EP2001985B1 - Feste, textil- und/oder hautpflegende zusammensetzung - Google Patents

Feste, textil- und/oder hautpflegende zusammensetzung Download PDF

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Publication number
EP2001985B1
EP2001985B1 EP07726685A EP07726685A EP2001985B1 EP 2001985 B1 EP2001985 B1 EP 2001985B1 EP 07726685 A EP07726685 A EP 07726685A EP 07726685 A EP07726685 A EP 07726685A EP 2001985 B1 EP2001985 B1 EP 2001985B1
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EP
European Patent Office
Prior art keywords
textile
skin care
care composition
solid
agents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP07726685A
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German (de)
English (en)
French (fr)
Other versions
EP2001985A1 (de
Inventor
Konstanze Mayer
Karl-Heinz Scheffler
Rene-Andres Artiga Gonzalez
Mario Sturm
Tobias Segler
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Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
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Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to PL07726685T priority Critical patent/PL2001985T3/pl
Publication of EP2001985A1 publication Critical patent/EP2001985A1/de
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/221—Mono, di- or trisaccharides or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C11D3/323—Amides; Substituted amides urea or derivatives thereof

Definitions

  • the invention relates to a solid, textile and / or skin care composition and their use and preparation. Furthermore, the invention relates to a washing or cleaning agent containing the solid, textile and / or skin care composition.
  • cationic fabric softening compounds include, for example, methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) ammonium compounds, methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) - ammonium compounds or N, N-dimethyl-N, N-di (tallow acyloxyethyl) ammonium compounds.
  • the US 2,594,257 discloses a solid detergent composition comprising sodium carbonate, attapulgites and carboxymethylcellulose.
  • the US 3,966,629 discloses a solid detergent comprising tripolyphosphate and sodium chloride, smectite clay and carboxymethylcellulose.
  • the US 5,318,714 discloses granules containing enzyme and sodium sulfate and coated with bentonite.
  • the WO 02/102950 A1 describes fabric treatment agents comprising kaolin, sodium carbonate and an optical brightener.
  • WO 05/005591 A1 discloses a water-soluble fabric freshener comprising a water-soluble carrier coated with a perfume, bentonite and silica gel.
  • the GB 2331305 A describes granules for use in detergents comprising montmorillonite clay, sodium tripolyphosphate and optical brightener.
  • the DE 102004010281 A1 relates to portioned fabric care compositions containing polyethylene glycol, bentonite and perfume.
  • WO 2007/02878 A1 describes particles containing carbonate and sulfate, perfume and phyllosilicate.
  • the particles may further comprise a textile and / or skin care compound.
  • the particles are prepared by mixing the perfume with the dried carrier material comprising carbonate, sulfate and phyllosilicate.
  • a solid, textile and / or tooth-care compound comprising a water-soluble carrier, a perfume, 0.1 to 10 wt.% Of a fabric-softening clay and a textile or skin-care compound which is used as a liquid wherein the water-soluble carrier is in particulate form and coated with a powder comprising the fabric softening clay and the textile and / or skin care compound.
  • Such a textile and / or skin care composition can be used in the main wash of an automatic washing or cleaning process.
  • the textile and / or skin care composition can be added, for example, together with the detergent or cleaning agent in the drum or the dispenser of a washing machine.
  • This has the advantage that no additional rinse is necessary and no unsightly deposits occur in the dispenser.
  • this solid composition is easier and better to handle than liquid compositions, since no drops remain on the edge of the bottle, which lead to subsequent storage of the bottle to edges on the ground or to unsightly deposits in the region of the closure. The same applies in the event that some of the composition is accidentally spilled during the dosage. Since textile-softening clays also have a water-softening effect, limescale deposits on the laundry are additionally prevented.
  • the textile softening clay and the textile and / or skin care compound are already transported directly to the laundry at the beginning of the washing process and so can develop their full potential.
  • the water-soluble carrier is selected from the group consisting of inorganic alkali metal salts, organic alkali metal salts, inorganic alkaline earth metal salts, organic alkaline earth metal salts, organic acids, carbohydrates, silicates, urea and mixtures thereof.
  • the water-soluble carrier comprises a carbohydrate and is selected from the group consisting of dextrose, fructose, galactose, isoglucose, glucose, sucrose, raffinose and mixtures thereof.
  • a water-soluble carrier which consists of carbohydrates or at least predominantly of carbohydrates, the problem of corrosion in the washing machine is avoided, which can occur in particular when using inorganic salts as a water-soluble carrier.
  • the solid, textile and / or skin care composition contains from 50 to 99% by weight, preferably from 75 to 95% by weight, of the water-soluble carrier.
  • the textile- and / or skin care compound is selected from the group consisting of textile-softening polymers, fluorescers, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, Antistatics, ironing aids, UV absorbers, repellents, impregnating agents and mixtures thereof.
  • the textiles treated with the textile and / or skin care composition according to the invention are given a further advantageous effect by the addition of one or more of these textile and / or skin care compounds or harmful or negative effects on the textiles during cleaning and / or conditioning and / or supporting fabrics, such as fading, graying, irritation of the skin, etc., diminished.
  • the textile and / or skin care composition comprises a fabric softening polymer, preferably selected from the group consisting of polysiloxanes, cationic polymers and mixtures thereof.
  • the textile softening effect of the textile and / or skin care composition can be further increased.
  • the solid, textile and / or skin care composition contains additional ingredients, preferably selected from the group consisting of dyes, perfume, fillers, binders and mixtures thereof.
  • the solid, textile and / or skin care composition additionally contains a perfume.
  • the amount of perfume is 0.1 to 20% by weight, preferably 1 to 10% by weight and particularly preferably 2 to 7% by weight.
  • Textile and / or skincare compositions are usually intended to impart a pleasant fragrance to the underwear and, for this reason, preferably contain a perfume.
  • the perfume impression of the laundry can be reinforced by polysiloxanes and / or cationic polymers optionally present in the textile and / or skin care composition.
  • Another advantage of the textile and / or skin care composition according to the invention, which is used in the main wash, is that the perfume is already transported directly to the laundry at the beginning of the washing and cleaning process and can thus develop its full potential.
  • the water-soluble carrier has particle sizes in the range of 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm.
  • Textile and / or skin care compositions having particle sizes in the range from 0.8 to 7 mm and particularly preferably in the range from 1 to 3 mm can be metered particularly well and in a targeted manner.
  • the invention also relates to the use of a solid, textile and / or skin care composition according to the invention for conditioning textile fabrics.
  • the invention relates to a method for producing a solid, textile and / or skin care composition
  • a method for producing a solid, textile and / or skin care composition comprising a particulate water-soluble carrier, a perfume 0.1 to 10 wt.% Of a fabric softening clay and a textile and / or skin care compound, which is used as a liquid in which the particulate carrier and the fabric softening clay are mixed in the presence of the textile and / or skin care compound.
  • the invention relates to a washing or cleaning agent comprising a solid, textile and / or skin care composition according to the invention.
  • the consumer By introducing the textile and / or skin care composition according to the invention into a washing or cleaning agent, the consumer is provided with a softening washing or cleaning agent ("2in1" washing or cleaning agent) and does not need to dose two agents.
  • a softening washing or cleaning agent "2in1" washing or cleaning agent” washing or cleaning agent
  • detergents or cleaning agents with different textile and / or skin care effects are obtained in a simple and rapid manner, since only the composition of the textile and / or skin care composition has to be changed.
  • the solid, textile and / or skin care composition contains as essential ingredients a water-soluble carrier, a perfume a fabric softening clay and a textile and / or skin care compound which is used as a liquid.
  • the textile and / or skin care composition contains a fabric softening clay, such as a smectite clay.
  • a fabric softening clay such as a smectite clay.
  • Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontronite clays, saponite clays, sauconite clays, and mixtures thereof.
  • Montmorillonite clays are the preferred softening clays.
  • Bentonites contain mainly montmorillonites and can serve as a preferred source of fabric softening clay.
  • Suitable bentonites are sold, for example, under the names Laundrosil® by Süd-Chemie or under the name Detercal by Laviosa.
  • the amount of textile-softening clay in the textile and / or skin care composition is between 0.1 and 10% by weight and is preferably 1 to 5% by weight.
  • the textile and / or skin care composition contains a textile and / or skin care compound.
  • a textile and / or skin care compound is preferably selected from the group consisting of textile-softening polymers, fluorescers, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, antistatic agents, ironing aids, UV absorbers, repellents, impregnating agents and Mixtures thereof.
  • the textile and / or skin care composition contains a textile-softening polymer, in particular a polysiloxane and / or a cationic polymer.
  • Polydimethylpolysiloxanes are known as efficient fabric care compounds.
  • Suitable polydimethysiloxanes include DC-200 (ex Dow Corning), Baysilone® M 50, Baysilone® M 100, Baysilone® M 350, Baysilone® M 500, Baysilone® M 1000, Baysilone® M 1500, Baysilone® M 2000 or Baysilone® M 5000 (all ex GE Bayer Silicones).
  • the polysiloxane contains the structural units a) and b).
  • a particularly preferred polysiloxane has the following structure: (CH 3 ) 3 Si [O-Si (CH 3 ) 2 ] n - [O-Si (CH 3 ) ⁇ (CH 2 ) 3 -NH- (CH 2 ) 2 -NH 2 ⁇ ] x -OSi ( CH 3 ) 3 where the sum n + x is a number between 2 and 10,000.
  • Suitable polysiloxanes having the structural units a) and b) are for example commercially available under the trade names DC2-8663, DC2-8035, DC2-8203, DC05-7022 or DC2-8566 (all ex Dow Corning). According to the invention are also suitable, for example, the commercially available products of Dow Corning ® 7224, Dow Corning ® 929 Cationic Emulsion or Formasil 410 (GE Silicones).
  • the cationic polymers do not necessarily have only a textile softening effect, but may additionally have a skin-care effect.
  • a skin-care compound is understood to mean a compound or a mixture of compounds which, upon contact of a textile with the solid, textile and / or skin-care composition, draw on the textile and, on contact of the textile with skin, confer an advantage on the skin compared with a textile which has not been treated with the textile and / or skin care composition according to the invention.
  • This benefit may include, for example, the transfer of the skin care compound from the textile to the skin, less water transfer from the skin to the textile, or less friction on the skin surface through the textile.
  • Suitable textile-care compounds preferably include fluorescers, anti-redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, antistatic agents, ironing auxiliaries, UV absorbers, repellents, impregnating agents.
  • fluorescers preferably include fluorescers, anti-redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, antistatic agents, ironing auxiliaries, UV absorbers, repellents, impregnating agents.
  • these textile-care compounds can be found in the description of the washing or cleaning agent according to the invention and can also be used in the solid, textile and / or skin care composition.
  • the solid, textile and / or skin care composition may also contain mixtures of said compounds.
  • the amount of textile and / or skin care compound in the textile and / or skin care composition is 0.1 to 10 wt .-% and preferably between 1 and 6 wt .-%.
  • the water-soluble carrier preferably includes inorganic alkali metal salts such as sodium chloride, potassium chloride, sodium sulfate, sodium carbonate, potassium sulfate, potassium carbonate, sodium bicarbonate, potassium bicarbonate or mixtures thereof, organic alkali metal salts such as sodium acetate, potassium acetate, sodium citrate, sodium tartrate or potassium sodium tartrate, inorganic alkaline earth metal salts such as calcium chloride or magnesium chloride, organic alkaline earth metal salts such as calcium lactate, carbohydrates, organic acids such as citric acid or tartaric acid, silicates such as water glass, sodium silicate or potassium silicate, urea and mixtures thereof.
  • inorganic alkali metal salts such as sodium chloride, potassium chloride, sodium sulfate, sodium carbonate, potassium sulfate, potassium carbonate, sodium bicarbonate, potassium bicarbonate or mixtures thereof
  • organic alkali metal salts such as sodium acetate, potassium acetate, sodium citrate, sodium tartrate or potassium
  • the water-soluble carrier may in particular comprise a carbohydrate, which is for example selected from the group consisting of dextrose, fructose, galactose, isoglucose, glucose, sucrose, raffinose and mixtures thereof.
  • the carbohydrate used may be, for example, candy or hail sugar.
  • the water-soluble carrier may also contain mixtures of said materials.
  • the water-soluble carrier has particle sizes in the range from 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm. More preferably, the water-soluble carrier comprises sucrose crystals having a particle size of 1 to 2 mm.
  • the texil and / or skin care compound is employed as a liquid, either neat or in the form of a solution, emulsion or dispersion, to increase the adhesiveness of the coating to the water-soluble carrier.
  • the textile and / or skin care composition according to the invention may optionally contain further ingredients.
  • dyes In order to improve the aesthetic impression of the textile and / or skin care composition, they can be dyed with suitable dyes.
  • Preferred dyes the selection of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of the laundry detergents or cleaners and to light and no pronounced substantivity to textile fibers so as not to stain them.
  • the textile and / or skin care composition contains a perfume.
  • perfume oils or fragrances individual fragrance compounds, e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type are used. Preferably, however, mixtures of different fragrances are used, which together produce an attractive fragrance.
  • perfume oils may also contain natural fragrance mixtures as are available from plant sources.
  • the amount of perfume in the textile and / or skin care composition is preferably between 0.1 and 20 wt.%, Particularly preferably between 1 and 10 wt.%, And most preferably between 2 and 7 wt .-%.
  • the textile and / or skin care composition may contain a filler, such as silica or salts.
  • the salts may include, for example, alkali or alkaline earth salts, such as, for example, sodium sulfate.
  • the amount of filler may be between 0.1 and 10 wt .-% and is preferably 1 to 5 wt.%.
  • the textile and / or skin care composition may also contain a pearlescing agent to increase gloss.
  • suitable pearlescing agents are ethylene glycol mono- and distearate (for example Cutina AGS from Cognis) and PEG-3-distearate.
  • the textile and / or skin care composition may also contain a binder.
  • Suitable binders include, for example, polyethylene glycols, fusible carbohydrates, polyesters, fatty acids, fatty acid soaps or quaternized ammonium compounds.
  • the coating powder comprising the fabric softening clay, perfume and the textile and / or skin care compound and optionally dyes, fillers and / or pearlescing agents, is applied to the water-soluble carrier in a mixer ,
  • the textile and / or skin care composition is particularly suitable for conditioning textile fabrics and is used together with a conventional Washing or cleaning agent in the (main) wash of a conventional washing and cleaning process brought into contact with the fabrics.
  • the textile and / or skin care composition can be incorporated into a detergent or cleaning agent.
  • a solid detergent or cleaning agent is mixed with 0.1 to 20% by weight, preferably 1 to 10% by weight, of the textile and / or skin care composition according to the invention.
  • the washing or cleaning agents according to the invention contain, in addition to the textile and / or skin care composition, surfactant (s), it being possible to use anionic, nonionic, zwitterionic and / or amphoteric surfactants. From an application point of view, preference is given to mixtures of anionic and nonionic surfactants.
  • the total surfactant content of a detergent is preferably below 40% by weight and more preferably below 35% by weight, based on the total detergent.
  • the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten.
  • alcohol ethoxylates with linear radicals of alcohols of native origin having 12 to 18 carbon atoms, for example of coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred.
  • the preferred ethoxylated alcohols include, for example, C 12-14 alcohols with 3 EO, 4 EO or 7 EO, C 9-11 alcohols with 7 EO, C 13-15 alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C 12-18 -alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C 12-14 -alcohol with 3 EO and C 12-18 -alcohol with 7 EO.
  • the degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.
  • Preferred alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE).
  • fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
  • Nonionic surfactants containing EO and PO groups together in the molecule can also be used according to the invention.
  • block copolymers with EO-PO block units or PO-EO block units can be used, but also EO-PO-EO copolymers or PO-EO-PO copolymers.
  • mixed alkoxylated nonionic surfactants can be used in which EO and PO units are not blockwise, but are statistically distributed. Such products are available by the simultaneous action of ethylene and propylene oxide on fatty alcohols.
  • nonionic surfactants and alkyl glycosides of the general formula RO (G) x can be used in which R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol which represents a glycose unit having 5 or 6 C atoms, preferably glucose.
  • the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1.2 to 1.4.
  • Alkyl glycosides are known, mild surfactants.
  • nonionic surfactants used either as the sole nonionic surfactant or in combination with other nonionic surfactants are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having from 1 to 4 carbon atoms in the alkyl chain, especially fatty acid methyl esters.
  • Nonionic surfactants of the amine oxide type for example N + -cocoalkyl-N, N-dimethylamine oxide and N-tallowalkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamides may also be suitable.
  • the amount of these nonionic surfactants is preferably not more than that of the ethoxylated fatty alcohols, especially not more than half thereof.
  • the content of nonionic surfactants in the detergents or cleaners is preferably 5 to 30% by weight, preferably 7 to 20% by weight and in particular 9 to 15% by weight, in each case based on the total washing or cleaning agent.
  • anionic surfactants for example, those of the sulfonate type and sulfates are used.
  • surfactants of the sulfonate type preferably come C 9-13 -Alkylbenzalsulfonate, olefinsulfonates, ie mixtures of alkene and Hydroxyalkansulfonaten and disulfonates, such as those from C 12-18 monoolefins with terminal or internal double bond by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acid hydrolysis of the sulfonation products into consideration.
  • alkanesulfonates which are obtained from C 12-18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization.
  • esters of ⁇ -sulfo fatty acids for example the ⁇ -sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids.
  • Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C 12 -C 18 fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C 10 -C 20 oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Also preferred are alk (en) ylsulfates of said chain length, which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials.
  • the C 12 -C 16 -alkyl sulfates and C 12 -C 15 -alkylsates and C 14 -C 15 -alkyl sulfates are preferred.
  • 2,3-alkyl sulfates which can be obtained as commercial products of Shell Oil Company under the name DAN ® , are suitable anionic surfactants.
  • EO ethylene oxide
  • Fatty alcohols with 1 to 4 EO are suitable. Due to their high foaming behavior, they are only used in detergents in relatively small amounts, for example in amounts of from 1 to 5% by weight.
  • Suitable anionic surfactants are also the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or as sulfosuccinic acid esters and the monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols.
  • Particularly preferred anionic surfactants are soaps.
  • Suitable are saturated and unsaturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid and, in particular, soap mixtures derived from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids.
  • the anionic surfactants may be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine.
  • the anionic surfactants are preferably present in the form of their sodium or potassium salts, in particular in the form of the sodium salts.
  • the content of anionic surfactants in detergents or cleaners is from 2 to 30% by weight, preferably from 4 to 25% by weight and in particular from 5 to 22% by weight, based in each case on the entire washing or cleaning agent.
  • washing or cleaning agents may contain other ingredients that further improve the performance and / or aesthetic properties of the detergent or cleaning agent.
  • preferred washing or cleaning agents additionally comprise one or more substances from the group of builders, bleaches, bleach activators, enzymes, perfumes, perfume carriers, fluorescers, dyes, foam inhibitors, silicone oils, antiredeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-caking agents , Color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, antistatic agents, bittering agents, cursing agents, repellents and impregnating agents, swelling and anti-slip agents, neutral filling salts and UV absorbers.
  • neutral fillers such as sodium sulfate or sodium carbonate may be included in the solid detergents or cleaners.
  • washing or cleaning agents according to the invention can be used in particular for cleaning and conditioning textile fabrics.
  • the washing or cleaning agent without the textile and / or skin care composition is first prepared by known processes which include, for example, drying steps, mixing steps, densification steps, shaping steps and / or the subsequent addition of heat-sensitive ingredients ("post addition"). ). Subsequently, the product obtained is mixed with a solid, textile and / or skin care composition.
  • the compaction step can be followed by further compaction and / or shaping steps.
  • Table 1 shows textile and / or skin care compositions E1 to E5 according to the invention.
  • Table 1 E1 E2 E3 E4 E5 NaCl crystals (5 to 10 mm) 79.99 - - - 89.49 Sucrose crystals (3 to 7 mm) - 75.99 83,99 84.99 - bentonite 6 5 5 5 5 silica 2 5 3 2 - Perfume 5 5 7 6 5 polydimethylsiloxane 7 9 - - - Polyquaternium-7 - - 1 - - Polyquaternium-10 - - - 2 - Tinopal® CBS-X * - - - - - 0.5 sodium sulphate - - - - - - dye 0.01 0.01 0.01 0.01 0.01 * ex Ciba
  • the textile and / or skin care compositions according to the invention exhibited a softening effect in comparison with water (the fabrics treated with water or with the textile and / or skin care compositions were treated after treatment and suspended drying from a panel consisting of 5 persons tapped).
  • the textile and / or skin care compositions of the present invention are capable of reducing the hardness of water. This determination was carried out with analysis sticks "total hardness test" (Merck) according to the manufacturer's instructions.
  • washing or cleaning agent prepared according to the invention, a solid, unperfumed washing or cleaning agent was mixed with 10% by weight (based on the total amount of finished washing or cleaning agent) of the textile and / or skin care composition E6 .
  • the washing or cleaning agent according to the invention showed good cleaning and conditioning properties.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Cosmetics (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
EP07726685A 2006-04-06 2007-03-07 Feste, textil- und/oder hautpflegende zusammensetzung Not-in-force EP2001985B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL07726685T PL2001985T3 (pl) 2006-04-06 2007-03-07 Stały zestaw do pielęgnacji tekstyliów i/lub skóry

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006016575A DE102006016575A1 (de) 2006-04-06 2006-04-06 Feste, textil- und/oder hautpflegende Zusammensetzung
PCT/EP2007/052127 WO2007113069A1 (de) 2006-04-06 2007-03-07 Feste, textil- und/oder hautpflegende zusammensetzung

Publications (2)

Publication Number Publication Date
EP2001985A1 EP2001985A1 (de) 2008-12-17
EP2001985B1 true EP2001985B1 (de) 2012-02-08

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Country Status (8)

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US (1) US8518867B2 (pl)
EP (1) EP2001985B1 (pl)
JP (1) JP5334836B2 (pl)
AT (1) ATE544841T1 (pl)
DE (1) DE102006016575A1 (pl)
ES (1) ES2378162T3 (pl)
PL (1) PL2001985T3 (pl)
WO (1) WO2007113069A1 (pl)

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DE102006054436A1 (de) 2006-11-16 2008-05-21 Henkel Kgaa Feste, textil- und/oder hautpflegende Zusammensetzung
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DE102008050360A1 (de) * 2008-10-02 2010-04-08 Süd-Chemie AG Waschmitteladditiv auf der Basis von Tonmineralien, sowie dessen Verwendung und Verfahren zu dessen Herstellung
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WO2017051776A1 (ja) * 2015-09-24 2017-03-30 ライオン株式会社 液体洗浄剤組成物
WO2017111323A1 (ko) * 2015-12-21 2017-06-29 주식회사 엘지생활건강 섬유 처리용 조성물
KR102073867B1 (ko) * 2015-12-21 2020-02-05 주식회사 엘지생활건강 섬유 처리용 조성물
KR102030757B1 (ko) * 2016-03-15 2019-10-10 주식회사 엘지생활건강 섬유 처리용 조성물
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Also Published As

Publication number Publication date
JP2009532592A (ja) 2009-09-10
EP2001985A1 (de) 2008-12-17
JP5334836B2 (ja) 2013-11-06
DE102006016575A1 (de) 2007-10-11
US20090082244A1 (en) 2009-03-26
ATE544841T1 (de) 2012-02-15
PL2001985T3 (pl) 2012-07-31
US8518867B2 (en) 2013-08-27
ES2378162T3 (es) 2012-04-09
WO2007113069A1 (de) 2007-10-11

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