EP1979585A1 - Appareil de purification de gaz d'echappement et procede de purification de gaz d'echappement - Google Patents

Appareil de purification de gaz d'echappement et procede de purification de gaz d'echappement

Info

Publication number
EP1979585A1
EP1979585A1 EP07706876A EP07706876A EP1979585A1 EP 1979585 A1 EP1979585 A1 EP 1979585A1 EP 07706876 A EP07706876 A EP 07706876A EP 07706876 A EP07706876 A EP 07706876A EP 1979585 A1 EP1979585 A1 EP 1979585A1
Authority
EP
European Patent Office
Prior art keywords
catalyst
exhaust gas
flow direction
flow
normal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP07706876A
Other languages
German (de)
English (en)
Inventor
Juji Suzuki
Masahiko Ogai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyota Motor Corp
Original Assignee
Toyota Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyota Motor Corp filed Critical Toyota Motor Corp
Publication of EP1979585A1 publication Critical patent/EP1979585A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
    • F01N3/025—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using fuel burner or by adding fuel to exhaust
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9431—Processes characterised by a specific device
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/944—Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • F01N13/0097—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series the purifying devices are arranged in a single housing
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
    • F01N3/0233—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles periodically cleaning filter by blowing a gas through the filter in a direction opposite to exhaust flow, e.g. exposing filter to engine air intake
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
    • F01N3/025—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using fuel burner or by adding fuel to exhaust
    • F01N3/0253—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using fuel burner or by adding fuel to exhaust adding fuel to exhaust gases
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/033—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
    • F01N3/035—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/0842—Nitrogen oxides
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0871—Regulation of absorbents or adsorbents, e.g. purging
    • F01N3/0885—Regeneration of deteriorated absorbents or adsorbents, e.g. desulfurization of NOx traps
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2093—Periodically blowing a gas through the converter, e.g. in a direction opposite to exhaust gas flow or by reversing exhaust gas flow direction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/01—Engine exhaust gases
    • B01D2258/012—Diesel engines and lean burn gasoline engines
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2240/00—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/36—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being an exhaust flap
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0821—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with particulate filters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Definitions

  • the present invention relates to an exhaust gas-purifying apparatus , comprising at least an NO x occlusion reduction catalyst and a filter catalyst arranged in series, and an exhaust gas purifying method using the same.
  • a catalyst for efficiently removing NO x from vehicle exhaust gas is known as an NO x occlusion reduction catalyst.
  • Such an NO x occlusion reduction catalyst is formed by supporting an NO x occluding material, selected from among alkali metals, alkali earth metals on the like, and noble metal, on an oxide support such as alumina.
  • NO x is adsorbed on an NO x occluding material in the form of nitrate or nitrite.
  • the exhaust gas in a rich atmosphere is allowed to flow in a pulsing manner, thereby decomposing nitrate or nitrite.
  • the emitted NO x is reduced and purified by a reduction component that is abundantly present in the atmosphere.
  • sulfur oxide (SO x ) present in the exhaust gas reacts with the NO x occluding material, undesirably causing sulfur poisoning related to the deterioration of NO x occlusion performance.
  • SO x sulfur oxide
  • the sulfur-poisoned NO x occluding material is present in the form of sulfate or sulfite, which has a higher decomposition temperature than nitrate or nitrite.
  • treatment for recovering the NO x occlusion function of the sulfur-poisoned NO x occluding material is performed.
  • the recovery treatment is a process of allowing exhaust gas in a high-temperature rich atmosphere added with a reducing agent to flow in a pulsing manner to thereby reduce and decompose the sulfur-poisoned NO x occluding material .
  • Japanese Patent No. 2605580 discloses a method of reducing and desorbing SO x through the inflow of rich gas having a low oxygen concentration. According to this method, SO x is found to be more easily removed under higher temperature conditions. Also, Japanese Patent Application Publication No.
  • H08-061052 discloses a method of heating a catalyst to 800 ⁇ 900 ° C in order to emit SO x from a sulfur-poisoned NO x occluding material .
  • Japanese Patent Application Publication No. 2000-230447 discloses a method of decreasing the temperature of the recovery process by supplying a large amount of reduction gas such as CO.
  • Japanese Patent Application Publication No .2002-013413 describes the reversed exhaust gas flow of the NO x occlusion reduction catalyst upon recovery from sulfur poisoning.
  • the temperature at the outlet of the catalyst is higher than that at the inlet thereof due to the reaction heat of the catalyst.
  • the original outlet having a high temperature becomes an inlet, and thus such heat is used to recover the NO x occlusion function.
  • the original inlet becomes an outlet, it is brought into contact with the exhaust gas having a high temperature due to the reaction heat of the catalyst, and therefore the NO x occlusion function may also be recovered at the original inlet.
  • the exhaust gas purifier for diesel engines developed to date is largely classified into a trap type exhaust gas purifier (wall flow) and an open type exhaust gas purifier (straight flow) .
  • the trap type exhaust gas purifier is known to be a clogged ceramic honeycomb body (diesel PM filter, hereinafter referred to as "DPF") .
  • the DPF in which both open ends of the cells of a ceramic honeycomb structure (e.g., a checkered pattern) comprises inlet cells, outlet cells and cell partition walls.
  • the inlet cells each are clogged at the downstream side of the exhaust gas flow direction.
  • the outlet cells each adjoin the respective inlet cells and clogged at the upstream side of the exhaust gas flow direction.
  • the cell partition walls each partition the respective inlet cells and outlet cells.
  • a continuous regenerative type DPF (filter catalyst) has been developed by forming a coating layer such as an alumina on the surface of the cell partition of the DPF and supporting noble metal such as platinum (Pt) on the coating layer.
  • the PM since the captured PM is oxidized and combusted through the catalytic reaction of n ' oble metal, the PM may be combusted simultaneously with or successively to the capture thereof, thereby making it possible to recover the filter function. Further, the catalytic reaction occurs at a relatively lowtemperature and the PMmaybe combusted even though the collected amount thereof is small. Thereby, the DPF is advantageously prevented from breakage due to low heat stress applied thereto.
  • a filter catalyst in which a coating layer is further supported with an NO x occluding material selected from among alkali metals, alkali earth metals, and rare earth elements.
  • NO x is occluded on the NO x occluding material and NO x emitted in a rich atmosphere is reduced, thereby increasing NO x purification performance highly. Therefore, in the case where the exhaust gas of a diesel engine is purified using the above filter catalyst, a system in which a reducing agent is intermittently added to the exhaust gas to thereby form a rich atmosphere is adopted.
  • this filter catalyst having the NO x occluding materials supported thereon has low HC oxidation activity of noble metal. Thus various methods of attaching a reducing agent to a filter catalyst or decreasing accumulation of PM need to be researched.
  • Japanese Patent Application Publication No. 2002-021544 discloses a purification technologies, in which an oxidation catalyst or an NO x occlusion reduction catalyst is disposedat theupstream side of a filter catalyst, andHC is supplied to the exhaust gas through the post spray of fuel into a combustion chamber or through the addition of fuel to the exhaust gas. It is also described that the reaction heat of the oxidation catalyst or NO x occlusion reduction catalyst make PM accumulated in the DPF or filter catalyst combusted and NO x reduced and purified.
  • the reducing agent such as light oil
  • the reducing agent need to be added before the NO x occlusion capability of the NO x occlusion reduction catalyst is saturated, in order to recover the ability to adsorb NO x . Accordingly, even upon acceleration or deceleration at a low speed, the reducing agent need to be added at relatively short time intervals . In such a case, however, since the temperature of the exhaust gas is relatively low and decreases further by the addition of the reducing agent, it is thus difficult to react the reducing agent with NO x .
  • the added reducing agent is attached to the filter catalyst in an unreacted state, and the supported catalyst metal is poisoned, and thus the activity thereof is decreased. Furthermore, while the PM adheres to the attached reducing agent, front end cells are undesirably clogged.
  • the NO x occlusion reduction catalyst is disposed at the upstream side of the filter catalyst, there is a need for recovery treatment from sulfur poisoning with respect to the NO x occlusion reduction catalyst.
  • the temperature of exhaust gas flowing into the NO x occlusion reduction catalyst is, for example, 300 ° C
  • the temperature distribution of each catalyst is as illustrated in FIG. 9.
  • a temperature not lower than 650 ° C is required.
  • the temperature of the downstream filter catalyst is increased, and noble metal supported on the filter catalyst may be deteriorated due to grain growth.
  • the PM accumulated in the filter catalyst may be combusted all. at once, undesirably causing heat stress. As a result, a filter catalyst may be damaged.
  • Embodiments of the present invention provide an exhaust gas purifying apparatus, comprising an NO x occlusion reduction catalyst disposed upstream thereof and a filter catalyst disposed downstreamthereof, thus improving recovery from sulfur poisoning, preventing deterioration and breakage of the filter catalyst.
  • the exhaust gas purifying apparatus for achieving the above object of the present invention is characterized in that it comprises a reducing agent supply device supplying a reducing agent to exhaust gas, a first catalyst comprising an NO x occlusion reduction catalyst obtainedby forming a catalyst layer on a surface of a honeycomb substrate having a straight flow structure, the catalyst layer including a porous oxide support and an NO x occluding material and noble metal supported thereon, a second catalyst obtainedby forming a catalyst layer at least on a surface of filter substrate having a wall flow structure and including a porous oxide support and at least a noble metal supported thereon, a container having at least the first catalyst and the second catalyst arranged in series, and a direction change device changing the flow direction of the exhaust gas in the container between a normal flow direction and a reverse flow direction, wherein in the normal flow direction, the first catalyst is disposed upstream of the exhaust gas flow direction and the second catalyst is disposed downstream thereof, in the reverse flow direction, the second catalyst is disposed upstream
  • the first catalyst, the second catalyst, and a third catalyst obtainedby forming a catalyst layer consisting of a porous oxide support and noble metal supported thereon on the surface of a honeycomb substrate having a straight flow structure are sequentially arranged in series, and the direction change device preferably changes (reverses) the flow direction of the exhaust gas between a normal flow direction in a sequence of the first catalyst, the second catalyst, and then the third catalyst and a reverse flow direction in a sequence of the third catalyst, the second catalyst, and then the first catalyst.
  • the exhaust gas purifying method according to the present invention is characterized in that it comprises a normal flow process for allowing exhaust gas to typically flow and a recovery process for allowing exhaust gas in a high-temperature rich atmosphere, added with a reducing agent, to flow in a pulsing manner so that a sulfur-poisoned NO x occluding material is reduced to thereby recover the NO x occlusion function, using the exhaust gas purifying apparatus of the present invention .
  • the recovery process the flow direction ' of the exhaust gas upon the normal flow process is changed (reversed) .
  • the method of the present invention also includes a regeneration process for allowing the exhaust gas in a lean atmosphere added with a reducing agent to flow in a pulsing manner to thereby generate combustion heat which is then used to combust PM accumulated in the second catalyst so as to regenerate the PM collection function.
  • a regeneration process for allowing the exhaust gas in a lean atmosphere added with a reducing agent to flow in a pulsing manner to thereby generate combustion heat which is then used to combust PM accumulated in the second catalyst so as to regenerate the PM collection function.
  • the flow direction of the exhaust gas upon the normal flow process is changed (reversed) .
  • the exhaust gas purifying apparatus of the present invention comprises the direction change device changing the flow direction of the exhaust gas in the container having the first catalyst, composed of an NO x occlusion reduction catalyst, and the second catalyst, serving as a filter catalyst, arranged in series, between the normal flow direction in which the first catalyst is disposed upstream of the exhaust gas flow direction and the second catalyst is disposed downstream thereof and the reverse flow direction in which the second catalyst is disposed upstream of the exhaust gas flow direction and the first catalyst is disposed downstream thereof . Further, in the recovery process of the exhaust gas purifying method of the present invention, the flow direction of the exhaust gas upon the normal flow process is changed (reversed) .
  • the flow direction of the exhaust gas in the recovery process becomes the direction toward the first catalyst from the second catalyst.
  • the amount of sulfur poisoning is increased toward the upstream side at a low temperature, and is larger in the first catalyst than in the second catalyst and also is larger at the upstream side of the first catalyst than at the downstream side thereof.
  • the exhaust gas flow direction is changed (reversed) in the recovery process so that the second catalyst is provided upstream with respect to the exhaust gas flow direction, the exhaust gas is further heated by the reaction heat of the second catalyst, and therefore the temperature of the first catalyst becomes higher than that of the second catalyst. Consequently, in the NO x occlusion reduction catalyst constituting the first catalyst, recovery from sulfur poisoning is improved.
  • the second catalyst which is downstream, has a higher temperature than the first catalyst, and the temperature of the downstream side of the second catalyst is higher than that of the upstream side thereof. That is, even though the temperature of the exhaust gas flowing into the second catalyst is decreased to 650°C or less upon the recovery process, the temperature of the exhaust gas flowing into the first catalyst is high, and thus the first catalyst may sufficiently recover from sulfur poisoning. Hence, it is possible to inhibit the deterioration andbreakage ofthe second catalyst (filter catalyst) due to heat.
  • the second catalyst (filter catalyst) further includes the NO x occluding materials supported thereon
  • the amount of sulfurpoisoning is larger atthe upstream sidethereof than at the downstream side thereof upon the normal flow process.
  • FIG.1 is a schematic view illustrating the exhaust gas purifying apparatus according to a first embodiment of the present invention, in which exhaust gas flows in a normal flow direction,
  • FIG.2 is a schematic view illustrating the exhaust gas purifying apparatus according to the first embodiment of the present invention, in which exhaust gas flows in a reverse flow direction,
  • FIG.3 is a schematic view illustrating the exhaust gas purifying apparatus according to a second embodiment of the present invention, in which exhaust gas flows in a normal flow direction,
  • FIG.4 is a schematic view illustrating the exhaust gas purifying apparatus according to the second embodiment of the present invention, in which exhaust gas flows in a reverse flow direction,
  • FIG. 5 is a graph illustrating the concentration distribution of sulfur
  • FIG. 6 is a graph illustrating the concentration distribution of ash
  • FIG.7 is a schematic view illustrating the exhaust gas purifying apparatus according to a third embodiment of the present invention, in which exhaust gas flows in a normal flow direction,
  • FIG.8 is a schematic view illustrating the exhaust gas purifying apparatus according to a fifth embodiment of the present invention, in which exhaust gas flows in a normal flow direction, and
  • FIG. 9 is a schematic view illustrating a general catalyst temperature distribution.
  • the apparatus for purifying exhaust gas comprises a first catalyst and a second catalyst .
  • the first catalyst comprises an NO x occlusion reduction catalyst, thatis, maybe composed of only an NO x occlusion reduction catalyst, or of a three-way catalyst or an oxidation catalyst and an NO x occlusion reduction catalyst that have been applied and divided.
  • TheNO x occlusion reduction catalyst is obtainedby forming a catalyst layer, consisting of a porous oxide support and an NO x occluding material and noble metal supported thereon, on the surface of a honeycomb substrate having a straight flow structure.
  • a conventional NO x occlusion reduction catalyst may be used.
  • the honeycomb substrate include a monolithic honeycomb substrate, formed of heat resistant ceramics such as cordierite, or a metallic honeycomb substrate formed of a metal foil.
  • the porous oxide is selected from among alumina, titania, zirconia, silica, ceria, composite oxides formed of a plurality of species thereof, and mixtures thereof.
  • the NO x occluding material is at least one selected from among alkali metals, alkali earth metals, and rare earth elements, and a mixture of alkali metal and alkali earth metal is preferably useful.
  • the NO x occluding material is preferably supported in a range of an amount of 0.05 ⁇ lmolper liter of the honeycomb substrate .
  • the noble metal is selected from among Pt, Rh, Pd, Ru, and Ir, and Pt having high oxidation activity is particularly useful .
  • the noble metal is preferably supported in a range of an amount of 0.1—5 g per liter of the honeycomb substrate.
  • the second catalyst is a filter catalyst obtained by forming a catalyst layer consisting of a porous oxide support and at least a noble metal supported thereon on at least the surface of a filter substrate having a wall flow structure.
  • the filter substrate is composed of inlet cells clogged at the downstream side of the exhaust gas flow direction, outlet cells adjacent to the inlet cells and clogged at the upstream side of the exhaust gas flow direction, and porous cell partitions having a plurality of fine pores and sectioning the inlet cells and the outlet cells.
  • a conventional DPF made of heat resistant ceramics such as cordierite or silicon carbide may be used.
  • the fine pores of the cell partition of the filter substrate are preferably distributed to have porosity of 40—80% and an average diameter of 10 — 50 ⁇ m. In the case where the porosity or average diameter falls outside of the above range, PM capture efficiency is decreased and the loss of exhaust pressure may be increased.
  • a catalyst layer including a porous oxide support and at least the noble metal supported thereon, is formed. Further, the catalyst layer is preferably formed on the inner surface of the fine pores of the cell partition.
  • Theporous oxide is selected fromamong alumina, titania, zirconia, silica, ceria, composite oxides formed of plurality of species thereof, and mixtures thereof.
  • the noble metal is one or more selected from among noble metals of a platinum group, including Pt, Rh, Pd, Ru, and Ir.
  • the noble metal is preferably supported in a range of an amount of 0.1 ⁇ 5 g per liter of the filter substrate. If the amount is less than the lower limit, the activity is very low and thus is unusable . On the other hand, if the amount exceeds the upper limit, the activity is saturated and the cost is increased.
  • the catalyst layer of the second catalyst further includes a NO x occluding material which is selected from among alkali metals, alkali earth metals, and rare earth elements, and which is supported thereon, as in the first catalyst. Due to the NO x occluding material included in the catalyst layer, NO x purification activity is increased.
  • the NO x occluding material is preferably supported in a range of an amount of 0.05 ⁇ l mol per liter of the filter substrate. If the amount is less than the lower limit, the activity is very low and thus unusable. On the other hand, if the amount exceeds the upper limit, the catalyst metal is covered, and thus the activity thereof is decreased.
  • porous oxide powder is formed into a slurry along with a binder component, such as alumina sol, and water. Subsequently, the slurry is attached to the partition and then burned. Subsequently, noble metal and an NO x occluding material are supported thereon.
  • a binder component such as alumina sol
  • the slurry may be forcibly charged in the fine pores of the cell partition through air blowing or suction.
  • the slurry remaining after being charged in the fine pores is preferably removed.
  • the catalyst layer is formed in a range of an amount of 30 ⁇ 200 g per liter of the filter substrate. If the amount of the catalyst layer is less than the lower limit, the durability of the noble metal or NO x occluding material is decreased. On the other hand, if the amount exceeds the upper limit, the loss of pressure is excessively increased and thus is unusable.
  • the exhaust gas purifying apparatus of the present invention comprises a reducing agent supply device supplying a reducing agent to the exhaust gas.
  • a reducing agent may be supplied to the exhaust gas under a fuel rich condition based on the air-to-fuel ratio in the combustion chamber.
  • active HC resulting from partial oxidation of a liquid reducing agent, such as light oil, may be supplied to the exhaust gas.
  • an oxidation catalyst be disposed in the uppermost end of the exhaust gas flow direction in the recovery process.
  • a third catalyst is further connected to the first catalyst and the second catalyst in series, and thus the first catalyst, the second catalyst, and the third catalyst, in that order, are preferably arranged.
  • the third catalyst is preferably at least one selected from among an NO x occlusion reduction catalyst, a three-way catalyst, and an oxidation catalyst, and preferably includes at least the NO x occlusion reduction catalyst.
  • the same purification performance may be assured even when the normal flow process is performedwithout changingthe direction after the recoveryprocess .
  • the second catalyst filter catalyst
  • the second catalyst since the second catalyst (filter catalyst) may be used in two directions, PM and ash accumulated in the fine pores of the cell partition are always discharged when the flow direction is changed, andan increase in the loss ofpressure may be effectively inhibited.
  • the exhaust gas primarily flows into the third catalyst in the recovery process. Since the third catalyst has high oxidation activity, heat generated when part of the reducing agent in the exhaust gas is oxidized is responsible for drastically increasing the temperature of the exhaust gas. Ultimately, even though low-temperature exhaust gas is supplied, recovery from sulfur poisoning remains high, thereby improving such capability.
  • the first catalyst is preferably composed of an oxidation catalyst or a three-way catalyst disposed at the upstream side of the exhaust gas and an NO x occlusion reduction catalyst disposed at the downstream side thereof.
  • the third catalyst is preferably composed of an oxidation catalyst or three-way catalyst disposed at the upstream side of the exhaust gas and an NO x occlusion reduction catalyst disposed at the downstream side thereof. In such cases, both functions are realized, so that the increase in the loss of exhaust pressure is inhibited and recovery from sulfur poisoning is improved.
  • the exhaust gas atmosphere in a normal flow process may be either a lean-burn atmosphere or an alternating lean / rich atmosphere.
  • the rich atmosphere may also be provided in a recovery process or in a regeneration process, as described below.
  • the temperature of the exhaust gas containing the reducing agent upon the recovery process preferably ranges from 650 to 700 ° C. If the temperature is above the upper limit, grain growth of the noble metal in the downstream catalyst results, or PM accumulated in the second catalyst is rapidly combusted, undesirably resulting in a broken filter substrate. On the other hand, if the temperature is below the lower limit, recovery from sulfur poisoning is decreased.
  • a regeneration process is preferably further performed by allowing the exhaust gas in the lean atmosphere added with the reducing agent to flow in a pulsing manner to thereby generate combustion heat which is then used to combust the PM accumulated in the second catalyst, thus regenerating the PM capture function.
  • the regeneration process is preferably carried out in the case where the loss value of exhaust pressure, determined by continuous detection, falls within a predetermined range .
  • the reducing atmosphere is typically weaker than in the recovery process.
  • the regeneration process precede the recovery process.
  • the temperature is drastically increased and thus the honeycomb substrate may be cracked, or may be melted and damaged. Consequently, the regeneration process, which acts to gradually increase the temperature, preferably precedes the recovery process.
  • the flow direction of the exhaust gas in the normal flow process is preferably changed.
  • the amount of PM capture by the filter substrate is larger at the upstream side (inlet cell) of the exhaust gas flow direction upon the normal flow process .
  • a liquid reducing agent is attached to an opening portion of the passage of the inlet cell, and also a large amount of PM may adhere thereto. Therefore, in the case where the flow direction of exhaust gas is changed in the regeneration process, the PM and ash may be blown by the flow of exhaust gas, resulting in increased regeneration efficiency.
  • FIGS .1 and 2 schematically illustrate the exhaust gas purifying apparatus according to the present invention.
  • an NO x occlusion reduction catalyst 2 (hereinafter referred to as NSR2) as a first catalyst and a filter catalyst 3 (hereinafter, referred to as DPNR3) as a second catalyst are sequentially arranged in series in a catalytic converter 1.
  • DPNR3 is an NO x occlusion reduction type filter catalyst.
  • An exhaust pipe 100 from an exhaust manifold is divided into two passages, that is, a first passage 101 and a second passage 102, in front of the catalytic converter 1. Then, the first passage 101 and the second passage 102 are combined with each other again.
  • first passage 101 and the second passage 102 are respectively disposed at either side of the catalytic converter 1, and are then connected to each other.
  • a first valve 200 for switching the exhaust gas from the exhaust pipe 100 to the first passage 101 or the second passage 102 is disposed.
  • a second valve 201 for turning on or off communication between the opening of the catalytic converter 1 and the first passage 101 is disposed.
  • a third valve 202 for turning on or off communication between the other opening of the catalytic converter 1 and the second passage 102 is disposed.
  • an injector 103 for adding light oil to the exhaust gas is further provided in the exhaust pipe 100.
  • the NSR2 comprises a cordierite-based honeycomb substrate (0.8 L, cell number 400/in 2 ) having a straight flow structure and 270 g/L of a catalyst layer formed thereon, the catalyst layer including K, Ba, Li, and 5 g/L of Pt, supported thereon.
  • the DPNR3 comprises a cordierite-based filter substrate (2.0 L, cell number 300/in 2 ) having a wall flow structure and 150 g/L of a catalyst layer, the catalyst layer including K, Ba, Li, and 5 g/L of Pt, supported thereon.
  • the catalyst layer is formed not only on the surface of the cell partition but also on the inner surface of fine pores thereof.
  • the exhaust gas purifying apparatus thus constructed was mounted to the exhaust system of a diesel engine for direct spray, having 2 L of exhaust air volume, on an engine bench. Further, while controlling lean and rich atmospheres to supply a rich spike for 0.2 sec at intervals of 30 sec, a normal flow process for 100 hours (about 5000 km) was conducted under conditions simulating 11 Lap driven by actual automobiles. At intervals of 10 hours during the normal flow process, a recovery process for adding light oil to the exhaust gas at a flow rate of 1000 cm 3 /min for 200 sec using the injector 103 was performed.
  • the second passage 102 is closed by the first valve 200, the communication between the first passage 101 and the catalytic converter 1 is allowedbythe secondvalve 201, and the communication between the second passage 102 and the catalytic converter 1 is blocked by the third valve 202. Accordingly, the exhaust gas flows into the catalytic converter 1 from the first passage 101, sequentially passes through the NSR2 and DPNR3, and is then discharged from the second passage 102.
  • the first passage 101 is closed by the first valve 200, communication between the second passage 102 and the catalytic converter 1 is allowed by the third valve 202, and communication between the first passage 101 and the catalytic converter 1 is blocked by the second valve 201.
  • the exhaust gas flows into the catalytic converter 1 from the second passage 102, sequentially passes through the DPNR3 and NSR2, and is then discharged from the first passage 101.
  • the exhaust gas purifying apparatus of the present example is the same exhaust gas purifying apparatus of Example 1, with the exception that NSR2, DPNR3, and NSR2 are sequentially arranged in a catalytic converter 1.
  • the NSR2 provided at each of the two sides of DPNR3 is the same as the case in which the NSR2 of Example 1 is halved.
  • such an exhaust gas purifying apparatus was mounted to the 2 L exhaust system of a diesel engine for direct spray, and the same normal flow process and recovery process were conducted.
  • the normal flow process was conducted under unchanged valve set conditions, and then the recovery process was conducted with the exhaust gas flow direction changed. That is, in the state shown in FIG. 3, the normal flow process was performed for 10 hours, afterwhich the recoveryprocess was performed in the state shown in FIG. 4, in which the valves were converted. Thereafter, the normal flow process was conducted for 10 hours under unchanged conditions, and then the recovery process was conducted in the state shown in FIG. 3, in which the valves were converted again, after which the normal flow process was conducted for 10 hours under unchanged conditions. These procedures were repeated.
  • the NO x purification efficiency was measured using the method of Example 1. Further, after measurement of the NO x purification efficiency, the NSR2 and DPNR3 were decomposed and the amount of sulfur poisoning was determined through element analysis. In addition, from the difference in weight compared to before the test, the amount of ash after the combustion of PM was calculated. The amounts of sulfur poisoning and ash were measured at the ends of the inlets and outlets of the catalysts. The results are given Table 5 and FIGS. 5 and ⁇ .
  • Example 1 the NO x purification efficiency was measured through the method of Example 1 and the amounts of sulfur poisoning and ash were measured through the method of Example 2. The results are given in Table 5 and FIGS. 5 and 6.
  • Comparative Example 1 related to the conventional exhaust gas purifying method, the amount of sulfur poisoning was higher toward the upstream side, and the sulfur poisoning ofNSR2 inthe uppermost endwas not recoveredeventhrough the recovery process.
  • Example 2 the exhaust gas flow direction was changed to thereby perform the recovery process, whereby the NSR2 on both sides of DPNR3 and the DPNR3 equally recovered from sulfur poisoning, and the ash amount of the DPN.R3 was decreased.
  • Example 3 As illustrated in FIG. 7, the exhaust gas purifying apparatus of the present invention is the same exhaust gas purifyingapparatus as in Example 1, with the exception that NSR2, DPNR3, andanoxidation catalyst 4 (hereinafter referred to ⁇ CCo4") are sequentially arranged in a catalytic converter 1.
  • the NSR2 is the same as the case in which the NSR2 of Example 1 is halved.
  • CCo4 is composed of a cordierite-based honeycomb substrate (2.0 L, cell number of 400/in 2 ) having a straight flow structure and 160 g/L of a catalyst layer formed thereon, the catalyst layer including 5 g/L of Pt supported thereon.
  • Such an exhaust gas purifying apparatus was mounted to the 2 L exhaust system of a diesel engine for direct spray, as in Example 1, and a normal flow process and a recovery process were performed, as in Example 2.
  • Example 2 Using the method of Example 1, the NO x purification efficiency was measured, and also the HC purification efficiency was measured in the normal flow process . Further, using the method of Example 2 , the amounts of sulfur poisoning and ash were measured. The results are shown in Table 10 below. Since the amounts of sulfur poisoning and ash are the same as in Example 2, a figure related thereto is omitted.
  • the normal flow process and recovery process were conducted in the same manner as in Example 2 using the exhaust gas purifying apparatus of Example 3, with the exception that the exhaust gas flow direction was changed only in the recovery process. That is, after the recovery process, the exhaust gas flow direction was changed again and thus the normal flow process was conducted. In the subsequent recovery process, the exhaust gas flow direction was changed. That is, in the state shown in FIG. 7, a normal flow process was performed for 10 hours. Thereafter, respective valves were converted to thereby set the state corresponding to FIG. 4, and thus the recovery process was performed, and then the normal flow process was performed for 10 hours in the state shown in FIG. 7. These procedures were repeated.
  • Example 3 Using the method of Example 3, the NO x purification efficiency and the HC purification efficiency were measured, and the amounts of sulfur poisoning and ash were measured using the method of Example 2. The results are shown in Table 10 below. Also, since the amounts of sulfur poisoning and ash are the same as in Example 2, a figure related thereto is omitted.
  • the exhaust gas purifying apparatus of the present example is the same exhaust gas purifying apparatus as in Example 1, with the exception that CCo4, NSR2, DPNR3, NSR2, and CCo4 are sequentially arranged in a catalytic converter 1.
  • the NSR2 and CCo4 are the same as the case in which each of the NSR2 and CCo4 of Example 4 is halved.
  • the respective catalyst layers of NSR and CCo4 may be formed on a single honeycomb substrate.
  • Such an exhaust gas purifying apparatus was mounted to a 2 L exhaust system of a diesel engine for direct spray as in Example 1, and a normal flow process and a recovery process were conducted according to the method of Example 3.
  • Example 3 Using the method of Example 3, NO x purification efficiency and the HC purification efficiency were measured, and the amounts of sulfurpoisoning and ashweremeasuredusingthemethod of Example 2. The results are shown in Table lObelow. Also, since the amounts of sulfur poisoning and ash are the same as in Example 2, a figure related thereto is omitted.
  • the exhaust gas flow direction of the present comparative example is given in Table 9 below.
  • the exhaust gas flow direction was maintained in a normal flow direction.
  • Example 3 Using the method of Example 3, the NO x purification efficiency and the HC purification efficiency were measured, and the amounts of sulfur poisoning and ash were measured using the method of Example 2. The results are shown in Table 10 below. Also, since the amounts of sulfur poisoning and ash are the same as in Comparative Example 1, a figure related thereto is omitted.
  • Example 3 the NO x purification efficiency'of Example 3 was slightly lower. This is because the rich spike is consumed in the CCo4 due to the flow of the exhaust gas in the sequence of CCo4, DPNR3, NSR2 in the normal flow process upon measurement . Thus, it is preferred that the NSR2 be disposed on both sides of the DPNR3.
  • the exhaust gas purifying apparatus and the exhaust gas purifying method can be applied not only to the purification of exhaust gases from diesel engines but also to the purification of exhaust gases from gasoline engines, gas engines, boilers, etc.
  • the invention has been shown and described with respect to preferred embodiments thereof, it will be understood by those skilled in the art that various changes and modification may be made without departing from the spirit and scope of the invention as defined in the following claims.

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  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
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  • Exhaust Gas After Treatment (AREA)
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  • Processes For Solid Components From Exhaust (AREA)
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Abstract

L'invention concerne un appareil de purification de gaz d'échappement, comprenant un catalyseur (2) de réduction d'occlusion de NOx et un catalyseur filtre (3) disposés en série.On permet aux gaz d'échappement de circuler du catalyseur (2) de réduction d'occlusion de NOx au catalyseur filtre (3) selon un processus d'écoulement normal et, dans un processus de récupération, pour permettre aux gaz d'échappement additionnés d'un agent réducteur de circuler, on inverse le sens d'écoulement des gaz d'échappement du catalyseur filtre (3) vers le catalyseur (2) de réduction d'occlusion de NOx. Étant donné que les gaz d'échappement sont chauffés par la chaleur de réaction du catalyseur filtre (3), le catalyseur (2) de réduction d'occlusion de NOx peut se remettre d'un empoisonnement au soufre dans les gaz d'échappement à basse température. De cette façon, on prévient une surchauffe du catalyseur filtre (3). Par conséquent, on peut améliorer la récupération après un empoisonnement au soufre et empêcher aussi une détérioration et une rupture du catalyseur filtre.
EP07706876A 2006-01-17 2007-01-10 Appareil de purification de gaz d'echappement et procede de purification de gaz d'echappement Withdrawn EP1979585A1 (fr)

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JP2007192055A (ja) 2007-08-02
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RU2392456C2 (ru) 2010-06-20
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