EP0993963B1 - Endlosdruckverfahren für einen Plastikfilm, Gerät hierfür, sowie damit hergestellter bedruckter Plastikfilm - Google Patents
Endlosdruckverfahren für einen Plastikfilm, Gerät hierfür, sowie damit hergestellter bedruckter Plastikfilm Download PDFInfo
- Publication number
- EP0993963B1 EP0993963B1 EP99402398A EP99402398A EP0993963B1 EP 0993963 B1 EP0993963 B1 EP 0993963B1 EP 99402398 A EP99402398 A EP 99402398A EP 99402398 A EP99402398 A EP 99402398A EP 0993963 B1 EP0993963 B1 EP 0993963B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- plastic film
- roll
- printing
- paper
- printed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F16/00—Transfer printing apparatus
- B41F16/02—Transfer printing apparatus for textile material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
- B41M5/0358—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the mechanisms or artifacts to obtain the transfer, e.g. the heating means, the pressure means or the transport means
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0011—Pre-treatment or treatment during printing of the recording material, e.g. heating, irradiating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
- B41M5/0052—Digital printing on surfaces other than ordinary paper by thermal printing
Definitions
- the invention relates to a method for continuously printing a film plastic plane, flocked or not, the device for its implementation and the film printed plastic obtained by this method.
- Sublimation transfer printing is already known as such and consists, in a first step, to print on a support paper patterns from inks consisting of sublimable dyes that are suitable to vaporize at a certain temperature and to settle permanently on synthetic materials, for example polyester or polyamide polymers, the printing process of the carrier paper can be any, for example an offset printing, a heliographic or flexographic printing, or an impression silkscreen with flat or rotating frame.
- the printing process of the carrier paper can be any, for example an offset printing, a heliographic or flexographic printing, or an impression silkscreen with flat or rotating frame.
- patterns in sublimable dyes previously printed on the backing paper are transferred by sublimation, putting in contact, under a regular pressure and a determined temperature, usually using of a thermal grille, the pre-printed paper with the textile support to print, usually for a period of 5 to 40 seconds.
- the grille In the case of printing in formats, thermal heating press with horizontal plates, or in the case of an impression continuously from rolls of printed paper and synthetic
- This sublimation transfer printing process can be used to to print certain plastics, provided that previously a layer of varnish on the plastic material to be printed, or to pre-process the pre-printed printing paper so as to make non-stick.
- This printing method is used in particular for printing injected or shaped plastic parts, such as flasks, skis, pens, helmets, and in this case the impression is made using a heating tool matching the shape of the room plastic to print.
- Another method of direct printing of plastic films is to use the known methods of the flexographic or screen printing type, but in this case, the ink does not penetrate the plastic, so that the printed patterns have a low resistance to scratching and friction. In addition, these printing methods do not allow to obtain the finest graphic effects, for example impressions in four-color photographic type.
- WO 93/22072 discloses a method of coating or for printing plastic sheets, comprising the steps of put a sheet of plastic on an endless conveyor belt, heat the plastic sheet to a temperature sufficient to adhere the plastic sheet to the conveyor belt, to cool the plastic sheet adhering to the conveyor belt, to coat or print the sheet plastic adhering to the conveyor belt with a composition coating or with inks or dyes, to dry the composition coatings or inks or dyes, to cool the plastic sheet and to remove it from the conveyor belt.
- the first cooling step before the next stage of coating or printing, excludes the use of a sublimation transfer printing process which requires a temperature at least equal to or greater than that required for the heating step to adhere the plastic sheet to the strip conveyor.
- WO93 / 22072 also discloses another method coating or printing plastic sheets or other substrates, such as knit, fabric, fleece or felt, this method of coating or print a conveyor belt with at least one layer of aqueous coating composition, a coating composition containing a solvent or a mixture of these two compositions, a hardenable lacquer UV, an ink or dye, or a PVC paste, to dry the composition or the ink deposited on the conveyor belt, to deposit the plastic sheet or other substrate on the conveyor belt thus coated or printed, to transfer the coating composition or ink from the tape conveyor to the plastic sheet or other substrate by use of heat, cool the plastic sheet or other substrate and remove it from the conveyor belt.
- Yet another known method for printing plastic films consists of heat sealing on the surface to be printed on the plastic film previously printed support, for example a printed polyester film in heliography, then laminated hot on the plastic film at the end of the extruder (EP 0 097 528, Figure 14).
- the object of the invention is to propose a process for the continuous printing of a plastic film, flocked or not, by a transfer printing process sublimation, while having quality, finesse and sharpness high print quality, such as four-color printing, and avoiding bonding between the plastic film both with the conveyor belt and with the pre-printed printing paper.
- the temperature for thermocolling the plastic film at temporary support is between 100 and 200 ° C, preferably between 170 and 180 ° C.
- the temperature for sublimation transfer can be between 170 and 230 ° C.
- the temperature at which the entire film Printed plastic and temporary support is cooled may be of the order from 20 to 30 ° C.
- the method of the invention consists, for a non-flocked plastic film, to pre-print the printing paper with a ink containing sublimable dyes, and softening agents or non-stick, to avoid sticking between plastic film and paper during the sublimation transfer printing step.
- these agents are chosen from silicones, fatty acids organic and chromium stearates.
- the method comprises preparing a flocked plastic film prior to the thermal printing step by applying an adhesive layer to the front of the plastic film and flocking white fibers to said adhesive layer.
- the adhesive layer is a polymer resin in aqueous emulsion or organic solution
- the flocks are preferably polyamide or polyester fibers, with a length of between 0.3 and 3.0 mm and a titer between 0.5 and 20 Dtex (0.5 and 20.10 -7 Kg.m -1) .
- the plastic film may be a calendered, extruded or coextruded film, selected among the polyvinyl chloride-based polymer resins, polystyrene, polypropylene, butadiene-styrene acrylic (ABS), polyurethane, polyester, polycarbonate, polyamide or any other mixture of these.
- ABS butadiene-styrene acrylic
- the printing paper can be printed by offset printing, flexographic, heliographic, screen printing, or inkjet printing.
- the cooling station comprises two cylinders with double envelope, each cylinder having a circulation of an agent refrigerant, for example water, in the jacket, so that said printed composite web comes into contact with the first cylinder by its temporary support band, then with the second cylinder by its printed plastic film tape.
- an agent refrigerant for example water
- the subject of the invention is also a strip of printed plastic film, characterized in that it is directly obtained by the above method.
- This device comprises a unwinding station 1 which supports rotatively, a reel 2 from which a web is unrolled temporary support 3 for example paper, and above the coil 2, a spool 17 from which is unwound a strip of plastic film 4, flocked or not.
- the temporary support is made of material that is not very sensitive to heat, to ensure dimensional stability to the plastic film, when the subsequent sublimation operation, this material having a anti-adherent feature at room temperature, to facilitate the detachment of the plastic film after thermal printing, as well as ability to adhere hot with the plastic film when the latter undergoes fusion, during heating and sublimation transfer operations later.
- a heating station 5 which comprises three guide rollers 6 arranged upstream of a drum rotary heater 7, which is rotated in the indicated clockwise direction by the arrow F in FIG.
- the strips 3 and 4 pass under a first roll 6, the front of the strip of plastic film 4 coming into contact with the roll 6 and the temporary support strip 3 coming into contact with the reverse side of the said strip 4.
- the set of strips 3 and 4 as well overlapping is routed horizontally to a second roll 6 against which the front side of the strip of plastic film 4 always bears, said strips 3 and 4 making a 90 ° turn upward around this second roll 6.
- the superimposed strips 3 and 4 perform a turn 180 ° around the third roller 6 which is located near the heating drum 7, so that the temporary support band 3 comes in contact with the heating cylinder 7, to prevent sticking by softening of the plastic film on the heating drum 7.
- the assembly strips 3 and 4 wrap around the heating drum 7 at an angle about 270 °, so that the plastic film strip 4 is brought to a temperature of about 200 ° C when the assembly leaves the drum 7.
- the plastic film strip adheres, because of its fusion, to the temporary support strip 3 which ensures a dimensional support to said strip of plastic film 4, the whole thus forming a composite strip 18 whose two layers are temporarily glued together.
- Said composite strip 18 is conveyed horizontally downstream of the heating drum 7 to a heat-printing machine 8.
- This thermo-printing machine 8 has at its entrance a roll of guidance 9 against which the temporary support of the band is supported composite.
- the composite strip is conveyed by a conveyor belt 10 around a rotating heating grille 11 which is driven by rotation in the counter-clockwise direction in FIG. 1.
- the conveyor belt 10 is consisting of an endless band that rolls around a plurality of rollers 12, some of these rollers being movable to adjust the tension of the carpet 10 and therefore the pressure exerted by the belt 10 against the front grille 11.
- the composite strip comes into contact with the conveyor belt 10 by its temporary support, to avoid any bonding between the plastic film and the carpet.
- the machine 8 further comprises at least one coil 13, for example two reels, from which is unwound a strip 14 of pre-printed paper with a pattern consisting of a sublimable ink.
- the band pre-printed paper 14 is guided by a roller 15 upstream of the carpet 10 and the heating radiator 11.
- the machine 8 comprises two other coils 16 arranged downstream of the heating shell 11 and the carpet 10, on which rolls 16 is wound the paper 14, after the Sublimation transfer of the ink onto the plastic film of the strip composite.
- the pre-printed paper 14 is sandwiched between the shell 11 and the front of the plastic film of the composite strip which is pressurized by the conveyor belt 10 against the shell 11.
- the pattern consisting of a sublimable ink is pre-printed on the side of the paper 14 which is intended to come into contact with the front of the plastic film of the composite tape to allow transfer by sublimation.
- sublimation transfer is done around of the heating grille 11, over an angular stroke of about 300 °, to a temperature between 180 and 230 ° C under a steady pressure generally less than 40 kPa exerted by the conveyor belt 10, and for an approximate duration of 5 to 40 s.
- the sublimable ink of the paper pre-printed 14 contains softening or non-sticking agents, for avoid gluing the pre-printed paper 14 on the plastic film.
- the plastic film has a flocked surface, intended for be printed, it is not necessary to provide such agents.
- the structure of the printing machine 8 will not be described more in detail because it is known in itself.
- two coils 13 and two coils 16 for the pre-printed paper 14 in order to avoid any interruption of the process, when one of the coils is completely unwound, the other taking over during the replacement of the reel completely unwound.
- each cylinder 21 or 22 has a double envelope on its side wall, to circulate inside this double envelope of water, for example at 10 ° C, to cool the band printed composite 19, up to a temperature generally included between 20 and 30 ° C.
- the composite strip first passes around the upper cylinder 21, coming into contact with its temporary support, in order to avoid film sticking printed plastic against this cylinder. Then, the already cooled composite strip passes around the lower cylinder 22, on the side of its plastic film printed, which is no longer likely to stick to the cylinder 22.
- the path of the tape composite around the two cylinders 21 and 22 has a configuration substantially S-shaped. At the outlet of the cooling station 20, the previously printed plastic film no longer adheres to the temporary support, because of the non-stick properties of this last.
- the two overlapping strips pass through a station winding 23 which comprises a coil 24 around which is wound the printed plastic film strip 104 and a coil 25 around it of which is wound the temporary support strip 3.
- a station winding 23 which comprises a coil 24 around which is wound the printed plastic film strip 104 and a coil 25 around it of which is wound the temporary support strip 3.
- the two superposed strips 3 and 104 pass between two rollers 27 downstream of which the two strips are separated into direction of their respective reels. Coils 24 and 25 and rollers 27 are rotated.
- the temporary support band 3 is first unrolled from the coil 2 all the way inside the device up to the coil winding 25, over a total length of about 20 to 30 meters. Then, the plastic film strip 4 is unwound from the spool 17, on a length of about 2 to 3 meters to the heating drum 7, because from from this place the strip of plastic film 4 adheres to the support strip temporary 3, which allows its training through the entire device.
- the temporary support band 3 which is wound on the coil 25, can be reused for the subsequent printing of a new plastic film tape.
- a checkerboard pattern 30 is pre-printed on the strip of printing paper 14, the checkerboard pattern 30 having in its square central equilateral triangle whose apex is directed to the left.
- Sure this strip of printing paper 14 is also printed a marker consisting of a longitudinal line 31 and a transverse line 32, for locate on said strip 14 the preprinted pattern 30.
- a band can be output of printed plastic film 104 having a checkered pattern 130 which is exactly the upside-down image of the pattern 30 of the preprinted paper 14, the top of the equilateral triangle now being turned to the right on the figure 3.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Printing Methods (AREA)
- Decoration By Transfer Pictures (AREA)
- Laminated Bodies (AREA)
- Coloring (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
Claims (12)
- Verfahren zur automatischen Endlosbedruckung einer beflockten oder nicht beflockten Kunststofffolie (4), dadurch gekennzeichnet, dass dieses Verfahren darin besteht,auf der Rückseite der Kunststofffolie (4) einen provisorischen nichtklebenden Träger (3), beispielsweise aus Papier, aufzubringen,die aus der Kunststofffolie und dem provisorischen Träger bestehende Einheit auf eine Temperatur zu erhitzen, bei der die Kunststofffolie ihren Erweichungspunkt erreicht und vorübergehend auf dem provisorischen Träger klebt, derart, dass dieser dafür sorgt, dass die Kunststofffolie bei dem darauffolgenden Wärmedruckvorgang dimensionsstabil bleibt,durch Sublimation ein Motiv (30, 40) zu übertragen, das aus einer auf ein Druckpapier (14) vorab aufgedruckten sublimierbaren Tinte besteht, durch Kontakt unter einem bestimmten Druck und bei einer bestimmten Temperatur mit der Vorderseite der auf dem provisorischen Träger (3) warmverklebten Kunststofffolie (4),die aus der derart bedruckten Kunststofffolie (104) und dem provisorischen Träger (3) bestehende Einheit auf eine Temperatur abzukühlen, die die Ablösung vom provisorischen Träger ermöglicht.
- Verfahren entsprechend Anspruch 1, dadurch gekennzeichnet, dass die Temperatur zur Warmverklebung der Kunststofffolie (4) auf dem provisorischen Träger (3) zwischen 100 und 200° C, vorzugsweise zwischen 170 und 180° C, beträgt.
- Verfahren entsprechend einer der Ansprüche 1 oder 2, dadurch gekennzeichnet, dass die Temperatur zur Übertragung durch Sublimation zwischen 170 und 230° C beträgt.
- Verfahren entsprechend einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Temperatur, auf die die aus der bedruckten Kunststofffolie (104) und dem provisorischen Träger (3) bestehende Einheit abgekühlt wird, zwischen 20 und 30° C beträgt.
- Verfahren entsprechend einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass es darin besteht, bei einer nicht beflockten Kunststofffolie das Druckpapier (14) mit einer Tinte vorzubedrucken, die sublimierbare Farbstoffe und Weichmacher oder Antiklebstoffe enthält, um ein Verkleben zwischen der Kunststofffolie (4) und dem Druckpapier (14) beim Druckvorgang durch Sublimationsübertragung zu vermeiden,.
- Verfahren entsprechend Anspruch 5, dadurch gekennzeichnet, dass die Zusätze unter den Silikonen, organischen Fettsäuren und Chromstearaten gewählt sind.
- Verfahren entsprechend einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass es darin besteht, vor dem Wärmedruckvorgang eine beflockte Kunststofffolie vorzubereiten, indem auf die Vorderseite der Kunststofffolie (4) eine Klebeschicht aufgebracht wird und diese Klebeschicht mit weißen Fasern beflockt wird.
- Verfahren entsprechend Anspruch 7, dadurch gekennzeichnet, dass die Klebeschicht ein Polymerharz in wässriger Emulsion oder organischer Lösung ist und die Flocken vorzugsweise aus Polyamid oder Polyester sind, eine Länge zwischen 0,3 und 3,0 mm haben und eine Feinheit zwischen 0,5 und 20 Dtex (0,5 und 20.10-7 Kg.m-1) aufweisen.
- Verfahren entsprechend einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, dass die Kunststofffolie (4) eine kalandrierte, extrudierte oder co-extrudierte Folie ist, die unter den Polyvinylchlorid-, Polystyrol-, Polypropylen-, Akryl-Butadien-Styrol-(ABS), Polyäthan-, Polyester-, Polycarbonat-, Polyamidharzen oder aus einer beliebigen Mischung davon gewählt ist.
- Vorrichtung zur Durchführung des Verfahrens entsprechend einem der Ansprüche 1 bis 9, dadurch gekennzeichnet, dass sie umfasst:eine Abwicklungsstation (1), mit einer Spule (17) für eine beflockte oder nicht beflockte Kunststofffolienbahn (4) und einer Spule (2) für eine Bahn des provisorischen Trägers (3),eine Erhitzungsstation (5), an deren Anfang die Bahn des provisorischen Trägers (3) gegen die Rückseite der Kunststofffolienbahn (4) aufgebracht wird, wobei die aus den übereinandergelegten Bahnen bestehende Einheit mit der Bahn des provisorischen Trägers gegen eine sich drehende Heizwalze (7) in Berührung kommt, so dass eine Verbundbahn (18) gebildet wird, die aus der mit dem provisorischen Träger heißverklebten Kunststofffolie besteht,eine Wärmedruckmaschine (8), umfassend ein unter Spannung stehendes Förderband (10), das mit dem provisorischen Träger (3) der Verbundbahn (18) in Berührung kommt, ein zur Drehung angetriebener Erhitzungskalander (11) und mindestens eine Spule (13) für eine Papierbahn (14), die mit einem Motiv (30, 40) vorbedruckt ist, das aus einer sublimierbaren Tinte besteht, wobei diese vorbedruckte Papierbahn vor dem Erhitzungskalander auf die Vorderseite der Kunststofffolie (4) des Verbundbandes (18) derart aufgebracht wird, dass das Förderband unter einer bestimmten Spannung das mit dem vorbedruckten Papier bedeckte Verbundband gegen den Erhitzungskalander andrückt, um die sublimierbare Tinte durch Sublimierung auf die Vorderseite der Kunststofffolie zu übertragen, wobei das Druckpapier hinter dem Erhitzungskalander von der bedruckten Verbundbahn (19) abgelöst wird.eine Abkühlstation (20), um die bedruckte Verbundbahn (19) auf eine Temperatur abzukühlen, bei der sich die Bahn des provisorischen Trägers (3) von der bedruckten Kunststofffolienbahn (104) abziehen lässt,eine Aufwicklungsstation (23), an deren Anfang die Bahn des provisorischen Trägers (3) von der bedruckten Kunststofffolienbahn (104) abgelöst wird, wobei die Bahnen jeweils auf eine zur Drehung angetriebene Spule (24, 25) aufgewickelt werden.
- Vorrichtung entsprechend Anspruch 10, dadurch gekennzeichnet, dass die Abkühlstation (20) zwei doppelwandige Zylinder (21, 22) aufweist, wobei jeder Zylinder in der Doppelummantelung einen Kühlmittelkreislauf, beispielsweise Wasser, derart aufweist, dass das bedruckte Verbundband (19) über sein Band des provisorischen Trägers (3) mit dem ersten Zylinder (21) und anschließend über sein bedrucktes Kunststofffolienband (104) mit dem zweiten Zylinder (22) in Berührung kommt.
- Bedrucktes Kunststofffolienband (104), dadurch gekennzeichnet, dass es direkt durch das Verfahren entsprechend einem der Ansprüche 1 bis 9 erhalten ist.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9812862A FR2784618B1 (fr) | 1998-10-14 | 1998-10-14 | Procede d'impression en continu d'un film plastique, dispositif pour sa mise en oeuvre et film plastique imprime obtenu par le procede |
FR9812862 | 1998-10-14 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0993963A1 EP0993963A1 (de) | 2000-04-19 |
EP0993963B1 true EP0993963B1 (de) | 2003-03-26 |
Family
ID=9531540
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99402398A Expired - Lifetime EP0993963B1 (de) | 1998-10-14 | 1999-09-30 | Endlosdruckverfahren für einen Plastikfilm, Gerät hierfür, sowie damit hergestellter bedruckter Plastikfilm |
Country Status (7)
Country | Link |
---|---|
US (1) | US6249297B1 (de) |
EP (1) | EP0993963B1 (de) |
AT (1) | ATE235377T1 (de) |
DE (1) | DE69906212T2 (de) |
ES (1) | ES2194424T3 (de) |
FR (1) | FR2784618B1 (de) |
PT (1) | PT993963E (de) |
Cited By (1)
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WO2020107367A1 (zh) * | 2018-11-30 | 2020-06-04 | 华衫环保纺织股份有限公司 | 经纱转印机 |
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US6596116B2 (en) * | 2000-08-23 | 2003-07-22 | Joseph Macedo | Methods for applying decorative designs to a continuous laminate |
TWI270478B (en) * | 2001-03-29 | 2007-01-11 | Fresco Plastics | Method and apparatus for continuously forming dye sublimation images in solid substrates |
US6998005B2 (en) * | 2001-03-29 | 2006-02-14 | Fresco Plastics Llc | Method and apparatus for forming dye sublimation images in solid plastic |
US8308891B2 (en) | 2001-03-29 | 2012-11-13 | Fresco Technologies, Inc. | Method for forming dye sublimation images in solid substrates |
WO2003031083A1 (en) | 2001-10-05 | 2003-04-17 | High Voltage Graphics, Inc. | Screen printed resin film applique or transfer made from liquid plastic dispersion |
US6951594B2 (en) * | 2002-06-27 | 2005-10-04 | Tweel Home Furnishings, Inc. | Printed oven mitt and method for making same |
US7410682B2 (en) * | 2002-07-03 | 2008-08-12 | High Voltage Graphics, Inc. | Flocked stretchable design or transfer |
AU2003251790A1 (en) * | 2002-07-03 | 2004-01-23 | High Voltage Graphics, Inc. | Process for printing and molding a flocked article |
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FR2862567B1 (fr) * | 2003-06-24 | 2006-02-17 | Bernard Claveau | Procede et dispositif de marquage par sublimation d'objets allonges |
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FR2875822B1 (fr) | 2004-08-04 | 2007-04-27 | Enduction Et De Flockage Sa So | Procede de fabrication en continu d'un support en nappe flocke colore |
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US8007889B2 (en) * | 2005-04-28 | 2011-08-30 | High Voltage Graphics, Inc. | Flocked multi-colored adhesive article with bright lustered flock and methods for making the same |
WO2007018483A1 (en) * | 2005-07-05 | 2007-02-15 | Aprentado, Ana, K | Method for forming a decorative flower pot |
US7799164B2 (en) * | 2005-07-28 | 2010-09-21 | High Voltage Graphics, Inc. | Flocked articles having noncompatible insert and porous film |
WO2007035809A2 (en) * | 2005-09-20 | 2007-03-29 | High Voltage Graphics, Inc. | Flocked elastomeric articles |
US20070110949A1 (en) * | 2005-11-17 | 2007-05-17 | High Voltage Graphics, Inc. | Flocked adhesive article |
US20070148397A1 (en) * | 2005-12-07 | 2007-06-28 | High Voltage Graphics, Inc. | Flocked multi-colored adhesive article with bright lustered flock |
US8475905B2 (en) | 2007-02-14 | 2013-07-02 | High Voltage Graphics, Inc | Sublimation dye printed textile |
EP2550882B1 (de) * | 2011-07-27 | 2019-08-21 | Bauer Hockey Ltd. | Sporthelm |
US20130288018A1 (en) * | 2012-04-30 | 2013-10-31 | Patrick W. Moller | System and method for printing on plastic and forming the printed plastic |
JP2016502470A (ja) | 2012-10-12 | 2016-01-28 | ハイ ボルテイジ グラフィックス インコーポレイテッドHigh Voltage Graphics,Inc. | 熱融着可能な可撓性の装飾品およびそれを製造する方法 |
US10011120B2 (en) | 2013-07-25 | 2018-07-03 | The Hillman Group, Inc. | Single heating platen double-sided sublimation printing process and apparatus |
US9333788B2 (en) | 2013-07-25 | 2016-05-10 | The Hillman Group, Inc. | Integrated sublimation transfer printing apparatus |
US9731534B2 (en) | 2013-07-25 | 2017-08-15 | The Hillman Group, Inc. | Automated simultaneous multiple article sublimation printing process and apparatus |
US9120326B2 (en) | 2013-07-25 | 2015-09-01 | The Hillman Group, Inc. | Automatic sublimated product customization system and process |
US9403394B2 (en) | 2013-07-25 | 2016-08-02 | The Hillman Group, Inc. | Modular sublimation transfer printing apparatus |
WO2015108404A1 (es) * | 2014-01-16 | 2015-07-23 | Mizrahi Aksiote Mario Moiz | Proceso de manufactura de elementos impresos para fachadas arquitectónicas y aparatos de línea blanca y productos resultantes |
MX2016010077A (es) | 2015-08-05 | 2017-03-10 | Hillman Group Inc | Aparato de impresion por sublimacion semi-automatizado. |
US10160244B1 (en) * | 2017-04-13 | 2018-12-25 | John Garrett Whitt | Method for dye-sublimation printing an orthotic substrate and orthotic product made thereby |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0097528A3 (de) * | 1982-06-21 | 1985-08-14 | Hlh Corporation | Absorption von Farbmustern in Kunststoffen |
AU3979493A (en) | 1992-04-24 | 1993-11-29 | Erich Killar | Process for coating or printing a plastic film with water or solvent-containing coating agents or mixtures thereof, U/V-curable paints or inks and PVC pastes |
WO1998024643A1 (en) * | 1996-12-03 | 1998-06-11 | Inexa Panel A/S | Fire resistant sandwich board |
-
1998
- 1998-10-14 FR FR9812862A patent/FR2784618B1/fr not_active Expired - Fee Related
-
1999
- 1999-09-30 ES ES99402398T patent/ES2194424T3/es not_active Expired - Lifetime
- 1999-09-30 AT AT99402398T patent/ATE235377T1/de not_active IP Right Cessation
- 1999-09-30 PT PT99402398T patent/PT993963E/pt unknown
- 1999-09-30 EP EP99402398A patent/EP0993963B1/de not_active Expired - Lifetime
- 1999-09-30 DE DE69906212T patent/DE69906212T2/de not_active Expired - Lifetime
- 1999-10-14 US US09/418,987 patent/US6249297B1/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020107367A1 (zh) * | 2018-11-30 | 2020-06-04 | 华衫环保纺织股份有限公司 | 经纱转印机 |
Also Published As
Publication number | Publication date |
---|---|
DE69906212D1 (de) | 2003-04-30 |
EP0993963A1 (de) | 2000-04-19 |
US6249297B1 (en) | 2001-06-19 |
FR2784618B1 (fr) | 2000-11-24 |
ES2194424T3 (es) | 2003-11-16 |
FR2784618A1 (fr) | 2000-04-21 |
DE69906212T2 (de) | 2004-02-05 |
PT993963E (pt) | 2003-06-30 |
ATE235377T1 (de) | 2003-04-15 |
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