WO2009007036A1 - Combinaisons de principes actifs aux propriétés insecticides, acaricides et nématicides - Google Patents

Combinaisons de principes actifs aux propriétés insecticides, acaricides et nématicides Download PDF

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Publication number
WO2009007036A1
WO2009007036A1 PCT/EP2008/005349 EP2008005349W WO2009007036A1 WO 2009007036 A1 WO2009007036 A1 WO 2009007036A1 EP 2008005349 W EP2008005349 W EP 2008005349W WO 2009007036 A1 WO2009007036 A1 WO 2009007036A1
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WIPO (PCT)
Prior art keywords
spp
plants
active
active compound
combinations
Prior art date
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PCT/EP2008/005349
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German (de)
English (en)
Inventor
Reiner Fischer
Heike Hungenberg
Roland Giebner
Original Assignee
Bayer Cropscience Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Publication of WO2009007036A1 publication Critical patent/WO2009007036A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof

Definitions

  • the present invention relates to novel drug combinations which consist of known cyclic ketoenols on the one hand and other known insecticidal active compounds on the other hand and are very well suited for controlling animal pests such as insects and / or unwanted acarids and / or nematodes in soil application.
  • acetylcholinesterase (AChE) inhibitors specified by the IRAC are very well suited for controlling animal pests in soil application.
  • acetylcholinesterase AChE
  • CChE acetylcholinesterase
  • Aldicarb (II-1) is known from US 3,217,037
  • Carbofuran (II-2) is known from DE-A-1493646
  • Cloethocarb (II-5) is known from DE-A-2231249 and / or
  • Thiodicarb (II-6) is known from DE-A-2530439 and / or - A -
  • Fenamiphos (II-7) known from DE-A-1121882 and / or
  • Isazofos ( ⁇ -10) is known from DE-A-2260015 and / or
  • Cadusafos (11-12) known from WO 83/00870 and / or
  • Chloroethoxyfos (II-l 3) known from EP-A-160344 and / or
  • Chlo ⁇ yriphos-methyl (11-15) is known from US 3,244,586.
  • insecticidal and / or acaricidal and / or nematicidal action of the active compound combinations according to the invention after soil application is substantially higher than the sum of the effects of the individual active substances. There is an unpredictable true synergistic effect and not just an effective supplement.
  • active compound combinations comprising the compounds of the formula (I-1) and at least one active compound of the formula (II).
  • the active ingredient combinations may also contain other fungicidal, acaricidal or insecticidal Zumischkomponenten beyond.
  • the active ingredients in the active compound combinations according to the invention are present in certain weight ratios, the improved action is particularly pronounced.
  • the weight ratios of the active ingredients in the drug combinations can be varied within a relatively wide range.
  • the combinations according to the invention comprise active compounds of the formula (I-1) or (1-2) and the mixing partner in the preferred and particularly preferred mixing ratios indicated in the table below:
  • insects and / or arachnids and / or nematodes which occur in wine, fruit growing, in agriculture, in garden centers and in forests. They can preferably be used as crop protection agents. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • the above mentioned pests include:
  • Symphyla e.g. Scutigerella immaculata.
  • Thysanura e.g. Lepisma saccharina.
  • Orthoptera e.g. Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.
  • Phthiraptera e.g. Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp.
  • Thysanoptera e.g. Herculothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.
  • Heteroptera e.g. Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.
  • Lepidoptera e.g. Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp., Earias insulana, Heliothis Spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria me
  • Hofmannophila pseudospretella Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae.
  • Otiorrhynchus sulcatus Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp.
  • Hymenoptera e.g. Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
  • siphonaptera e.g. Xenopsylla cheopis, Ceratophyllus spp.
  • Ornithodoros spp. Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus Spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp. Brevipalpus spp ..
  • vegetables e.g. Fruit vegetables and inflorescences as vegetables, such as peppers, hot peppers, tomatoes, aubergines, cucumbers, pumpkins, zucchini,
  • leafy vegetables such as lettuce, chicory, endives, kraken, ruffians, lamb's lettuce, iceberg lettuce, leeks, spinach, chard;
  • tubers, root and stem vegetables such as celery, beetroot, carrots, radishes, horseradish, salsify, asparagus, turnips, palm sprouts, bamboo shoots, as well as onion vegetables, such as onions, leeks, fennel, garlic;
  • cabbage such as cauliflower, broccoli, kohlrabi, red cabbage, cabbage, kale, savoy cabbage, Brussels sprouts, Chinese cabbage.
  • citrus such as oranges, grapefruit, tangerines, lemons, limes, bitter oranges, kumquats, satsumas are understood to be among the perennial crops;
  • pomaceous fruits such as apples, pears and quinces
  • stone fruit such as peaches, nectarines, cherries, plums, plums, apricots
  • wine hops, olives, tea, soya, oilseed rape, cotton, sugar cane, beets, potatoes, tobacco and tropical crops such as mangoes, papayas, figs, pineapples, dates, bananas, durians, kakis, coconuts, cocoa , Coffee, avocados, lychees,
  • almonds and nuts such as hazelnuts, walnuts, pistachios, cashews, Brazil nuts, pecans, butternuts, chestnuts, hickory nuts, macadamia nuts, peanuts, in addition, soft fruits such as currants, gooseberries, raspberries, blackberries, blueberries, strawberries, cranberries, kiwis, cranberries.
  • ornamental plants are understood to be annual and perennial plants, e.g. Cut flowers such as roses, carnations, gerberas, lilies, daisies, chrysanthemums, tulips, daffodils, anemones, poppies, amyrillis, dahlias, azaleas, mallows,
  • Shrubs and conifers such as ficus, rhododendron, spruce, fir,
  • spices one- and perennial plants such as anise, chilli, pepper, pepper, vanilla, marjoram, thyme, cloves, juniper berries, cinnamon, tarragon, Koryander, saffron, ginger.
  • the active compound combinations can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension-emulsion concentrates, active substance-impregnated natural and synthetic substances and very fine encapsulations in polymeric substances.
  • formulations are prepared in a known manner, e.g. by mixing the active compounds with extenders, ie liquid solvents and / or solid carriers, if appropriate using surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents.
  • organic solvents can also be used as auxiliary solvents.
  • Suitable liquid solvents are essentially: aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • Ais solid carriers are suitable:
  • Ammonium salts and ground natural minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as finely divided silica, alumina and silicates, as solid carriers for granules are suitable: e.g. broken and fractionated natural rocks such as calcite, marble, pumice,
  • suitable emulsifiers and / or foam formers are: e.g. nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. Alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolysates; suitable dispersants are: e.g. Lignin-sulphite liquors and methylcellulose.
  • adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-like polymers, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids, such as
  • Kephalins and lecithins and synthetic phospholipids may be mineral and vegetable oils.
  • Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • the formulations generally contain between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%.
  • the active compound combinations according to the invention can be used in commercial formulations as well as in the formulations prepared from these formulations in admixture with others
  • Active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth regulators or herbicides.
  • the insecticides include, for example, phosphoric acid esters, carbamates, carboxylic esters, chlorinated hydrocarbons, phenylureas, microorganism-produced substances and the like.
  • a mixture with other known active substances, such as herbicides or with fertilizers and growth regulators is possible.
  • the active compound combinations according to the invention may also be present when used as insecticides in their commercial formulations as well as in the formulations prepared from these formulations in admixture with synergists.
  • Synergists are compounds which increase the effect of the active ingredients without the added synergist itself having to be active.
  • the active substance content of the application forms prepared from the commercial formulations can vary within wide ranges.
  • the active ingredient concentration of the use forms may be from 0.0000001 to 95% by weight of active ingredient, preferably between 0.0001 and 1% by weight.
  • the application is done in a custom forms adapted to the application.
  • plants and parts of plants can be treated.
  • plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
  • Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights.
  • Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, by way of example, leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and roots, tubers and rhizomes .
  • the plant parts also include crops as well as vegetative and generative propagation material, for example cuttings, tubers, rhiomes, offshoots and seeds.
  • the treatment according to the invention of the plants and plant parts with the active compound combinations takes place directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, evaporating,
  • Nebulizing, spreading, spreading and propagating material especially in seeds, further by single or multi-layer wrapping.
  • plants and their parts can be treated.
  • wild or obtained by conventional biological breeding methods such as crossing or protoplast fusion
  • transgenic plants and plant cultivars produced by genetic engineering Methods were optionally obtained in combination with conventional methods (Genetic Modified Organisms) and their parts treated.
  • the term “parts” or “parts of plants” or “plant parts” has been explained above.
  • plants of the commercially available or in use plant cultivars are particularly preferably treated.
  • the treatment according to the invention may also give rise to superadditive ("synergistic") effects.
  • superadditive for example, reduced application rates and / or extensions of the spectrum of action and / or an increase in the effect of the substances and agents usable according to the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to water or soil salt content, increased flowering power facilitated harvest, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or machinability of the harvested products, which exceed the actual expected effects.
  • the preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits"). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased
  • transgenic plants include the important crops, such as cereals (wheat, rice), maize, soya, potato, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), corn, soy, potato , Cotton and oilseed rape.
  • Traits which are particularly emphasized are the increased defense of the plants against insects by toxins formed in the plants, in particular those produced by the genetic material from Bacillus thuringiensis (for example by the genes Cry ⁇ A (a), CryIA (b), Cry ⁇ A (c), CryllA, CrylllA, CryIHB2, Cry9c Cry2Ab, Cry3Bb and CrylF and combinations thereof) are produced in the plants (hereinafter "Bt plants”).
  • Bt plants Traits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene).
  • PAT phosphinotricin
  • Traits conferring genes may also occur in combinations with each other in the transgenic plants.
  • Examples of “Bt plants” are maize varieties, cotton varieties, soybean varieties and potato varieties which are sold under the trade names YIELD GARD® (eg corn, cotton, soya), KnockOut® (eg maize), StarLink® (eg maize), Bollgard® ( Cotton), Nucotn® (cotton) and NewLeaf® (potato).
  • YIELD GARD® eg corn, cotton, soya
  • KnockOut® eg maize
  • StarLink® eg maize
  • Bollgard® Cotton
  • Nucotn® cotton
  • NewLeaf® potato
  • Herbicide-tolerant plants are maize varieties, cotton varieties and soybean called under the trade names Roundup Ready® (tolerance to glyphosate such as corn, cotton, soy), Liberty Link® (tolerance to phosphinotricin, eg rapeseed), IMI® (tolerance to imidazolinones) and STS® (tolerance to sulfonylureas eg corn) are sold.
  • Herbicide-resistant (conventionally grown herbicide-tolerant) plants also include the varieties sold under the name Clearfield® (e.g., corn). Of course, these statements also apply to future or future marketed plant varieties with these or future developed genetic traits.
  • the listed plants can be treated particularly advantageously according to the invention with the active compound mixture according to the invention.
  • the preferred ranges given above for the mixtures also apply to the treatment of these plants.
  • Particularly emphasized is the plant treatment with the mixtures specifically mentioned in the present text.
  • a synergistic effect is always present in insecticides, nematicides and acaricides whenever the effect of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
  • X means the degree of killing, expressed in% of the untreated control, when using the active substance A at a rate of m g / ha or in a concentration of m ppm,
  • Y is the degree of kill, expressed as% of untreated control, using the
  • Active ingredient B in an application rate of n g / ha or in a concentration of n ppm means and
  • Active substances A and B in amounts of m and n g / ha or in a concentration of m and n ppm,
  • the combination is over-additive in its kill, i. there is a synergistic effect.
  • the actually observed kill rate must be greater than the expected kill rate (E) value calculated from the above formula.
  • the kill is determined in%. 100% means that all animals have been killed; 0% means that no animals were killed.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with water to the desired concentration.
  • Vessels are filled with sand, drug solution, Meloidogyne incognita egg larvae suspension and lettuce seeds.
  • the lettuce seeds germinate and the plantlets develop.
  • the galls develop at the roots.
  • the nematicidal activity is determined by means of bile formation in%. 100% means that no bile was found; 0% means that the number of bile on the treated plants corresponds to that of the untreated control.
  • Plant damaging insects Meloidogyne incognita - test
  • Test insect Diabrotica balteata - larvae in soil
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • the preparation of active compound is poured onto the ground.
  • the concentration of the active ingredient in the preparation plays virtually no role, the only decisive factor is the
  • Emulsifier 1 part by weight of alkylaryl polyglycol ether
  • Active substance with the stated amount of solvent and the stated amount of emulsifier and the concentrate is diluted with water to the desired concentration.
  • Soybean shoots (Glycine max) of the variety Roundup Ready (trademark of Monsanto Comp. USA) are treated by spraying with the preparation of active compound in the desired concentration and populated with the tobacco budworm Heliothis virescens while the leaves are still moist.
  • the kill of the insects is determined.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • Transgenic cabbage plants (Brassica oleracea) which are heavily infested with the green peach aphid Myzus persicae are treated by spraying with the preparation of active compound in the desired concentration.
  • the kill of the insects is determined.

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Les nouvelles combinaisons de principes actifs à base de composés de formule (I- 1) ou (I-2) et de composés de formules (II-1) à (II-15) présentés dans la description possèdent d'excellentes propriétés insecticides, acaricides et/ou nématicides.
PCT/EP2008/005349 2007-07-11 2008-07-01 Combinaisons de principes actifs aux propriétés insecticides, acaricides et nématicides WO2009007036A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07112279A EP2014164A1 (fr) 2007-07-11 2007-07-11 Combinaison dýagents actifs à propriétés insecticides, acaricides et nématicides
EP07112279.0 2007-07-11

Publications (1)

Publication Number Publication Date
WO2009007036A1 true WO2009007036A1 (fr) 2009-01-15

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EP (1) EP2014164A1 (fr)
CL (1) CL2008002021A1 (fr)
WO (1) WO2009007036A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107156173A (zh) * 2017-06-16 2017-09-15 江苏辉丰农化股份有限公司 含有螺虫乙酯与噻唑膦的杀虫组合物
WO2019197612A1 (fr) * 2018-04-13 2019-10-17 Bayer Cropscience Aktiengesellschaft Utilisation de dérivés d'acide tétramique pour lutter contre les bioagresseurs animaux par arrosage ou pulvérisation
WO2019197617A1 (fr) * 2018-04-13 2019-10-17 Bayer Cropscience Aktiengesellschaft Utilisation de dérivés d'acide tétramique pour lutter contre des bioagresseurs animaux par arrosage, pulvérisation, traitement de trou de plantation ou application sur raie.

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103651367A (zh) * 2012-09-03 2014-03-26 陕西美邦农药有限公司 一种含螺甲螨酯的高效杀虫组合物

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002017715A1 (fr) * 2000-08-31 2002-03-07 Bayer Cropscience Ag Combinaison de substances actives ayant des proprietes insecticides et acaricides
WO2006029799A1 (fr) * 2004-09-16 2006-03-23 Bayer Cropscience Ag Cetoenols cycliques a substitution iode-phenol

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002017715A1 (fr) * 2000-08-31 2002-03-07 Bayer Cropscience Ag Combinaison de substances actives ayant des proprietes insecticides et acaricides
WO2006029799A1 (fr) * 2004-09-16 2006-03-23 Bayer Cropscience Ag Cetoenols cycliques a substitution iode-phenol

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107156173A (zh) * 2017-06-16 2017-09-15 江苏辉丰农化股份有限公司 含有螺虫乙酯与噻唑膦的杀虫组合物
WO2019197612A1 (fr) * 2018-04-13 2019-10-17 Bayer Cropscience Aktiengesellschaft Utilisation de dérivés d'acide tétramique pour lutter contre les bioagresseurs animaux par arrosage ou pulvérisation
WO2019197617A1 (fr) * 2018-04-13 2019-10-17 Bayer Cropscience Aktiengesellschaft Utilisation de dérivés d'acide tétramique pour lutter contre des bioagresseurs animaux par arrosage, pulvérisation, traitement de trou de plantation ou application sur raie.
CN111970926A (zh) * 2018-04-13 2020-11-20 拜耳作物科学股份公司 特特拉姆酸衍生物通过灌溉施用或滴浇施用防治害虫的用途

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CL2008002021A1 (es) 2009-01-16
EP2014164A1 (fr) 2009-01-14

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