EP2337984B1 - Cuve a membrane ondulée renforcée - Google Patents

Cuve a membrane ondulée renforcée Download PDF

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Publication number
EP2337984B1
EP2337984B1 EP09784452.6A EP09784452A EP2337984B1 EP 2337984 B1 EP2337984 B1 EP 2337984B1 EP 09784452 A EP09784452 A EP 09784452A EP 2337984 B1 EP2337984 B1 EP 2337984B1
Authority
EP
European Patent Office
Prior art keywords
tank
reinforcing element
membrane
reinforcing
corrugation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP09784452.6A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2337984A1 (fr
Inventor
Mokrane Yataghene
Bruno DELETRÉ
Géry CANLER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gaztransport et Technigaz SA
Original Assignee
Gaztransport et Technigaz SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gaztransport et Technigaz SA filed Critical Gaztransport et Technigaz SA
Priority to EP12155836.5A priority Critical patent/EP2455650B1/fr
Priority to EP12154056.1A priority patent/EP2453159B1/fr
Publication of EP2337984A1 publication Critical patent/EP2337984A1/fr
Application granted granted Critical
Publication of EP2337984B1 publication Critical patent/EP2337984B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C3/00Vessels not under pressure
    • F17C3/02Vessels not under pressure with provision for thermal insulation
    • F17C3/025Bulk storage in barges or on ships
    • F17C3/027Wallpanels for so-called membrane tanks
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/01Shape
    • F17C2201/0147Shape complex
    • F17C2201/0157Polygonal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/05Size
    • F17C2201/052Size large (>1000 m3)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/01Reinforcing or suspension means
    • F17C2203/011Reinforcing means
    • F17C2203/012Reinforcing means on or in the wall, e.g. ribs
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2209/00Vessel construction, in particular methods of manufacturing
    • F17C2209/23Manufacturing of particular parts or at special locations
    • F17C2209/232Manufacturing of particular parts or at special locations of walls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/03Mixtures
    • F17C2221/032Hydrocarbons
    • F17C2221/033Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0146Two-phase
    • F17C2223/0153Liquefied gas, e.g. LPG, GPL
    • F17C2223/0161Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/03Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
    • F17C2223/033Small pressure, e.g. for liquefied gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00Purposes of gas storage and gas handling
    • F17C2260/01Improving mechanical properties or manufacturing
    • F17C2260/011Improving strength
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/01Applications for fluid transport or storage
    • F17C2270/0102Applications for fluid transport or storage on or in the water
    • F17C2270/0105Ships
    • F17C2270/0107Wall panels

Definitions

  • the present invention relates to a sealed tank.
  • the present invention relates to a sealed and thermally insulated tank for the transport of liquefied natural gas (LNG) by ship.
  • LNG liquefied natural gas
  • the document FR 2 781 557 describes a tank integrated in the structure of a ship, which allows the transport of LNG.
  • the walls of the tank successively comprise, from inside the tank to the outside, a primary watertight barrier, a primary thermally insulating barrier, a secondary watertight barrier and a secondary thermal insulating barrier.
  • the primary waterproof barrier is a membrane made of corrugated metal plates made of stainless steel. Specifically, each plate has a series of waves parallel to the axis of the ship and another series of waves perpendicular to the axis of the ship.
  • the waves provided on the metal plates of the membrane are intended to allow the membrane to deform to limit the stresses generated by the thermal shrinkage and the effect of the beam of the ship.
  • the document FR 2 861 060 proposes to provide reinforcing ribs on the waves.
  • a problem that the present invention proposes to solve is to provide a vessel that does not exhibit at least some of the aforementioned drawbacks of the prior art.
  • an object of the invention is to improve the pressure resistance of the membrane, in order to avoid or limit the plastic deformations.
  • the solution proposed by the invention is a sealed tank, at least one wall comprises a waterproof membrane and according to claim 1.
  • the membrane may comprise several plates, the plate may have several waves, and a reinforcing element may be arranged under one or more waves of one or more plates.
  • the support may be for example a thermally insulating layer, and more specifically a plywood panel with a thermally insulating layer.
  • the reinforcing element has an internal passage that allows gas to flow between the wave and the support through the reinforcing element.
  • an external passage allows gas to flow between the wave and the support bypassing the reinforcing element.
  • the reinforcing element is made of a material chosen from: plywood, polyethylene, polycarbonate, polycarbonate reinforced with glass fibers, polyether imide, and expanded polystyrene.
  • the reinforcing element comprises an outer envelope whose shape corresponds substantially to the shape of the wave.
  • the reinforcing element comprises at least one reinforcing web inside said envelope.
  • the minimum distance between the reinforcing element and the wave is between 0% and 5% of the height of the wave.
  • the plate has a first series of waves parallel to each other, and a second series of waves parallel to each other and transverse to the waves of the first series, the reinforcing element being inserted under a wave of the first series.
  • the reinforcing element can be inserted under several waves of the first series.
  • the reinforcing element is inserted under the wave slidably with respect to the membrane and the support.
  • the manufacture of the tank does not require a fixing step of the reinforcing element.
  • the reinforcing element is fixed to the membrane or to the support. This ensures that the reinforcing element remains positioned at the desired location.
  • the membrane has an undercut, the reinforcing element being clipped to, or wedged in, the undercut.
  • At least two reinforcing elements are respectively arranged under two adjacent waves of the membrane, one of said two reinforcing elements forming a stop for the other of said two reinforcing elements.
  • a reinforcing element is made prisoner by the other and is thus held in place.
  • the reinforcing element has at least one weak point able to deform or break if it is subjected to a stress greater than a determined threshold.
  • the membrane is in contact with the support.
  • the invention also provides a floating structure comprising a tank according to the invention above. It can be a ship or other type of floating installation.
  • a tank according to one embodiment of the invention may have a multilayer structure similarly to the vessels of the documents FR 2 781 557 and FR 2 861 060 cited in the introduction.
  • the vessel has a primary waterproof membrane made of corrugated metal plates that rest on a plywood panel of a primary heat-insulating layer. Since the general aspects of this multilayer structure are known, the features of the tank according to one embodiment of the invention are described below.
  • the plate 1 shown on the figure 1 is a corrugated plate, made of stainless steel, of generally rectangular shape.
  • the primary waterproof membrane of the tank is made by welding several plates of this type side by side.
  • the plate 1 comprises three large waves 2 extending along the length of the plate 1, and nine small waves 3 extending along the width of the plate 1. We speak of large waves 2 and small waves 3 because the height long wave 2 is greater than that of small waves 3.
  • the plate 1 could have a different number of large waves 2 and / or small waves 3.
  • the waves of the plate 1 could have reinforcing ribs as described in FIG. FR 2 861 060 .
  • the waves of the plate 1 could also have other configurations, for example as in the documents FR 2,735,847 or KR-10-2005-0050170 .
  • the plate 1 rests on the plywood 4 of the underlying thermally insulating layer.
  • the plate 1 could be based on another type of support.
  • a reinforcing element 5 is arranged under the large wave 2, between the plate 1 and the plywood 4.
  • "sub” means that the reinforcing element 5 is covered by the wave, but does not necessarily mean that it is lower. Indeed, on the vertical walls of the tank, the reinforcing element 5 is at the horizontal of the wave which covers it.
  • the length of the reinforcing element 5 corresponds to the distance between two small waves 3.
  • reinforcing elements 5 can be arranged, each under a large wave 2 between two small waves 3.
  • the number and the distribution of the reinforcing elements 5 can be determined according to the distribution of the stresses provided in operation in the membrane of the tank .
  • the length of the reinforcing element 5 may be less than the distance between two small waves 3 or, if the geometry of the crossover between waves allows, greater than this distance.
  • reinforcing elements 5 may be provided under the small waves 3.
  • the reinforcing element 5 is put in place as shown on the figure 2 without being fixed to the plate 1 or the plywood 4. It can therefore possibly slide under the large wave 2. The manufacture of the tank therefore does not require a fixing step of the reinforcing elements 5.
  • the reinforcing member 5 may be attached to the membrane or plywood 4.
  • FIGS. 3 to 11 represent different shapes that may be suitable.
  • the views of Figures 3 to 9 are perspective views of a slice of the reinforcing element 5, the length of which may be greater than that shown.
  • the views of Figures 10 and 11 are sectional views. In these different figures, the same reference signs are used to designate similar elements.
  • the reinforcing element 5 of the figure 3 has a full section. Its two lateral faces 6 are curved and of shape corresponding to that of the wave 2. However, the lateral faces 6 do not extend to the top of the wave 2 and the reinforcing element 5 has an upper face 7 flat. Gas can flow between the top of the wave 2 and the upper face 7.
  • the reinforcing element 5 of the figure 4 has an envelope whose outer shape corresponds to the shape of the wave 2.
  • a circular passage 9 allows the gas to pass through the reinforcing element 5.
  • the passage 9 has a shape corresponding to the outer shape of the envelope, to provide a larger passage area.
  • the reinforcing element 5 of the figure 6 also has an envelope whose outer shape corresponds to the shape of the wave 2 and a passage 9.
  • internal webs 10 pass through the passage 9.
  • the Figures 7 to 9 represent alternative configurations of the sails 10.
  • the reinforcement elements Figures 3 to 9 can be made for example of one of the following materials: polyethylene, polycarbonate, glass fiber reinforced polycarbonate, polyether imide, and expanded polystyrene. They can be manufactured by any appropriate technique (injection, molding, extrusion, machining, .
  • the reinforcing elements 5 of the Figures 10 and 11 have a full section. Their side faces 6 each have two flat strips. As for the reinforcing element of the figure 3 gas can pass between the upper face 7 and the top of the wave.
  • the reinforcing elements 5 of the Figures 10 and 11 can for example be made of plywood, by machining.
  • the reinforcing element 5 of the figure 11 has a tongue 22 fixed to its lower face 23.
  • the tongue 23 allows to fix the reinforcing element 5 to the plywood 4, for example at the junction between two plywood plates.
  • the figure 12 shows, on the left-hand side, the geometry of the waves at the level of a cross between a large wave 2 and a small wave 3. It can be seen that the membrane presents at this level an undercut 20.
  • the right part of the figure 12 shows that the reinforcing element 5 arranged under a large wave 2 has, at its end, tabs 21 which allow fixing the reinforcing element 5 to the membrane, by clipping at the undercut 20. Alternatively, the tabs 21 could be stuck.
  • the figure 13 represents in perspective a reinforcing element 5 which is intended to be arranged simultaneously under several large waves 2 and small waves 3. Its shape corresponds to those of the waves, including at crossings. Internal passages 9 are provided both in the parts situated under the small waves 3 and under the long waves 2.
  • the figure 14 represents two reinforcing elements 5, one being intended to be arranged under a large wave 2 and the other under a small wave 3, crossing at the crossing of the waves.
  • the reinforcing elements 5 each have a notch 24 for positioning them relative to each other.
  • the reinforcing elements 5 have a rectangular section.
  • reinforcing element 5 allows the waves to deform in the event of thermal contraction, and offer support to the waves in case of deformation due to hydrostatic and dynamic pressures. To achieve this goal, it can be expected that, when the tank is empty (so in the absence of thermal loading and hydrostatic or dynamic pressure), the minimum distance between the reinforcing element 5 and the wave under which it is between 0% and 5% of the height of the wave.
  • reinforcement element 5 each have particular properties: cost and ease of manufacture, mechanical strength, quantity of material, etc. Depending on the applications, the most appropriate form may be chosen.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Ocean & Marine Engineering (AREA)
EP09784452.6A 2008-10-08 2009-06-30 Cuve a membrane ondulée renforcée Active EP2337984B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP12155836.5A EP2455650B1 (fr) 2008-10-08 2009-06-30 Cuve à membrane ondulée renforcée
EP12154056.1A EP2453159B1 (fr) 2008-10-08 2009-06-30 Cuve a membrane ondulée renforcée

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0805567A FR2936784B1 (fr) 2008-10-08 2008-10-08 Cuve a membrane ondulee renforcee
PCT/FR2009/051267 WO2010040922A1 (fr) 2008-10-08 2009-06-30 Cuve a membrane ondulée renforcée

Related Child Applications (4)

Application Number Title Priority Date Filing Date
EP12154056.1A Division EP2453159B1 (fr) 2008-10-08 2009-06-30 Cuve a membrane ondulée renforcée
EP12154056.1A Division-Into EP2453159B1 (fr) 2008-10-08 2009-06-30 Cuve a membrane ondulée renforcée
EP12155836.5A Division-Into EP2455650B1 (fr) 2008-10-08 2009-06-30 Cuve à membrane ondulée renforcée
EP12155836.5A Division EP2455650B1 (fr) 2008-10-08 2009-06-30 Cuve à membrane ondulée renforcée

Publications (2)

Publication Number Publication Date
EP2337984A1 EP2337984A1 (fr) 2011-06-29
EP2337984B1 true EP2337984B1 (fr) 2019-11-27

Family

ID=40586195

Family Applications (3)

Application Number Title Priority Date Filing Date
EP09784452.6A Active EP2337984B1 (fr) 2008-10-08 2009-06-30 Cuve a membrane ondulée renforcée
EP12154056.1A Active EP2453159B1 (fr) 2008-10-08 2009-06-30 Cuve a membrane ondulée renforcée
EP12155836.5A Active EP2455650B1 (fr) 2008-10-08 2009-06-30 Cuve à membrane ondulée renforcée

Family Applications After (2)

Application Number Title Priority Date Filing Date
EP12154056.1A Active EP2453159B1 (fr) 2008-10-08 2009-06-30 Cuve a membrane ondulée renforcée
EP12155836.5A Active EP2455650B1 (fr) 2008-10-08 2009-06-30 Cuve à membrane ondulée renforcée

Country Status (12)

Country Link
EP (3) EP2337984B1 (enrdf_load_stackoverflow)
JP (3) JP5379234B2 (enrdf_load_stackoverflow)
KR (7) KR20140042936A (enrdf_load_stackoverflow)
CN (3) CN102588732B (enrdf_load_stackoverflow)
AU (1) AU2009301016B2 (enrdf_load_stackoverflow)
BR (1) BRPI0920667B1 (enrdf_load_stackoverflow)
ES (2) ES2767975T3 (enrdf_load_stackoverflow)
FR (1) FR2936784B1 (enrdf_load_stackoverflow)
MX (1) MX2011003688A (enrdf_load_stackoverflow)
MY (2) MY174853A (enrdf_load_stackoverflow)
RU (3) RU2535293C2 (enrdf_load_stackoverflow)
WO (1) WO2010040922A1 (enrdf_load_stackoverflow)

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FR2936784B1 (fr) * 2008-10-08 2010-10-08 Gaztransp Et Technigaz Cuve a membrane ondulee renforcee
FR2963818B1 (fr) * 2010-08-11 2014-01-03 Gaztransp Et Technigaz Structure de paroi etanche
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KR101349881B1 (ko) * 2012-06-13 2014-01-16 삼성중공업 주식회사 액화천연가스 저장탱크의 1차 방벽용 보강 부재 고정 장치
FR2998256B1 (fr) 2012-11-16 2019-12-20 Gaztransport Et Technigaz Procede de fabrication d'une paroi de cuve etanche et thermiquement isolee
FR3009745B1 (fr) * 2013-08-15 2016-01-29 Gaztransp Et Technigaz Cuve etanche et thermiquement isolante comportant une piece d'angle
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FR3074253B1 (fr) * 2017-11-27 2019-11-01 Gaztransport Et Technigaz Cuve etanche et thermiquement isolante
FR3077278B1 (fr) 2018-02-01 2020-02-07 Gaztransport Et Technigaz Paroi etanche a membrane ondulee renforcee
FR3083789B1 (fr) 2018-07-13 2020-07-10 Gaztransport Et Technigaz Paroi de cuve comportant une membrane d'etancheite presentant une ondulation ayant une portion curviligne renforcee
FR3084438B1 (fr) 2018-07-26 2020-07-31 Gaztransport Et Technigaz Cuve etanche et thermiquement isolante
FR3084346B1 (fr) * 2018-07-27 2020-12-25 Gaztransport Et Technigaz Paroi etanche a membrane ondulee renforcee
FR3087871B1 (fr) 2018-10-31 2022-09-09 Gaztransport Et Technigaz Securisation de pieces de liaison au bord d’une plaque constitutive d’une cuve etanche a membranes ondules
FR3094338B1 (fr) * 2019-03-26 2021-09-10 Gaztransport Et Technigaz Dispositif de maintien de renforts d’ondes lors de l’installation d’une paroi de cuve.
CN112124523B (zh) * 2020-04-21 2022-10-14 沪东中华造船(集团)有限公司 一种用于Mark3型液货舱薄膜加强楔的安装方法
CN112145954B (zh) * 2020-09-21 2022-04-26 浙江振申绝热科技股份有限公司 一种膜式低温储罐的金属内罐的罐底结构
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JP5778606B2 (ja) 2015-09-16
MY154077A (en) 2015-04-30
CN102588732B (zh) 2014-12-10
RU2535293C2 (ru) 2014-12-10
JP2012111558A (ja) 2012-06-14
KR101645155B1 (ko) 2016-08-03
AU2009301016B2 (en) 2016-01-14
RU2505737C2 (ru) 2014-01-27
EP2453159A2 (fr) 2012-05-16
EP2455650A3 (fr) 2012-12-12
BRPI0920667A2 (pt) 2016-01-12
JP5379258B2 (ja) 2013-12-25
EP2453159A3 (fr) 2012-12-12
JP2012144298A (ja) 2012-08-02
CN102588733A (zh) 2012-07-18
EP2455650A2 (fr) 2012-05-23
JP5379234B2 (ja) 2013-12-25
MX2011003688A (es) 2011-05-02
KR102594126B1 (ko) 2023-10-24
AU2009301016A1 (en) 2010-04-15
KR20110070998A (ko) 2011-06-27
CN102588732A (zh) 2012-07-18
RU2012107912A (ru) 2013-09-10
KR20220003163A (ko) 2022-01-07
BRPI0920667B1 (pt) 2020-05-12
JP2012505125A (ja) 2012-03-01
KR20160027222A (ko) 2016-03-09
CN102588733B (zh) 2014-12-10
ES2821391T3 (es) 2021-04-26
KR20120031312A (ko) 2012-04-02
FR2936784A1 (fr) 2010-04-09
RU2012105125A (ru) 2013-08-20
MY174853A (en) 2020-05-19
EP2453159B1 (fr) 2020-07-29
EP2455650B1 (fr) 2019-10-30
KR20170115105A (ko) 2017-10-16
CN102177389A (zh) 2011-09-07
RU2011116959A (ru) 2012-11-10
RU2533271C2 (ru) 2014-11-20
KR20140042936A (ko) 2014-04-07
ES2767975T3 (es) 2020-06-19
WO2010040922A1 (fr) 2010-04-15
FR2936784B1 (fr) 2010-10-08
EP2337984A1 (fr) 2011-06-29

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