EP1952469A2 - Direkte elektronenübertragung über enzyme in bioanoden, biokathoden und biobrennstoffzellen - Google Patents

Direkte elektronenübertragung über enzyme in bioanoden, biokathoden und biobrennstoffzellen

Info

Publication number
EP1952469A2
EP1952469A2 EP06849336A EP06849336A EP1952469A2 EP 1952469 A2 EP1952469 A2 EP 1952469A2 EP 06849336 A EP06849336 A EP 06849336A EP 06849336 A EP06849336 A EP 06849336A EP 1952469 A2 EP1952469 A2 EP 1952469A2
Authority
EP
European Patent Office
Prior art keywords
bioanode
biocathode
enzyme
biofuel cell
carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06849336A
Other languages
English (en)
French (fr)
Other versions
EP1952469A4 (de
Inventor
Shelley D. Minteer
Becky L. Treu
Rodica Duma
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
St Louis University
Original Assignee
St Louis University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by St Louis University filed Critical St Louis University
Publication of EP1952469A2 publication Critical patent/EP1952469A2/de
Publication of EP1952469A4 publication Critical patent/EP1952469A4/de
Withdrawn legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/16—Biochemical fuel cells, i.e. cells in which microorganisms function as catalysts
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N11/00—Carrier-bound or immobilised enzymes; Carrier-bound or immobilised microbial cells; Preparation thereof
    • C12N11/02—Enzymes or microbial cells immobilised on or in an organic carrier
    • C12N11/04—Enzymes or microbial cells immobilised on or in an organic carrier entrapped within the carrier, e.g. gel or hollow fibres
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N11/00—Carrier-bound or immobilised enzymes; Carrier-bound or immobilised microbial cells; Preparation thereof
    • C12N11/02—Enzymes or microbial cells immobilised on or in an organic carrier
    • C12N11/08—Enzymes or microbial cells immobilised on or in an organic carrier the carrier being a synthetic polymer
    • C12N11/082—Enzymes or microbial cells immobilised on or in an organic carrier the carrier being a synthetic polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N11/00—Carrier-bound or immobilised enzymes; Carrier-bound or immobilised microbial cells; Preparation thereof
    • C12N11/02—Enzymes or microbial cells immobilised on or in an organic carrier
    • C12N11/08—Enzymes or microbial cells immobilised on or in an organic carrier the carrier being a synthetic polymer
    • C12N11/089—Enzymes or microbial cells immobilised on or in an organic carrier the carrier being a synthetic polymer obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N11/00—Carrier-bound or immobilised enzymes; Carrier-bound or immobilised microbial cells; Preparation thereof
    • C12N11/14—Enzymes or microbial cells immobilised on or in an inorganic carrier
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Genetics & Genomics (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • General Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Biotechnology (AREA)
  • General Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Inert Electrodes (AREA)
  • Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
EP06849336A 2005-11-02 2006-11-02 Direkte elektronenübertragung über enzyme in bioanoden, biokathoden und biobrennstoffzellen Withdrawn EP1952469A4 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US73274205P 2005-11-02 2005-11-02
US78465006P 2006-03-22 2006-03-22
PCT/US2006/060492 WO2007084249A2 (en) 2005-11-02 2006-11-02 Direct electron transfer using enzymes in bioanodes, biocathodes, and biofuel cells

Publications (2)

Publication Number Publication Date
EP1952469A2 true EP1952469A2 (de) 2008-08-06
EP1952469A4 EP1952469A4 (de) 2009-12-16

Family

ID=38288092

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06849336A Withdrawn EP1952469A4 (de) 2005-11-02 2006-11-02 Direkte elektronenübertragung über enzyme in bioanoden, biokathoden und biobrennstoffzellen

Country Status (6)

Country Link
US (1) US8415059B2 (de)
EP (1) EP1952469A4 (de)
JP (1) JP2009515303A (de)
KR (1) KR20080080105A (de)
CA (1) CA2627650A1 (de)
WO (1) WO2007084249A2 (de)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2706216A (en) * 1951-06-22 1955-04-12 Lesti Arnold Color television receiver with registration control
WO2008036347A2 (en) * 2006-09-20 2008-03-27 President And Fellows Of Harvard College Methods and apparatus for stimulating and managing power from microbial fuel cells
CA2686161A1 (en) * 2007-05-04 2008-11-13 Akermin, Inc. Immobilized enzymes and uses thereof
CN101425583B (zh) * 2007-11-02 2011-06-08 清华大学 燃料电池膜电极及其制备方法
CN101465434B (zh) * 2007-12-19 2010-09-29 清华大学 燃料电池膜电极及其制备方法
CN101425584B (zh) * 2007-11-02 2011-05-04 清华大学 燃料电池膜电极及其制备方法
CN101635362B (zh) 2008-07-25 2012-03-28 清华大学 膜电极及采用该膜电极的燃料电池
JP5273645B2 (ja) * 2008-03-11 2013-08-28 独立行政法人産業技術総合研究所 バイオ燃料電池
CN101752567B (zh) 2008-12-17 2012-09-19 清华大学 膜电极及采用该膜电极的燃料电池
CN101752568B (zh) 2008-12-17 2012-06-20 清华大学 膜电极及采用该膜电极的生物燃料电池
US9077042B2 (en) * 2008-07-25 2015-07-07 Tsinghua University Membrane electrode assembly and biofuel cell using the same
TWI382580B (zh) * 2008-08-08 2013-01-11 Hon Hai Prec Ind Co Ltd 膜電極及採用該膜電極的生物燃料電池
JP5219265B2 (ja) * 2008-08-13 2013-06-26 トヨタ自動車株式会社 酵素電極およびその製造方法
JP2012504047A (ja) 2008-09-29 2012-02-16 アケルミン・インコーポレイテッド 二酸化炭素の捕捉を加速するためのプロセス
JP2010209375A (ja) * 2009-03-09 2010-09-24 Sony Corp 電解方法
FI122265B (fi) * 2009-12-16 2011-11-15 Teknologian Tutkimuskeskus Vtt Monikerrosrakenne
WO2011110202A1 (de) 2010-03-11 2011-09-15 Roche Diagnostics Gmbh Verfahren zur elektrochemischen messung einer analytkonzentration in-vivo und brennstoffzelle hierfür
FR2963989B1 (fr) * 2010-08-19 2016-03-11 Univ Joseph Fourier Biopile a transfert direct
US9303255B2 (en) 2010-08-26 2016-04-05 Aisin Seiki Kabushiki Kaisha Electrode having enzyme crystals immobilized thereon, method for producing electrode having enzyme crystals immobilized thereon, and biological fuel cell and biosensor provided with electrode having enzyme crystals immobilized thereon
PL220927B1 (pl) * 2010-12-10 2016-01-29 Inst Chemii Fizycznej Polskiej Akademii Nauk Biokatoda, sposób wykonania biokatody i ogniwo cynkowo-tlenowe
JP2012190787A (ja) * 2011-02-24 2012-10-04 Sony Corp 微生物燃料電池、該電池の燃料と微生物、およびバイオリアクタとバイオセンサ
KR101241340B1 (ko) * 2011-03-25 2013-03-11 단국대학교 산학협력단 미세 탐침 어레이를 구비한 미생물 연료전지
US9509009B2 (en) * 2011-06-08 2016-11-29 Cfd Research Corporation Enzyme catalyzed oxidation of hydrocarbons
JP2013239292A (ja) * 2012-05-14 2013-11-28 Hitachi Ltd 微生物燃料電池用アノード、微生物燃料電池、微生物燃料電池用アノードの製造方法
FR3003076B1 (fr) 2013-03-07 2015-04-10 Centre Nat Rech Scient Supercondensateur electrochimique
US11575171B2 (en) * 2013-07-01 2023-02-07 Pei Zhang Biological battery and biological cathode electrode
US9647289B1 (en) * 2014-02-19 2017-05-09 Haskell Dighton Unit for glucose depletion
CN104591407B (zh) * 2015-01-19 2016-05-04 南京农业大学 一种利用重组脂肪氧合酶降解三苯甲烷类染料的方法
WO2016129273A1 (ja) * 2015-02-09 2016-08-18 国立大学法人東北大学 酵素電極の製造方法及び酵素電極
MY185305A (en) * 2017-11-16 2021-04-30 Univ Malaya Algal-alginate film for bio-photovoltaic device
KR102223880B1 (ko) * 2019-04-23 2021-03-05 한양대학교 에리카산학협력단 다공성 전극을 구비하는 마이크로 유체 미생물 연료전지 및 이의 제조방법
CN112864406B (zh) * 2019-11-27 2023-05-30 大连大学 一种乳糖燃料电池的构建方法
CN111146451A (zh) * 2019-12-27 2020-05-12 扬州大学 一种藕粉碳球生物燃料电池及其制备方法
KR102484500B1 (ko) * 2020-09-03 2023-01-04 한양대학교 에리카산학협력단 마이크로 유체 연료전지 및 이의 제조방법

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003019705A2 (en) * 2001-08-24 2003-03-06 Isis Innovation Limited Anode comprising hydrogenase for a fuel cell
WO2003067697A2 (fr) * 2002-02-07 2003-08-14 Commissariat A L'energie Atomique Pile a combustible, utilisant dans le compartiment cathodique et eventuellement dans le compartiment anodique des enzymes de type oxydoreductase
WO2005096430A1 (en) * 2004-03-15 2005-10-13 St. Louis University Microfluidic biofuel cell

Family Cites Families (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4117202A (en) 1976-11-12 1978-09-26 Beck Timothy A Solar powered biological fuel cell
JPS5912135B2 (ja) 1977-09-28 1984-03-21 松下電器産業株式会社 酵素電極
US4207076A (en) 1979-02-23 1980-06-10 Texaco Inc. Gasoline-ethanol fuel mixture solubilized with ethyl-t-butyl ether
US4490464A (en) 1981-04-08 1984-12-25 Gorton Lo G Electrode for the electrochemical regeneration of coenzyme, a method of making said electrode, and the use thereof
US5682884A (en) 1983-05-05 1997-11-04 Medisense, Inc. Strip electrode with screen printing
US4602987A (en) 1984-09-24 1986-07-29 Aquanautics Corporation System for the extraction and utilization of oxygen from fluids
US4705503A (en) 1986-02-03 1987-11-10 Regents Of The University Of Minnesota Metabolite sensor including a chemical concentration sensitive flow controller for a drug delivery system
GB8612861D0 (en) * 1986-05-27 1986-07-02 Cambridge Life Sciences Immobilised enzyme biosensors
JPS6428556A (en) 1987-07-23 1989-01-31 Bridgestone Corp Enzyme electrode
US5262035A (en) 1989-08-02 1993-11-16 E. Heller And Company Enzyme electrodes
US5264105A (en) 1989-08-02 1993-11-23 Gregg Brian A Enzyme electrodes
US5320725A (en) 1989-08-02 1994-06-14 E. Heller & Company Electrode and method for the detection of hydrogen peroxide
JP2884746B2 (ja) 1990-09-03 1999-04-19 松下電器産業株式会社 非水電解液２次電池
US5211984A (en) 1991-02-19 1993-05-18 The Regents Of The University Of California Membrane catalyst layer for fuel cells
US5262305A (en) 1991-03-04 1993-11-16 E. Heller & Company Interferant eliminating biosensors
JPH04278450A (ja) 1991-03-04 1992-10-05 Adam Heller バイオセンサー及び分析物を分析する方法
US5593852A (en) 1993-12-02 1997-01-14 Heller; Adam Subcutaneous glucose electrode
US5264092A (en) 1991-10-02 1993-11-23 Moltech Corporation Redox polymer modified electrode for the electrochemical regeneration of coenzyme
GB9218376D0 (en) 1992-08-28 1992-10-14 Cranfield Inst Of Tech Media for biocatalytic electrochemical reactions in the gaseous phase
US5393615A (en) 1994-02-03 1995-02-28 Miles Inc. Mediators suitable for the electrochemical regeneration of NADH, NADPH or analogs thereof
US5718947A (en) 1995-03-14 1998-02-17 The Dow Chemicalcompany Processes for forming thin, durable coatings of cation-containing polymers on selected substrates
US5919583A (en) 1995-03-20 1999-07-06 E. I. Du Pont De Nemours And Company Membranes containing inorganic fillers and membrane and electrode assemblies and electrochemical cells employing same
US5520786A (en) 1995-06-06 1996-05-28 Bayer Corporation Mediators suitable for the electrochemical regeneration of NADH, NADPH or analogs thereof
US6387625B1 (en) 1995-06-27 2002-05-14 The University Of North Carolina At Chapel Hill Monolayer and electrode for detecting a label-bearing target and method of use thereof
US5665222A (en) 1995-10-11 1997-09-09 E. Heller & Company Soybean peroxidase electrochemical sensor
US6294281B1 (en) 1998-06-17 2001-09-25 Therasense, Inc. Biological fuel cell and method
US6500571B2 (en) 1998-08-19 2002-12-31 Powerzyme, Inc. Enzymatic fuel cell
US20030164335A1 (en) 1998-10-23 2003-09-04 Grate Jay W. Method for high throughput separations in microfluidic systems using small particles
CN1349670A (zh) 1999-05-06 2002-05-15 三帝公司 燃料电池和薄膜
DE10025033A1 (de) 2000-05-20 2001-11-29 Dmc2 Degussa Metals Catalysts Verfahren zur elektrischen Energiegewinnung mit Hilfe einer Brennstoffzelle
US6460733B2 (en) 2001-02-20 2002-10-08 Mti Microfuel Cells, Inc. Multiple-walled fuel container and delivery system
JP3898454B2 (ja) 2001-03-06 2007-03-28 シャープ株式会社 固体高分子型燃料電池
JP2002300875A (ja) * 2001-04-04 2002-10-15 Fuji Spinning Co Ltd アルカリ土金属処理固定化酵素の製造方法
JP4772203B2 (ja) * 2001-04-12 2011-09-14 花王株式会社 糖骨格を有する化合物の製法
US20030198858A1 (en) 2001-04-13 2003-10-23 Sun Hoi-Cheong Steve Enzymatic fuel cell with membrane bound redox enzyme
US6855243B2 (en) 2001-04-27 2005-02-15 Lifescan, Inc. Electrochemical test strip having a plurality of reaction chambers and methods for using the same
CA2448512A1 (en) 2001-05-31 2003-01-23 Michigan Biotechnology Institute Electrode compositions and configurations for electrochemical bioreactor systems
CA2352626A1 (fr) 2001-07-12 2003-01-12 Co2 Solution Inc. Couplage d'une pile a hydrogene a un bioreacteur enzymatique de transformation et sequestration du co2
IL145182A (en) 2001-08-29 2005-11-20 Yissum Res Dev Co Self-powered biosensor
US20050101841A9 (en) 2001-12-04 2005-05-12 Kimberly-Clark Worldwide, Inc. Healthcare networks with biosensors
US7018518B2 (en) 2002-02-04 2006-03-28 Yissum Research Development Company Of The Hebrew University Of Jerusalem Biosensor carrying redox enzymes
US7368190B2 (en) * 2002-05-02 2008-05-06 Abbott Diabetes Care Inc. Miniature biological fuel cell that is operational under physiological conditions, and associated devices and methods
US7638228B2 (en) * 2002-11-27 2009-12-29 Saint Louis University Enzyme immobilization for use in biofuel cells and sensors
US7311926B2 (en) 2002-12-20 2007-12-25 Battelle Memorial Institute Biocomposite materials and methods for making the same
US20060269826A1 (en) 2003-03-03 2006-11-30 Eugenii Katz Novel electrode with switchable and tunable power output and fuel cell using such electrode
JP4083612B2 (ja) * 2003-03-25 2008-04-30 富士フイルム株式会社 酵素反応を利用した電気エネルギー発生・貯蔵方法および装置
US8859151B2 (en) 2003-11-05 2014-10-14 St. Louis University Immobilized enzymes in biocathodes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003019705A2 (en) * 2001-08-24 2003-03-06 Isis Innovation Limited Anode comprising hydrogenase for a fuel cell
WO2003067697A2 (fr) * 2002-02-07 2003-08-14 Commissariat A L'energie Atomique Pile a combustible, utilisant dans le compartiment cathodique et eventuellement dans le compartiment anodique des enzymes de type oxydoreductase
WO2005096430A1 (en) * 2004-03-15 2005-10-13 St. Louis University Microfluidic biofuel cell

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
HE HUANG ET AL: "Electrochemistry and electrocatalysis with heme proteins in chitosan biopolymer films" ANALYTICAL BIOCHEMISTRY, vol. 308, 2002, pages 141-151, XP002549678 *
IVNITSKI D ET AL: "Glucose oxidase anode for biofuel cell based on direct electron transfer" ELECTROCHEMISTRY COMMUNICATION, ELSEVIER, AMSTERDAM, NL, vol. 8, no. 8, 1 August 2006 (2006-08-01), pages 1204-1210, XP025182241 ISSN: 1388-2481 [retrieved on 2006-08-01] *
KLOTZBACH ET AL: "Effects of hydrophobic modification of chitosan and Nafion on transport properties, ion-exchange capacities, and enzyme immobilization" JOURNAL OF MEMBRANE SCIENCE, ELSEVIER SCIENTIFIC PUBL.COMPANY. AMSTERDAM, NL, vol. 282, no. 1-2, 5 October 2006 (2006-10-05), pages 276-283, XP005615192 ISSN: 0376-7388 *
See also references of WO2007084249A2 *

Also Published As

Publication number Publication date
EP1952469A4 (de) 2009-12-16
US20110014549A9 (en) 2011-01-20
JP2009515303A (ja) 2009-04-09
KR20080080105A (ko) 2008-09-02
CA2627650A1 (en) 2007-07-26
WO2007084249A2 (en) 2007-07-26
US8415059B2 (en) 2013-04-09
WO2007084249A3 (en) 2007-11-01
US20090305113A1 (en) 2009-12-10

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