EP2258451B1 - Thermisches Auslöseelement für Sprinkler, Ventile oder dergleichen - Google Patents
Thermisches Auslöseelement für Sprinkler, Ventile oder dergleichen Download PDFInfo
- Publication number
- EP2258451B1 EP2258451B1 EP10155380.8A EP10155380A EP2258451B1 EP 2258451 B1 EP2258451 B1 EP 2258451B1 EP 10155380 A EP10155380 A EP 10155380A EP 2258451 B1 EP2258451 B1 EP 2258451B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- release element
- thermal release
- releasing liquid
- triggering
- valves
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000007788 liquid Substances 0.000 claims description 31
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 150000002430 hydrocarbons Chemical class 0.000 claims description 13
- -1 aliphatic ester compound Chemical class 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 11
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 239000002775 capsule Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000002360 explosive Substances 0.000 description 21
- 239000011521 glass Substances 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000000975 dye Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000009172 bursting Effects 0.000 description 2
- 150000002367 halogens Chemical group 0.000 description 2
- 239000000383 hazardous chemical Substances 0.000 description 2
- 238000003908 quality control method Methods 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 2
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- CNJBWKOJASUYMS-UHFFFAOYSA-N 1-nitroethane nitromethane 1-nitropropane Chemical compound C[N+]([O-])=O.CC[N+]([O-])=O.CCC[N+]([O-])=O CNJBWKOJASUYMS-UHFFFAOYSA-N 0.000 description 1
- 240000003517 Elaeocarpus dentatus Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000008431 aliphatic amides Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- FJBFPHVGVWTDIP-UHFFFAOYSA-N dibromomethane Chemical class BrCBr FJBFPHVGVWTDIP-UHFFFAOYSA-N 0.000 description 1
- BBACEXPVAOVQET-UHFFFAOYSA-N ethyl 3-oxobutanoate methyl 3-oxobutanoate Chemical compound C(CC(=O)C)(=O)OCC.COC(CC(=O)C)=O BBACEXPVAOVQET-UHFFFAOYSA-N 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C37/00—Control of fire-fighting equipment
- A62C37/08—Control of fire-fighting equipment comprising an outlet device containing a sensor, or itself being the sensor, i.e. self-contained sprinklers
- A62C37/10—Releasing means, e.g. electrically released
- A62C37/11—Releasing means, e.g. electrically released heat-sensitive
- A62C37/14—Releasing means, e.g. electrically released heat-sensitive with frangible vessels
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/1624—Destructible or deformable element controlled
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/1624—Destructible or deformable element controlled
- Y10T137/1797—Heat destructible or fusible
Definitions
- the invention relates to a thermal triggering element for sprinklers, valves or the like in the form of a filled in a completely enclosed interior with an explosive vessel.
- Such glass kegs as a thermal tripping element are for example in the DE 36 01 203 A1 described.
- Such triggering elements are filled with an explosive liquid, which expands when heated and leads to bursting of the typically clamped in a valve seat, the valve in the closed position holding vessel, so that a triggering of the valve or the like.
- the explosive liquid on the one hand permit a highly temperature-sensitive and temperature-sensitive release of the triggering element equipped therewith and on the other hand bring with respect to the prior art reduced health hazards and environmental hazards and so make the processing less dangerous.
- the groups include aliphatic bromides, hydrocarbons having a nitro group, monohalogenated benzene rings and aliphatic ester compounds each having two doubly bonded oxygen atoms.
- aliphatic bromides may be those which are double-halogenated.
- Aliphatic bromides improve the sensitivity of otherwise identical thermal tripping elements compared to today's usual explosive liquids by about 15%.
- the standard deviation of the operating temperature field is also improved by 15% compared to conventional explosive liquids.
- Nitro compounds have a high voltage coefficient and a high thermal conductivity due to their NO 2 structure. In addition, they have a low dynamic viscosity, whereby the small density and the higher heat capacity, which is otherwise disadvantageous in terms of the tripping time, can be compensated. Thus, even such substances lead to fast tripping times and also allow the choice of narrow temperature fields.
- Cyclic molecules which already have good properties as an explosive liquid anyway, have high voltage coefficients and a low heat capacity as benzene rings with at most one halogen, which again leads to fast triggering times and narrow temperature fields.
- aliphatic ester compounds with two doubly bound oxygen atoms in turn allow very narrow temperature fields and, although not to the same extent as the aforementioned substance groups, still have good release times. Due to the high boiling point, they are particularly suitable for use in high-temperature thermal tripping elements.
- the triggering properties of the thermal tripping elements can be determined in a controlled manner, that is, they can be designed.
- the explosive liquid may be added with advantage additives, in particular one or more dye (s). Since most of the selected triggering liquids are colorless transparent, the addition of a dye not only in the quality control facilitates, for example, recognizing a gas bubble deliberately left in the interior and estimating the size thereof, but by adding different dyes as in the prior art known and already used codes for different triggering temperatures are indexed.
- advantage additives in particular one or more dye (s). Since most of the selected triggering liquids are colorless transparent, the addition of a dye not only in the quality control facilitates, for example, recognizing a gas bubble deliberately left in the interior and estimating the size thereof, but by adding different dyes as in the prior art known and already used codes for different triggering temperatures are indexed.
- Fig. 1 in the schematically clamped between two bearing elements, a trigger element is shown, which is filled in accordance with the invention with a described and claimed explosive liquid.
- the triggering element shown is a glass keg 1, as it is known in principle from the prior art.
- the glass keg shown here essentially corresponds in its design to that in the DE 36 01 203 described form and expression.
- the glass keg encloses a hollow interior 2 completely and lies in its use as a trigger element with opposite ends 3 and 4 on bearing elements 5 and 6, is clamped between them.
- one of the bearing elements for example, the bearing element 5 is a valve plate of a sprinkler, the other layer element, such as the bearing element 6, a bearing bracket opposite this, as is often encountered in sprinkler systems.
- the glass keg 1 can also be integrated as a thermal triggering element in an emergency discharge valve of a gas container or in similar devices.
- the essential feature of the invention is now the explosive liquid introduced into the interior 2, which leads to bursting of the glass bottle 1 and thus triggering of the thermal release device when heated due to the thermal expansion.
- the triggering liquid is filled while leaving a defined gas bubble (usually air) filled in the interior, the gas bubbles catching the first thermal expansion of the triggering liquid, until in particular by a phase transition is an explosive expansion, which bursts the glass keg 1.
- the triggering liquid contains in the interior of the interior 2 at least one hydrocarbon, consisting of an aliphatic bromide, preferably a di-halogenated aliphatic bromide, a hydrocarbon having a nitro group, a monohalogenated benzene rings and an aliphatic ester compound with two double-bonded oxygen atoms or a mix of different Hydrocarbons from one or more of these groups.
- the explosive liquid can only contain these hydrocarbons, but in particular consists entirely of one or more of the hydrocarbons mentioned.
- additives can be added to the explosive liquid, in particular one or more dyes. Since most of the selected tripping liquids are colorless transparent, the addition of a dye not only facilitates recognition of the desired gas bubble in the quality control and estimation of its size, but by the addition of different dyes, the codes known in the art and already used for different trigger temperatures are indicated.
Landscapes
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Fire-Extinguishing By Fire Departments, And Fire-Extinguishing Equipment And Control Thereof (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200920007987 DE202009007987U1 (de) | 2009-06-05 | 2009-06-05 | Thermisches Auslöseelement für Sprinkler, Ventile o.dgl. |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2258451A1 EP2258451A1 (de) | 2010-12-08 |
EP2258451B1 true EP2258451B1 (de) | 2016-03-02 |
Family
ID=42635545
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10155380.8A Active EP2258451B1 (de) | 2009-06-05 | 2010-03-03 | Thermisches Auslöseelement für Sprinkler, Ventile oder dergleichen |
Country Status (4)
Country | Link |
---|---|
US (1) | US8402985B2 (zh) |
EP (1) | EP2258451B1 (zh) |
CN (1) | CN101905069B (zh) |
DE (1) | DE202009007987U1 (zh) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE202011050661U1 (de) | 2011-07-07 | 2011-09-09 | Job Lizenz Gmbh & Co. Kg | Thermisches Auslöseelement für Sprinkler, Ventile oder dergleichen |
US8800588B2 (en) * | 2011-12-13 | 2014-08-12 | GM Global Technology Operations LLC | Glass bulb thermally-activated pressure relief device, safety inspection method, and equipment |
DE202012100623U1 (de) * | 2012-02-24 | 2012-03-22 | Job Lizenz Gmbh & Co. Kg | Brandschutzeinrichtung für elektrische Kleingeräte |
US8910651B2 (en) * | 2013-03-13 | 2014-12-16 | GM Global Technology Operations LLC | Thermal pressure relief devices and related systems and methods |
US9573007B2 (en) | 2013-03-15 | 2017-02-21 | Tyco Fire Products Lp | Fire protection sprinkler |
SK7760Y1 (sk) * | 2016-05-31 | 2017-05-03 | Roman Malovec | Samohasiace automatické požiarne zariadenie a spôsob protipožiarnej ochrany |
EP4008411B1 (en) * | 2020-12-04 | 2024-02-28 | Marioff Corporation OY | Sprinkler bulb |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070207354A1 (en) * | 2004-10-05 | 2007-09-06 | Societe Bic | Fuel Cartridge with an Environmentally Sensitive Valve |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1905676A (en) * | 1930-04-15 | 1933-04-25 | Gen Fire Extinguisher Co | Automatic sprinkler or fire extinguisher and other fire device |
US2185422A (en) * | 1932-03-24 | 1940-01-02 | Patrol Valve Company | Thermostatic device |
NL6614205A (zh) * | 1966-10-08 | 1968-04-09 | ||
US3798092A (en) * | 1972-08-25 | 1974-03-19 | Commerical Solvents Corp | Low-temperature liquid explosive composition |
US4018164A (en) * | 1973-09-10 | 1977-04-19 | Breed Corporation | Projectile fuze containing a floating body |
DE3601203A1 (de) | 1985-09-09 | 1987-03-19 | Eduard J Dipl Ing Job | Glasfaesschen fuer sprinkler fuer feuerloeschanlagen oder andere thermische ausloeseeinrichtungen |
CH672745A5 (zh) | 1987-02-13 | 1989-12-29 | Johann Georg Mohler | |
GB2314770B (en) * | 1996-01-25 | 1999-10-27 | Norbulb Sprinkler Elemente Gmb | Sprinkler Actuator |
US5758355A (en) * | 1996-08-07 | 1998-05-26 | Aurum Software, Inc. | Synchronization of server database with client database using distribution tables |
GB9620598D0 (en) * | 1996-10-03 | 1996-11-20 | Grinnell Mfg Uk Ltd | Thermally responsive frangible bulb |
JP2009119240A (ja) * | 2008-05-02 | 2009-06-04 | Yamato Grand Kk | 消火性シート |
-
2009
- 2009-06-05 DE DE200920007987 patent/DE202009007987U1/de not_active Expired - Lifetime
-
2010
- 2010-03-03 EP EP10155380.8A patent/EP2258451B1/de active Active
- 2010-04-13 US US12/759,349 patent/US8402985B2/en active Active
- 2010-04-19 CN CN201010224033.6A patent/CN101905069B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070207354A1 (en) * | 2004-10-05 | 2007-09-06 | Societe Bic | Fuel Cartridge with an Environmentally Sensitive Valve |
Also Published As
Publication number | Publication date |
---|---|
US8402985B2 (en) | 2013-03-26 |
CN101905069A (zh) | 2010-12-08 |
US20100307605A1 (en) | 2010-12-09 |
EP2258451A1 (de) | 2010-12-08 |
DE202009007987U1 (de) | 2010-10-28 |
CN101905069B (zh) | 2014-03-12 |
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