EP2154698B1 - Procédé de fabrication d'un transformateur de résine de coulée résistant aux fissures et transformateur de résine de coulée résistant aux fissures - Google Patents
Procédé de fabrication d'un transformateur de résine de coulée résistant aux fissures et transformateur de résine de coulée résistant aux fissures Download PDFInfo
- Publication number
- EP2154698B1 EP2154698B1 EP09161058.4A EP09161058A EP2154698B1 EP 2154698 B1 EP2154698 B1 EP 2154698B1 EP 09161058 A EP09161058 A EP 09161058A EP 2154698 B1 EP2154698 B1 EP 2154698B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- resin
- cast
- added
- liquid
- filler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920005989 resin Polymers 0.000 title claims description 79
- 239000011347 resin Substances 0.000 title claims description 79
- 238000000034 method Methods 0.000 title claims description 19
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 238000005266 casting Methods 0.000 claims description 37
- 239000007788 liquid Substances 0.000 claims description 22
- 239000000945 filler Substances 0.000 claims description 12
- 239000003607 modifier Substances 0.000 claims description 11
- 238000004804 winding Methods 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 4
- 239000003365 glass fiber Substances 0.000 claims description 3
- 239000012764 mineral filler Substances 0.000 claims description 3
- 229920002379 silicone rubber Polymers 0.000 claims description 3
- 239000004945 silicone rubber Substances 0.000 claims description 3
- 150000003512 tertiary amines Chemical class 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 230000000630 rising effect Effects 0.000 claims description 2
- 229910021529 ammonia Inorganic materials 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- -1 ammonia compound Chemical class 0.000 claims 2
- 235000013312 flour Nutrition 0.000 claims 2
- 238000002955 isolation Methods 0.000 claims 2
- 239000003822 epoxy resin Substances 0.000 description 5
- 229920000647 polyepoxide Polymers 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000010292 electrical insulation Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 230000008646 thermal stress Effects 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 229920006336 epoxy molding compound Polymers 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/40—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes epoxy resins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F27/00—Details of transformers or inductances, in general
- H01F27/28—Coils; Windings; Conductive connections
- H01F27/32—Insulating of coils, windings, or parts thereof
- H01F27/327—Encapsulating or impregnating
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F41/00—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
- H01F41/02—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
- H01F41/04—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets for manufacturing coils
- H01F41/12—Insulating of windings
- H01F41/127—Encapsulating or impregnating
Definitions
- the invention relates to a method for producing a crack-resistant cast-resin transformer, wherein a casting resin for electrical insulation of a winding body of the cast-resin transformer is used. Furthermore, the invention relates to a cast-resin transformer with an existing of cast resin electrical insulation of a winding body of the cast resin transformer.
- casting resins in particular epoxy resins
- electrical insulation of electrical components in particular high-voltage transformers
- casting resins have the advantage that casting resins on the one hand have high electrical strengths and on the other hand are mechanically very stable in the cured state.
- the problem with the use of casting resins is that the casting resin is liquid and thus difficult to process only in the heated state.
- the DE 44 32 188 A1 an epoxy resin molding compound, which in addition to a phosphorus-modified epoxy resin further additives and inorganic fillers.
- the epoxy resin molding composition is technically simpler and thus cheaper to produce and should have a lower water absorption and higher thermal shock resistance compared to known epoxy molding compounds.
- a potting compound in particular for producing molded parts with embedded therein inserts, consisting of a base component and at least one additive, wherein the base component is a casting resin and the base component at least two additives, in particular quartz powder and a mineral fiber material having.
- a problem with the casting resin transformers produced hitherto in the state of the art is that they have a high electrical output Load or, in the case of a cold shock test prescribed in accordance with standard IEC600 76 - 11, cracks, especially at the material transitions.
- the risk of cracking is greater, the faster the curing of the casting resin during manufacture takes place. For this reason, very long curing times have hitherto been chosen in the prior art, so that a virtually uniform cooling of all components of the entire cast-resin transformer is ensured.
- the curing process until removal of the final casting mold from the cast-resin transformer therefore takes in part more than 30 hours.
- Object of the present invention is therefore to shorten the curing process during the production of a cast-resin transformer.
- a toughening modifier of up to 20 phr is added to the liquid casting resin in comparison with the base component of the casting resin.
- the term phr parts per hundred resin
- phr parts per hundred resin
- an accelerator is added in such a concentration that results in a gel time of less than 15 minutes at 140 ° C, wherein the enriched with these two components liquid casting resin for casting of the winding body and the thus-cast winding body for curing one linear or stepped rising temperature profile is exposed.
- An example of this is the following temperature profile, in which within 4 hours, the composite liquid casting resin is continuously increased from a temperature of 80 ° C to 100 ° C. Subsequently, the temperature is continuously increased to 130 ° C and then finally cured for several hours at this temperature. An otherwise slow cooling in the cooling area for reducing the internal thermal stresses (annealing) is not necessary according to the present method.
- Toughness modifiers are known for improving the temperature resistance of casting resins (for example DE 601 04 449 T2 ).
- the use of cure accelerators for example DE 42 06 733 C2 ), the polymerization or polyaddition accelerates conversion to a crosslinked composite matrix of the thermosetting molding resin.
- the sole or non-coordinated addition of accelerators to a liquid casting resin leads just to a rapid curing with high mechanical stresses, which forms in case of frequent temperature changes of the cast resin transformer during operation, the cracks to be avoided.
- the crack resistance of the casting resin can be increased in such a way that mechanical stresses just do not arise during the curing process and thus at the same time the curing times can be reduced.
- the combination of the toughness modifier with adjusted accelerator concentrations and a co-ordinated curing process reduces or eliminates the cracking of a cast resin transformer thus produced.
- liquid casting resin as an accelerator in particular a tertiary amine and / or a quaternary ammonium compound is added.
- the temperature profile is controlled during the curing process of the liquid casting resin by means of a temperature distribution in a furnace surrounding the winding body.
- a filler is added to the liquid casting resin, in particular a mineral quartz powder.
- a filler is added to the liquid casting resin, in order in addition to increase the composite matrix of the hardening casting resin by the glass short fibers to reinforce.
- a toughening modifier of up to 20 phr is added to the casting resin of the cast-resin transformer.
- a filler is advantageously added to the casting resin, wherein, based on the weight percent of the filler of up to 5 percent by weight glass short fibers are added to the casting resin.
- the filler is a mineral filler, in particular an amorphous quartz powder.
- the accelerator is in particular a tert. Amine and / or a quaternary ammonium compound and the toughness modifier, a copolymer, in particular an acrylonitrile or a silicone rubber.
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Insulating Of Coils (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Claims (11)
- Procédé de fabrication d'un transformateur à résine de coulée résistant aux fissures, dans lequel on utilise une résine de coulée pour isoler électriquement un corps d'enroulement du transformateur à résine de coulée, un modificateur de viscosité étant ajouté à la résine de coulée liquide et la résine de coulée liquide ainsi composée servant à la coulée du corps d'enroulement,
caractérisé en ce que
la quantité du modificateur de viscosité représente jusqu'à 20 parties pour 100 parties de résine et le corps d'enroulement ainsi coulé est, pour le durcissement, réchauffé à une température croissante et la température est élevée sous la forme d'un profil de température défini linéairement et/ou en forme d'escalier pendant le durcissement de la résine de coulée liquide composée. - Procédé suivant la revendication 1,
caractérisé en ce que
l'on ajoute à la résine de coulée liquide comme modificateur de viscosité un copolymère, notamment un copolymère d'acrylonitrile ou un caoutchouc en silicone. - Procédé suivant l'une des revendications 1 ou 2,
caractérisé en ce que
l'on règle le profil de température pendant le processus de durcissement de la résine de coulée liquide composée au moyen d'une répartition de température dans un four entourant le corps d'enroulement. - Procédé suivant l'une des revendications 1 à 3,
caractérisé en ce que
l'on ajoute à la résine de coulée composée liquide un accélérateur, notamment une amine tertiaire et/ou un composé d'ammonium quaternaire. - Procédé suivant la revendication 4,
caractérisé en ce que
l'on maîtrise la concentration de l'accélérateur pour obtenir une durée de gel de moins de 15 minutes à 140°C et on l'adapte ainsi au processus de durcissement. - Procédé suivant l'une des revendications 1 à 5,
caractérisé en ce que
l'on ajoute à la résine de coulée liquide une charge, jusqu'à 5 pourcent en poids de courtes fibres de verre étant ajoutées, rapporté au pourcentage en poids de la charge. - Procédé suivant la revendication 6,
caractérisé en ce que
l'on ajoute à la résine de coulée liquide comme charge une charge minérale, notamment de la poudre de quartz amorphe. - Transformateur à résine de coulée ayant une isolation électrique en résine de coulée d'un corps d'enroulement du transformateur à résine de coulée,
caractérisé en ce que
la résine de coulée liquide contient jusqu'à 20 parties pour 100 parties de résine d'un modificateur de viscosité et en ce que la résine de coulée composée d'abord liquide est réchauffée au moyen d'un profil de température défini croissant linéairement et/ou en escalier et est ainsi durcie sans fissure. - Transformateur à résine de coulée suivant la revendication 8,
caractérisé en ce que
la résine de coulée est additionnée d'une charge, jusqu'à 5 pourcent en poids des fibres courtes de verre, rapporté au pourcentage en poids de la charge, étant ajoutées à la résine de coulée. - Transformateur à résine de coulée suivant l'une des revendications 8 ou 9,
caractérisé en ce que
la charge est une charge minérale, notamment de la poudre de quartz amorphe. - Transformateur à résine de coulée suivant l'une des revendications 8 à 10,
caractérisé en ce que
la résine de coulée liquide composée comprend un accélérateur, notamment une amine tertiaire et/ou un composé d'ammonium quaternaire, et le modificateur de viscosité est un copolymère, notamment un acrylonitrile ou un caoutchouc en silicone.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL09161058T PL2154698T3 (pl) | 2008-05-27 | 2009-05-26 | Sposób wytwarzania odpornego na pękanie transformatora zalewanego żywicą i odporny na pękanie transformator zalewany żywicą |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102008025541A DE102008025541A1 (de) | 2008-05-27 | 2008-05-27 | Verfahren zum Herstellen eines rissfestem Gießharztransformators und rissfester Gießharztransformator |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2154698A2 EP2154698A2 (fr) | 2010-02-17 |
EP2154698A3 EP2154698A3 (fr) | 2012-08-29 |
EP2154698B1 true EP2154698B1 (fr) | 2013-11-06 |
Family
ID=40942443
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09161058.4A Active EP2154698B1 (fr) | 2008-05-27 | 2009-05-26 | Procédé de fabrication d'un transformateur de résine de coulée résistant aux fissures et transformateur de résine de coulée résistant aux fissures |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP2154698B1 (fr) |
DE (1) | DE102008025541A1 (fr) |
ES (1) | ES2442442T3 (fr) |
PL (1) | PL2154698T3 (fr) |
PT (1) | PT2154698E (fr) |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1100113B (de) * | 1955-08-23 | 1961-02-23 | Westinghouse Electric Corp | Isolierstoff fuer elektrotechnische Zwecke |
US4665111A (en) * | 1984-10-12 | 1987-05-12 | Siemens Aktiengesellschaft | Casting compound for electrical and electronic components and modules |
JP2524011B2 (ja) * | 1991-05-23 | 1996-08-14 | 株式会社日立製作所 | 高圧コイル注型用熱硬化性樹脂組成物、該組成物で注型、硬化してなるモ―ルドコイル、パネル |
DE4206733C2 (de) | 1992-03-04 | 1998-09-03 | Bakelite Ag | Gießharz und seine Verwendung zur Herstellung von Elektrovergußmassen |
DE4343121A1 (de) | 1993-12-17 | 1995-06-22 | Abb Patent Gmbh | Verfahren zur Herstellung einer Gießkeramik |
DE4432188A1 (de) | 1994-09-09 | 1996-03-14 | Siemens Ag | Epoxidharzformmassen zur Umhüllung von elektronischen Bauelementen |
DE19648134A1 (de) * | 1996-11-21 | 1998-05-28 | Beck & Co Ag Dr | Verfahren zur Tränkung von Bauteilen |
US6198373B1 (en) * | 1997-08-19 | 2001-03-06 | Taiyo Yuden Co., Ltd. | Wire wound electronic component |
CZ20031466A3 (cs) | 2000-11-29 | 2003-08-13 | Vantico Ag | Systém plněné epoxidové pryskyřice mající vysoké hodnoty mechanické pevnosti |
DE10224587A1 (de) | 2002-06-04 | 2003-12-18 | Abb Patent Gmbh | Vergußmasse |
DE10252435A1 (de) * | 2002-11-12 | 2004-05-27 | Abb Technology Ag | Verfahren und Anordnung zur Aushärtung von Spulen |
DE102004054527B4 (de) * | 2004-11-05 | 2006-10-12 | Siemens Ag | Verfahren zur Herstellung einer von einer Isolierung freizuhaltenden Stelle eines isolierten Leiters und Trennmittel |
-
2008
- 2008-05-27 DE DE102008025541A patent/DE102008025541A1/de not_active Ceased
-
2009
- 2009-05-26 PT PT91610584T patent/PT2154698E/pt unknown
- 2009-05-26 EP EP09161058.4A patent/EP2154698B1/fr active Active
- 2009-05-26 PL PL09161058T patent/PL2154698T3/pl unknown
- 2009-05-26 ES ES09161058.4T patent/ES2442442T3/es active Active
Also Published As
Publication number | Publication date |
---|---|
PT2154698E (pt) | 2013-11-22 |
PL2154698T3 (pl) | 2014-04-30 |
DE102008025541A1 (de) | 2009-12-17 |
EP2154698A2 (fr) | 2010-02-17 |
EP2154698A3 (fr) | 2012-08-29 |
ES2442442T3 (es) | 2014-02-11 |
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