EP2251443B1 - Poche de traitement - Google Patents

Poche de traitement Download PDF

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Publication number
EP2251443B1
EP2251443B1 EP09251258A EP09251258A EP2251443B1 EP 2251443 B1 EP2251443 B1 EP 2251443B1 EP 09251258 A EP09251258 A EP 09251258A EP 09251258 A EP09251258 A EP 09251258A EP 2251443 B1 EP2251443 B1 EP 2251443B1
Authority
EP
European Patent Office
Prior art keywords
ladle
interior space
pocket
accordance
continuous sidewall
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP09251258A
Other languages
German (de)
English (en)
Other versions
EP2251443A1 (fr
Inventor
Emmanuel Berthelet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foseco International Ltd
Original Assignee
Foseco International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to EP09251258A priority Critical patent/EP2251443B1/fr
Application filed by Foseco International Ltd filed Critical Foseco International Ltd
Priority to AT09251258T priority patent/ATE529539T1/de
Priority to PL09251258T priority patent/PL2251443T3/pl
Priority to DK09251258.1T priority patent/DK2251443T3/da
Priority to SI200930116T priority patent/SI2251443T1/sl
Priority to ES09251258T priority patent/ES2373268T3/es
Priority to RS20110538A priority patent/RS52039B/en
Priority to PT09251258T priority patent/PT2251443E/pt
Priority to BRPI1003637A priority patent/BRPI1003637A2/pt
Priority to JP2012509081A priority patent/JP5639154B2/ja
Priority to AU2010244265A priority patent/AU2010244265B2/en
Priority to CA2760249A priority patent/CA2760249C/fr
Priority to RU2011149480/02A priority patent/RU2530922C2/ru
Priority to CN201080002007.7A priority patent/CN102084010B/zh
Priority to MX2010014295A priority patent/MX2010014295A/es
Priority to UAA201114414A priority patent/UA104891C2/uk
Priority to PCT/GB2010/000824 priority patent/WO2010128273A1/fr
Priority to US12/737,335 priority patent/US20120152060A1/en
Priority to KR1020107029318A priority patent/KR101657126B1/ko
Publication of EP2251443A1 publication Critical patent/EP2251443A1/fr
Priority to ZA2011/06905A priority patent/ZA201106905B/en
Application granted granted Critical
Publication of EP2251443B1 publication Critical patent/EP2251443B1/fr
Priority to HR20110923T priority patent/HRP20110923T1/hr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00—Refining of pig-iron; Cast iron
    • C21C1/06—Constructional features of mixers for pig-iron
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C33/00—Making ferrous alloys
    • C22C33/08—Making cast-iron alloys
    • C22C33/10—Making cast-iron alloys including procedures for adding magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/04—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like tiltable
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00—Refining of pig-iron; Cast iron
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00—Refining of pig-iron; Cast iron
    • C21C1/10—Making spheroidal graphite cast-iron
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/0075—Treating in a ladle furnace, e.g. up-/reheating of molten steel within the ladle
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00—Charging; Discharging; Manipulation of charge
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00—Charging; Discharging; Manipulation of charge
    • F27D3/0025—Charging or loading melting furnaces with material in the solid state
    • F27D3/0026—Introducing additives into the melt

Definitions

  • the present invention relates to a ladle for treating molten metal with vaporisable additives, in particular, to a ladle for treating iron with magnesium (Mg) to form ductile iron.
  • Mg magnesium
  • Ductile iron also known as spheroidal graphite (s.g.) iron or nodular iron
  • s.g. spheroidal graphite
  • nodulariser or nodullser
  • the nodulariser promotes the precipitation of graphite in the form of discrete nodules.
  • the nodulariser will usually contain magnesium, as pure magnesium, or as an alloy, such as magnesium-ferrosilicon (MgFeSi alloy) or nickel-magnesium (NiMg alloy), which may contain rare earth metals.
  • magnesium is added to the liquid iron to give a residual magnesium content of about 0.04%, the iron is inoculated and cast. It is difficult to add magnesium to iron because magnesium boils at a relatively low temperature (1090°C) so there is violent agitation of the liquid iron and considerable loss of magnesium in vapour form.
  • One object of the present invention is the provision of a ladle for the treatment of metal with vaporisable additives.
  • Another object of the present invention is to provide a method for the treatment of molten metal with vaporisable additives.
  • a treatment ladle comprising a ladle shell containing a generally tubular refractory ladle liner, said ladle being pivotable between a horizontal position and a vertical position, said ladle liner having a first end and a second end with a continuous sidewall therebetween, an interior space being defined between said first and second ends and the continuous sidewall, said ladle liner additionally comprising a pocket for holding a treatment agent, said pocket being located adjacent the first end and in fluid communication with the interior space and located closer to the top than the bottom of the interior space when the ladle is in its horizontal position and closer to the bottom than the top of the interior space when the ladle is in its vertical position, and a spout for receiving and pouring molten metal located closer to the top than the bottom of the interior space when the ladle is in its horizontal and vertical positions, wherein in the horizontal position, a lower volume of the interior space defined below a plane midway between the top and bottom of the
  • the first end of the ladle liner constitutes the lower extent of the interior space.
  • a treatment agent will be placed in the pocket and the ladle will be filled with molten metal whilst it is in the horizontal position.
  • the ladle will be half filled such that the molten metal is filled to a height corresponding to the midway plane.
  • the ladle is then pivoted 90° to the vertical position such that the metal flows into the pocket containing the treatment agent.
  • the treatment agent vaporises on contact with the molten metal and bubbles through the head of metal above the pocket.
  • the ladle is then pivoted again in order to dispense the treated molten metal through the spout.
  • the ladle is pivoted greater than 90° from the horizontal position, via the vertical position, to a third position in which the treated molten metal is dispensed (the dispensing position).
  • the ladle of the present invention is useful because it minimises the surface area of the metal that is exposed to the air when the ladle is in the horizontal position.
  • the reduction in surface area is associated with a reduction in heat loss from the metal. If the heat loss is reduced, metal may be poured Into the ladle at a lower temperature thereby reducing the wear on the refractory lining and other foundry apparatus.
  • a lower temperature for pouring into the ladle will also favour lower magnesium vapour expansion, which reduces the violence of the reaction (between the magnesium and the hot metal). This is thought to improve magnesium recovery since more magnesium vapour is efficiently kept within the liquid iron, and reduces the temperature loss after treatment since lower reaction violence means that there is less contact of metal with the colder atmosphere.
  • Another advantage of the ladle of the present invention is that it maximises the head of metal above the treatment agent when the ladle is in the vertical position.
  • An increased head of metal is associated with a reduction in the violence of the reaction between the metal and the treatment agent and In the case of a magnesium-containing treatment agent, improved and more consistent magnesium recovery.
  • the advantages of the invention are obtained due to the shape of the ladle liner, in particular the shape of the parts of the ladle liner which are in contact with the molten metal when the ladle is being filled (the horizontal position) and when the molten metal is being treated (the vertical position).
  • a vertical plane (intermediate the first and second ends of the liner when the ladle is in its horizontal position) is chosen in order to evaluate the shape of the ladle liner.
  • the vertical plane should be chosen such that it represents a typical cross-section of the ladle liner.
  • the vertical plane may be chosen at any point between the first and second ends.
  • the vertical plane may be equidistant the first and second ends of the liner when the ladle is in its horizontal position.
  • the pocket extends from the first end of the ladle liner away from the interior space (i.e. extends below the first end when the ladle is in its vertical position). This provides an additional increase in the head of metal over the treatment agent when the ladle is in the vertical position because molten metal can fill the pocket. As discussed above, an increased head of metal is associated with a reduction in the violence of the reaction between the metal and the treatment agent and in the case of a magnesium-containing treatment agent, improved and more consistent magnesium recovery.
  • the length of the pocket may be from 50 to 1200mm, from 200 to 1000mm or from 400 to 600mm.
  • the pocket is located within the interior space.
  • the pocket must either be in fluid communication with the interior space or be capable of being in fluid communication therewith upon contact with the metal.
  • the pocket may be defined by a mesh or grille having sufficiently small openings to retain the treatment agent whilst still permitting molten metal therethrough or it may be made of material that melts (such as metal) thereby providing access to the contents of the pocket.
  • the volume of the pocket will generally be small relative to the volume of the interior space.
  • the shape of the pocket is not particularly limited but conveniently the pocket will be elongate to ensure retention of the treatment agent. It may have a circular or a triangular cross-section.
  • the ratio of the lower volume to the upper volume may be at least 1.5:1, at least 2:1 or at least 3:1.
  • the height of the interior space (the distance between the top and bottom of the interior space, as defined by the interior of the continuous sidewall) when the ladle is in its horizontal position may be from 200mm to 1500mm, from 400mm to 1000mm, or from 600mm to 800mm.
  • the height of the interior space (the distance between the top and bottom of the interior space) when the ladle is its vertical position may be from 400mm to 3000mm, from 800mm to 2000mm or from 1000mm to 1500mm.
  • the ratio of the height of the interior space when the ladle is in its vertical position to the height of the interior space when the ladle is in its horizontal position may be at least 1:1, at least 2:1, at least 3:1 or at least 5:1.
  • the ratio of the height of the interior space when the ladle is in its vertical position to the height of the interior space when the ladle is in its horizontal position may be no more than 6:1, no more than 4:1, or no more than 3:1.
  • the ratio of the height of the interior space when the ladle is in its vertical position to the length of the pocket may be at least 1.5:1, at least 2:1, at least 2.5:1 or at least 3:1.
  • the continuous sidewall has an interior surface and an exterior surface which may have the same or different shapes. Conveniently the continuous sidewall will have a uniform thickness such that the interior and exterior surfaces have the same shape. It will be understood that it is the interior surface of the continuous sidewall which defines the shape of the interior space and therefore references to the cross-section of the continuous sidewall refer to the cross-section of the interior surface of the continuous sidewall.
  • the continuous sidewall may be defined by three or more wall portions such that the cross-section of the continuous sidewall is substantially polygonal. In an embodiment where the continuous sidewall is defined by three wall portions, the cross-section of the continuous sidewall is substantially triangular. In an embodiment where the continuous sidewall is defined by three wall portions of equal length, the cross-section of the continuous sidewall has the shape of an equilateral triangle. In any of the embodiments where the cross-section is based on a polygon, the corners may be radiussed/rounded and/or the sides may be bowed outward. Conveniently, the cross-section of the sidewall may be measured in the vertical plane intermediate the first and second ends.
  • the ratio of the height of the interior space when the ladle is in its vertical position to the length of a sidewall portion may be at least 1:1, at least 1.5:1 or at least 2:1.
  • the triangular cross-section will define an inscribed circle, i.e. the largest circle that can be contained within the triangle.
  • the ratio of the height of the interior space when the ladle is in its vertical position to the radius of the circle inscribed by the triangular cross-section may be at least 1.5:1, at least 2:1, at least 2.5:1 or at least 3:1.
  • the ladle comprises a spout for initially receiving and then dispensing the molten metal after treatment. This is particularly beneficial since it allows metal to be poured directly from the ladle into the casting moulds, without the need for re-ladling operations. This has a dual benefit of reducing temperature loss, and improving casting productivity by eliminating a step in the casting process.
  • Suitable refractory materials include those described in EP0675862B1 and in particular KALTEK (RTM) which is a refractory lining made from silica, alumina and magnesite which is bonded by an organic material such as phenolic resin.
  • RTM KALTEK
  • the continuous sidewall is of unitary construction.
  • the ladle may be mounted onto a crane or a forklift or other machinery in order to pivot the ladle.
  • the ladle shell may be a conventional cylindrical shell or a modified shell adapted to the shape of the ladle liner. If a conventional cylindrical shell is employed, it will be necessary for the interior and exterior surfaces of the continuous sidewall to have different shapes, i.e. the refractory liner will not have a uniform thickness. If a non-cylindrical shell is employed, the interior and exterior surfaces of the continuous sidewall may have the same shape. For example, where the ladle liner comprises a sidewall having a triangular cross-section, the shell may also have a triangular cross-section i.e. it may be a triangular prism.
  • the ladle shell and the ladle liner have substantially the same shape. This has the advantage that a minimum amount of refractory material may be employed.
  • the ladle may comprise a conventional cylindrical ladle shell. This may be convenient when re-using a conventional cylindrical shell. The efficiencies of the ladle liner would at least partially offset the expense of the additional refractory material needed to fit the ladle liner within the shell.
  • a method for the treatment of molten metal comprising loading the ladle of the first aspect by placing a treatment agent in the pocket, filling the ladle whilst it is in its horizontal position to a level below the pocket with molten metal, and pivoting the ladle to its vertical position such that molten metal flows onto the treatment agent in the pocket.
  • the method comprises pivoting the ladle greater than 90° from the horizontal position, via the vertical position to a dispensing position in which the molten metal is dispensed through the spout after treatment. In a further embodiment, the method comprises pivoting the ladle approximately 180° from the horizontal position, via the vertical position to the dispensing position in which the treated metal is dispensed.
  • the ladle is filled to a level corresponding to the plane midway between the top and bottom of the interior space when the ladle is in its horizontal position.
  • the method of the present invention is particularly suitable for the preparation of ductile iron, in which case the treatment agent is a nodulariser and the molten metal is iron.
  • the treatment agent is a magnesium-containing nodulariser.
  • Suitable nodularisers include pure magnesium, magnesium ferrosilicon alloy (MgFeSi alloy), nickel-magnesium alloy and magnesium-iron briquettes.
  • the ladle and method of the present invention may be used for the production of both ductile (spheroidal graphite) iron and vermicular (compacted graphite) iron.
  • the method may comprise inoculation of the molten metal after reaction with the treatment agent (e.g. the nodulariser).
  • Inoculants are alloys added in small amounts to induce eutectic graphite nucleation. Suitable inoculants include those based on ferrosilicon and calcium silicide.
  • the method may comprise initialisation of the molten metal prior to reaction with the treatment agent.
  • An initialiser is thought to inactivate the oxygen activity of the molten metal so that subsequent treatment is more successful.
  • Suitable initialisers include those described WO2008/012492 .
  • Fig 1A shows a ladle 10 in accordance with an embodiment of the invention.
  • the ladle 10 comprises a generally tubular steel shell 12 and a generally tubular refractory liner 14 (partially visible) within the shell 12.
  • the ladle 10 has an opening 16 at its upper end and a projection 18 at its lower end.
  • the shape of the shell 12 is complementary to the exterior shape of the refractory liner 14 such that the projection 18 corresponds to the shape of a pocket (not visible) for holding a treatment agent.
  • the ladle also comprises a closable lid 20, the inner surface of which defines the second end of the refractory liner 14.
  • the shell 12 and the refractory liner 14 flare out toward the upper end, adjacent the opening 16 to form a spout 17.
  • the ladle 10 is shown in its vertical position such that the spout is at the top of the ladle and the pocket in at the bottom of the ladle. In this configuration a treatment agent can be easily loaded
  • the ladle 10 is made in two parts as shown in figures 1B and 1C .
  • the main body of the ladle 10a is made by placing a former 22a within the shell 12 and filling the gap between the shell 12 and the former 22a with a refractory material (KALTEK (RTM)). Once the refractory material solidifies the former 22a is removed.
  • the projection part of the ladle 10b is made by placing another former 22b in the shell corresponding to the projection 18 and filling the gap between the former 22b and the projection 18 with refractory material. It will be understood that the external surfaces of the formers 22a, 22b correspond to the shape of the interior of the refractory ladle liner 14. The two parts 10a,b are then attached to one another.
  • Fig 1C shows a cross-section of the ladle 10 before the formers 22a, 22b have been removed and without the lid 20.
  • the refractory liner 14 comprises a continuous sidewall 24, a lower end 26 (a first end) and since the lid 20 is not fitted, the ladle is entirely open at its upper end. The uppermost part of the continuous sidewall defines the position where the lid 20 will be fitted (the second end 28).
  • the ladle liner 14 comprises a pocket 30 for holding a treatment agent.
  • the pocket 30 extends away from the first end 26. This provides an advantage in that there will be a greater head of metal above the treatment agent. It will be noted that the walls of the pocket 30 are thicker than the continuous sidewall 24. The thicker wall provides additional insulation for the vaporisation of the treatment agent.
  • the height of the interior space when the ladle is in its vertical position is labelled x.
  • the height of the interior space when the ladle is pivoted to be in its horizontal position is labelled y.
  • the depth of the pocket is labelled z.
  • the approximate values of x, y and z are 1380mm, 640mm and 480mm respectively.
  • the ratio of x:y is approximately 2.2:1 and the ratio of x:z is approximately 2.9:1.
  • Fig 1D shows a cross-section of the former 22a.
  • the external surface of the former 22a defines the interior surface of the continuous sidewall 24 and hence the cross-section of the interior space.
  • the cross-section of the former 22a is based upon an equilateral triangle in which the corners have been rounded and the sides have been bowed outward.
  • Fig 1E shows a cross-section of the former 22b.
  • the external surface of the former 22b defines the walls of the pocket 30.
  • the cross-section of the former 22b is related to the cross-section of the former 22a (shown in dashed lines).
  • the cross-section of the former 22b is again approximately triangular.
  • the pocket 30 could have a different cross-section, for example a circular cross-section.
  • a triangular cross-section is believed to be advantageous because it assists in retaining a treatment agent within the pocket 30 when the ladle is pivoted from a vertical to a horizontal position.
  • Fig 1F shows a cross-section of the main part of the ladle 10a comprising the shell 12 and the continuous refractory sidewall 24.
  • the sidewall 24 is based on an equilateral triangle (shown in dotted lines) where each corner makes contact with the sidewall 24.
  • the length of each side of the triangle is approximately 740mm such that the ratio of the height of the interior space when the ladle is in its vertical position (labelled x in figure 1C ) to the length of a length of the sidewall portion is approximately 1.8:1.
  • the triangle comprises an inscribed circle (also shown as a dotted line).
  • the inscribed circle has a diameter of approximately 427mm such that the ratio of the ratio of the height of the interior space when the ladle is in its vertical position (labelled x in figure 1C ) to the length of a diameter of the circle is approximately 3.2:1
  • the proportions of the ladle shown in figures 1A to 1F are considered to be particularly beneficial for the treatment of metal with a treatment agent, combining good heat retention with efficient treatment.
  • Figures 2A and 2B are schematic drawings of the ladle 10 shown in Fig 1A in its horizontal position.
  • the ladle 10 comprises a first end 26, a second end 28 and a continuous sidewall 24 as described previously.
  • the upper part of the sidewall defines the top 40 of the interior space and the lower part of the sidewall defines the bottom 42 of the interior space.
  • a vertical plane 44 intermediate the first and second ends is shown. The vertical plane is chosen to be closer to the first end 26 than the second end 28 because this corresponds to a position where the continuous sidewall 24 has a regular shape.
  • a horizontal plane 46 midway between the top 40 and the bottom 42 of the interior space is shown.
  • the volume of the interior space defined between the bottom of the interior space 42, the first end 26, the midway plane 46 and the vertical plane 44 is labelled I (the lower volume).
  • the volume of the interior space defined between the top of the interior space 40, the first end 26, the midway plane 46 and the vertical plane 44 is labelled II (the upper volume). Referring to Fig 2A volumes I and II appear to be equal but it is clear from Fig 2B that volume I is greater than volume 2 due to the shape of the cross-section of the continuous sidewall 24.
  • the triangular prism shape of the ladle in accordance with an embodiment of the present invention is advantageous as compared to a cylindrical ladle in terms of heat loss from the metal when it is horizontal position and an increased head of metal over the treatment agent when it is in a vertical position (the second position).
  • a vertical position the second position
  • the ladle is filled half-way the surface of the metal exposed to the air will be smaller than a comparable cylindrical ladle.
  • the ladle is pivoted from a horizontal position to a vertical position the metal height will be greater than a comparable cylindrical ladle.
  • Example 1 In order to fairly evaluate the rate of heat loss for a ladle in accordance with an embodiment of the present invention (Example 1) the inventors designed two ladles, Example 1 (in accordance with an embodiment of the invention) and a further ladle for comparison (Comparative Example 1) and ran simulations using the MAGMASOFT simulation tool.
  • MAGMASOFT is a leading simulation tool supplied by MAGMA G manereitechnologie GmbH that models the mould filling and solidification of castings. It is typically used by foundries to avoid expensive and time consuming foundry trials.
  • the Example 1 ladle is shown in fig 3A (vertical position) and fig 3B and 3C (horizontal position).
  • the interior space has a substantially triangular cross-section.
  • Comparative Example 1 is shown in fig 4A (vertical position) and fig 4B and 4C (horizontal position).
  • the interior space has a circular cross-section.
  • a dotted line is shown in each figure to demonstrate the level of the molten metal when the ladles are filled to their working capacities.
  • a comparison of the properties of the two ladles is shown in the table below.
  • Example 1 Comparative Example 1 Working Capacity (kg) 3000 3000 Metal volume total surface area (mm 2 ) 3719746 3892335 Top surface area (mm 2 ) 1028446 1354917 Height of metal - horizontal (mm) 417.7 427 Height of metal - vertical (mm) 897 747 Geometric Modulus (volume/surface area) (cm) 11.5 11
  • both ladles hold the same quantity of metal, they are filled to different levels because of their differing shapes.
  • the metal In the horizontal position, the metal is filled to a similar height in both cases but when the ladles are rotated to a vertical position, the metal height is much greater for Example 1 than for Comparative Example 1.
  • the greater height of metal above the vaporisable treatment agent means that the vaporised treatment agent must travel through more metal and so is more likely to remain within the molten metal, leading to better recovery rates.
  • the total surface area of the metal (in contact with the air or the walls of the ladle) and the top surface area of the metal (in contact with the air) is smaller for Example 1 than for Comparative Example 1. This corresponds to a greater geometric modulus for Example 1 than Comparative Example 1. Therefore the molten metal in the ladle of Example 1 would cool more slowly than the molten metal in the ladle of Comparative Example 1.
  • the ladle was modelled as containing molten steel and having a refractory lining with insulating properties as that of KALTEK (RTM) material.
  • the model considers the boundary material above the metal to be air.
  • the simulation was run with two different starting temperatures (1400°C and 1580°C) for the refractory lining.
  • the results after 240 seconds are shown in figures 5A to 5D .
  • the simulation output is a shaded contour diagram of the metal, with the darkness of the shading being inversely proportional to the temperature of the liquid metal, i.e. the darker the shading the colder the metal - the actual values are indicated by the temperature key in the simulation.
  • Figures 5A and 5B show the surface temperature of the metal when the refractory lining has a starting temperature of 1400°C for Example 1 and Comparative Example 1 respectively.
  • the surface temperature of the metal is higher for the ladle of the invention than for the comparative example even though both ladles contain the same amount of metal and have identical starting temperatures. This is shown by the higher proportion of darker contours (shading) on the metal surface in figure 5B compared to 5A because the darker the shading, the colder the metal is.
  • Figures 5C and 5D show the surface temperature of the metal when the refractory lining has a starting temperature of 1580°C for Example 1 and Comparative Example 1 respectively. Again, the surface temperature of the metal is higher for the ladle of the invention than for the comparative example as shown by the lighter shading in figure 5C compared to figure 5D . This demonstrates that the ladle of the invention allows the metal to remain hotter for longer.
  • the ladle 10 shown in Fig 1A was placed in a vertical position with the pocket 18 at the lowest point. 20.8kg magnesium ferrosilicon alloy (5.38% Mg) was then loaded into the pocket using a long necked funnel placed in the opening. After the treatment agent was loaded the ladle was rotated 90° to a horizontal position. The ladle was then filled with 1600kg molten iron at a temperature of 1480°C. The ladle was then rotated back to the vertical position such that the molten Iron flowed into the pocket. A white flare was seen as the molten iron reacted with the magnesium alloy. The metal was poured out of ladle by tilting it and pouring out of the spout 17. The results are below.
  • Example 2 Comparative Example 2 4 minutes 10 minutes 4 minutes 9 minutes Mg residual (%) 0.0550 0.0474 0.0450 0.0350 S before treatment (%) 0.0140 0.0140 0.0070 0.0070 S after treatment (%) 0.0110 0.0104 0.0046 0.0040 Mg added (%) 0.06994 0.06994 0.09684 0.09684 Mg Recovery (%) 82 72 48 38
  • the magnesium recovery is considerably higher for Example 2 than Comparative Example 2. Therefore the ladle In accordance with an embodiment of the present appears to provide better recovery rates than the standard tundish ladle.

Claims (15)

  1. Poche de coulée de traitement, comprenant une carcasse de poche de coulée contenant un revêtement de poche de coulée réfractaire généralement tubulaire, ladite poche de coulée pouvant être pivotée entre une position horizontale et une position verticale ;
    ledit revêtement de la poche de coulée comportant une première extrémité et une deuxième extrémité, avec une paroi latérale continue entre elles, un espace intérieur étant défini entre lesdites première et deuxième extrémités et la paroi latérale continue ;
    ledit revêtement de la poche de coulée comprenant en outre une poche pour contenir un agent de traitement, ladite poche étant agencée près de la première extrémité et étant en communication de fluide avec l'espace intérieur, et étant agencée plus près de la partie supérieure que de la partie inférieure de l'espace intérieur lorsque la poche de coulée se trouve dans sa position horizontale et plus proche de la partie inférieure que de la partie supérieure de l'espace intérieur lorsque la poche de coulée se trouve dans sa position verticale, et une busette pour recevoir et couler du métal fondu, agencée plus près de la partie supérieure que de la partie inférieure de l'espace intérieur lorsque la poche de coulée se trouve dans ses positions horizontale et verticale ;
    dans laquelle, dans la position horizontale, un volume inférieur de l'espace intérieur, défini au-dessous d'un plan situé à mi-chemin entre la partie supérieure et la partie inférieure de l'espace intérieur et entre la première extrémité et un plan vertical situé entre les première et deuxième extrémités, est plus grand qu'un volume supérieur de l'espace intérieur, défini au-dessus du plan situé à mi-chemin et entre la première extrémité et ledit plan vertical.
  2. Poche de coulée selon la revendication 1, dans laquelle la poche s'étend à partir de la première extrémité du revêtement de la poche de coulée et à l'écart de l'espace intérieur.
  3. Poche de coulée selon les revendications 1 ou 2, dans laquelle le rapport entre le volume inférieur et le volume supérieur correspond au moins à 1,5 : 1.
  4. Poche de coulée selon l'une quelconque des revendications précédentes, dans laquelle le rapport entre la hauteur de l'espace intérieur, lorsque la poche de coulée se trouve dans sa position verticale, et la hauteur de l'espace intérieur, lorsque la poche de coulée se trouve dans sa position horizontale correspond au moins à 2 :1.
  5. Poche de coulée selon l'une quelconque des revendications précédentes, dans laquelle le rapport entre la hauteur de l'espace intérieur, lorsque la poche de coulée se trouve dans sa position verticale, et la hauteur de l'espace intérieur, lorsque la poche de coulée se trouve dans sa position horizontale, n'est pas supérieur à 6 :1.
  6. Poche de coulée selon l'une quelconque des revendications précédentes, dans laquelle la poche s'étend à partir de la première extrémité du revêtement de la poche de coulée et à l'écart de l'espace intérieur, le rapport entre la hauteur de l'espace intérieur, lorsque la poche de coulée se trouve dans sa position verticale, et la longueur de la poche correspondant au moins à 2 :1.
  7. Poche de coulée selon l'une quelconque des revendications précédentes, dans laquelle la paroi latérale continue est définie par trois ou plusieurs parties de paroi, de sorte que la section transversale de la paroi latérale continue est pratiquement polygonale.
  8. Poche de coulée selon la revendication 7, dans laquelle la paroi latérale continue est définie par trois parties de paroi, de sorte que la section transversale de la paroi latérale continue est pratiquement triangulaire.
  9. Poche de coulée selon les revendications 7 ou 8, dans laquelle les coins du polygone sont arrondis et /ou les côtés du polygone sont courbés vers l'extérieur.
  10. Poche de coulée selon l'une quelconque des revendications précédentes, dans laquelle la paroi latérale continue est définie par trois parties de paroi latérale, de sorte que la section transversale de la paroi latérale continue est pratiquement triangulaire, le rapport entre la hauteur de l'espace intérieur, lorsque la poche de coulée se trouve dans la position verticale, et la longueur d'au moins une des parties de paroi latérale correspondant au moins à 1,5 :1.
  11. Poche de coulée selon l'une quelconque des revendications précédentes, dans laquelle la paroi latérale continue a une construction monobloc.
  12. Poche de coulée selon l'une quelconque des revendications précédentes, dans laquelle la carcasse de la poche de coulée et le revêtement de la poche de coulée ont pratiquement la même forme.
  13. Procédé de traitement de métal fondu, comprenant les étapes ci-dessous :
    chargement de la poche de coulée selon l'une quelconque des revendications 1 à 12 en plaçant un agent de traitement dans la poche ;
    remplissage de la poche de coulée de métal fondu pendant qu'elle se trouve dans sa position horizontale, à un niveau situé au-dessous de la poche ; et
    pivotement de la poche de coulée vers sa position verticale, de sorte que le métal fondu s'écoule sur l'agent de traitement dans la poche.
  14. Procédé selon la revendication 13, dans lequel la poche de coulée est pivotée de plus de 90° à partir de la position horizontale, passant par la position verticale, vers une position de distribution, dans laquelle le métal fondu traité est distribué à travers la busette.
  15. Procédé selon les revendications 13 ou 14, dans lequel l'agent de traitement est un agent de sphéroïdisation.
EP09251258A 2009-05-06 2009-05-06 Poche de traitement Active EP2251443B1 (fr)

Priority Applications (21)

Application Number Priority Date Filing Date Title
AT09251258T ATE529539T1 (de) 2009-05-06 2009-05-06 Behandlungspfanne
PL09251258T PL2251443T3 (pl) 2009-05-06 2009-05-06 Kadź obróbcza
DK09251258.1T DK2251443T3 (da) 2009-05-06 2009-05-06 Behandlingsstøbeske
SI200930116T SI2251443T1 (sl) 2009-05-06 2009-05-06 Livarski lonec za obdelavo
ES09251258T ES2373268T3 (es) 2009-05-06 2009-05-06 Cuchara de tratamiento.
RS20110538A RS52039B (en) 2009-05-06 2009-05-06 FOUNDRY FOR PROCESSING
PT09251258T PT2251443E (pt) 2009-05-06 2009-05-06 Concha de tratamento
EP09251258A EP2251443B1 (fr) 2009-05-06 2009-05-06 Poche de traitement
US12/737,335 US20120152060A1 (en) 2009-05-06 2010-04-26 Treatment ladle
AU2010244265A AU2010244265B2 (en) 2009-05-06 2010-04-26 Treatment ladle
BRPI1003637A BRPI1003637A2 (pt) 2009-05-06 2010-04-26 panela de tratamento e método para o tratamento de metal em fusão
RU2011149480/02A RU2530922C2 (ru) 2009-05-06 2010-04-26 Ковш для обработки
CN201080002007.7A CN102084010B (zh) 2009-05-06 2010-04-26 处理钢包
MX2010014295A MX2010014295A (es) 2009-05-06 2010-04-26 Caldero de colada para tratamiento.
UAA201114414A UA104891C2 (uk) 2009-05-06 2010-04-26 Ківш і спосіб обробки розплавленого металу добавками, які випаровуються
PCT/GB2010/000824 WO2010128273A1 (fr) 2009-05-06 2010-04-26 Poche de traitement
JP2012509081A JP5639154B2 (ja) 2009-05-06 2010-04-26 処理取鍋
KR1020107029318A KR101657126B1 (ko) 2009-05-06 2010-04-26 처리 레이들 및 용융 금속 처리 방법
CA2760249A CA2760249C (fr) 2009-05-06 2010-04-26 Poche de traitement
ZA2011/06905A ZA201106905B (en) 2009-05-06 2011-09-21 Treatment ladle
HR20110923T HRP20110923T1 (hr) 2009-05-06 2011-12-12 Posuda za lijevanje

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP09251258A EP2251443B1 (fr) 2009-05-06 2009-05-06 Poche de traitement

Publications (2)

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EP2251443A1 EP2251443A1 (fr) 2010-11-17
EP2251443B1 true EP2251443B1 (fr) 2011-10-19

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EP09251258A Active EP2251443B1 (fr) 2009-05-06 2009-05-06 Poche de traitement

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JP (1) JP5639154B2 (fr)
KR (1) KR101657126B1 (fr)
CN (1) CN102084010B (fr)
AT (1) ATE529539T1 (fr)
AU (1) AU2010244265B2 (fr)
BR (1) BRPI1003637A2 (fr)
CA (1) CA2760249C (fr)
DK (1) DK2251443T3 (fr)
ES (1) ES2373268T3 (fr)
HR (1) HRP20110923T1 (fr)
MX (1) MX2010014295A (fr)
PL (1) PL2251443T3 (fr)
PT (1) PT2251443E (fr)
RS (1) RS52039B (fr)
RU (1) RU2530922C2 (fr)
SI (1) SI2251443T1 (fr)
UA (1) UA104891C2 (fr)
WO (1) WO2010128273A1 (fr)
ZA (1) ZA201106905B (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102952914A (zh) * 2011-08-20 2013-03-06 鞍钢股份有限公司 一种鱼雷罐添加物的集中熔化方法
CN103909236A (zh) * 2013-01-09 2014-07-09 广西玉柴机器股份有限公司 铁液蠕化处理方法及其转包
FR3006695A1 (fr) * 2013-06-10 2014-12-12 Mourad Toumi Procede et dispositif de traitement d'un metal ou d'un alliage metallique en fusion par une substance additive
CN108788027A (zh) * 2018-06-23 2018-11-13 共享装备股份有限公司 球墨铸铁的球化装置及球化方法
KR102605727B1 (ko) * 2022-03-08 2023-11-29 주식회사 부천주물 하이브리드 래들 및 그 하이브리드 래들을 이용한 용탕 자동 주입시스템 및 하이브리드 래들을 이용한 용탕 자동 주입시스템의 용탕 주입방법

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1815214C3 (de) * 1968-01-26 1975-06-19 Georg Fischer Ag, Schaffhausen (Schweiz) 03.12.68 Schweiz 17961-68 Kippbares BehandlungsgefäB zum Behandeln von Metall-Schmelzen durch Einbringen verdampfbarer Zusätze, insbesondere zum Herstellen von Eisen-Kohlenstoff-GuBwerkstoffen mit Kugelgraphit durch Einbringen von Reinmagnesium in die im Gefäß enthaltene Schmelze Georg Fischer AG, Schaffhausen (Schweiz)
US3833361A (en) * 1970-07-06 1974-09-03 Kusaka Rare Metal Prod Co Ltd Method for adding special elements to molten pig iron
CH549095A (de) * 1971-03-31 1974-05-15 Fischer Ag Georg Verfahren und vorrichtung zur erzeugung von gusseisen mit kugelgraphit.
US3955974A (en) * 1971-05-18 1976-05-11 Georg Fischer Aktiengesellschaft Apparatus and method for treating a metal melt with a vaporizable substance
US4391636A (en) * 1981-12-16 1983-07-05 Wintec Company Method of and apparatus for the production of nodular (ductile) cast iron
US4488711A (en) * 1983-03-24 1984-12-18 Sperry Corporation Treating ladle for ductile iron treatment
SU1202704A1 (ru) * 1983-08-03 1986-01-07 Rabinovich Benedikt V Устройство дл разливки жидкого металла
US4509979A (en) * 1984-01-26 1985-04-09 Modern Equipment Company Method and apparatus for the treatment of iron with a reactant
SE453302B (sv) * 1984-10-16 1988-01-25 Asea Ab Anordning for skyddad slaggfri avtappning ur tippbar cylindrisk behallare
SU1371972A1 (ru) * 1986-05-15 1988-02-07 Днепропетровский химико-технологический институт им.Ф.Э.Дзержинского Чайниковый ковш дл модифицировани железоуглеродистых сплавов
CH679987A5 (fr) * 1989-11-28 1992-05-29 Fischer Ag Georg
IT1248457B (it) * 1991-04-05 1995-01-19 Benet Di Bennati Ettore Metodo e apparecchiatura per il trattamento di bagni metallici mediante un materiale con elevato potenziale di gas o vapore
GB9226662D0 (en) 1992-12-22 1993-02-17 Foseco Int Refractory compositions
ES2127445T3 (es) * 1994-09-22 1999-04-16 Metallurg Hafner & Polte Mit B Recipiente sumergible para introducir magnesio puro en un caldero de tratamiento y empleo de este recipiente sumergible.
GB0614705D0 (en) * 2006-07-25 2006-09-06 Foseco Int Improved meethod of producing ductile iron
CN100513586C (zh) * 2007-07-04 2009-07-15 芜湖新兴铸管有限责任公司 一种球墨铸铁管的生产工艺及装置

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MX2010014295A (es) 2011-03-03
DK2251443T3 (da) 2012-02-06
RS52039B (en) 2012-04-30
BRPI1003637A2 (pt) 2016-02-23
KR101657126B1 (ko) 2016-09-13
RU2011149480A (ru) 2013-06-20
CA2760249C (fr) 2016-07-05
KR20120007432A (ko) 2012-01-20
RU2530922C2 (ru) 2014-10-20
UA104891C2 (uk) 2014-03-25
AU2010244265A1 (en) 2010-11-11
US20120152060A1 (en) 2012-06-21
CN102084010B (zh) 2014-08-27
CA2760249A1 (fr) 2010-11-11
ES2373268T3 (es) 2012-02-01
AU2010244265B2 (en) 2013-11-21
CN102084010A (zh) 2011-06-01
ATE529539T1 (de) 2011-11-15
WO2010128273A1 (fr) 2010-11-11
ZA201106905B (en) 2012-11-29
JP5639154B2 (ja) 2014-12-10
EP2251443A1 (fr) 2010-11-17
PL2251443T3 (pl) 2012-03-30
SI2251443T1 (sl) 2012-01-31
HRP20110923T1 (hr) 2012-01-31
PT2251443E (pt) 2011-12-22
JP2012526198A (ja) 2012-10-25

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