EP2077312A1 - Brennstoffe für homogen geladene verdichtungsgezündete Maschinen - Google Patents

Brennstoffe für homogen geladene verdichtungsgezündete Maschinen Download PDF

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Publication number
EP2077312A1
EP2077312A1 EP08021384A EP08021384A EP2077312A1 EP 2077312 A1 EP2077312 A1 EP 2077312A1 EP 08021384 A EP08021384 A EP 08021384A EP 08021384 A EP08021384 A EP 08021384A EP 2077312 A1 EP2077312 A1 EP 2077312A1
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EP
European Patent Office
Prior art keywords
fuel
percent
less
volume
engine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP08021384A
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English (en)
French (fr)
Inventor
Gen Shibata
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Eneos Corp
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Nippon Oil Corp
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Filing date
Publication date
Application filed by Nippon Oil Corp filed Critical Nippon Oil Corp
Publication of EP2077312A1 publication Critical patent/EP2077312A1/de
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/04Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/08Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852Ethers; Acetals; Ketals; Orthoesters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters

Definitions

  • spark ignition gasoline engine fuel is injected into the intake port or the combustion chamber, and premixed gas of air fuel mixture is formed. Then the premixed gas is ignited by a spark plug and combusted.
  • the fuel is required to have high vaporization and low auto-ignitability characteristics. Since the spark ignition gasoline engine emits nitrogen oxides (NOx), hydrocarbons (HC) and carbon monoxide, a three-way catalyst has been widely used for purifying these emissions. However, an exhaust gas purification system such as a three-way catalyst is only applicable to a range where the air-fuel ratio is in a very narrow range of stoichiometric air-fuel ratio and it is the causes of low thermal efficiency and poor fuel consumption comparing with the compression ignition diesel engine.
  • a high temperature combustion region the temperature of which is higher than 2200K, is not locally formed in the cylinder and this is the cause of low NOx emission characteristics (less than 10 ppm by mass) without a reduction catalyst.
  • the thermal efficiency and fuel consumption of the homogeneous charge compression ignition engine are equivalent to those of the diesel engine.
  • Fig. 5 shows the change in maximum pressure rise rate at Point 3 over 400 cycles.
  • Fig. 3 shows the changes in maximum pressure rise rate over 400 cycles at Point 1
  • Fig. 4 shows the changes in maximum pressure rise rate over 400 cycles at Point 2
  • Fig. 5 shows the changes in maximum pressure rise rate over 400 cycles at Point 3.
  • NTL series fuels corresponding to the fuel of the present invention are reduced in maximum pressure rise rate by 20 percent or greater, comparing with PRF series fuels (PRF90, PRF85) when they were used under the same operation conditions (same IMEP, same HTHR CA50). Further, when the fuels other than Comparative Example 1 (NDB fuel, NMP fuel) are compared with the NTL series fuels of Example 1, none of the other fuels can reduce the maximum pressure rise rate as much as the fuels of Example 1.
  • NTL series fuels (NTL75, NTL80, NTL85) according to the present invention exhibited an increase by 28 to 113 percent in indicated mean effective pressure, compared with comparative fuels (PRF series fuels, NDB series fuels, NMP series fuels, NCP series fuels) under the same maximum pressure rise rate condition.
  • PRF series fuels NDB series fuels
  • NMP series fuels NCP series fuels
  • Figs. 7 , 9 and 11 this is because the fuel of the present invention prolongs combustion period by utilizing difference in ignition temperature between a component containing mainly a paraffinic fuel and a component containing mainly an aromatic fuel so as to avoid the rapid combustion of the fuel and thus the more fuel can be combusted under the same maximum pressure rise rate, thereby increasing the heat release rate.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Combustion Methods Of Internal-Combustion Engines (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Output Control And Ontrol Of Special Type Engine (AREA)
  • Combined Controls Of Internal Combustion Engines (AREA)
EP08021384A 2007-12-17 2008-12-09 Brennstoffe für homogen geladene verdichtungsgezündete Maschinen Withdrawn EP2077312A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2007324363 2007-12-17

Publications (1)

Publication Number Publication Date
EP2077312A1 true EP2077312A1 (de) 2009-07-08

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EP08021384A Withdrawn EP2077312A1 (de) 2007-12-17 2008-12-09 Brennstoffe für homogen geladene verdichtungsgezündete Maschinen

Country Status (5)

Country Link
US (1) US20090151236A1 (de)
EP (1) EP2077312A1 (de)
JP (1) JP5355064B2 (de)
KR (1) KR20090065458A (de)
CN (1) CN101503637B (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012142079A3 (en) * 2011-04-14 2013-01-17 Chevron U.S.A. Inc. A fuel composition
WO2020074441A1 (de) * 2018-10-08 2020-04-16 Oxfa Gmbh Verwendung eines ameisensäurealkylesters und/oder eines oxymethylendimethylethers oder polyoxymethylendimethylethers

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MX2012004809A (es) * 2009-10-30 2012-06-14 Chevron Usa Inc Composicion de combustible.
JP2013509489A (ja) * 2009-10-30 2013-03-14 シェブロン ユー.エス.エー. インコーポレイテッド 燃料組成物
JP5526408B2 (ja) * 2010-01-19 2014-06-18 国立大学法人東北大学 燃料物性決定方法及び燃料物性決定装置
JP5453221B2 (ja) 2010-11-18 2014-03-26 国立大学法人東北大学 燃焼実験装置
CN103184083A (zh) * 2011-12-30 2013-07-03 李述玉 含氧助燃环保节能汽油及其生产方法
US9688928B2 (en) 2013-12-11 2017-06-27 Phillips 66 Company Processes for making homogeneous charge compression ignition engine fuel blends
US10246657B2 (en) 2013-12-11 2019-04-02 Phillips 66 Company Fuel blends for homogeneous charge compression ignition engines
EP3080414B1 (de) * 2013-12-11 2020-11-04 Phillips 66 Company Motorkraftstoffe mit homogener kompressionszündung und verfahren zur herstellung dieser motorkraftstoffe
CN104789277A (zh) * 2014-01-22 2015-07-22 李卫教 一种脂肪酸甲酯与二甲醚合成新型生物柴油的生产工艺
US11261391B1 (en) * 2014-04-18 2022-03-01 National Technology & Engineering Solutions Of Sandia, Llc Fuel and fuel blend for internal combustion engine
AT516289B1 (de) * 2014-10-06 2016-07-15 Ge Jenbacher Gmbh & Co Og Verfahren zum Betreiben einer Selbstzündungs-Brennkraftmaschine
CN105647598A (zh) * 2014-11-05 2016-06-08 周向进 含有助燃剂的汽油产品及其制造方法
JP6448688B2 (ja) * 2017-03-06 2019-01-09 Jxtgエネルギー株式会社 燃料油を内燃機関において使用する方法
CN109164393B (zh) * 2018-07-27 2021-05-04 清华大学 电池热失控实验装置、系统及其方法
CN110823949B (zh) * 2019-09-25 2020-08-28 西安交通大学 一种基于放热率曲线快速计算乙醇汽油辛烷值敏感性的方法
CN111996042B (zh) * 2020-07-30 2022-03-29 清华大学 火花点燃激发压燃式内燃机用燃料
CN113583723A (zh) * 2021-08-06 2021-11-02 山东京博石油化工有限公司 一种点燃式高压缩比发动机燃料及其制备方法

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012142079A3 (en) * 2011-04-14 2013-01-17 Chevron U.S.A. Inc. A fuel composition
EP2697340A2 (de) * 2011-04-14 2014-02-19 Chevron U.S.A., Inc. Kraftstoffzusammensetzung
EP2697340A4 (de) * 2011-04-14 2014-10-22 Chevron Usa Inc Kraftstoffzusammensetzung
AU2012242964B2 (en) * 2011-04-14 2017-05-25 Chevron U.S.A. Inc. A fuel composition
AU2012242964C1 (en) * 2011-04-14 2017-08-24 Chevron U.S.A. Inc. A fuel composition
WO2020074441A1 (de) * 2018-10-08 2020-04-16 Oxfa Gmbh Verwendung eines ameisensäurealkylesters und/oder eines oxymethylendimethylethers oder polyoxymethylendimethylethers

Also Published As

Publication number Publication date
JP5355064B2 (ja) 2013-11-27
JP2009167398A (ja) 2009-07-30
CN101503637A (zh) 2009-08-12
US20090151236A1 (en) 2009-06-18
CN101503637B (zh) 2013-08-21
KR20090065458A (ko) 2009-06-22

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