EP2376890A1 - Essai rapide d'abrasion pour granulés - Google Patents

Essai rapide d'abrasion pour granulés

Info

Publication number
EP2376890A1
EP2376890A1 EP09801719A EP09801719A EP2376890A1 EP 2376890 A1 EP2376890 A1 EP 2376890A1 EP 09801719 A EP09801719 A EP 09801719A EP 09801719 A EP09801719 A EP 09801719A EP 2376890 A1 EP2376890 A1 EP 2376890A1
Authority
EP
European Patent Office
Prior art keywords
granules
test according
rapid test
abrasion
grinding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP09801719A
Other languages
German (de)
English (en)
Inventor
Marisa Cruz
Rainer Fuchs
Frank Dieter Kuhn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Evonik Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Degussa GmbH filed Critical Evonik Degussa GmbH
Publication of EP2376890A1 publication Critical patent/EP2376890A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N3/00—Investigating strength properties of solid materials by application of mechanical stress
    • G01N3/56—Investigating resistance to wear or abrasion
    • G01N3/565—Investigating resistance to wear or abrasion of granular or particulate material
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N3/00—Investigating strength properties of solid materials by application of mechanical stress
    • G01N3/56—Investigating resistance to wear or abrasion
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2203/00—Investigating strength properties of solid materials by application of mechanical stress
    • G01N2203/02—Details not specific for a particular testing method
    • G01N2203/026—Specifications of the specimen
    • G01N2203/0284—Bulk material, e.g. powders

Definitions

  • the present invention relates to a rapid abrasion test for granules, preferably inorganic or organic granules, particularly preferably plastic granules, in particular for artificial turf filling materials.
  • the rapid test of the present invention allows determination of the strength and adhesion of fabric layers to surfaces or intermediate layers of multi-layered granules.
  • Plastic granules are a typical form of delivery of thermoplastics from raw material manufacturers to the plastics processing industry. Because of their flowability, they are a bulk material, such as sand or gravel, and thus comparatively easy to transport and process.
  • European Patent Application EP 1 416 009 A1 discloses the use of coated rubber particles as a bedding material or as a loose elastic layer for artificial turf or other floor coverings.
  • the rubber particles are usually irregular, n-shaped and preferably have a mean size between 0.4 mm and 2.5 mm to a maximum of 4.0 mm.
  • the individual rubber particles are over their entire surface with a 5 microns to 35 microns thick Cover provided.
  • the coating forms a permanently elastic sheath, the washing out of pollutants such. B. should largely prevent zinc. In addition to be reduced by this encapsulation typical for rubber old rubber odor.
  • Plastic granules in a simple manner can be quickly and inexpensively determined and assessed.
  • the plastic granules are ground in a special ball mill (500 revolutions), with no pulverization or other changes of the rubber granules are allowed.
  • the particle size of the plastic granules is determined before and after grinding and compared, with an abrasion resistance of at least 95% is required to pass the test.
  • Abrasion stability ⁇ 95% in the exact execution of the test with suitable filling materials is advantageous to allow as many artificial turf particle systems, but not in order to determine the suitability of different materials in a quick and easy way and to compare meaningful with each other.
  • this method different Coatings that have a different abrasion behavior, not or only slightly differentiated from each other, because the resulting measurement results are very close to each other. Thus, for example, no "ranking", so no classification different abrasion resistant
  • Coatings are made relative to each other. Or such a classification succeeds only in a narrow framework, which differs only slightly or not at all from the usual fluctuation range of the obtained measured values.
  • ISA In the classification of fillers by this test by ISA, all products with an abrasion resistance of ⁇ 95% are considered to be suitable for use as artificial turf fillers in accordance with the Dutch Standard for Gum Infill Materials, ISA-M37.
  • test apparatus can z. B. are hardly transported due to the weight of the device, a quantitative as possible
  • the mill is difficult to temper to measure the abrasion behavior at different temperatures.
  • the generation of detectable or measurable abrasion by means of ring shear cell also takes a long time.
  • a quantitative transfer of the material after grinding from the apparatus is difficult and also a cleaning of the apparatus is difficult.
  • the apparatus is still difficult to temper, in order to measure the abrasion behavior at different temperatures can.
  • abrasion determination methods for plastic blocks and skins (and thus for, for example, through-dyed material such as EPDM or TPE) are described in DIN V18035-7: 2002-06 and are not applicable to abrasion measurements on coated scrap tire rubber granulate.
  • the test should be as fast and as effective as possible, as universally applicable as possible and allow the most accurate classification of the abrasion of various granules. He should be particularly suitable for testing coated rubber particles.
  • test apparatus • As versatile as possible, a possibly necessary test apparatus should be as easy to transport as possible and have the smallest possible space requirement.
  • Abrasion behavior allows. o a distinction of equally coated rubber particles or uncoated rubber particles, but different weathering or pretreatment of the product allowed. o allows a distinction between equally coated organic or inorganic bodies or polymers or uncoated organic or inorganic bodies or polymers after different weathering or pretreatment.
  • test allows conclusions on the strength and adhesion of fabric layers on surfaces or in intermediate layers of multilayer granules.
  • the test according to the invention is extremely fast, reliable and effective, can be used universally and allows a very accurate classification of the abrasion of various granules. It is particularly suitable for testing coated rubber particles, which are used as filling materials for artificial turf.
  • Bonding of the coating to the rubber surface and the rubber bulk material to win over the pigment bond in the coating and / or on the coating thickness or the coating thickness distribution of the coating is possible, especially at higher temperatures, to simulate the behavior of artificial turf fillers in the topmost filler layer in summer, and / or at low temperatures to reduce the behavior of synthetic turf fillers in the cold season (fall, Winter).
  • the test according to the invention serves to quickly determine the abrasion resistance of granules, suitably of inorganic or organic granules, preferably of
  • Plastic granules particularly preferably of coated plastic granules, in particular of coated rubber particles, the u. a. be used as a bedding material or as a loose elastic layer for artificial turf or other floor coverings.
  • the rubber particles are usually irregular, n-shaped and preferably have a mean size between 0.4 mm and 4.0 mm.
  • the maximum particle size of the particles is preferably less than 10 mm, more preferably less than 7 mm.
  • the minimum particle size of the particles is preferably greater than 0.1 mm, more preferably greater than 0.5 mm.
  • the individual rubber particles are preferably provided with a 5 ⁇ m to 35 ⁇ m thick coating.
  • the coating preferably forms a permanently elastic sheath, the washing out of pollutants such. B. should largely prevent zinc. In addition to be reduced by this encapsulation typical for rubber old rubber odor. Further details of such plastic granules can be found, for example, in European patent application EP 1 416 009 A1.
  • the test according to the invention is in particular able to differentiate different coatings well.
  • the quality of colored coatings can be assessed by a more or less strong coloring of the wall of the cutting mill after the abrasion test has been carried out.
  • the degree of coloring of the mill wall is by a visual comparison with different comparison dyeings determinable.
  • other suitable methods for determining mill wall adhesions after abrasion test performance may be used to determine how far curing of layers has progressed, which is particularly advantageous in colorless coating systems.
  • the test according to the invention can also be used to assess the connection of a composite material.
  • the test according to the invention comprises the following steps:
  • a cutting mill is used in the context of the present invention, which usually consists of a horizontally or vertically arranged rotor, which is equipped with knives, which in the context of a first particularly preferred
  • Embodiment of the present invention work against anchored in the mill housing knife.
  • a schematic sketch of such a mill is in Römpp Lexikon Chemie, publisher: J. Falbe, M. Regitz, 10th edition, Georg Thieme Verlag, Stuttgart, New York, 1998, Volume: 4, keyword:
  • the housing of the mill does not comprise anchored knives, so that the ground granules can be more easily removed from the housing.
  • the working principle of the granulator is preferably cutting / impact.
  • the intensity of the grinding can be controlled via the energy emitted by the mill.
  • the rotational speed of the granulator is preferably in the range of 100 / min to 30,000 / min, in particular in the range of 1000 / min to 25000 / min.
  • the peripheral speed of the cutting mill is preferably in the range of 10 to 100 m / s, in particular in the range of 20 m / s to 80 m / s.
  • the dimensioning of the mill can basically be chosen freely and adapted to the requirements of the case.
  • the grinding chamber of the cutting mill during milling to at least 10%, based on the maximum useful volume of the granulator filled.
  • the cutting mill and the cutting tool are preferably made of a harder material than that too investigating granules.
  • the material to be ground is preferably placed in the chamber of the granulator and sheared by a stainless steel beater within a predetermined loading time ("grinding time"), whereby a rubbing, breaking and cutting of granules or layers occurs on the granules the massive and complex nature of the shears is achieved by rapid testing of the abrasion resistance of granules, especially of coated plastic granules
  • the results of the test are mainly influenced by the following variables: o elasticity of the coating o shear strength of the coating o intensity of adhesion of the coating on the particle, o particle size o particle size distribution, o particle elasticity, o shear strength of the particles.
  • milling times in the range from 5 seconds to 10 minutes, in particular in the range from 5 seconds to 150 seconds, are preferably selected.
  • the action of the grinding power of the granulator can be continuous or discontinuous. It has proven a procedure especially in which the Grinding force is preferably not varied during the grinding.
  • the grinding chamber of the cutting mill can be tempered during the grinding, in particular heated or cooled, to gain knowledge about the abrasion behavior of the granules at other temperatures. Also, a change in tempering tempering is conceivable. For this purpose, it is preferable to use a suitable, tempered liquid, e.g. Water, introduced into the heating / cooling chamber of the grinding chamber.
  • a suitable, tempered liquid e.g. Water
  • Cutting mills suitable for the purposes of the present invention are commercially available. The following mill has proven particularly successful:> Analytical mill: Universal mill M20, o Manufacturer: IKA-Werke GmbH & Co. KG o Operating principle: cutting / impact o Speed max. (l / min.): 20000 o Material racket / knife: stainless steel 1.4034 o Material grinding chamber: stainless steel 1.4301
  • sieves Preferably round test sieves (called sieves for short) are used, the screen frame of which preferably consists of metal.
  • the sieves preferably have a nominal diameter of 200 mm.
  • the sieve lid, all sieve frames and sieve pan preferably fit tightly closed or in one another.
  • the sieves are preferably covered with metal wire mesh according to DIN ISO 3310 Part 1.
  • a sieve set of 6 sieves with metal wire mesh (mesh size: 63 ⁇ m, 125 ⁇ m, 250 ⁇ m, 500 ⁇ m, lmm, 2mm) is sufficient.
  • it is particularly preferred to use a sieve set comprising a 500 ⁇ m sieve and a bottom.
  • the separation is preferably achieved by a horizontal, circular movement of the sieve set with a rotational frequency of preferably 300 + - 30 min "1 and an amplitude of 15 mm.
  • the screening is sieved batchwise, more preferably at several intervals, most preferably at 3 to 10 intervals, especially at 5 intervals.
  • the intervals are preferably the same length and are expediently 1 minute to 5 minutes, in particular 3 minutes, long.
  • the screening is preferably interrupted and then restarted again. This can possibly be programmed on the screening machine.
  • Sieving machines suitable for the purposes of the present invention are commercially available.
  • the following screening machine has proven particularly successful: > Screening machine: Model: AS 400 Control o Manufacturer: Retsch GmbH o Screening movement: horizontal circling o Speed digital: 50 - 300 min "1 o Interval operation 1 - 10 min o W x H x D: 540 x 260 x 507 mm
  • the determination of the particle size distribution is carried out in a known manner by weighing the sieves.
  • the result of the sieve analysis is compared with at least one reference value in order to classify the abrasion of the investigated granulate.
  • the determined particle size distribution of the ground product is preferably compared with the result of at least one other granulate in order to classify the attrition of the investigated granulate in comparison to the other granules.
  • the determined particle size distribution of the milled product is compared with the particle size distribution of the unmilled starting material in order to classify the attrition of the investigated granulate.
  • the determined particle size distribution of the milled product is compared with at least a predetermined limit in order to classify the abrasion of the investigated granules.
  • the proportion of particles smaller than 500 ⁇ m has proven to be a particularly suitable criterion for assessing the attrition of the particles.
  • the walls are tested after grinding for possible deposits, which were caused by the shear stress of the granules in the granulator.
  • optical comparison e.g., with appropriate reference samples, references, reference scales
  • ground material 20 g are filled into the chamber of the cutting mill.
  • the analysis mill used is a mill manufactured by IKA-Werke GmbH & Co. KG, model Universal Mill M20.
  • the chamber is closed by the corresponding devices on the lid and the millbase for 110 seconds at room temperature, using 15 ° C cooling water temperature and a flow rate for cooling the grinding bowl of 500-1000 ml / minute ground.
  • the ground pattern is transferred to the previously weighed sieves by means of a hair brush.
  • the color residues or coatings are compared with suitable references.
  • the sieve stack loaded with the sample (eg 500 ⁇ m and soil) is placed on a Retsch screening machine, model AS 400 Control, and the sieves are carefully clamped by means of the sieve clamping unit. This closes the screen system.
  • the sample is subjected to a sieve analysis (based on DIN 53477 with 5 intervals of 3 minutes). The individual sieve residues are determined by means of a balance.
  • Sieve residue (%) [sieve residue (g) - Siebtara (g) 100 / sample weight (g)
  • CGTR coated ground tire rubber
  • TPE thermoplastic elastomer
  • EPDM ethylene propylene dimer copolymer

Landscapes

  • General Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Tires In General (AREA)
  • Crushing And Grinding (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

L'invention concerne un essai rapide permettant de déterminer l'abrasion de granulés, cet essai consistant à i.) broyer des granulés, ii.) soumettre le produit broyé à une analyse granulométrique par tamisage et iii.) comparer les résultats de l'analyse avec au moins une valeur de référence pour déterminer la catégorie d'abrasion des granulés. Selon l'invention, les granulés sont broyés dans un broyeur à couteaux.
EP09801719A 2009-01-13 2009-12-29 Essai rapide d'abrasion pour granulés Withdrawn EP2376890A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009000175A DE102009000175A1 (de) 2009-01-13 2009-01-13 Schnellabriebtest für Granulate
PCT/EP2009/067974 WO2010081629A1 (fr) 2009-01-13 2009-12-29 Essai rapide d'abrasion pour granulés

Publications (1)

Publication Number Publication Date
EP2376890A1 true EP2376890A1 (fr) 2011-10-19

Family

ID=41863921

Family Applications (1)

Application Number Title Priority Date Filing Date
EP09801719A Withdrawn EP2376890A1 (fr) 2009-01-13 2009-12-29 Essai rapide d'abrasion pour granulés

Country Status (7)

Country Link
US (1) US20110247392A1 (fr)
EP (1) EP2376890A1 (fr)
CN (1) CN102272573A (fr)
BR (1) BRPI0923941A2 (fr)
DE (1) DE102009000175A1 (fr)
TW (1) TW201107745A (fr)
WO (1) WO2010081629A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012210599B4 (de) * 2012-06-22 2023-06-07 Bayerische Motoren Werke Aktiengesellschaft Verfahren zur Feststellung der Qualität von beschichteten Kleinteilen oder beschichteten Verbindungselementen
CN104865145B (zh) * 2014-02-21 2017-09-15 中石化洛阳工程有限公司 一种测定催化剂抗磨损能力的方法
CN104677763B (zh) * 2015-03-03 2017-03-01 沈阳工业大学 橡胶湿磨粒磨损试验机
CN104931371A (zh) * 2015-04-02 2015-09-23 青岛科技大学 一种新型橡胶磨耗试验机
WO2017064562A1 (fr) * 2015-10-15 2017-04-20 Simsage Pty Ltd Appareil et procédé permettant de déterminer la dureté d'un matériau granulaire
CN108801829B (zh) * 2018-06-06 2020-08-04 上海大学 一种打磨过程中最优磨具粒度的选择方法
CN111610305B (zh) * 2020-04-28 2021-11-09 北京科技大学 使用转鼓定量评价炼钢用铁合金抗碎性和耐磨性的方法
CN112730126A (zh) * 2020-12-08 2021-04-30 兰州空间技术物理研究所 一种多环境真空摩擦磨损试验系统

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US4658631A (en) * 1986-04-01 1987-04-21 Swon James E Friability drum tester for pharmaceutical tablets
US4938055A (en) * 1989-01-26 1990-07-03 Ozeki Chemical Industry Co., Ltd. Apparatus for testing abrasion
US5285681A (en) * 1990-12-20 1994-02-15 Purina Mills, Inc. On-line pellet durability tester
JPH0915130A (ja) * 1995-06-29 1997-01-17 Sumitomo Heavy Ind Ltd 耐摩耗性評価試験装置における試験圧力制御方法
DE10251818B4 (de) 2002-11-04 2006-06-08 Mülsener Recycling- und Handelsgesellschaft mbH Lose, rieselfähige Gummipartikel, Verfahren zu deren Herstellung und deren Verwendung
US7022402B2 (en) * 2003-07-14 2006-04-04 E. I. Du Pont De Nemours And Company Dielectric substrates comprising a polymide core layer and a high temperature fluoropolymer bonding layer, and methods relating thereto
US7452399B2 (en) * 2003-10-10 2008-11-18 Whittington Albert A Coating for fertilizer
DE102005013957A1 (de) * 2005-03-26 2006-09-28 Clariant Produkte (Deutschland) Gmbh Phosphorhaltige thermostabilisierte Flammschutzmittelagglomerate
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Also Published As

Publication number Publication date
DE102009000175A1 (de) 2010-07-15
CN102272573A (zh) 2011-12-07
WO2010081629A1 (fr) 2010-07-22
BRPI0923941A2 (pt) 2016-01-12
TW201107745A (en) 2011-03-01
US20110247392A1 (en) 2011-10-13

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