EP2097548A1 - Tôle d'acier à haute résistance et à remarquable résistance à l'impact, et son procédé de fabrication - Google Patents
Tôle d'acier à haute résistance et à remarquable résistance à l'impact, et son procédé de fabricationInfo
- Publication number
- EP2097548A1 EP2097548A1 EP07851742A EP07851742A EP2097548A1 EP 2097548 A1 EP2097548 A1 EP 2097548A1 EP 07851742 A EP07851742 A EP 07851742A EP 07851742 A EP07851742 A EP 07851742A EP 2097548 A1 EP2097548 A1 EP 2097548A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- steel sheet
- hot
- cold
- rolling
- manganese
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 134
- 239000010959 steel Substances 0.000 title claims abstract description 134
- 239000011572 manganese Substances 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 33
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 229910052748 manganese Inorganic materials 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 19
- 239000010936 titanium Substances 0.000 claims abstract description 22
- 239000010955 niobium Substances 0.000 claims abstract description 21
- 239000010960 cold rolled steel Substances 0.000 claims abstract description 20
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000010703 silicon Substances 0.000 claims abstract description 18
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 16
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 14
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 6
- 239000011574 phosphorus Substances 0.000 claims abstract description 6
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 6
- 239000011593 sulfur Substances 0.000 claims abstract description 6
- 239000012535 impurity Substances 0.000 claims abstract description 3
- 238000005096 rolling process Methods 0.000 claims description 22
- 230000008569 process Effects 0.000 claims description 19
- 229910001566 austenite Inorganic materials 0.000 claims description 18
- 238000000137 annealing Methods 0.000 claims description 13
- 238000007747 plating Methods 0.000 claims description 12
- 238000005097 cold rolling Methods 0.000 claims description 10
- 238000005098 hot rolling Methods 0.000 claims description 9
- 230000009467 reduction Effects 0.000 claims description 7
- 238000009713 electroplating Methods 0.000 claims description 5
- 230000009977 dual effect Effects 0.000 claims description 3
- 238000004804 winding Methods 0.000 claims description 2
- 238000000151 deposition Methods 0.000 claims 1
- 230000008021 deposition Effects 0.000 claims 1
- 229910000617 Mangalloy Inorganic materials 0.000 abstract description 14
- 238000005482 strain hardening Methods 0.000 abstract description 4
- 239000012071 phase Substances 0.000 description 25
- 230000000694 effects Effects 0.000 description 10
- 230000001965 increasing effect Effects 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 9
- 230000009466 transformation Effects 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 230000003247 decreasing effect Effects 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 229910000734 martensite Inorganic materials 0.000 description 5
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000005728 strengthening Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 3
- 229910052814 silicon oxide Inorganic materials 0.000 description 3
- 238000009864 tensile test Methods 0.000 description 3
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910000794 TRIP steel Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000009749 continuous casting Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- 229910000885 Dual-phase steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 231100000078 corrosiveness Toxicity 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- CADICXFYUNYKGD-UHFFFAOYSA-N sulfanylidenemanganese Chemical compound [Mn]=S CADICXFYUNYKGD-UHFFFAOYSA-N 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Abstract
L'invention concerne une tôle d'acier à haute résistance et degré de façonnabilité élevé compte tenu de son pouvoir d'élongation de sa résistance à l'impact, ainsi que son procédé de fabrication. Cette tôle d'acier à forte teneur en manganèse comprend, en poids: de 0,2 à 1,5 % de carbone (C); de 10 à 25 % de manganèse (Mn); de 0,01 à 3 % d'aluminium (Al); 0,03 % ou moins de phosphore (P); 0,03 % de soufre (S); 0,04 % d'azote (N); au moins un élément pris dans le groupe composé de: silicium (Si), à raison de 0,02 à 2,5 %; titane (Ti) à raison de 0,01 à 0,10 %; et de niobium (Nb) à raison de 0,01 à 0,10 %, le reste étant constitué par du fer et autres puretés inévitables. La tôle d'acier à forte teneur en manganèse peut être obtenue par laminage à chaud, par laminage à froid ou par plaquage et convient pour des tôles intérieures complexes ainsi que pour des éléments de structure pour coque d'automobile compte tenu de son aptitude au façonnage à la presse, de sa capacité d'étirement et de son indice élevé de durcissement à la contrainte. De plus, cette tôle à forte teneur en manganèse peut s'utiliser pour des pièces telles que des parties latérales avant d'une automobile, grâce, en autres caractéristiques, à son remarquable pouvoir d'absorption des chocs.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020060135658A KR100851158B1 (ko) | 2006-12-27 | 2006-12-27 | 충돌특성이 우수한 고망간형 고강도 강판 및 그 제조방법 |
PCT/KR2007/006780 WO2008078940A1 (fr) | 2006-12-27 | 2007-12-24 | Tôle d'acier à haute résistance et à remarquable résistance à l'impact, et son procédé de fabrication |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2097548A1 true EP2097548A1 (fr) | 2009-09-09 |
EP2097548A4 EP2097548A4 (fr) | 2010-02-24 |
Family
ID=39562686
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07851742A Withdrawn EP2097548A4 (fr) | 2006-12-27 | 2007-12-24 | Tôle d'acier à haute résistance et à remarquable résistance à l'impact, et son procédé de fabrication |
Country Status (6)
Country | Link |
---|---|
US (1) | US20090074605A1 (fr) |
EP (1) | EP2097548A4 (fr) |
JP (1) | JP5393459B2 (fr) |
KR (1) | KR100851158B1 (fr) |
CN (1) | CN101432456A (fr) |
WO (1) | WO2008078940A1 (fr) |
Families Citing this family (55)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2878257B1 (fr) * | 2004-11-24 | 2007-01-12 | Usinor Sa | Procede de fabrication de toles d'acier austenitique, fer-carbone-manganese a tres hautes caracteristiques de resistance et d'allongement, et excellente homogeneite |
KR101020546B1 (ko) * | 2008-07-18 | 2011-03-09 | 현대자동차주식회사 | 초고강도 twip 강판 및 그 제조방법 |
KR101113666B1 (ko) | 2008-08-13 | 2012-02-14 | 기아자동차주식회사 | 초고강도 트윕 강판 및 그 제조방법 |
KR101054773B1 (ko) * | 2008-09-04 | 2011-08-05 | 기아자동차주식회사 | Twip형 초고강도 강판의 제조방법 |
EP2208803A1 (fr) | 2009-01-06 | 2010-07-21 | ThyssenKrupp Steel Europe AG | Acier à résistance élevée, formable à froid, produit plat en acier, procédé de fabrication d'un produit plat en acier et utilisation du produit plat en acier |
US20120045358A1 (en) * | 2009-04-28 | 2012-02-23 | Hyundai Steel Company | High manganese nitrogen-containing steel sheet having high strength and high ductility, and method for manufacturing the same |
DE102010034161B4 (de) * | 2010-03-16 | 2014-01-02 | Salzgitter Flachstahl Gmbh | Verfahren zur Herstellung von Werkstücken aus Leichtbaustahl mit über die Wanddicke einstellbaren Werkstoffeigenschaften |
DE102010018602A1 (de) * | 2010-04-28 | 2011-11-03 | Volkswagen Ag | Verwendung eines hochmanganhaltigen Leichtbaustahls für Strukturbauteile eines Fahrzeugsitzes sowie Fahrzeugsitz |
BR112012031466B1 (pt) * | 2010-06-10 | 2019-07-09 | Tata Steel Ijmuiden Bv | Método de produção de uma chapa de aço austenítica excelente em resistência à fratura retardada e tira ou chapa |
EP2402472B2 (fr) † | 2010-07-02 | 2017-11-15 | ThyssenKrupp Steel Europe AG | Acier à résistance élevée pouvant être déformé à froid et produit plat en acier constitué d'un tel acier |
WO2012052626A1 (fr) | 2010-10-21 | 2012-04-26 | Arcelormittal Investigacion Y Desarrollo, S.L. | Tole d'acier laminee a chaud ou a froid, don procede de fabrication et son utilisation dans l'industrie automobile |
KR101280500B1 (ko) | 2010-11-22 | 2013-07-01 | 포항공과대학교 산학협력단 | 수소지연파괴 저항성이 우수한 고강도 고망간 강선재 및 그 제조방법 |
CN102127704B (zh) * | 2011-03-02 | 2012-11-28 | 武汉钢铁(集团)公司 | 900MPa级高强度高塑性中碳热轧钢及其制造方法 |
JP5856002B2 (ja) * | 2011-05-12 | 2016-02-09 | Jfeスチール株式会社 | 衝突エネルギー吸収能に優れた自動車用衝突エネルギー吸収部材およびその製造方法 |
EP2796585B1 (fr) * | 2011-12-23 | 2017-09-27 | Posco | Feuille d'acier à haute teneur en manganèse, non magnétique, ayant une haute résistance et son procédé de fabrication |
CN104334460A (zh) * | 2012-06-06 | 2015-02-04 | 杰富意钢铁株式会社 | 三片罐及其制造方法 |
KR101406400B1 (ko) * | 2012-06-08 | 2014-06-13 | 주식회사 포스코 | 용접성 및 가공성이 우수한 초고강도 강판 및 그 제조방법 |
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KR102020406B1 (ko) * | 2017-12-21 | 2019-09-10 | 주식회사 포스코 | 항복강도 및 성형성이 우수한 고강도 강판 및 이의 제조방법 |
KR102020386B1 (ko) | 2017-12-24 | 2019-09-10 | 주식회사 포스코 | 고 강도 오스테나이트계 고 망간 강재 및 그 제조방법 |
CN108467991B (zh) * | 2018-03-12 | 2020-09-29 | 上海交通大学 | 一种用于超低温的高强韧高锰钢及其热处理工艺 |
CN109097680B (zh) * | 2018-08-10 | 2020-07-28 | 宝武集团鄂城钢铁有限公司 | 一种使用50t中频感应炉冶炼制得的高锰高铝无磁钢板的制造方法 |
KR102290780B1 (ko) * | 2018-10-25 | 2021-08-20 | 주식회사 포스코 | 항복강도가 우수한 오스테나이트계 고망간 강재 및 그 제조방법 |
WO2020085852A1 (fr) * | 2018-10-25 | 2020-04-30 | 주식회사 포스코 | Acier austénitique à haute teneur en manganèse ayant une haute limite d'élasticité et son procédé de fabrication |
CN111850419A (zh) * | 2020-07-31 | 2020-10-30 | 燕山大学 | 一种高锰奥氏体钢及其制备方法 |
KR20230072727A (ko) * | 2021-11-18 | 2023-05-25 | 주식회사 포스코 | 내마모성이 우수한 열연강판, 강관 및 이들의 제조방법 |
WO2023212717A1 (fr) * | 2022-04-29 | 2023-11-02 | United States Steel Corporation | Alliages d'acier à faible teneur en ni ayant une résistance à la dégradation par l'hydrogène |
CN117265419A (zh) * | 2022-06-15 | 2023-12-22 | 宝山钢铁股份有限公司 | 强度1000-1600MPa的高成形性、易磷化高锰冷轧钢板及其制造方法 |
CN115961213A (zh) * | 2022-12-19 | 2023-04-14 | 江苏鸿泰钢铁有限公司 | 一种高屈服强度的钢材及其制备方法 |
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2007
- 2007-12-24 EP EP07851742A patent/EP2097548A4/fr not_active Withdrawn
- 2007-12-24 US US12/298,959 patent/US20090074605A1/en not_active Abandoned
- 2007-12-24 WO PCT/KR2007/006780 patent/WO2008078940A1/fr active Application Filing
- 2007-12-24 CN CNA2007800156253A patent/CN101432456A/zh active Pending
- 2007-12-24 JP JP2009523729A patent/JP5393459B2/ja active Active
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WO2005019483A1 (fr) * | 2003-07-22 | 2005-03-03 | Usinor | Procede de fabrication de toles d’acier austenitique fer-carbone-manganese, a haute resistance, excellente tenacite et aptitude a la mise en forme a froid, et toles ainsi produites |
WO2006082104A1 (fr) * | 2005-02-02 | 2006-08-10 | Corus Staal Bv | Acier austenitique a tenue et aptitude au formage elevees, procede de production dudit acier et son utilisation |
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Also Published As
Publication number | Publication date |
---|---|
WO2008078940A1 (fr) | 2008-07-03 |
KR20080060982A (ko) | 2008-07-02 |
KR100851158B1 (ko) | 2008-08-08 |
EP2097548A4 (fr) | 2010-02-24 |
JP5393459B2 (ja) | 2014-01-22 |
JP2009545676A (ja) | 2009-12-24 |
US20090074605A1 (en) | 2009-03-19 |
CN101432456A (zh) | 2009-05-13 |
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