EP2094087B1 - Pesticidal compositions - Google Patents
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- EP2094087B1 EP2094087B1 EP07859856.2A EP07859856A EP2094087B1 EP 2094087 B1 EP2094087 B1 EP 2094087B1 EP 07859856 A EP07859856 A EP 07859856A EP 2094087 B1 EP2094087 B1 EP 2094087B1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/32—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing heterocyclic radicals
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
- A61P33/14—Ectoparasiticides, e.g. scabicides
Definitions
- the present invention relates to pesticidal compositions comprising anthranilamide compounds of the formula (I) described hereinafter or their salts and other pesticides.
- an organophosphorus compound, a carbamate compound, a pyrethroid compound or the like has been used as an effective ingredient for an insecticide, but as this result, some insects have had a resistance to these insecticides in recent years. Therefore, it is demanded to provide an insecticide effective for these insects having a resistance.
- Patent Document 1 An anthranilamide compound of the formula (I) described hereinafter or its salt is disclosed in Patent Document 1. Further, Patent Document 2 discloses in test A and test C at pages 83 to 85 a controlling effect of a combination of a specific anthranilamide compound with imidacloprid or thiamethoxam against diamondback moth or aphid.
- Conventional pesticides have respectively characteristic spectrums and effects, but have some problems that the effects are sometimes unsatisfactory to certain pests, that their residual activities are sometimes poor and the effects are not satisfactorily maintained for a certain period of time, and that satisfactory pesticidal effects can not be practically achieved depending on applications. Also, even if there are some pesticides excellent in their pesticidal effects, they are demanded to be improved in respect of safety to fishes, crustacea and domestic animals and are also demanded to achieve a high pesticidal effect at a small dosage.
- the present inventors have intensively studied to solve these problems, and as a result of the study, they have discovered that by combining an anthranilamide compound of the following formula (I) or its salt with other pesticide, unexpected effects of killing pests grown in some place by one time and reducing a dosage than in a case of using an active compound respectively alone, can be achieved.
- the present invention has been accomplished on the basis of this discovery.
- the present invention provides A pesticidal composition
- a pesticidal composition comprising an anthranilamide compound or its salt and other insecticide and/or fungicide, wherein the weight ratio of the anthranilamide compound or its salt to the insecticide and/or fungicide is from 1:40000 to 100:1, wherein the anthranilamide compound is N-[2-bromo-4-chloro-6-[[ ⁇ -methyl-(cyclopropylmethyl)amino]carbonyl]-phenyl]-3-bromo-1-(3-chloro-2-pyridyl)-1H-pyrazole-5-carboxamide, wherein the insecticide is at least one member selected from the group consisting of organophosphorus compounds, carbamate compounds, pyrethroid compounds, neonicotinoide compounds, benzoylurea compounds, nereistoxin derivatives, hydrazine compounds, juvenile hormone-like compounds, antibiotics, semisynthetic antibiotics, pyrrole compounds, thiadia
- the present invention further provides a non-therapeutical method for controlling pests by applying synergistically effective amounts of the above anthranilamide compound or its salt and other pesticide.
- the salt of the anthranilamide compound includes all kinds so long as they are agriculturally acceptable.
- an alkali metal salt such as a sodium salt or a potassium salt
- an alkaline earth metal salt such as a magnesium salt or a calcium salt
- an ammonium salt such as a dimethylammonium salt or a triethylammonium salt
- an inorganic acid salt such as a hydrochloride, a perchlorate, a sulfate or a nitrate
- an organic acid salt such as an acetate or a methanesulfonate
- the anthranilamide compound of the formula (I) may have optical isomers or geometrical isomers, and such isomers and mixtures thereof are both included in the present invention. Further, in the present invention, various isomers other than those mentioned above, may be included within the scope of the common knowledge in this technical field. Further, depending upon the type of such an isomer, the chemical structure may be different from the above-mentioned formula (I), but it is obvious to one skilled in the art that such a structure is in isomeric relation and thus falls within the scope of the present invention.
- the anthranilamide compound of the above formula (I) or its salt can be obtained by the method disclosed in Patent Document 1.
- the pesticidal composition of the present invention has a stably high pesticidal effect against pests, and pests can be controlled by this composition.
- Preferred compounds as the insecticide are exemplified below.
- compositions of the present invention are particularly useful, for example, as agents for controlling various pests which become problematic in the agricultural and horticultural fields, i.e. agricultural and horticultural pesticides, agents for controlling sanitary insect pests which are sanitarily harmful to the human, i.e. control agents against sanitary insect pests, agents for controlling pests harmful to trees and turf, i.e. control agents against pests on trees and turf, agents for controlling pests harmful to clothes and household goods, i.e. control agents against clothes and household goods insect pests, and agents for controlling pests which are parasitic on animals i.e. pesticides against parasites on animals.
- agricultural and horticultural pesticides agents for controlling sanitary insect pests which are sanitarily harmful to the human, i.e. control agents against sanitary insect pests, agents for controlling pests harmful to trees and turf, i.e. control agents against pests on trees and turf, agents for controlling pests harmful to clothes and household goods, i.e. control agents against clothes and household goods insect pest
- the agricultural and horticultural pesticides are useful as an insecticide, a miticide, a nematicide, a soil pesticide and a fungicide, and they are effective for controlling plant parasitic mites such as two-spotted spider mite ( Tetranychus urticae ), carmine spider mite ( Tetranychus cinnabarinus ), kanzawa spider mite ( Tetranychus kanzawai ), citrus red mite ( Panonychus citri ), European red mite ( Panonychus ulmi ), broad mite ( Polyphagotarsonemus latus ), pink citrus rust mite ( Aculops pelekassi ) and bulb mite ( Rhizoglyphus echinopus ); agricultural insect pests such as diamondback moth ( Plutella xylostella ), cabbage armyworm ( Mamestra brassicae ), common cutworm ( Spodoptera litura ), codling moth ( Laspeyresia pomonella ), boll
- the fungicides are effective for controlling diseases such as blast, brown spot or sheath blight of rice ( Oryza sativa, etc.); powdery mildew, scab, rust, snow mold, snow blight, loose smut, eye spot, leaf spot or glume blotch of cereals ( Hordeum vulgare , Tricum aestivum , etc.); melanose or scab of citrus ( Citrus spp., etc.); blossom blight, powdery mildew, Alternaria leaf spot or scab of apple ( Malus pumila ); scab or black spot of pear ( Pyrus serotina , Pyrus ussuriensis , Pyrus communis ); brown rot, scab or Phomopsis rot of peach ( Prunus persica , etc.); anthracnose, ripe rot, powdery mildew or downy mildew of grape ( Vitis vinifera spp., etc.); anthracnose,
- controlling agents against sanitary insect pests they are effective for controlling insects which carry pathogen to infect human with diseases, such as Culex tritaenitorhynchus , Aedes aegypt i, Anopheles , Aedes albopictus , Anopheles sinensis , Aedes togoi , Mansonia, Aedes , Phlebotominae , Agriosphodrus , tsetse fly ( Glossina ), house mosquito ( Culex pipiens ), tropical rat mite ( Ornithonyssus bacoti ), housefly ( Musca domestica ), cockroaches, Simulium, Chrysops, flea ( Siphonaptera ), tick ( Ixodoidea ), Trombiculidae and louse ( Anoplura ), insects which directly harm human by blood sucking, biting or the like, such as hornet ( Vespinae ),
- control agents against pests on trees and turf they are effective for controlling trees pests such as Bursaphelenchus xylophilus, Monochamus alternatus, Lymantria dispar, Monema flavescens, Hyphantria cunea, bagworm ( Psychidae ), Ceroplastes , Coccoidea , Stephanitis pyrioides and Dendrolimus spectabilis; and pests against turf such as Scarabaeidae , Spodoptera depravata, Parapediasia teterrella , hunting billbug ( Sphenophorus venatus ) and Gryllotalpidae .
- trees pests such as Bursaphelenchus xylophilus, Monochamus alternatus, Lymantria dispar, Monema flavescens, Hyphantria cunea, bagworm ( Psychidae ), Ceroplastes , Coccoidea , Stephanitis pyri
- control agents against clothes and household goods insect pests they are effective for controlling case making clothes moth ( Tinea pellionella ), black carpet beetle ( Anthrenus scrophularidae ) and termite ( Rhinotermitidae ).
- the agricultural and horticultural pesticides are particularly effective for controlling plant parasitic mites, agricultural insect pests, plant parasitic nematodes, various diseases or the like. Further, they are effective against insect pests having acquired resistance to organophosphorus, carbamate and/or synthetic pyrethroid insecticides.
- the compounds of the formula (I) have excellent systemic properties, and by the application of the compounds of the formula (I) to soil treatment, not only noxious insects, noxious mites, noxious nematodes, noxious gastropods and noxious isopods in soil but also foliage pests can be controlled.
- the pesticides against parasites on animals are effective for controlling e.g. external parasites which are parasitic on the body surface of host animals (such as the back, the axilla, the lower abdomen or inside of the thigh) or internal parasites which are parasitic in the body of host animals (such as the stomach, the intestinal tract, the lung, the heart, the liver, the blood vessels, the subcutis or lymphatic tissues), but they are particularly effective for controlling the external parasites.
- external parasites which are parasitic on the body surface of host animals (such as the back, the axilla, the lower abdomen or inside of the thigh) or internal parasites which are parasitic in the body of host animals (such as the stomach, the intestinal tract, the lung, the heart, the liver, the blood vessels, the subcutis or lymphatic tissues), but they are particularly effective for controlling the external parasites.
- the external parasites may, for example, be animal parasitic acarina or fleas. Their species are so many that it is difficult to list all of them, and therefore, their typical examples will be given.
- the animal parasitic acarina may, for example, be ticks such as Boophilus microplus, Rhipicephalus sanguineus , Haemaphysalis longicornis , Haemaphysalis flava , Haemaphysalis campanulata , Haemaphysali s concinna, Haemaphysalis japonica, Haemaphysalis kitaokai, Haemaphysalis ias , Ixodes ovatus, Ixodes nipponensis, Ixodes persulcatus, Amblyomma testudinarium, Haemaphysalis megaspinosa , Dermacentor reticulatus, and Dermacentor taiwanesis; common red mite ( Dermanyssus gallinae ); northern fowl mites such as Ornithonyssus sylviarum , and Or
- the fleas may, for example, be externally parasitic wingless insects belonging to Siphonaptera, more specifically, fleas belonging to Pulicidae , Ceratephyllus, etc.
- Fleas belonging to Pulicidae may, for example, be Ctenocephalides canis, Ctenocephalides felis , Pulex irritans, Echidnophaga gallinacea, Xenopsylla cheopis, Leptopsylla segnis , Nosopsyllus fasciatus, and Monopsyllus anisus.
- the pesticides against parasites on animals are particularly effective for the control of fleas belonging to Pulicidae, particularly Ctenocephalides canis and Ctenocephalides felis, among them.
- Other external parasites may, for example, be sucking lice ( Anoplura ) such as shortnosed cattle louse ( Haematopinus eurysternus ), horse sucking louse ( Haematopinus asini ), sheep louse, longnosed cattle louse ( Linognathus vituli ), and head louse ( Pediculus capitis ); biting lice such as dog biting louse ( Trichodectes canis ); and blood-sucking dipterous insects such as horsefly ( Tabanus trigonus ), biting midges ( Culicoides schultzei ), and blackfly ( Simulium ornatum ).
- sucking lice Anoplura
- Anoplura such as shortnosed cattle louse ( Haematopinus eurysternus ), horse sucking louse ( Haematopinus asini ), sheep louse, longnosed cattle louse ( Linognathus
- the internal parasites may, for example, be nematodes such as lung worms, whipworms ( Trichuris ), tuberous worms, gastric parasites, ascaris, and filarioidea; cestoda such as Spirometra erinacei , Diphyllobothrium latum, Dipylidium caninum , Taenia multiceps , Echinococcus granulosus and Echinococcus multilocularis ; trematoda such as Schistosoma japonicum and Fasciola hepatica; and protozoa such as coccidia, malaria parasites ( Plasmodium malariae ), intestinal sarcocyst, toxoplasma, and cryptosporidium.
- nematodes such as lung worms, whipworms ( Trichuris ), tuberous worms, gastric parasites, ascaris, and filarioidea
- cestoda such as Spirometra erin
- the host animals may, for example, be pet animals, domestic animals, and poultry, such as dogs, cats, mice, rats, hamsters, guinea pigs, squirrels, rabbits, ferrets, birds (such as pigeons, parrots, hill mynas, Java sparrows, honey parrots, lovebirds and canaries), cows, horses, pigs, sheep, ducks and chickens.
- the pesticides against parasites on animals are particularly effective for the control of pests parasitic on pet animals or domestic animals, especially for the control of external parasites, among them.
- pet animals or domestic animals they are effective particularly for dogs, cats, cows and horses.
- the weight ratio of the active compounds of at least one compound of the formula (I) or its salt to other pesticide is from 1:100,000 to 100,000:1, preferably from 1:40,000 to 40,000:1, more preferably from 1:40,000 to 100:1.
- the pesticidal composition of the present invention is, in the same manner as conventional agricultural chemicals, formulated together with agricultural adjuvants into an emulsifiable concentrate, a dust, granules, a wettable powder, water-dispersible granules, a suspension concentrate, a soluble concentrate, an aerosol, a paste, etc. That is, the pesticidal composition of the present invention may be formulated by mixing the respective active compounds, or by mixing formulations of the respective active compounds.
- the ratio of the agricultural adjuvants is from 1 to 99.999 parts by weight based on from 0.001 to 99 parts by weight of the active compounds, preferably from 5 to 99.99 parts by weight based on from 0.01 to 95 parts by weight, more preferably from 20 to 99.99 parts by weight based on from 0.01 to 80 parts by weight. In the actual application of such a formulation, it may be used as it is, or may be diluted to a predetermined concentration with a diluent such as water.
- the agricultural adjuvants there may be mentioned carriers, emulsifiers, suspending agents, dispersants, extenders, penetrating agents, wetting agents, thickeners, defoaming agents, stabilizers or antifreezing agents. They may be added as the case requires.
- the carriers may be classified into solid carriers and liquid carriers.
- solid carriers there may be mentioned powders of animal and plant origin, such as starch, activated carbon, soybean flour, wheat flour, wood powder, fish powder or powdered milk; or mineral powders such as talc, kaolin, bentonite, calcium carbonate, zeolite, diatomaceous earth, white carbon, clay or alumina; sulfur powder; anhydrous sodium sulfate; and the like.
- liquid carriers there may be mentioned water; alcohols such as methyl alcohol or ethylene glycol; ketones such as acetone, methyl ethyl ketone or N-methyl-2-pyrrolidone; ethers such as dioxane or tetrahydrofuran; aliphatic hydrocarbons such as kerosine, gas oil or the like; aromatic hydrocarbons such as xylene, trimethylbenzene, tetramethylbenzene, cyclohexane or solvent naphtha; halogenated hydrocarbons such as chloroform or chlorobenzene; acid amides such as dimethylformamide; esters such as ethyl acetate or glycerine ester of a fatty acid; nitriles such as acetonitrile; sulfur-containing compounds such as dimethyl sulfoxide; vegetable oils such as soybean oil or corn oil; and the like.
- alcohols such as methyl alcohol or ethylene glycol
- ketones such as acetone,
- the pesticidal composition of the present invention is applied in an active ingredient concentration of a compound of the formula (I) or its salt of from 0.001 to 100,000 ppm, preferably from 0.005 to 50,000 ppm, more preferably from 0.005 to 20,000 ppm, and in an active ingredient concentration of other pesticide of from 0.0001 to 100,000 ppm, preferably from 0.0025 to 50,000 ppm, more preferably from 0.0025 to 20,000 ppm.
- the active ingredient concentration may optionally be changed depending upon the formulation, the manner, purpose, timing or place of the application and the condition of the insect pests. For instance, aquatic noxious insects can be controlled by applying a formulation having the above-mentioned concentration to the site of the outbreak, and thus, the concentration of the active ingredient in water is less than the above-mentioned range.
- the amount of the application of the active ingredient per unit surface area is usually from about 0.001 to 50,000 g, preferably from 0.005 to 10,000 g, per hectare as an active ingredient of a compound of the formula (I) or its salt, and from about 0.0001 to 50,000, preferably from 0.0025 to 10,000 g, per hectare as an active ingredient of other pesticide. However, in a certain special case, the amount of the application may be outside the above range.
- Various formulations containing the compounds of the present invention or their diluted compositions may be applied by conventional methods for application which are commonly employed, such as spraying (e.g. spraying, jetting, misting, atomizing, powder or grain scattering or dispersing in water), soil application (e.g.
- the active ingredient may also be applied by a so-called ultra low-volume application method. In this method, the composition may be composed of 100% of the active ingredient.
- a compound of the formula (I) or its salt may be mixed with or may be used in combination with other agricultural chemicals, fertilizers or phytotoxicity-reducing agents, whereby synergistic effects or activities may sometimes be obtained.
- Such other agricultural chemicals include, for example, a herbicide, an antivirus agent, an attractant, a plant hormone and a plant growth regulating agent.
- a pesticidal composition having a compound of the formula (I) or its salt mixed with or used in combination with one or more active compounds of other agricultural chemicals the application range, the application time, the pesticidal activities, etc. may be improved to preferred directions.
- Each active compounds may separately be formulated so that they may be mixed for use at the time of application, or they may be formulated together.
- the present invention includes such a pesticidal composition.
- the agricultural chemicals which may be mixed with or may be used in combination with the compound of the formula (I) or its salt may, for example, be active compounds of herbicides as disclosed in Farm Chemicals Handbook (2002 ), particularly soil application type.
- the above components are uniformly mixed to obtain a wettable powder.
- the above components are uniformly mixed to obtain a dust.
- a mixture of the above respective components, Compound No. 1 and azadiractin are mixed in a weight ratio of 7:2:1 to obtain a wettable powder.
- the above components (1) to (5) are uniformly mixed and pulverized to obtain a base liquid, to which the above components (6) and (7) are added, and the mixture is uniformly mixed, granulated and dried to obtain water-dispersible granules.
- the above components (1) to (4) are preliminarily uniformly mixed and diluted with a proper amount of acetone, and then the mixture is sprayed onto the component (5), and acetone is removed to obtain granules.
- the above components are uniformly mixed and dissolved to obtain an ultra low volume formulation.
- the above components are uniformly mixed and pulverized to obtain a water-based suspension concentrate.
- an emulsifiable concentrate prepared by uniformly mixing and dissolving Compound No. 1, an emulsifying agent (SORPOL 2806B) and N,N-dimethylacetamide in a ratio of 5:5:90, and a commercially available insecticide or a commercially available fungicide were used. They were diluted to a predetermined concentration with water containing a spreader (Shin-Rinoh 0.04%) and subjected to the test by themselves or as a mixed liquid.
- SORPOL 2806B emulsifying agent
- N,N-dimethylacetamide in a ratio of 5:5:90
- a commercially available insecticide or a commercially available fungicide were used. They were diluted to a predetermined concentration with water containing a spreader (Shin-Rinoh 0.04%) and subjected to the test by themselves or as a mixed liquid.
- a leaf segment of cabbage was dipped for about 10 seconds in an insecticidal solution and dried in air.
- a wet filter paper was laid in a petri dish having a diameter of 9 cm, and the dried leaf segment of cabbage was placed thereon.
- 10 Second-instar larvae of common cutworm were released therein and after putting a cover, left in a constant temperature chamber at 25°C with lightening.
- dead larvae were counted, and the mortality was calculated by the following equation.
- the insects that were moribund were counted as dead insects.
- the test results are shown in Tables 1 to 35.
- Mortality % number of dead insects / number of surviving insects + number of dead insects ⁇ 100
- the theoretical mortality (%) can be calculated from the colby's formula.
- the pesticidal composition of the present invention has a synergistic effect regarding controlling of pests.
- the theoretical mortality (%) by the colby's formula are shown in brackets in Tables 1 to 35.
- Japanese radish leaf (cut into about 2 cm x 3 cm) was put in a test tube in which water was put, and Larvae of green peach aphid were released on the leaf.
- the larvae on the leaf were counted, and the leaf infested with the larvae was dipped for about 10 seconds in an insecticidal solution, dried in air and left in a constant temperature chamber at 25°C with lightening.
- dead larvae were counted, and the mortality was calculated from the following equation. Aphids that dropped from leaf or were moribund were included in the number of dead. The evaluation results are shown in Tables 36 to 45.
- Mortality % number of dead insects / number of tretead insects / 100 TABLE 36 Flonicamid (ppm) Compound No. 1 (ppm) 1.5 0.8 0 1.5 100(84) 82(67) 46 0.8 89(72) 80(43) 8 0 70 38 TABLE 37 Azadirachtin (ppm) Compound No. 1 (ppm) 12.5 6.2 0 1.5 100(94) 100(46) 46 0.8 100(89) 85(8) 8 0 88 0 TABLE 38 Bifenthrin (ppm) Compound No.
- a rice seedling was dipped for about 10 seconds in an insecticidal solution and dried in air.
- the root was wrapped with absorbent cotton wet with water, and the rice seedling was put in a test tube.
- 5 Second-instar larvae of green rice leafhopper were released therein, and after covering the opening of the test tube with gauze, left in a constant temperature chamber at 25°C with lightening (two replications were made).
- dead larvae were counted, and the mortality was calculated by the following equation.
- the insects that were moribund were counted as dead insects.
- the test results are shown in Tables 46 to 51.
- Mortality % number of dead insects / number of surviving insects + number of dead insects ⁇ 100
- the pesticidal composition of the present invention provides a percent inhibition of emergence (%) higher than the theoretical value (%) and thereby has a synergistic effect regarding controlling of pests.
- the theoretical mortality (%) can be calculated by the colby's formula.
- the pesticidal composition of the present invention provides a mortality (%) higher than the theoretical mortality (%) and is thereby has a synergistic effect regarding controlling of pests.
- Knockdown rate % number of knockdown ticks / number of released larvae ⁇ 100
- the pesticidal composition of the present invention provides a knockdown rate (%) higher than the theoretical knockdown rate (%) and thereby has a synergistic effect regarding controlling of pests.
- the theoretical mortality (%) can be calculated by the Colby's formula.
- the pesticidal composition of the present invention provides a mortality (%) higher than the theoretical mortality (%) and thereby has a synergistic effect regarding controlling of pests.
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DE10353281A1 (de) * | 2003-11-14 | 2005-06-16 | Bayer Cropscience Ag | Wirkstoffkombination mit insektiziden und akariziden Eigenschaften |
DE102004021564A1 (de) * | 2003-11-14 | 2005-07-07 | Bayer Cropscience Ag | Wirkstoffkombinationen mit insektiziden Eigenschaften |
DE102004006075A1 (de) * | 2003-11-14 | 2005-06-16 | Bayer Cropscience Ag | Wirkstoffkombinationen mit insektiziden Eigenschaften |
US8821898B2 (en) * | 2003-12-04 | 2014-09-02 | Bayer Cropscience Ag | Active compound combinations having insecticidal and acaricidal properties |
KR100870171B1 (ko) * | 2003-12-04 | 2008-11-24 | 바이엘 크롭사이언스 아게 | 살충성을 가지는 활성 물질 배합물 |
KR100963370B1 (ko) * | 2004-02-18 | 2010-06-14 | 이시하라 산교 가부시끼가이샤 | 안트라닐아미드계 화합물, 그의 제조 방법 및 그것을함유하는 유해 생물 방제제 |
CA2585378A1 (en) * | 2004-11-18 | 2006-05-26 | E.I. Du Pont De Nemours And Company | Anthranilamide insecticides |
WO2006118267A1 (ja) * | 2005-05-02 | 2006-11-09 | Ishihara Sangyo Kaisha, Ltd. | アントラニルアミド系化合物、それらの製造方法及びそれらを含有する有害生物防除剤 |
TWI317316B (en) * | 2005-12-02 | 2009-11-21 | Watlow Electric Mfg | Split-sleeve heater and removal tool |
JP5449669B2 (ja) * | 2006-12-14 | 2014-03-19 | 石原産業株式会社 | 有害生物防除組成物 |
JP5507045B2 (ja) * | 2006-12-15 | 2014-05-28 | 石原産業株式会社 | アントラニルアミド系化合物の製造方法 |
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