EP2113024A1 - Détergent pour la vaisselle - Google Patents

Détergent pour la vaisselle

Info

Publication number
EP2113024A1
EP2113024A1 EP08707986A EP08707986A EP2113024A1 EP 2113024 A1 EP2113024 A1 EP 2113024A1 EP 08707986 A EP08707986 A EP 08707986A EP 08707986 A EP08707986 A EP 08707986A EP 2113024 A1 EP2113024 A1 EP 2113024A1
Authority
EP
European Patent Office
Prior art keywords
salts
acid
dishwashing
dishwashing detergent
detergent formulations
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP08707986A
Other languages
German (de)
English (en)
Other versions
EP2113024B1 (fr
Inventor
Thomas Klein
Ralf-Johann Moritz
Thomas Staffel
Jürgen STRAUB
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lanxess Deutschland GmbH
BK Giulini GmbH
Original Assignee
Lanxess Deutschland GmbH
BK Giulini GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE102008000029A external-priority patent/DE102008000029A1/de
Application filed by Lanxess Deutschland GmbH, BK Giulini GmbH filed Critical Lanxess Deutschland GmbH
Publication of EP2113024A1 publication Critical patent/EP2113024A1/fr
Application granted granted Critical
Publication of EP2113024B1 publication Critical patent/EP2113024B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0073—Anticorrosion compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates

Definitions

  • the present invention relates to the use of a phosphate-reduced builder system based on alkali metal polyphosphate and sodiumiminodisuccinate for the production of material-saving dishwashing detergent formulations for automatic, automatic dishwashing.
  • Phosphate-reduced are those formulations whose phosphate content is insufficient to bind the resulting from the water hardness and hardness-forming ions of the dish soil maximum total hardness in the wash liquor and compensate for this gap with a non-belonging to the group of phosphates complexing agent. Levels of tripolyphosphate of about 50% have been found to be adequate (+/- 5%). Thus, phosphate-reduced formulations in the sense of the present invention are characterized by a phosphate content of less than
  • the purification is carried out in dishwashing machines at higher pH and a higher temperature, preferably between 45 ° and 70 0 C.
  • the alkaline medium used in fat and oil based contaminants are saponified and thus removed from the dishes.
  • Colored stains, such as tea stains, are removed by oxidation by a bleach system.
  • Starch and protein components are hydrolytically split by enzymes and thus more easily removed.
  • Surfactants play a role only as a wetting agent in low concentrations and, in contrast to hand dishwashing detergents, have low foaming properties.
  • the fourth product was introduced by the "machine care workers", who after a certain number of operations are supposed to clean and care for the machine themselves
  • the previous conclusion is the use of deodorant fragrances as the fifth element combined, eg "3 in 1" or "5 in 1".
  • the first automatic dishwashing products consisted of more than 90%
  • NTPP Sodium tripolyphosphate
  • NTPP combines good complexing power for calcium and magnesium ions with protection of glass, porcelain and magnesium
  • tripolyphosphate as a complexing agent could not be sufficiently assumed by metasilicate as well as by citrate.
  • Phosphates are cheaper than organic complexing agents.
  • biodegradable organic complexing agents with low toxicity have been developed.
  • the medium strength Complexing agent called sodium iminodisuccinate (Na-IDS) and the stronger complexing agent sodium methylglycine diacetate (Na-MGDA). These chelating agents have also been used for phosphate-free dishwashing detergents.
  • No. 3,697,453 A describes the use of phosphate-reduced builder systems with salts of iminodisuccinic acid and up to 40% of polyphosphates for the production of mechanical
  • WO 2006/029806 describes such a phosphate-free formulation for use as a cleaning formulation for machine dishwashing.
  • This formulation contains 1 to 20 wt .-% copolymers, which are composed of the monomers maleic acid, maleic anhydride and acrylic acid, and of isobutene, styrene, etc. are.
  • As a preferred complexing agent Methylglycindiessigklare / MGDA and / or their Na salts claimed.
  • Copolymers based on maleic acid / acrylic acid, which may also be hydrophobed, together with the complexing agents form the builder system in many cleaning formulations.
  • gentle on material within the meaning of the present invention means in particular corrosion protection against color decors or glazes on the dishes to be cleaned, which may preferably consist of glass, porcelain, metal, earthenware or plastic.
  • alkali polyphosphate preferably sodium tripolyphosphate (NTPP) and
  • Na-IDS sodiumiminodisuccinate
  • the builder system to be used according to the invention contains from 25 to 40% by weight of component a) and from 15 to 30% by weight of component b), more preferably from 25 to 35% by weight of component a) and from 15 to 25% by weight .-% component b).
  • Alkali is understood according to the invention potassium and sodium.
  • the combination according to the invention of a) and b) for use in dishwashing detergents is surprising because this combination reaches the level of classic, exclusively phosphate-containing formulations, especially since Na-fDS was classified among the complexing agents only as a moderate complex and the skilled person had to assume that Na-IDS will not show the desired success when used in dishwashing machines.
  • the inventive combination of a) and b) shows in the stated amounts of the individual components over the prior art significantly improved corrosion behavior compared to the material to be cleaned, as the known from the prior art combinations this being the legal requirements for a modern phosphate reduced dishwashing detergent fulfill.
  • the mixture to be used according to the invention may contain, in addition to the two constituents of the constituents alkali nitripolyphosphate and Na-IDS as complexing agent, preferably NTPP and Na-IDS, further constituents which support or improve the action of the two.
  • These constituents include polymers and copolymers (which may also be hydrophobicized), such as polyacrylic acid or its salts, copolymers of acrylic acid with other comonomers or their salts, polycarboxylates based on polyaspartic acid or its salts, carboxymethylcellulose or its salt, oxidized starch or cellulose, meta-cate, phyllosilicates, orthosilicates, carbonates or bicarbonates.
  • the complexing agents to be used according to the invention may contain, in addition to Na-IDs, one or more complexing agents of the series nitrilotriacetic acid or its salts, hydroxyethylenediaminetriacetic acid or salts thereof, ethylenediaminetetraacetic acid or its salts, ethylenetriammapentaacetic acid or its salts, methylglycinediacetic acid or its salts, glutamic diacetic acid or its salts, or hydroxyminodisuccinic acid or its derivatives Salts, ethylenediamine disuccinic acid or salts thereof and also aspartic acid diacetate and salts thereof.
  • Dishwashing detergent formulations according to the invention for machine dishwashing still contain, in addition to the combination of components a) and b) to be used according to the invention c) 1 to 15 wt .-%, preferably 1 to 10 wt .-% low-foaming nonionic surfactants and
  • dishwashing detergent formulations according to the invention may additionally be added
  • dishwashing detergent formulations according to the invention may still be added in addition to the components a) to d) and e) or instead of e)
  • enzymes preferably protease, amylase or lipase.
  • the dishwashing detergent formulations according to the invention may in addition to the components a) to d) and optionally e) and / or f) or parts of one of the components e) or f) still
  • additives such as anionic or zwitterionic ionic surfactants, bleach catalysts, alkali carriers, corrosion inhibitors, defoamers, dyes, fragrances, fillers, organic solvents or water.
  • the formulation may be processed as a tablet, powder, gel, capsule or solution. These may be formulations for both household and commercial applications.
  • Cleaning apparatuses in which the combination of components a) and b) or the cleaning formulations obtainable therefrom can be used are domestic dishwashers, dishwashers in commercial kitchens and dishwashing machines on ships, in vehicles and aircraft, but also apparatus cleaning machines in medical or chemical laboratories.
  • the cleaning formulations according to the invention containing components a) to d) contain weakly or low foaming nonionic surfactants. These are in Generally in proportions of 0.1 to 20 wt .-%, preferably 0.1 to 15 wt .-%, particularly preferably 0.25 to 10 wt .-%.
  • Preferred nonionic surfactants include the surfactants of the general formula (I)
  • R 2 is a linear or branched alkyl radical having 8 to 22 C atoms
  • R 1 and R 3 independently of one another are hydrogen or a linear or branched alkyl radical having 1 to 10 C atoms or H, where R 1 is preferably methyl,
  • p and m are independently 0 to 300.
  • p is an integer from 1 to 5 and m is an integer from 0 to
  • the surfactants of formula (I) may be both random copolymers and block copolymers, preferably block copolymers.
  • di- and multiblock copolymers composed of ethylene oxide and propylene oxide, which (for example, under the name Pluronic ® BASF
  • the formulations may further contain anionic or zwitterionic surfactants, preferably in admixture with nonionic surfactants. Suitable anionic and zwitterionic surfactants are also mentioned in EP-A 851 023 and DE-A 198 19 187.
  • the dishwashing detergent formulations according to the invention comprising component a) to d) comprise bleaching agents and optionally bleach activators.
  • Bleaching agents are subdivided into oxygen bleaching agents and chlorine-containing bleaching agents. Use as oxygen bleach find alkali metal perborates and their hydrates and alkali metal percarbonates.
  • Preferred bleaching agents here are sodium perborate in the form of the mono- or tetrahydrate, sodium percarbonate or the hydrates of sodium percarbonate.
  • oxygen bleaching agents are persulfates and hydrogen peroxide.
  • Typical oxygen bleaching center are also organic peracids such as perbenzoic acid, peroxy-alpha-naphthoic acid, peroxylauric acid, peroxystearic acid, Phthalimidoperoxycapronsäure, 1, 12-diperoxydodecanedioic acid, 1, 9-Diperoxyazelainklare, diperoxoisophthalic or 2-Decyldiperoxybutan-l, 4-diacid.
  • organic peracids such as perbenzoic acid, peroxy-alpha-naphthoic acid, peroxylauric acid, peroxystearic acid, Phthalimidoperoxycapronsäure, 1, 12-diperoxydodecanedioic acid, 1, 9-Diperoxyazelainklare, diperoxoisophthalic or 2-Decyldiperoxybutan-l, 4-diacid.
  • Dishwashing detergent formulation can be used:
  • Oxygen bleaching agents are used in amounts of generally from 0.5 to 30% by weight, preferably from
  • Chlorine-containing bleaches as well as the combination of bleach with peroxide-containing bleaches may also be used.
  • Known chlorine-containing bleaching agents are, for example, 1,3-dichloro-5,5-dimethylhydantoin, N-chlorosulfamide, chloramine T, dichloroamine
  • chlorine-containing bleaching agents are sodium hypochlorite, calcium hypochlorite, potassium hypochlorite, magnesium hypochlorite, potassium dichloroisocyanurate or sodium dichloroisocyanurate.
  • Chlorine-containing bleaching agents are used in amounts of generally from 0.1 to 20% by weight, preferably from 0.2 to 10% by weight, particularly preferably from 0.3 to 8% by weight, based on the total dishwashing detergent formulation ,
  • bleach stabilizers such as phosphonates, borates, metaborates, metasilicates or magnesium salts can be added in small amounts.
  • Bleach activators are compounds which are aliphatic under perhydrolysis conditions
  • Peroxocarbonsäsuren preferably having 1 to 10 carbon atoms, in particular 2 to 4 Carbon atoms, and / or substituted perbenzoic acid.
  • Suitable compounds are those which contain one or more N- or O-acyl groups and / or optionally substituted benzoyl groups, for example substances from the class of the anhydrides, esters, imides, acylated imidazoles or oximes. Examples are tetraacetylethylenediamine (TAED), tetraacetylmethylenediamine (TAMD), tetraacetylglycoluril (TA-GU), tetraacetylhexylenediamine
  • TAED tetraacetylethylenediamine
  • TAMD tetraacetylmethylenediamine
  • TA-GU tetraacetylglycoluril
  • TAHD N-acylimides such as N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates such as n-nonanoyl or isononanoyloxybenzenesulfonates (n- or iso-NOBS), pentaacetylglucose (PAG), l, 5-diacetyl-2 , 2-dioxohexahydr> l, 3,5-triazine (DADHT) or isatoic anhydride (ISA).
  • nitrile quats such as, for example, N-methyl-morpholinium-acetonitrile (MMA salts) or trimethylammonium acetonitrile salts (TMAQ salts).
  • Bleach activators are preferably suitable from the group consisting of polyacylated alkylenediamines, particularly preferably TAED, N-acylimides, particularly preferably NOSI, acylated phenolsulfonates, more preferably n- or iso-NOBS, MMA and TMAQ.
  • Carboxylic acid anhydrides such as phthalic anhydride; acylated polyhydric alcohols such as triacetin, ethylene glycol diacetate or 2,5-diacetoxy-2,5-dihydrofuran; the known from DE-A 19 616 693 and DE-A 19 616 767 enol esters and acetylated sorbitol and
  • acylated sugar derivatives in particular pentaacetylgkycose (PAG), pentaacetyl-fructose, tetraacetyl-xylose and octaacetyl lactose, and acetylated, optionally N-alkylated glucamine and gluconolactone, and / or N-acylated lactams, for example N-benzoyl-caprolactam, which are described in WO 94/27 970, WO 94/28 102, WO 94/28 103, WO 95/00 626, WO 95/14759 and WO 95/17 498 are known.
  • PAG pentaacetylgkycose
  • pentaacetyl-fructose pentaacetyl-fructose
  • tetraacetyl-xylose tetraacetyl-xylose
  • hydrophilically substituted acylacetals listed in DE-A 19 616 769 and the acyl lactams described in DE-A 19 616 770 and WO 95/14075 can be used in the same way as the combinations of conventional bleach activators known from DE-A 44 43 177.
  • Bleach activators are used in amounts of generally from 0.1 to 10% by weight, preferably from 1 to
  • the dishwashing detergent formulations according to the invention which contain components a) to d) may contain further builders. It is possible to use water-soluble and water-insoluble builders whose main task is the binding of calcium and magnesium.
  • R 1 , R 2 and R 3 are independently H, CH 3 or C 2 H 5 ,
  • R 4 denotes a linear, branched or cyclic radical having 1 to 6 carbon atoms or an aromatic radical having 6 to 2 carbon atoms,
  • polycarboxylic acids and their salts such as polyacrytic acid, polymethacrylic acid, copolymers of maleic acid and acrylic acid,
  • Silicates such as sodium disilicate and sodium metasilicate
  • water-soluble binders such as zeolites and crystalline phyllosilicates.
  • Examples of preferred monomers a1) are maleic acid, maleic anhydride, acrylic acid, methacrylic acid, fumaric acid, itaconic acid and citraconic acid.
  • Preferred copolymers a) contain, as monomers a1), monomers selected from the group consisting of maleic acid, maleic anhydride and acrylic acid.
  • Optionally used preferred monomers a2) are, for example, isobutene, diisobutene,
  • copolymers a) contain as monomers a2) monomers which are selected from the group consisting of isobutene, diisobutene (2-methyl-3,3-dimethyl-1-butene) and styrene.
  • Optionally used preferred monomers a3) have at least 10, preferably 10 to 26 carbon atoms.
  • Particularly preferred monomers a3) are 1-decene, 1-dodecane, 1-tetradecene, 1-
  • copolymers a) comprise as monomers a3) monomers which are selected from the group consisting of 1-dodecene, 1-octadecene, C 22 -ot-olefins and polyisobutene having on average 12 to 100 carbon atoms.
  • copolymers a) comprise both monomers a1) selected from maleic acid, maleic anhydride and acrylic acid, as well as monomers a2) which are selected from isobutene, diisobutene and styrene as well as monomers a3) which are selected from the group consisting of 1-dodecene, 1-octadecene, C 22 -ct-Olef ⁇ n, a mixture of C 20 -C 24 -Ct-O lefinen and polyisobutene with an average of 12 to 100 carbon atoms.
  • Particularly preferred are copolymers of 30 to 70 wt .-% maleic acid and maleic anhydride as monomers al),
  • the dishwashing detergent formulations according to the invention containing the components a) to d) can contain enzymes.
  • the dishwashing detergent can be added between 0.1 and 5% by weight of enzymes, based on the total preparation, in order to increase its performance or, under milder conditions, to achieve the same cleaning performance
  • the most commonly used enzymes include lipases, Amylases, cellulases and proteases. Furthermore, for example, esterases, pectinases, lactases and peroxidases can be used.
  • the dishwashing detergent formulations according to the invention which contain components a) to d) may additionally contain, as component g), further additives, such as anionic or zwitterionic surfactants, bleach catalysts, alkali carriers, corrosion inhibitors, defoamers,
  • the sulfone imines and / or bleach-enhancing transition metal salts or transition metal complexes known from EP-A 446 982 and EP-A 453 003 may also be present as so-called bleach catalysts in the dishwashing detergent formulations according to the invention.
  • Suitable transition metal compounds include, for example, the manganese, iron, cobalt, ruthenium or molybdenum complexes known from DE-A 19 529 905 and their N-analogues known from DE-A 19 620 267, which A 19 536 082 known manganese, iron, cobalt, ruthenium or molybdenum carbonyl, which in DE-A 19 605
  • TMTACN 3,4,7-trimethyl-1,4,7-triazacyclononane
  • PF 6 " PF 6 "
  • Suitable bleach catalysts are preferably bleach-enhancing transition metal complexes or transition metal salts from the group consisting of the manganese salts and complexes and the cobalt salts and complexes. Particularly preferred are the cobalt (amane) complexes, the
  • Cobalt (acetate) complexes the cobalt ⁇ carbonyl complexes, the chlorides of cobalt or manganese, manganese sulfate or [(TMTACN) 3 Mn IV Mn IV ( ⁇ -O 3 ) 2+ (PF 6 " ) 2 .
  • Bleach catalysts can be used in amounts of from 0.0001 to 5% by weight, preferably from 0.0025 to 1% by weight, particularly preferably from 0.01 to 0.25% by weight, based on the total dishwashing detergent formulation ,
  • alkali carriers may be present.
  • alkali carriers may be present.
  • Alkali metal sesquicarbonates ammonium and / or alkali metal silicates and mixtures of the aforementioned substances, preference being given to using ammonium and / or alkali metal carbonates, in particular sodium carbonate, sodium bicarbonate or sodium sesquicarbonate.
  • silver protectants from the group of the triazoles, the Benzotriazoie, the Bisbenzotriazole, the Aminotriazoie, the Alkylaminotriazole and the transition metal salts or complexes can be used. Particularly preferred to use are benzotriazole and / or alkylaminotriazole.
  • dishwashing formulations often use active chlorine-containing agents which can markedly reduce the corrosion of the silver surface.
  • oxygen and nitrogen-containing organic redox-active compounds such as di- and trihydric phenols, e.g.
  • salt and complex inorganic compounds such as salts of metals Mn, Ti, Zr, Hf, V, Co and Ce are often used.
  • the transition metal salts which are selected from the group of manganese and / or cobalt salts and / or complexes, more preferably from the group of the cobalt (amine) complexes, the cobalt (acetate) complexes, the cobalt ( carbonyl) complexes, the chlorides of cobalt or manganese and of manganese sulfate.
  • zinc compounds or bismuth compounds can be used to prevent corrosion on the items to be washed.
  • Paraffin oils and silicone oils can be optimally used as defoamers and for the protection of plastic and metal surfaces.
  • Antifoams are preferably used in proportions of 0.001% by weight to 5% by weight.
  • dyes such as patent blue, preservatives such as Kathon CG, perfumes or other fragrances may be added to the dishwashing detergent formulations according to the invention containing components a) and b) and c) and d).
  • the scarf cleaner formulations according to the invention for the automatic cleaning of dishes based on a builder system with the components a) and b) and also the components c) and d) can be used both in powder form and as tabs.
  • NPP Pentasodium triphosphate
  • sodium tripolyphosphate is partially replaced by sodium imino disuccinate, sodium methylglycine diacetate, trisodium citrate and sodium sulfate.
  • VN 1 Basic recipe as above (not according to the invention)
  • VN 2 NTPP reduced to 30%, supplemented by 15.5% Na IDS (according to the invention)
  • VN 3 NTPP reduced to 30%, supplemented by 15.5% Na-MGDA (not according to the invention)
  • VN 4 NTPP reduced to 30%, supplemented with 5.5% Na citrate (not according to the invention)
  • VN 5 NTPP reduced to 25%, supplemented with 20.5% Na IDS
  • VN 6 NTPP reduced to 20%, supplemented by 25.5% Na-IDS
  • VN 7 NTPP reduced to 15%, supplemented with 30.5% Na- ⁇ DS
  • VN 8 NTPP reduced to 10%, supplemented by 35.5% Na-IDS

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention concerne l'utilisation d'un système "builder" à teneur réduite en phosphate à base de tripolyphosphate alcalin et d'iminodisuccinate de sodium de formulations détergentes pour la vaisselle, préservant les matériaux, destinées au lavage automatique, en machine, de la vaisselle.
EP08707986A 2007-01-19 2008-01-18 Détergent pour la vaisselle Not-in-force EP2113024B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102007003885A DE102007003885A1 (de) 2007-01-19 2007-01-19 Geschirrreinigungsmittel
DE102008000029A DE102008000029A1 (de) 2008-01-10 2008-01-10 Geschirrreinigungsmittel
PCT/EP2008/050541 WO2008087200A1 (fr) 2007-01-19 2008-01-18 Détergent pour la vaisselle

Publications (2)

Publication Number Publication Date
EP2113024A1 true EP2113024A1 (fr) 2009-11-04
EP2113024B1 EP2113024B1 (fr) 2012-12-12

Family

ID=39269305

Family Applications (1)

Application Number Title Priority Date Filing Date
EP08707986A Not-in-force EP2113024B1 (fr) 2007-01-19 2008-01-18 Détergent pour la vaisselle

Country Status (12)

Country Link
US (1) US20100144576A1 (fr)
EP (1) EP2113024B1 (fr)
JP (1) JP2010516832A (fr)
CN (1) CN101631848A (fr)
AR (1) AR064974A1 (fr)
CA (1) CA2675811A1 (fr)
CL (1) CL2008000155A1 (fr)
DE (1) DE102007003885A1 (fr)
IL (1) IL199890A0 (fr)
MX (1) MX2009007599A (fr)
TW (1) TW200846463A (fr)
WO (1) WO2008087200A1 (fr)

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DE102007047433A1 (de) * 2007-10-04 2009-04-09 Lanxess Deutschland Gmbh Flüssigwasch- und Flüssigreinigungsmittel
GB2491619B (en) * 2011-06-09 2014-10-01 Pq Silicas Bv Builder granules and process for their preparation
CN103074764A (zh) * 2012-12-19 2013-05-01 青岛天鹅针织有限公司 一种湿巾
DE102013225591A1 (de) * 2013-12-11 2015-06-11 Henkel Ag & Co. Kgaa Maschinelles Geschirrspülmittel enthaltend N-basierte Komplexbildner
DE102013225584A1 (de) * 2013-12-11 2015-06-11 Henkel Ag & Co. Kgaa Maschinelles Geschirrspülmittel enthaltend N-basierte Komplexbildner
WO2016132735A1 (fr) * 2015-02-17 2016-08-25 日本曹達株式会社 Composition de pastille de détergent pour lave-vaisselle et procédé de production de pastille de détergent pour lave-vaisselle
WO2021062632A1 (fr) * 2019-09-30 2021-04-08 Ecolab Usa Inc. Solution de lavage de vaisselle contenant de l'amidon oxydé
CN114634845A (zh) * 2022-03-23 2022-06-17 广州蓝月亮实业有限公司 一种餐具洗涤组合物

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US20100144576A1 (en) 2010-06-10
CL2008000155A1 (es) 2008-07-25
CN101631848A (zh) 2010-01-20
WO2008087200A1 (fr) 2008-07-24
JP2010516832A (ja) 2010-05-20
EP2113024B1 (fr) 2012-12-12
TW200846463A (en) 2008-12-01
CA2675811A1 (fr) 2008-07-24
MX2009007599A (es) 2009-11-23
DE102007003885A1 (de) 2008-07-24
IL199890A0 (en) 2010-04-15
AR064974A1 (es) 2009-05-06

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