EP2272993A1 - Procédé de fabrication d'une pièce forgée à partir d'un alliage gamma à base titane-aluminium - Google Patents

Procédé de fabrication d'une pièce forgée à partir d'un alliage gamma à base titane-aluminium Download PDF

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Publication number
EP2272993A1
EP2272993A1 EP10450090A EP10450090A EP2272993A1 EP 2272993 A1 EP2272993 A1 EP 2272993A1 EP 10450090 A EP10450090 A EP 10450090A EP 10450090 A EP10450090 A EP 10450090A EP 2272993 A1 EP2272993 A1 EP 2272993A1
Authority
EP
European Patent Office
Prior art keywords
temperature
forging
titanium
die
intermediate product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP10450090A
Other languages
German (de)
English (en)
Other versions
EP2272993B1 (fr
Inventor
Sascha Kremmer
Heinz Romen-Kierner
Wilfried Wallgram
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Voestalpine Boehler Aerospace GmbH and Co KG
Original Assignee
Voestalpine Boehler Aerospace GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Voestalpine Boehler Aerospace GmbH and Co KG filed Critical Voestalpine Boehler Aerospace GmbH and Co KG
Priority to PL10450090T priority Critical patent/PL2272993T3/pl
Publication of EP2272993A1 publication Critical patent/EP2272993A1/fr
Application granted granted Critical
Publication of EP2272993B1 publication Critical patent/EP2272993B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C14/00—Alloys based on titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21J—FORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
    • B21J5/00—Methods for forging, hammering, or pressing; Special equipment or accessories therefor
    • B21J5/06—Methods for forging, hammering, or pressing; Special equipment or accessories therefor for performing particular operations
    • B21J5/08—Upsetting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21J—FORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
    • B21J9/00—Forging presses
    • B21J9/02—Special design or construction
    • B21J9/06—Swaging presses; Upsetting presses
    • B21J9/08—Swaging presses; Upsetting presses equipped with devices for heating the work-piece
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21K—MAKING FORGED OR PRESSED METAL PRODUCTS, e.g. HORSE-SHOES, RIVETS, BOLTS OR WHEELS
    • B21K3/00—Making engine or like machine parts not covered by sub-groups of B21K1/00; Making propellers or the like
    • B21K3/04—Making engine or like machine parts not covered by sub-groups of B21K1/00; Making propellers or the like blades, e.g. for turbines; Upsetting of blade roots
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/16—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
    • C22F1/18—High-melting or refractory metals or alloys based thereon
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05B—INDEXING SCHEME RELATING TO WIND, SPRING, WEIGHT, INERTIA OR LIKE MOTORS, TO MACHINES OR ENGINES FOR LIQUIDS COVERED BY SUBCLASSES F03B, F03D AND F03G
    • F05B2230/00—Manufacture
    • F05B2230/20—Manufacture essentially without removing material
    • F05B2230/25—Manufacture essentially without removing material by forging

Definitions

  • the invention relates to a method for producing a forging of a gamma titanium-aluminum base alloy.
  • Titanium-aluminum base alloys are essentially formed of intermetallic titanium aluminides and have a high melting point, low density, a high specific modulus of elasticity, good oxidation behavior and high specific tensile strength and creep resistance in the temperature range of 600 ° C to 800 ° C, So meet the ever-increasing demands on special materials such as for next-generation components of aircraft engines and internal combustion engines.
  • Titanium aluminide materials are not yet optimized with regard to their alloy composition and their production and processing.
  • An alloy that has good processability as well as balanced mechanical properties that can be created by suitable heat treatments includes the elements titanium, aluminum, niobium, molybdenum and boron and is therefore referred to in the art as TNM alloy.
  • the object of the invention is to improve the difficult and expensive processing of titanium aluminide materials and has the task of a method to create the type mentioned for economic production.
  • This object is achieved in a method in which a cylindrical or rod-shaped starting or starting material in one or more steps at those locations at which the forging to be formed volume concentrations, by electrical current passage or by induction across the cross-section to a temperature of 1150 higher ° C heated and deformed by application of force, in particular upsetting deformed and such a forging blank is created with different cross-sectional areas over its longitudinal extent, which blank is finally deformed in one or more subsequent steps each after heating to forming temperature, in particular in a die.
  • the alloy consists mainly of gamma-titanium-aluminum and alpha 2-titanium-aluminum and has only an optionally small proportion of beta-phase, which phase has ductile properties depending on the temperature.
  • beta-phase increases in the material, which justifies an improvement in the ductility of the material.
  • a forging blank produced according to the invention can now be finally deformed after warming up, for example in a forging furnace, in one or more subsequent step (s), in particular in a die, whereby advantageously a die filling is achieved with a lower material flow and / or material usage due to the volume concentrations can be done.
  • a method in which or the sequential step (e) of final deformation of the forging blank or of the intermediate product from at least partial coating of the surface with a means which reduces the heat radiation and thereby the surface temperature drop reducing means, a heating of the forging blank or intermediate product to forming temperature, a heat soak, a transfer and a forming thereof is formed in particular in a die (be), advantageously feasible.
  • the oxide phase acts as a heat-resistant insulating component, with one or more additives or adhesives having lower proportions Oxide grains bind (connect) and hold on the substrate (hold).
  • the liquid component (s) serve to homogenize the phases and to adjust a desired level of liquid for homogeneous application to the surface of the workpiece or part.
  • a method which can be carried out without error is advantageous, in which the final deformation takes place in a die which has a temperature which is at least 300 ° C. lower than the forging blank or the intermediate product.
  • a method according to the invention in which the final deformation takes place in a die having up to 900 ° C, preferably up to 800 ° C, lower temperature than the forging blank or the intermediate intensifies the above advantages, because such a low mold temperature Use of common hot working steels for thermally tempered dies allows without fear of a risk of hard waste of the same in operation.
  • the method for a production of turbine blades eg. made of a TNM alloy, usable.
  • a power source (not shown) is connected to a terminal 2 and a slightly concave shaped flat caliper 3.
  • a rod 1 is pressed in a press on the flat saddle 3, wherein between the flat saddle 3 and the terminal 2 electric current flows, which heats the rod in this area by the ohmic resistance.
  • a heating of a rod or rod part can also be done by means of an induction coil and alternating current.
  • titanium-aluminum base alloys have particularly good compression properties and are not prone to buckling. Furthermore, a rapid, targeted heating of a rod area is possible by a heat technology with electrical current passage or by induction, with a precise adjustment of the forming temperature in the so-called deformability window of the alloy can be achieved.
  • FIG. 3 and FIG. 4 show a puncture of one end of a rod 1 in a mold 3 to form a desired shaped end portion 11th
  • Blanks, as in FIG. 3 and FIG. 4 As shown schematically, for a turbine blade forging, a rod having a diameter of 30 mm ⁇ and a length of 225 mm was made of an alloy Ti-43.5Al- (Nb-Mo-B) 5 atom%. The production length was 192mm with a head diameter of 45mm and a head length of 63mm.
  • the heating and compression time was 60 sec., With a heating current of 7740 A and a forming temperature of 1250 ° C had been set.
  • Fig. 5 shows in a form compressed blanks.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Forging (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
EP10450090.5A 2009-06-05 2010-05-19 Procédé de fabrication d'une pièce forgée à partir d'un alliage gamma à base titane-aluminium Not-in-force EP2272993B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL10450090T PL2272993T3 (pl) 2009-06-05 2010-05-19 Sposób wytwarzania odkuwki ze stopu podstawowego gamma-tytan-aluminium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ATA879/2009A AT508323B1 (de) 2009-06-05 2009-06-05 Verfahren zur herstellung eines schmiedestückes aus einer gamma-titan-aluminium-basislegierung

Publications (2)

Publication Number Publication Date
EP2272993A1 true EP2272993A1 (fr) 2011-01-12
EP2272993B1 EP2272993B1 (fr) 2013-09-18

Family

ID=42711831

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10450090.5A Not-in-force EP2272993B1 (fr) 2009-06-05 2010-05-19 Procédé de fabrication d'une pièce forgée à partir d'un alliage gamma à base titane-aluminium

Country Status (8)

Country Link
US (1) US8828160B2 (fr)
EP (1) EP2272993B1 (fr)
JP (1) JP5669451B2 (fr)
AT (1) AT508323B1 (fr)
CA (1) CA2706289C (fr)
ES (1) ES2434016T3 (fr)
IL (1) IL206181A (fr)
PL (1) PL2272993T3 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2386663A1 (fr) * 2010-05-12 2011-11-16 Böhler Schmiedetechnik GmbH & Co KG Procédé de fabrication d'un composant et composants constitués d'un alliage à base d'aluminium-titane
WO2013110260A1 (fr) * 2012-01-25 2013-08-01 Mtu Aero Engines Gmbh Procédé de fabrication de pièces forgées dans un alliage tial et pièce forgée fabriquée par ce procédé
CN103586392A (zh) * 2013-11-15 2014-02-19 西安航空动力股份有限公司 大型钛合金风扇阻尼台叶片毛坯的制造方法
EP3067435B1 (fr) 2015-03-09 2017-07-26 LEISTRITZ Turbinentechnik GmbH Procede de production d'un composant tres resistant en alliage d'aluminure de titane alpha+gamma pour machines a piston et turbines a gaz, en particulier groupes motopropulseurs
EP3427858A1 (fr) * 2017-07-14 2019-01-16 MTU Aero Engines GmbH Forgeage à haute température, en particulier des aluminures de titane
CN109454403A (zh) * 2017-09-06 2019-03-12 丹阳蓝思信息技术有限公司 一种钛合金棒材及其制备方法
CN111085644A (zh) * 2020-01-20 2020-05-01 南京中远海运船舶设备配件有限公司 一种改善大规格电镦端面凹陷及促进晶粒匀细化的方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6369753B2 (ja) * 2013-10-01 2018-08-08 日立金属株式会社 熱間鍛造方法
CN104308068A (zh) * 2014-08-29 2015-01-28 孙金福 一种十字形锻件
DE102015115683A1 (de) * 2015-09-17 2017-03-23 LEISTRITZ Turbinentechnik GmbH Verfahren zur Herstellung einer Vorform aus einer Alpha+Gamma-Titanaluminid-Legierung zur Herstellung eines hochbelastbaren Bauteils für Kolbenmaschinen und Gasturbinen, insbesondere Flugtriebwerke
CN116967724B (zh) * 2023-09-25 2023-12-05 陕西长羽航空装备股份有限公司 一种航空飞机零部件制造用大直径高筒薄壁锻件成形方法

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1849185A (en) * 1927-10-10 1932-03-15 Holding Des Brevets Et Procede Method of and apparatus for shaping metallic stock
FR1086289A (fr) * 1952-06-27 1955-02-10 Massey Harris Co Ltd Procédé et appareil pour obtenir à l'aide de faibles pressions de fortes déformations de pièces mécaniques telles que des arbres de machines
GB901251A (en) * 1959-07-08 1962-07-18 Daniel Alfred Cavanagh Improvements in precision forging methods and apparatus
US5054301A (en) * 1990-03-26 1991-10-08 Honda Giken Kogyo Kabushiki Kaisha Method of forming metallic product
DE4416471A1 (de) * 1994-05-10 1995-11-23 Langenstein & Schemann Gmbh Elektrostauchmaschine mit Gesenkbuchse
EP0781612A1 (fr) * 1994-07-18 1997-07-02 Fuji Oozx Inc. Electrode pour appareil de refoulement électrique
JPH09327746A (ja) * 1996-06-12 1997-12-22 Fuji Oozx Inc 電気鍛縮機用電極装置
EP1127953A2 (fr) * 2000-02-23 2001-08-29 Fuji Oozx Inc. Procédé de fabrication d'une soupape à champignon en alliage de titane
DE102005022506A1 (de) * 2005-05-11 2006-11-16 Universität Stuttgart Verfahren zum Schmieden eines Bauteils aus einer Titanlegierung

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6123548A (ja) * 1984-07-11 1986-02-01 Goto Tanko Kk フランジ付車軸の鍛造法
US5076858A (en) * 1989-05-22 1991-12-31 General Electric Company Method of processing titanium aluminum alloys modified by chromium and niobium
US5304344A (en) * 1989-06-02 1994-04-19 General Electric Company Gamma titanium aluminum alloys modified by chromium and tungsten and method of preparation
JP2728305B2 (ja) * 1989-12-25 1998-03-18 新日本製鐵株式会社 金属間化合物ＴｉＡ▲ｌ▼基合金の熱間加工法
DE59103639D1 (de) * 1990-07-04 1995-01-12 Asea Brown Boveri Verfahren zur Herstellung eines Werkstücks aus einer dotierstoffhaltigen Legierung auf der Basis Titanaluminid.
DE59106047D1 (de) * 1991-05-13 1995-08-24 Asea Brown Boveri Verfahren zur Herstellung einer Turbinenschaufel.
JPH10156473A (ja) * 1996-11-25 1998-06-16 Nippon Steel Corp ＴｉＡｌ基金属間化合物の熱間加工法
JP4287991B2 (ja) * 2000-02-23 2009-07-01 三菱重工業株式会社 ＴｉＡｌ基合金及びその製造方法並びにそれを用いた動翼
JP4209092B2 (ja) * 2001-05-28 2009-01-14 三菱重工業株式会社 ＴｉＡｌ基合金及びその製造方法並びにそれを用いた動翼
JP2008132527A (ja) * 2006-11-29 2008-06-12 Honda Motor Co Ltd アプセット成形装置

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1849185A (en) * 1927-10-10 1932-03-15 Holding Des Brevets Et Procede Method of and apparatus for shaping metallic stock
FR1086289A (fr) * 1952-06-27 1955-02-10 Massey Harris Co Ltd Procédé et appareil pour obtenir à l'aide de faibles pressions de fortes déformations de pièces mécaniques telles que des arbres de machines
GB901251A (en) * 1959-07-08 1962-07-18 Daniel Alfred Cavanagh Improvements in precision forging methods and apparatus
US5054301A (en) * 1990-03-26 1991-10-08 Honda Giken Kogyo Kabushiki Kaisha Method of forming metallic product
DE4416471A1 (de) * 1994-05-10 1995-11-23 Langenstein & Schemann Gmbh Elektrostauchmaschine mit Gesenkbuchse
EP0781612A1 (fr) * 1994-07-18 1997-07-02 Fuji Oozx Inc. Electrode pour appareil de refoulement électrique
JPH09327746A (ja) * 1996-06-12 1997-12-22 Fuji Oozx Inc 電気鍛縮機用電極装置
EP1127953A2 (fr) * 2000-02-23 2001-08-29 Fuji Oozx Inc. Procédé de fabrication d'une soupape à champignon en alliage de titane
DE102005022506A1 (de) * 2005-05-11 2006-11-16 Universität Stuttgart Verfahren zum Schmieden eines Bauteils aus einer Titanlegierung

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
HABEL U ET AL: "PROCESSING, MICROSTRUCTURE AND TENSILE PROPERTIES OF .GAMMA.-TIAL PM ALLOY 395MM", GAMMA, TITANIUM, ALUMINIDES, PROCEEDINGS OF A SYMPOSIUM; 20030000, 2003, pages 297 - 304, XP008068139 *
ZHANG, JIULAI ET AL: "Forging of .beta.-phase containing . gamma .- TiAl alloys", STRUCTURAL ALUMINIDES FOR ELEVATED TEMPERATURES: GAMMA TITANIUM AND OTHER METALLIC ALUMINIDES, PROCEEDINGS OF [A] SYMPOSIUM HELD DURING [THE] TMS ANNUAL MEETING & EXHIBITION, NEW ORLEANS, LA, UNITED STATES, MAR. 9-13, 2008 , 265-272. EDITOR(S): KIM,, 2008, XP009138755 *
ZHANG, X. D. ET AL: "Hot work processing, microstructure and mechanical properties of two-phase . gamma . titanium aluminides", MATERIALS SCIENCE & ENGINEERING, A: STRUCTURAL MATERIALS: PROPERTIES, MICROSTRUCTURE AND PROCESSING , A185(1-2), 17-24 CODEN: MSAPE3; ISSN: 0921-5093, 1994, XP024348822 *

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2386663A1 (fr) * 2010-05-12 2011-11-16 Böhler Schmiedetechnik GmbH & Co KG Procédé de fabrication d'un composant et composants constitués d'un alliage à base d'aluminium-titane
US8864918B2 (en) 2010-05-12 2014-10-21 Boehler Schmiedetechnik Gmbh & Co. Kg Method for producing a component and components of a titanium-aluminum base alloy
WO2013110260A1 (fr) * 2012-01-25 2013-08-01 Mtu Aero Engines Gmbh Procédé de fabrication de pièces forgées dans un alliage tial et pièce forgée fabriquée par ce procédé
US10107112B2 (en) 2012-01-25 2018-10-23 MTU Aero Engines AG Method for producing forged components from a TiAl alloy and component produced thereby
CN103586392A (zh) * 2013-11-15 2014-02-19 西安航空动力股份有限公司 大型钛合金风扇阻尼台叶片毛坯的制造方法
CN103586392B (zh) * 2013-11-15 2015-05-27 西安航空动力股份有限公司 大型钛合金风扇阻尼台叶片毛坯的制造方法
EP3067435B1 (fr) 2015-03-09 2017-07-26 LEISTRITZ Turbinentechnik GmbH Procede de production d'un composant tres resistant en alliage d'aluminure de titane alpha+gamma pour machines a piston et turbines a gaz, en particulier groupes motopropulseurs
EP3067435B2 (fr) † 2015-03-09 2021-11-24 LEISTRITZ Turbinentechnik GmbH Procede de production d'un composant tres resistant en alliage d'aluminure de titane alpha+gamma pour machines a piston et turbines a gaz, en particulier groupes motopropulseurs
EP3427858A1 (fr) * 2017-07-14 2019-01-16 MTU Aero Engines GmbH Forgeage à haute température, en particulier des aluminures de titane
DE102017212082A1 (de) 2017-07-14 2019-01-17 MTU Aero Engines AG Schmieden bei hohen temperaturen, insbesondere von titanaluminiden
CN109454403A (zh) * 2017-09-06 2019-03-12 丹阳蓝思信息技术有限公司 一种钛合金棒材及其制备方法
CN111085644A (zh) * 2020-01-20 2020-05-01 南京中远海运船舶设备配件有限公司 一种改善大规格电镦端面凹陷及促进晶粒匀细化的方法

Also Published As

Publication number Publication date
US8828160B2 (en) 2014-09-09
AT508323A1 (de) 2010-12-15
IL206181A0 (en) 2010-12-30
JP2010280002A (ja) 2010-12-16
EP2272993B1 (fr) 2013-09-18
PL2272993T3 (pl) 2014-02-28
CA2706289A1 (fr) 2010-12-05
AT508323B1 (de) 2012-04-15
ES2434016T3 (es) 2013-12-13
JP5669451B2 (ja) 2015-02-12
IL206181A (en) 2016-02-29
CA2706289C (fr) 2014-02-04
US20100329877A1 (en) 2010-12-30

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