EP2043439A1 - Combinaisons de principes actifs ayant des proprietes insecticides et acaricides - Google Patents

Combinaisons de principes actifs ayant des proprietes insecticides et acaricides

Info

Publication number
EP2043439A1
EP2043439A1 EP07765107A EP07765107A EP2043439A1 EP 2043439 A1 EP2043439 A1 EP 2043439A1 EP 07765107 A EP07765107 A EP 07765107A EP 07765107 A EP07765107 A EP 07765107A EP 2043439 A1 EP2043439 A1 EP 2043439A1
Authority
EP
European Patent Office
Prior art keywords
spp
active
active compound
combinations
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP07765107A
Other languages
German (de)
English (en)
Inventor
Reiner Fischer
Wolfram Andersch
Thomas König
Anton Kraus
Emmanuel Salmon
Heike Hungenberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer CropScience AG
Original Assignee
Bayer CropScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer CropScience AG filed Critical Bayer CropScience AG
Publication of EP2043439A1 publication Critical patent/EP2043439A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl

Definitions

  • the present invention relates to novel drug combinations which consist of known cyclic ketoenols on the one hand and other known insecticidal active compounds on the other hand and are very well suited for controlling animal pests such as insects and unwanted acarids.
  • R Br (XIX); 4 - [(4-Chloro- ⁇ , ⁇ , ⁇ -trifluoro-3-tolyl) oxy] -6 - [( ⁇ , ⁇ , ⁇ -trifluoro-4-bromo-3-tolyl) oxy] -pyrimidine
  • insecticidal and / or acaricidal activity of the active compound combinations according to the invention is substantially better than the effects of the previously known active compound combination from WO 02/037963 consisting of cis / trans isomer mixtures of the formula I-I-I or I-2-a and an active compound of the compounds 1 to 26.
  • active compound combinations comprising the compound of the formula (1-1) and at least one active compound of the compounds 1 to 26.
  • active ingredient combinations comprising the compound of the formula (I-2) and at least one active compound of the compounds I to 26.
  • the active ingredient combinations may also contain other fungicidal, acaricidal or insecticidal Zumischkomponenten beyond. If the active ingredients in the active compound combinations according to the invention are present in certain weight ratios, the improved action is particularly pronounced. However, the weight ratios of the active ingredients in the drug combinations can be varied within a relatively wide range.
  • the combinations according to the invention contain active compounds of the formula (I-1) or (1-2) and the mixing partner in the preferred and particularly preferred mixing ratios indicated in the table below:
  • the active compound combinations according to the invention are suitable for controlling animal pests, preferably arthropods and nematodes, in particular insects and / or arachnids, in wine and fruit growing, in horticulture, in agriculture, animal health, in forests, in the protection of stored products and materials, and occur in the hygiene sector. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • animal pests preferably arthropods and nematodes, in particular insects and / or arachnids, in wine and fruit growing, in horticulture, in agriculture, animal health, in forests, in the protection of stored products and materials, and occur in the hygiene sector.
  • the above mentioned pests include:
  • Symphyla e.g. Scutigerella immaculata.
  • Thysanura e.g. Lepisma saccharina.
  • Orthoptera e.g. Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.
  • Phthiraptera e.g. Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp.
  • Thysanoptera e.g. Herculothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.
  • Heteroptera e.g. Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.
  • Lepidoptera e.g. Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp., Earias insulana, Heliothis Spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria me
  • Sitophilus spp. Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus.
  • Hymenoptera e.g. Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
  • Diptera e.g. Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp.
  • Oestrus spp. Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hylemyia spp., Liriomyza spp.
  • siphonaptera e.g. Xenopsylla cheopis, Ceratophyllus spp.
  • arachnids e.g. Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoropts spp , Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.
  • Scorpio maurus Latrodectus mactans, Acarus siro, Argas spp., Orni
  • the plant parasitic nematodes include e.g. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp.
  • the active compound combinations can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension-emulsion concentrates, active substance-impregnated natural and synthetic substances and ultrafine encapsulations in polymeric substances.
  • formulations are prepared in a known manner, for example by mixing the active compounds with extenders, ie liquid solvents and / or solid carriers, optionally with the use of surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents.
  • extenders ie liquid solvents and / or solid carriers
  • surface-active agents ie emulsifiers and / or dispersants and / or foam-forming agents.
  • organic solvents can also be used as auxiliary solvents.
  • Suitable liquid solvents are essentially: aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • aromatics such as xylene, toluene, or alkylnaphthalenes
  • chlorinated aromatics and chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene chloride
  • Suitable solid carriers are:
  • Ammonium salts and ground natural minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as fumed silica, alumina and silicates, as solid carriers for granules are suitable: e.g. crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, coconut shells, corn cobs and tobacco stalks; suitable emulsifiers and / or foam formers are: e.g.
  • nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. Alkylaryl polyglycol ether. Alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolysates; suitable dispersants are: e.g. Lignin-sulphite liquors and methylcellulose.
  • Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids such as cephalins and lecithins, and synthetic phospholipids may be used in the formulations.
  • Other additives may be mineral and vegetable oils.
  • Dyes such as inorganic pigments such as iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc can be used.
  • the formulations generally contain between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%.
  • the active compound combinations according to the invention can be present in commercially available formulations as well as in the formulations prepared from these formulations in admixture with other active ingredients, such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances or herbicides.
  • active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances or herbicides.
  • the insecticides include, for example, phosphoric acid esters, carbamates, carboxylic esters, chlorinated hydrocarbons, phenylureas, microorganism-produced substances and the like.
  • the active compound combinations according to the invention may also be present when used as insecticides in their commercial formulations as well as in the formulations prepared from these formulations in admixture with synergists.
  • Synergists are compounds which increase the effect of the active ingredients without the added synergist itself having to be active.
  • the active substance content of the application forms prepared from the commercial formulations can vary within wide ranges.
  • the active ingredient concentration of the use forms may be from 0.0000001 to 95% by weight of active ingredient, preferably between 0.0001 and 1% by weight.
  • the application is done in a custom forms adapted to the application.
  • plants and parts of plants can be treated.
  • plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
  • Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights.
  • Under plant parts are all above-ground and underground parts and organs of plants, such as shoot, leaf, flower and root
  • leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, as well as roots, tubers and rhizomes are listed.
  • the plant parts also include crops as well as vegetative and generative propagation material, for example cuttings, tubers, rhiomes, offshoots and seeds.
  • the treatment according to the invention of the plants and plant parts with the active compound combinations takes place directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, vaporizing, atomizing, spreading, spreading and in propagation material, in particular in seeds, further by single or multi-layer wrapping.
  • plants and their parts can be treated.
  • wild-type or plant species obtained by conventional biological breeding methods such as crossing or protoplast fusion
  • plant cultivars and their parts are treated.
  • transgenic plants and plant cultivars which have been obtained by genetic engineering methods if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated.
  • the term "parts” or “parts of plants” or “plant parts” has been explained above.
  • the treatment according to the invention may also give rise to superadditive ("synergistic") effects.
  • superadditive for example, reduced application rates and / or extensions of the spectrum of action and / or an increase in the effect of the substances and agents usable in the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering power facilitated harvest, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or machinability of the harvested products, which exceed the actual expected effects.
  • the preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits").
  • traits are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms salt, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products.
  • Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants to certain herbicidal active substances.
  • transgenic plants include the important crops such as cereals (wheat, rice), corn, soy, potato, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soy, potato, cotton and rapeseed should be highlighted.
  • Traits which are particularly emphasized are the increased defense of the plants against insects by toxins which are formed in the plants, in particular those which are produced by the genetic material from Bacillus thuringiensis (for example by the genes Cry ⁇ A (a), Cry ⁇ A (b), Cry ⁇ A (c), CryllA, CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF and combinations thereof) are produced in the plants (hereinafter "Bt plants”).
  • Bt plants Traits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene).
  • genes which confer the desired properties can also occur in combinations with one another in the transgenic plants.
  • “Bt plants” are maize varieties, cotton varieties, soybean varieties and potato varieties which are marketed under the trade names YIELD GARD® (eg corn, cotton, soy), KnockOut® (eg corn), StarLink® (eg maize), Bollgard® (Cotton), Nucotn® (cotton) and NewLeaf® (potato).
  • herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties which are sold under the trade names Roundup Ready® (tolerance to glyphosate eg corn, cotton, soya), Liberty Link® (tolerance to phosphinotricin, eg rapeseed), IMI® (tolerance to Imidazolinone) and STS® (tolerance to Sulfonylureas such as corn) are sold.
  • Herbicide-resistant (conventionally grown on herbicide tolerance) plants are also the varieties marketed under the name Clearfield® (eg corn) mentioned. Of course, these statements also apply to future or future marketed plant varieties with these or future developed genetic traits.
  • the listed plants can be treated particularly advantageously according to the invention with the active compound mixture according to the invention.
  • the preferred ranges given above for the mixtures also apply to the treatment of these plants.
  • Particularly emphasized is the plant treatment with the mixtures specifically mentioned in the present text.
  • X means the degree of killing, expressed in% of the untreated control, when using the active substance A at a rate of m g / ha or in a concentration of m ppm,
  • Y means the degree of killing, expressed in% of the untreated control, when using the active ingredient B in an application rate of n g / ha or in a concentration of n ppm
  • E means the degree of killing, expressed in% of the untreated control, when using the active compounds A and B at application rates of m and n g / ha or in a concentration of m and n ppm,
  • the combination is over-additive in its kill, ie there is a synergistic effect.
  • the actually observed kill rate must be greater than the expected kill rate (E) value calculated from the above formula.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cotton leaves (Gossypium herbaceum), which are heavily infested by the cotton aphid ⁇ Aphis gossypii), are treated by being dipped into the preparation of active compound of the desired concentration.
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves ⁇ Brassica oleraceä) that are heavily infested with the green peach aphid ⁇ Myzus persicae) are treated by spraying with the preparation of active compound of the desired concentration.
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves (Brassica oleraceä) which are heavily infested with the green peach aphid ⁇ Myzus persicae) are treated by being dipped in the preparation of active compound at the desired concentration.
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves (Brassica oleraced) are treated by spraying with the preparation of active compound in the desired concentration and are populated with larvae of the horseradish leaf beetle ⁇ Phaedon cochleariae) while the leaves are still moist.
  • the kill is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves ⁇ Brassica oleraceä) are treated by spraying with the preparation of active compound in the desired concentration and are populated with larvae of the armyworm (Spodoptera frugiperda) while the leaves are still moist.
  • the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed.
  • the determined kill values are calculated according to the Colby formula (see page 1).
  • Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Bean leaf discs Phaseolus vulgaris infected by all stages of the common spider mite (Tetranychus urticae) are sprayed with an active compound preparation of the desired concentration.
  • the effect is determined in%. 100% means that all spider mites have been killed; 0% means that no spider mites have been killed.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves (Brassica olerace®) are treated by spraying with the preparation of active compound in the desired concentration and are populated with larvae of the horseradish leaf beetle ⁇ Phaedon cochleariae) while the leaves are still moist.
  • the kill is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Test insect Diabrotica balteata - larvae in soil
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • the preparation of active compound is poured onto the ground.
  • the concentration of the active substance in the preparation plays virtually no role, the only decisive factor is the amount of active ingredient per unit volume of soil, which is stated in ppm (mg / l).
  • the soil is poured into 0.25 1 pots and allowed to stand at 20 0 C.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • Soybean shoots (Glycine max) of the variety Roundup Ready (trademark of Monsanto Comp. USA) are treated by spraying with the preparation of active compound in the desired concentration and are populated with the tobacco budworm Heliothis virescens while the leaves are still moist.
  • the kill of the insects is determined.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the stated amount of solvent and the stated amount of emulsifier and the concentrate is diluted with water to the desired concentration.
  • Transgenic cabbage plants (Brassica oleracea) which are heavily infested with the green peach aphid Myzus persicae are treated by spraying with the preparation of active compound in the desired concentration.
  • the kill of the insects is determined.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

La présente invention concerne de nouvelles combinaisons de principes actifs comprenant des composés de formule (I-1) ou (I-2) et les principes actifs (1) à (26) mentionnés dans la description, lesdites combinaisons ayant de très bonnes propriétés insecticides et acaricides.
EP07765107A 2006-07-11 2007-07-06 Combinaisons de principes actifs ayant des proprietes insecticides et acaricides Withdrawn EP2043439A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006031975A DE102006031975A1 (de) 2006-07-11 2006-07-11 Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
PCT/EP2007/005994 WO2008006513A1 (fr) 2006-07-11 2007-07-06 Combinaisons de principes actifs ayant des propriétés insecticides et acaricides

Publications (1)

Publication Number Publication Date
EP2043439A1 true EP2043439A1 (fr) 2009-04-08

Family

ID=38430547

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07765107A Withdrawn EP2043439A1 (fr) 2006-07-11 2007-07-06 Combinaisons de principes actifs ayant des proprietes insecticides et acaricides

Country Status (9)

Country Link
US (1) US20100204167A1 (fr)
EP (1) EP2043439A1 (fr)
JP (1) JP2009542744A (fr)
KR (1) KR20090031600A (fr)
CN (1) CN101489388A (fr)
BR (1) BRPI0712885A2 (fr)
DE (1) DE102006031975A1 (fr)
MX (1) MX2009000016A (fr)
WO (1) WO2008006513A1 (fr)

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7488753B2 (en) * 2003-10-09 2009-02-10 Pacific Arrow Limited Composition comprising triterpene saponins and compounds with angeloyl functional group, methods for preparing same and uses thereof
US8614197B2 (en) * 2003-10-09 2013-12-24 Pacific Arrow Limited Anti-tumor compounds with angeloyl groups
EP2039248A1 (fr) * 2007-09-21 2009-03-25 Bayer CropScience AG Combinaisons d'agents actifs à propriétés insecticides et acaricides
ES2398315T3 (es) * 2007-12-20 2013-03-15 Bayer Cropscience Ag Uso de derivados de ácido tetrámico para combatir nematodos
EP2127522A1 (fr) 2008-05-29 2009-12-02 Bayer CropScience AG Combinaisons de principes actifs presentant des propriétés insecticides et acaricides
CN101406182B (zh) * 2008-06-18 2011-05-18 张少武 一种含炔螨特与溴螨酯的杀螨组合物
CN101416627B (zh) * 2008-11-06 2011-08-10 张少武 含有炔螨特和溴螨酯的具有增效作用的杀螨组合物
TW201031327A (en) * 2008-11-14 2010-09-01 Bayer Cropscience Ag Active compound combinations having insecticidal and acaricidal properties
US8389443B2 (en) 2008-12-02 2013-03-05 Bayer Cropscience Ag Geminal alkoxy/alkylspirocyclic substituted tetramate derivatives
US8846946B2 (en) 2008-12-02 2014-09-30 Bayer Cropscience Ag Germinal alkoxy/alkylspirocyclic substituted tetramate derivatives
DE102009028001A1 (de) 2009-07-24 2011-01-27 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
JP2011037760A (ja) * 2009-08-11 2011-02-24 Sumitomo Chemical Co Ltd 有害生物防除組成物
CN101669497B (zh) * 2009-10-16 2013-03-27 深圳诺普信农化股份有限公司 一种杀螨组合物
CN102823606B (zh) * 2009-10-28 2014-04-30 陕西上格之路生物科学有限公司 一种含联苯肼酯的杀螨组合物
CN101743966B (zh) * 2009-12-29 2012-10-31 华南农业大学 茶皂素与杀螨剂混配的杀虫剂
TWI513407B (zh) * 2010-02-19 2015-12-21 Sumitomo Chemical Co 害蟲控制組成物
CN101874498A (zh) * 2010-07-08 2010-11-03 东莞市瑞德丰生物科技有限公司 一种杀虫杀螨组合物
CN101990893A (zh) * 2010-11-01 2011-03-30 吴明龙 含乙螨唑和哒螨灵的农药组合物
CN102037985B (zh) * 2010-11-22 2013-04-10 陕西汤普森生物科技有限公司 一种含联苯肼酯与嘧螨醚的农药组合物
CN102007922A (zh) * 2011-01-01 2011-04-13 陕西上格之路生物科学有限公司 一种含乙螨唑和炔螨特的杀螨组合物
CN102754651B (zh) * 2011-04-25 2015-01-14 深圳诺普信农化股份有限公司 一种杀螨剂及其应用
CN103651405B (zh) * 2011-04-26 2014-11-12 陕西韦尔奇作物保护有限公司 一种含有乙螨唑的农药组合物
CN102210321A (zh) * 2011-05-04 2011-10-12 陕西韦尔奇作物保护有限公司 一种含有乙螨唑的农药组合物
CN102228055A (zh) * 2011-05-06 2011-11-02 陕西韦尔奇作物保护有限公司 一种含有喹螨醚的农药组合物
CN102228027A (zh) * 2011-05-06 2011-11-02 陕西韦尔奇作物保护有限公司 一种含有喹螨醚的农药组合物
CN102228039A (zh) * 2011-05-11 2011-11-02 青岛海利尔药业有限公司 一种含有螺虫乙酯与溴虫腈的杀虫组合物
CN102246779A (zh) * 2011-05-17 2011-11-23 海利尔药业集团股份有限公司 一种含有螺虫乙酯与多杀菌素的杀虫组合物
CN103355326A (zh) * 2012-04-07 2013-10-23 陕西韦尔奇作物保护有限公司 一种高效农药组合物
CN103355327A (zh) * 2012-04-10 2013-10-23 陕西韦尔奇作物保护有限公司 一种含多杀霉素的杀虫组合物
CN102657194A (zh) * 2012-04-26 2012-09-12 山东农业大学 一种含哒螨灵和螺虫乙酯的农药组合物
CN102675237A (zh) * 2012-05-24 2012-09-19 南京工业大学 2，4-二苯基噁唑啉类新化合物、合成方法及其杀螨活性
CN103503874A (zh) * 2012-06-27 2014-01-15 陕西美邦农药有限公司 一种含灭螨醌的农药组合物
CN102742583A (zh) * 2012-07-23 2012-10-24 中国农业大学 一种防治食心虫的杀虫剂组合物及其制备方法和应用
CN103039467A (zh) * 2012-12-28 2013-04-17 海利尔药业集团股份有限公司 一种含有氟螨嗪与螺虫乙酯的杀虫组合物
CN104996440A (zh) * 2015-07-06 2015-10-28 山东省烟台市农业科学研究院 一种复配杀虫剂及其应用
CN105494344B (zh) * 2015-12-29 2018-08-03 南京华洲药业有限公司 一种含炔螨特与多杀霉素的增效杀虫组合物及其应用
CN110612982A (zh) * 2015-12-30 2019-12-27 江苏龙灯化学有限公司 一种含有螺虫乙酯与依维菌素的杀虫组合物
WO2017174544A1 (fr) * 2016-04-07 2017-10-12 Bayer Cropscience Aktiengesellschaft Associations de principes actifs aux propriétés insecticides et acaricides
JP7287392B2 (ja) * 2018-05-28 2023-06-06 日産化学株式会社 農薬乳化性組成物
CN109221222A (zh) * 2018-09-20 2019-01-18 上海悦联生物科技有限公司 一种复配农用化学品组合物及农用化学品及应用
CN110664776A (zh) * 2019-10-10 2020-01-10 佛山市正典生物技术有限公司 一种乙螨唑微囊及其制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10055941A1 (de) * 2000-11-10 2002-05-23 Bayer Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE10231333A1 (de) * 2002-07-11 2004-01-22 Bayer Cropscience Ag Cis-Alkoxysubstituierte spirocyclische 1-H-Pyrrolidin-2,4-dion-Derivate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2008006513A1 *

Also Published As

Publication number Publication date
CN101489388A (zh) 2009-07-22
WO2008006513A1 (fr) 2008-01-17
JP2009542744A (ja) 2009-12-03
US20100204167A1 (en) 2010-08-12
MX2009000016A (es) 2009-01-23
DE102006031975A1 (de) 2008-01-17
KR20090031600A (ko) 2009-03-26
BRPI0712885A2 (pt) 2012-10-09

Similar Documents

Publication Publication Date Title
WO2008006513A1 (fr) Combinaisons de principes actifs ayant des propriétés insecticides et acaricides
EP1974606B1 (fr) Insecticides sélectifs à base de phtalamides et de phytoprotecteurs
EP2043438A1 (fr) Combinaisons de principes actifs ayant des propriétés insecticides et acaricides
EP1771064B1 (fr) Insecticides a base de neonicotinoides et de phytoprotecteurs
WO2008006516A1 (fr) Combinaisons de principes actifs ayant des propriétés insecticides et acaricides
EP3001905B1 (fr) Combinaisons d&#39;agents actifs a proprietes insecticides et acaricides
WO2008006515A1 (fr) Combinaisons de principes actifs ayant des propriétés insecticides et acaricides
WO2008006514A1 (fr) Combinaisons de principes actifs ayant des propriétés insecticides et acaricides
EP2008517A1 (fr) Combinaisons dýagents acaricides
US20090281157A1 (en) Active Ingredient Combinations With Insecticidal and Acaricidal Properties
EP2923576B1 (fr) Combinaisons d&#39;agents actifs à propriétés insecticides et acaricides
WO2007144089A1 (fr) Combinaisons d&#39;agents actifs avec propriétés insecticides et acaricides
JP4677101B2 (ja) 活性剤の組み合わせ
WO2009007036A1 (fr) Combinaisons de principes actifs aux propriétés insecticides, acaricides et nématicides
WO2000035286A1 (fr) Combinaisons de constituants actifs

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20090211

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL BA HR MK RS

RIN1 Information on inventor provided before grant (corrected)

Inventor name: HUNGENBERG, HEIKE

Inventor name: SALMON, EMMANUEL

Inventor name: KRAUS, ANTON

Inventor name: KOENIG, THOMAS

Inventor name: ANDERSCH, WOLFRAM

Inventor name: FISCHER, REINER

17Q First examination report despatched

Effective date: 20090525

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20101125