EP2396177A1 - Wärmeübertragungsband mit uv-vernetzbarer schutzschicht - Google Patents
Wärmeübertragungsband mit uv-vernetzbarer schutzschichtInfo
- Publication number
- EP2396177A1 EP2396177A1 EP10708267A EP10708267A EP2396177A1 EP 2396177 A1 EP2396177 A1 EP 2396177A1 EP 10708267 A EP10708267 A EP 10708267A EP 10708267 A EP10708267 A EP 10708267A EP 2396177 A1 EP2396177 A1 EP 2396177A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- layer
- thermal transfer
- protective layer
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000012546 transfer Methods 0.000 title claims abstract description 35
- 239000000203 mixture Substances 0.000 claims abstract description 70
- 239000011248 coating agent Substances 0.000 claims abstract description 18
- 238000000576 coating method Methods 0.000 claims abstract description 18
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 238000004132 cross linking Methods 0.000 claims abstract description 11
- 229920000642 polymer Polymers 0.000 claims abstract description 9
- 239000000178 monomer Substances 0.000 claims abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 7
- 239000012748 slip agent Substances 0.000 claims abstract description 6
- 239000011241 protective layer Substances 0.000 claims description 35
- 239000010410 layer Substances 0.000 claims description 32
- 239000000470 constituent Substances 0.000 claims description 18
- 238000007639 printing Methods 0.000 claims description 10
- 229920000570 polyether Polymers 0.000 claims description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000003085 diluting agent Substances 0.000 claims description 4
- 238000010894 electron beam technology Methods 0.000 claims description 4
- -1 polysiloxane acrylates Polymers 0.000 claims description 4
- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 claims description 3
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 claims description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 3
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 3
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 2
- 239000012965 benzophenone Substances 0.000 claims description 2
- MKFQSQXDVBJGQM-UHFFFAOYSA-N bis(1-cyclohexyl-6-hydroxycyclohexa-2,4-dien-1-yl)methanone Chemical compound OC1C=CC=CC1(C(=O)C1(C(C=CC=C1)O)C1CCCCC1)C1CCCCC1 MKFQSQXDVBJGQM-UHFFFAOYSA-N 0.000 claims description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 2
- 230000005855 radiation Effects 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 claims description 2
- 230000000052 comparative effect Effects 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 230000008020 evaporation Effects 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000000930 thermomechanical effect Effects 0.000 description 4
- 239000012943 hotmelt Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- 238000010023 transfer printing Methods 0.000 description 3
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 2
- GNKZMNRKLCTJAY-UHFFFAOYSA-N 4'-Methylacetophenone Chemical compound CC(=O)C1=CC=C(C)C=C1 GNKZMNRKLCTJAY-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- FSDNTQSJGHSJBG-UHFFFAOYSA-N piperidine-4-carbonitrile Chemical compound N#CC1CCNCC1 FSDNTQSJGHSJBG-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OZDCBKYPNBVRSA-UHFFFAOYSA-N (4,4-dimethoxycyclohexa-1,5-dien-1-yl)-phenylmethanone Chemical compound C1=CC(OC)(OC)CC=C1C(=O)C1=CC=CC=C1 OZDCBKYPNBVRSA-UHFFFAOYSA-N 0.000 description 1
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 1
- PCKZAVNWRLEHIP-UHFFFAOYSA-N 2-hydroxy-1-[4-[[4-(2-hydroxy-2-methylpropanoyl)phenyl]methyl]phenyl]-2-methylpropan-1-one Chemical compound C1=CC(C(=O)C(C)(O)C)=CC=C1CC1=CC=C(C(=O)C(C)(C)O)C=C1 PCKZAVNWRLEHIP-UHFFFAOYSA-N 0.000 description 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 description 1
- UGVRJVHOJNYEHR-UHFFFAOYSA-N 4-chlorobenzophenone Chemical compound C1=CC(Cl)=CC=C1C(=O)C1=CC=CC=C1 UGVRJVHOJNYEHR-UHFFFAOYSA-N 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000700 radioactive tracer Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/405—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography characterised by layers cured by radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/06—Printing methods or features related to printing methods; Location or type of the layers relating to melt (thermal) mass transfer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/36—Backcoats; Back layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/38—Intermediate layers; Layers between substrate and imaging layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
Definitions
- gliding agent c) from 0.5 to 10%, preferably from 5 to 10%
- - photoinitiator d) from 0 to 7%, preferably from 3 to 7%.
- the cylinders are preferably co-rotating cylinders rotating at a speed of between 30 and 1000 m / min.
- the coating temperature is generally between 10 and 60 ° C. It is thus possible to coat a uniform layer with a basis weight of between 0.05 and 0.30 g / m 2 , preferably 0.10 to 0.20 g / m 2 .
- the uniform thickness of said protective layer is thus between 0.05 ⁇ m and 0.4 ⁇ m, preferably between 0.10 to 0.25 ⁇ m, depending on the densities of the constituents.
- Viscosity at 25 ° C. 1020 mPa.s
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Laminated Bodies (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL10708267T PL2396177T3 (pl) | 2009-02-16 | 2010-02-02 | Taśma termotransferowa zawierająca ochronną warstwę sieciowalną UV |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0950966A FR2942170B1 (fr) | 2009-02-16 | 2009-02-16 | Ruban de transfert thermique comportant une couche de protection reticulable aux u.v. |
| PCT/FR2010/050167 WO2010092277A1 (fr) | 2009-02-16 | 2010-02-02 | Ruban de transfert thermique comportant une couche de protection réticulable aux u.v. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2396177A1 true EP2396177A1 (de) | 2011-12-21 |
| EP2396177B1 EP2396177B1 (de) | 2014-08-13 |
Family
ID=41055120
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP10708267.9A Active EP2396177B1 (de) | 2009-02-16 | 2010-02-02 | Thermisches übertragungsband, das eine uv-vernetzbare schutzschicht enthält |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8669204B2 (de) |
| EP (1) | EP2396177B1 (de) |
| JP (1) | JP5558495B2 (de) |
| ES (1) | ES2521522T3 (de) |
| FR (1) | FR2942170B1 (de) |
| PL (1) | PL2396177T3 (de) |
| WO (1) | WO2010092277A1 (de) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101632964B1 (ko) * | 2014-08-08 | 2016-06-27 | 주상명 | 다용도 슬립 방지 기능을 갖는 잉크 조성물 및 이를 이용한 슬립 방지 기능을 갖는 시트의 제조방법 |
| TWI647124B (zh) * | 2016-06-02 | 2019-01-11 | 大勤化成股份有限公司 | Ultraviolet transfer method |
| CN107903382A (zh) * | 2017-11-23 | 2018-04-13 | 河南省科学院化学研究所有限公司 | 条码碳带背涂层用树脂及其制备方法和条码碳带背涂液及其应用 |
| CN110143068A (zh) * | 2019-05-23 | 2019-08-20 | 广东可得智能科技有限公司 | 一种打印机用色带生产工艺 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8725452D0 (en) | 1987-10-30 | 1987-12-02 | Ici Plc | Dyesheet |
| JPH01222993A (ja) * | 1988-03-03 | 1989-09-06 | Ricoh Co Ltd | 感熱転写シート |
| JPH04158090A (ja) * | 1990-10-23 | 1992-06-01 | Dainippon Ink & Chem Inc | 活性エネルギー線硬化型熱転写フィルムバックコート用組成物 |
| US5141915A (en) * | 1991-02-25 | 1992-08-25 | Minnesota Mining And Manufacturing Company | Dye thermal transfer sheet with anti-stick coating |
| JP2987534B2 (ja) * | 1991-12-05 | 1999-12-06 | 株式会社リコー | 感熱転写記録シート |
| JP3380093B2 (ja) * | 1995-08-23 | 2003-02-24 | 信越化学工業株式会社 | 感熱転写用シート |
| US5866508A (en) * | 1995-12-21 | 1999-02-02 | Ricoh Company, Ltd. | Thermosensitive recording material |
| JP3640329B2 (ja) * | 1996-12-06 | 2005-04-20 | 日本化薬株式会社 | 感熱記録体 |
| US6335307B1 (en) * | 1998-03-19 | 2002-01-01 | Matsushita Electric Industrial Co., Ltd. | Medium for thermal transfer recording, and method of thermal transfer recording |
| US6245416B1 (en) * | 1998-05-20 | 2001-06-12 | Ncr Corporation | Water soluble silicone resin backcoat for thermal transfer ribbons |
| JP4023607B2 (ja) * | 2003-03-20 | 2007-12-19 | 大日本印刷株式会社 | 熱転写シート |
-
2009
- 2009-02-16 FR FR0950966A patent/FR2942170B1/fr active Active
-
2010
- 2010-02-02 US US13/148,485 patent/US8669204B2/en active Active
- 2010-02-02 ES ES10708267.9T patent/ES2521522T3/es active Active
- 2010-02-02 PL PL10708267T patent/PL2396177T3/pl unknown
- 2010-02-02 WO PCT/FR2010/050167 patent/WO2010092277A1/fr active Application Filing
- 2010-02-02 EP EP10708267.9A patent/EP2396177B1/de active Active
- 2010-02-02 JP JP2011549638A patent/JP5558495B2/ja active Active
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2010092277A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2521522T3 (es) | 2014-11-12 |
| EP2396177B1 (de) | 2014-08-13 |
| JP2012517916A (ja) | 2012-08-09 |
| US8669204B2 (en) | 2014-03-11 |
| FR2942170A1 (fr) | 2010-08-20 |
| JP5558495B2 (ja) | 2014-07-23 |
| WO2010092277A1 (fr) | 2010-08-19 |
| US20110311739A1 (en) | 2011-12-22 |
| FR2942170B1 (fr) | 2015-10-02 |
| PL2396177T3 (pl) | 2015-02-27 |
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