectional view in the radial plane of a mass analysis device, of a reflectron geometry known from the state of the art, as presented in the patent application WO2006 / 120148 supra.
- a mass analyzer 100 comprises a sample 101 of small size, for example in the form of a tip, from which ions are emitted and accelerated by extraction electrodes 102. The emitted ions follow in the analysis chamber of the analyzer. 100 of the trajectories 109 and 110. The ions are reflected in an ionic mirror 103 forming a curved equipotential surface electrostatic field 104. The equipotential lines have a center of curvature 105.
- the ion mirror 103 consists of a rear electrode 107 and of a gate electrode 106.
- a detector 108 collects the ions.
- the detector 108 is sensitive to the position of the point of impact of the ions on its surface.
- the center of curvature 105 of the equipotential lines of the field generated by the ion mirror 103 is typically at a greater distance from the mirror 103 than from the sample 101.
- the ion mirror 103 allows divergent ion trajectories from the sample 101 to become substantially less divergent or even slightly convergent after reflection. Thus, at a great distance from the mirror 103, the ion trajectories can still be picked up by the detector 108 whose size can remain reasonable.
- the intensity of the electrostatic field inside the ion mirror 103, and hence the length of the trajectories within the ion mirror 103, is chosen so that ions emitted from the sample in the same direction, but with different energies, along the paths 109 and 110, reach the detector 108 essentially at the same time; that is, the focus in terms of flight time with respect to ion energy is ensured.
- the distance between the ion mirror 103 and the detector 108 is chosen so that ions emitted from the sample in the same direction, but with different energies, reach the detector 108 at essentially the same point of impact; that is, the spatial focus with respect to ion energy is ensured.
- different starting points on the surface of the sample 101 correspond to different emission angles, as is the case, for example, in atomic probe microscopes, an image of the sample can be solved at the same time. detector level, with low chromatic aberration. It clearly appears on the figure 1 that the geometry of the mass analyzer 100 presented here does not allow to increase the angular acceptance beyond 90 °.
- the figure 2 shows the sectional view in the radial plane of a mass analysis device, an example of reflectron geometry according to an embodiment of the present invention.
- the sample 101 is disposed near the center of curvature 105 of the equipotential lines 104 of the electrostatic field generated by the ion mirror 103.
- the electrode 107 of the electrostatic mirror 103 has a spherical geometry, and that the gate electrode 106.
- the equipotential lines 104 of the electrostatic field have a spherical symmetry.
- the ions are emitted from the surface of the sample 101 and accelerated by the extraction electrodes 102, then reflected by the ion mirror 103.
- the ions pass through a point 111, conjugate of the point at which the sample 101 forming a tip can be assimilated into a first approximation. Downstream of point 111, the ions reach the detector 108, sensitive to the position of the points of impact with its surface.
- the electrostatic field prevailing inside the ion mirror 103, and therefore the length of the trajectories of the ions within the ion mirror 103, are chosen so that ions emitted from the surface of the sample 101, in the same direction. direction but with different energies, along paths 109 and 110, reach the detector 108 essentially at the same time; that is, the focus in terms of flight time with respect to ion energy is ensured.
- the focus in terms of flight time relative to the energy of the ions can not be rigorously achieved in practice at the detector 108, since the surface on which the condition of such a focus is filled is of substantially spherical shape. with a center located at the conjugate point 111. Nevertheless, this surface is substantially parallel to the central region of the surface of the detector 108, thus the dependence of the flight time of an ion at its energy remains low for an angular dispersion of relatively large emission, this increasing dependence as the square of the distance separating the center of the detector 108 to the point of impact of the ion considered on the surface of the detector 108.
- the angles formed between the ion trajectories and the normal lines at the surface of the gate electrode 106 of the ion mirror 103 at the points of intersection between the latter are reduced. These angles tend towards zero when the sample 101 tends towards the center of curvature 105 of the ion mirror 103. In other words, the trajectories of the ions are practically perpendicular to the surface of the gate electrode 106 of the ion mirror 103. This particular configuration makes it possible to reduce the effects of ion dispersion caused by the inhomogeneities of the local electrostatic field at the proximity of the gate electrode 106.
- the difference between the trajectories 109 and 110, ions leaving from the surface of the sample 101 in the same direction, but having different energies, remains reduced after reflection by the ion mirror 103; this gap tends to zero when the sample 101 tends towards the center of curvature 105 of the equipotential lines 104 of the electrostatic field produced by the ion mirror 103.
- the coincidence, at the level of the detector 108, trajectories of ions of the same initial direction but having different energies is not perfect, it remains excellent if the energy dispersion of the ions remains relatively low. Space chromatic aberration is still said to be weak. In this way, ions with different emission directions can be solved at the detector 108 with good accuracy.
- the radius of curvature of the rear electrode 107 may for example be equal to 400 mm, the distance from the sample 101 to the center of curvature 105 may be equal to 30 mm, and the The distance from the detector 108 to the focusing point 111 may be 275 mm. More generally, it will be possible to choose to position the sample 101 at a distance from the center of curvature 105 less than a given percentage of the radius of curvature of the rear electrode 107, for example 25%.
- the figure 3 presents the perspective view, of an example of the image formed at a position-sensitive detector, of ions emitted from a sample in different directions in the radial plane and in the transverse plane, according to a mode embodiment of the present invention.
- This embodiment of the invention allows the analysis of ions emitted from the surface of the sample 101 with a large angular dispersion, in theory up to ⁇ radians, using a finite size detector 108.
- the angular acceptance is all the greater as the center of the detector 108 is close to the conjugate point 111 of the point at which the sample 101 is assimilated.
- this embodiment of the invention allows large mass resolution with wide angular acceptance, as well as good spatial resolution, due to low spatial chromatic aberration.
- this embodiment of the invention is particularly suitable for an atomic probe microscope type application. Due to the offset of the sample 101 with respect to the axis in the radial plane, the aperture or energy focusing can be realized differently in the radial plane and in the transverse plane. To alleviate this problem, it may be advantageous to use an electrostatic mirror 103 which is not of strictly spherical geometry. In such a configuration, the radius of curvature and thus the center of curvature in the radial plane are different from the radius of curvature and the center of curvature in the transverse plane.
- the figure 4 shows the perspective view of an exemplary geometry of a reflectron with a detector 108 placed at the conjugate point of focus of the point at which the sample 101 is located, according to another embodiment of the present invention.
- the intensity of the electrostatic field generated by the ion mirror 103 can be chosen so as to allow focussing in terms of flight time relative to the energy of the ions, at the detector 108.
- This particular embodiment may be advantageous if a spatial resolution of the ions is not necessary.
- This embodiment allows a high mass resolution for ions emitted from the surface of the sample 101 with a large angular dispersion.
- This characteristic can be obtained by placing the detector at a position coinciding with the focusing point 111 in terms of flight time relative to the energy of the ions. More generally, it will be possible to position the detector 108 at a distance from the focusing point 111 less than a given percentage of the radius of curvature of the rear electrode 107, for example 25%.
- the reflectron geometry can be simplified by using a gate electrode 106 and a rear electrode 107 of cylindrical surfaces.
- the electrodes of the ion mirror 103 can be equipped with additional mechanical alignment means and / or additional electrode sets for adjusting the shape of the electrostatic field. It is also advantageous, for a better adjustment of the performance of the mass analyzer 100, to allow a displacement of the detector 108 along the main axis of the analysis device 100 and / or the sample 101 along the three axes. It may also be advantageous to provide the sample holding mechanism with means for tilting the sample in order to correct tilting defects of the sample and / or the sample holder.
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- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
- Electron Tubes For Measurement (AREA)
Claims (11)
- Flugzeitmassenanalysevoruchtung (100), insbesondere vom Massenspektrometer- oder vom Atomsondentyp, die Folgendes umfasst:- Mittel zum Empfangen einer Probe (101),- Mittel zum Extrahieren von Ionen von der Oberfläche der Probe (101),- einen Detektor (108),- einen Ionenspiegel (103), der ein elektrostatisches Feld erzeugt, dessen Äquipotentiallinien durch eine erste Krümmung in einer ersten Richtung in der Radialebene der Massenanalysevorrichtung (100) und einen ersten Krümmungsmittelpunkt (105) und eine zweite Krümmung in einer zweiten Richtung lotrecht zur ersten Richtung in der Transversalebene der Massenanalysevorrichtung (100) und einen zweiten Krümmungsmittelpunkt definiert werden,dadurch gekennzeichnet, dass die Probe (101) in einem Abstand vom ersten Krümmungsmittelpunkt (105) angeordnet ist, der kleiner als ein Viertel des ersten Krümmungsradius ist.
- Flugzeitmassenanalysevoruchtung (100) nach Anspruch 1, dadurch gekennzeichnet, dass der Detektor (108) in einem Abstand vom räumlichen Brennpunkt (111) der von der Probe (101) emittierten Ionen in der ersten Richtung nach der Reflexion durch den Ionenspiegel (103) angeordnet ist, der kleiner als ein Viertel des ersten Krümmungsradius ist.
- Flugzeitmassenanalysevoruchtung (100) nach Anspruch 1, dadurch gekennzeichnet, dass der Detektor stromabwärts vom räumlichen Brennpunkt (111) der von der Probe (101) emittierten Ionen in der ersten Richtung nach der Reflexion durch den Ionenspiegel (103) angeordnet ist.
- Flugzeitmassenanalysevoruchtung (100) nach einem der vorherigen Ansprüche, dadurch gekennzeichnet, dass der Detektor (108) für die zweidimensionale Position des Auftreffens der Ionen auf der Oberfläche empfindlich ist.
- Flugzeitmassenanalysevoruchtung (100) nach einem der vorherigen Ansprüche, dadurch gekennzeichnet, dass der Detektor (108) entlang der Hauptachse der Massenanalysevorrichtung (100) verschoben werden kann.
- Flugzeitmassenanalysevoruchtung (100) nach einem der vorherigen Ansprüche, dadurch gekennzeichnet, dass der Ionenspiegel (108) eine hintere Elektrode (107) und eine Gitterelektrode (106) umfasst, wobei das elektrostatische Feld zwischen der hinteren Elektrode (107) und der Gitterelektrode (106) gebildet wird.
- Flugzeitmassenanalysevoruchtung (100) nach Anspruch 6, dadurch gekennzeichnet, dass die hintere Elektrode (107) und die Gitterelektrode (106) eine zylindrische Oberfläche haben.
- Flugzeitmassenanalysevoruchtung (100) nach Anspruch 6, dadurch gekennzeichnet, dass die hintere Elektrode (107) und die Gitterelektrode (106) eine sphärische Oberfläche haben.
- Flugzeitmassenanalysevoruchtung (100) nach einem der vorherigen Ansprüche, dadurch gekennzeichnet, dass sie zusätzliche Mittel umfasst, mit denen das von dem Ionenspiegel (103) erzeugte elektrostatische Feld variiert werden kann.
- Flugzeitmassenanalysevoruchtung (100) nach einem der vorherigen Ansprüche, dadurch gekennzeichnet, dass die Probe (101) in allen Richtungen verschoben und/oder geschwenkt werden kann.
- Flugzeitmassenanalysevoruchtung (100) nach einem der vorherigen Ansprüche, dadurch gekennzeichnet, dass die Ionenextraktionsmittel die Ionen von der Oberfläche der Probe (101) durch Felddesoiption und/oder Laserdesorption oder Sekundärionenemission ablösen.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0950955A FR2942349B1 (fr) | 2009-02-13 | 2009-02-13 | Dispositif d'analyse de masse a large acceptance angulaire comprenant un reflectron |
PCT/EP2010/051764 WO2010092141A1 (fr) | 2009-02-13 | 2010-02-12 | Dispositif d'analyse de masse a large acceptance angulaire comprenant un reflectron |
Publications (2)
Publication Number | Publication Date |
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EP2396806A1 EP2396806A1 (de) | 2011-12-21 |
EP2396806B1 true EP2396806B1 (de) | 2015-04-29 |
Family
ID=41009757
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP20100703478 Active EP2396806B1 (de) | 2009-02-13 | 2010-02-12 | Massenanalyseeinrichtung mit grosser winkelannahmefähigkeit mit einem reflektron |
Country Status (5)
Country | Link |
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US (1) | US8502139B2 (de) |
EP (1) | EP2396806B1 (de) |
JP (1) | JP2012518246A (de) |
FR (1) | FR2942349B1 (de) |
WO (1) | WO2010092141A1 (de) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8642951B2 (en) * | 2011-05-04 | 2014-02-04 | Agilent Technologies, Inc. | Device, system, and method for reflecting ions |
CN103907171B (zh) * | 2011-10-28 | 2017-05-17 | 莱克公司 | 静电离子镜 |
US9627190B2 (en) * | 2015-03-27 | 2017-04-18 | Agilent Technologies, Inc. | Energy resolved time-of-flight mass spectrometry |
US10614995B2 (en) | 2016-06-27 | 2020-04-07 | Cameca Instruments, Inc. | Atom probe with vacuum differential |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56141159A (en) * | 1980-04-04 | 1981-11-04 | Shimadzu Corp | Electronic energy analyzer |
JPH0665022B2 (ja) * | 1986-06-11 | 1994-08-22 | 株式会社島津製作所 | 飛行時間型質量分析計 |
JPH0789476B2 (ja) * | 1986-12-08 | 1995-09-27 | 株式会社島津製作所 | 飛行時間型質量分析計 |
US5017780A (en) * | 1989-09-20 | 1991-05-21 | Roland Kutscher | Ion reflector |
JPH0815188A (ja) * | 1995-07-14 | 1996-01-19 | Hitachi Ltd | 表面分析装置 |
US6518569B1 (en) * | 1999-06-11 | 2003-02-11 | Science & Technology Corporation @ Unm | Ion mirror |
US6858839B1 (en) * | 2000-02-08 | 2005-02-22 | Agilent Technologies, Inc. | Ion optics for mass spectrometers |
CA2410455A1 (en) * | 2000-05-30 | 2001-12-06 | The Johns Hopkins University | Portable time-of-flight mass spectrometer system |
US7091479B2 (en) * | 2000-05-30 | 2006-08-15 | The Johns Hopkins University | Threat identification in time of flight mass spectrometry using maximum likelihood |
JP2003014606A (ja) * | 2001-07-03 | 2003-01-15 | Jeol Ltd | アトムプローブ電界イオン顕微鏡 |
US6717135B2 (en) * | 2001-10-12 | 2004-04-06 | Agilent Technologies, Inc. | Ion mirror for time-of-flight mass spectrometer |
GB2390740A (en) * | 2002-04-23 | 2004-01-14 | Thermo Electron Corp | Spectroscopic analyser for surface analysis and method therefor |
AU2003237266A1 (en) * | 2002-05-30 | 2003-12-31 | The Johns Hopkins University | Non-linear time-of-flight mass spectrometer |
JP4176532B2 (ja) * | 2002-09-10 | 2008-11-05 | キヤノンアネルバ株式会社 | 反射型イオン付着質量分析装置 |
US7087897B2 (en) * | 2003-03-11 | 2006-08-08 | Waters Investments Limited | Mass spectrometer |
JP2008502104A (ja) * | 2004-06-03 | 2008-01-24 | イマゴ サイエンティフィック インストルメンツ コーポレーション | レーザ原子プロービング方法 |
JP2009507328A (ja) | 2005-05-11 | 2009-02-19 | イメイゴ サイエンティフィック インストゥルメンツ コーポレイション | リフレクトロン |
JP5097106B2 (ja) | 2005-05-13 | 2012-12-12 | ハンツマン アドバンスト マテリアルズ (スイッツァランド) ゲーエムベーハー | 染料混合物 |
WO2006134380A2 (en) * | 2005-06-17 | 2006-12-21 | Imago Scientific Instruments Corporation | Atom probe |
JP5032076B2 (ja) * | 2006-09-12 | 2012-09-26 | 株式会社テクノフロント | 質量分析装置 |
-
2009
- 2009-02-13 FR FR0950955A patent/FR2942349B1/fr not_active Expired - Fee Related
-
2010
- 2010-02-12 JP JP2011549575A patent/JP2012518246A/ja active Pending
- 2010-02-12 US US13/201,323 patent/US8502139B2/en active Active
- 2010-02-12 WO PCT/EP2010/051764 patent/WO2010092141A1/fr active Application Filing
- 2010-02-12 EP EP20100703478 patent/EP2396806B1/de active Active
Also Published As
Publication number | Publication date |
---|---|
FR2942349B1 (fr) | 2012-04-27 |
EP2396806A1 (de) | 2011-12-21 |
US20110303841A1 (en) | 2011-12-15 |
WO2010092141A1 (fr) | 2010-08-19 |
JP2012518246A (ja) | 2012-08-09 |
FR2942349A1 (fr) | 2010-08-20 |
US8502139B2 (en) | 2013-08-06 |
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