EP1845325B1 - Vorrichtung zum schmelzen von metall mittels elektronenstrahlen und verfahren zur herstellung hochschmelzender metallgussblöcke mit dieser vorrichtung - Google Patents

Vorrichtung zum schmelzen von metall mittels elektronenstrahlen und verfahren zur herstellung hochschmelzender metallgussblöcke mit dieser vorrichtung Download PDF

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Publication number
EP1845325B1
EP1845325B1 EP06712160A EP06712160A EP1845325B1 EP 1845325 B1 EP1845325 B1 EP 1845325B1 EP 06712160 A EP06712160 A EP 06712160A EP 06712160 A EP06712160 A EP 06712160A EP 1845325 B1 EP1845325 B1 EP 1845325B1
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EP
European Patent Office
Prior art keywords
furnace
electron
lining
melting
titanium
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EP06712160A
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English (en)
French (fr)
Japanese (ja)
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EP1845325A4 (de
EP1845325A1 (de
Inventor
Takeshi Shiraki
Yoshihiro Hatta
Norio Yamamoto
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Toho Titanium Co Ltd
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Toho Titanium Co Ltd
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Priority claimed from JP2005016396A external-priority patent/JP4443430B2/ja
Priority claimed from JP2005363412A external-priority patent/JP4860253B2/ja
Application filed by Toho Titanium Co Ltd filed Critical Toho Titanium Co Ltd
Publication of EP1845325A1 publication Critical patent/EP1845325A1/de
Publication of EP1845325A4 publication Critical patent/EP1845325A4/de
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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B17/00—Furnaces of a kind not covered by any preceding group
    • F27B17/0016—Chamber type furnaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/001—Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B34/00—Obtaining refractory metals
    • C22B34/10—Obtaining titanium, zirconium or hafnium
    • C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
    • C22B34/1295—Refining, melting, remelting, working up of titanium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/16—Remelting metals
    • C22B9/22—Remelting metals with heating by wave energy or particle radiation
    • C22B9/228—Remelting metals with heating by wave energy or particle radiation by particle radiation, e.g. electron beams
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D1/00—Casings; Linings; Walls; Roofs
    • F27D1/02—Crowns; Roofs
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D99/00—Subject matter not provided for in other groups of this subclass
    • F27D99/0001—Heating elements or systems
    • F27D99/0006—Electric heating elements or system
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D99/00—Subject matter not provided for in other groups of this subclass
    • F27D99/0001—Heating elements or systems
    • F27D99/0006—Electric heating elements or system
    • F27D2099/003—Bombardment heating, e.g. with ions or electrons

Definitions

  • the present invention relates to an apparatus and to a method for melting and producing an ingot of a refractory metal such as titanium, and in particular, relates to an electron beam melting technology in which contamination sources such as LDI (Low Density Inclusions) into the ingot is reduced, and the furnace availability is effectively improved.
  • contamination sources such as LDI (Low Density Inclusions) into the ingot is reduced, and the furnace availability is effectively improved.
  • Titanium metal has been conventionally used for materials and parts for aviation widely; this titanium metal has been developed for various uses, and it is widely used in building materials, road materials, sporting goods, and the like.
  • titanium metal has been obtained by producing titanium sponge by the Kroll method (titanium tetrachloride is reduced by magnesium metal to yield titanium), crushing the titanium sponge, forming briquettes by pressing the ground titanium sponge, forming a consumable electrode by combining plural briquettes, and melting the electrode of the briquettes by employing VAR furnace, generally.
  • an electron-beam furnace in which a titanium sponge is melted by an electron beam and the molten titanium is flowed into a mold to obtain an ingot, is employed instead of the vacuum arc furnace.
  • an electron-beam hearth melting furnace is frequently used because of a superior purifying ability.
  • impurities or the like the amount of impurities and compounds (hereinafter referred to as "impurities or the like") produced on the furnace wall or the like, are increased in proportion to the heat number of the melting.
  • impurities or the like attached on the furnace wall are not controlled, the impurities or the like themselves cannot bear their own weights and they will fall into the lower portion of the furnace. If the impurities or the like fall into the molten metal in the mold or hearth, the impurities are newly incorporated into the mold or hearth and which will lower the ingot quality.
  • the metallic powder and metallic agglomeration adhering to the furnace wall are removed as much as possible after completing a sequence of melting processes and pulling the titanium ingot out of the furnace.
  • this maintenance operation typically takes about 3 to 7 days until the furnace is ready to be reused.
  • the next melting operation cannot be performed during the maintenance operation, resulting a decrease of the furnace availability.
  • the furnace availability is increased by reducing the time for the melting and the maintenance operation as much as possible.
  • the maintenance operation is conducted by hand; however, for example, a method without operator's contribution has been suggested ,in which method the furnace is washed with high pressure water as a solution for decreasing the furnace availability, (see Japanese Unexamined Patent Application Publication No. 2004-183923 ). Since high pressure water is employed to remove adhered material in this method, it is expected that the maintenance operation can be completed in a relatively shorter time than that of the maintenance operation by hand.
  • an improving technique has been disclosed, regarding the ceiling wall or the like of an electron-beam furnace.
  • an apparatus for holding a condensed material has been disclosed, in which apparatus a concave water-cooled surface is arranged on the hearth to collect condensed material of evaporated components of an alloy processed in the hearth (see Japanese Unexamined Patent Application Publication No. Hei 11 (1999)-132664) .
  • a plectrum structured parts are arranged on the ceiling wall of an electron-beam furnace, solid impurities deposited on the concave parts are effectively inhibited to fall downwardly.
  • a method for preventing the falling of impurity metal evaporated and deposited in the furnace including a process in which Nb-Al alloy is melted by a heating means in a vacuum, and it is held in a hearth arranged in the furnace while A1 is evaporated and purified Nb is flowed into a water-cooled crucible, resulting Nb ingot, and a process in which a rotator with a cooling means is arranged above the water-cooled crucible and a woven stainless net is movably attached below the rotator to keep the evaporated Al the adhering and solidifying state on the woven stainless net with near uniformity and density, (see Hei 11 (1999)-061288 ).
  • impurities and titanium vapor evaporated from a melted pool can be condensed on a circular mesh plate at an upper area of the melted pool held in the mold, and as a result, the amount of the condensed material on the ceiling wall of the electron-beam furnace can be reduced.
  • the ingot should not contain HDI (High Density Inclusions) or LDI (Low Density Inclusions) extremely and impurities into the ingot is not allowed even in the smallest amounts.
  • HDI High Density Inclusions
  • LDI Low Density Inclusions
  • the present invention has been completed in view of the above requirements, and an object of the invention is to provide an electron-beam furnace in which, during production of a titanium ingot by melting titanium sponge or titanium scrap, contamination of additional impurities is suppressed, impurities once evaporated from the hearth or melting metal pool in the mold are difficult to again be brought in the melting metal pool, and the furnace availability thereof is improved by reducing maintenance time.
  • the inventors have performed research regarding an electron-beam furnace that can reduce contamination of impurities, which evaporate from the melting metal pool in the hearth or the mold, and will not come into the melting metal pool again.
  • condensed impurities can be held on an upper surface of the fin-shaped member, preventing impurities from falling to the lower part of the furnace by lining at least one of the inner surface of the furnace wall and the ceiling wall with titanium or stainless steel, and by arranging fin-shaped members on the ceiling wall.
  • the inventors also discovered that the above-mentioned fin-shaped member should be preferably made of titanium or stainless steel; in such a case, corrosion of the furnace wall and the ceiling wall can be effectively reduced due to the titanium vapor from the melting metal pool of the hearth or mold.
  • the present invention has been completed in view of such knowledge.
  • the electron-beam furnace for refractory metal of the present invention is consisted of a feeder unit for raw materials , a furnace wall connected with the a feeder unit for raw materials, and a ceiling wall;
  • the apparatus has a melting unit for raw material including at least a hearth, a water-cooled mold and an electron gun, and an evacuation unit of exhaust gas connected with the melting unit for raw material;
  • the apparatus is lined by the titanium or stainless steel on at least a furnace wall and a ceiling wall, and has plural fin-shaped members made of titanium or stainless steel on the ceiling wall.
  • the inventors discovered that the amount of titanium vapor from the melting metal pool condensed on the ceiling wall can be effectively reduced by arranging the shield members on the furnace wall so that the shield members are positioned below the ceiling wall. It should be noted that the inventors also discovered that the above-mentioned effect can be sufficiently achieved by arranging the above-mentioned shield members extending from the furnace wall toward the center direction and the upper portion of the apparatus in lateral view. The invention as described below has been completed in view of this knowledge.
  • the shield member be arranged on the furnace wall so as to extend from the furnace wall toward the center direction and the upper portion of the apparatus in lateral view, and it is more preferable that the shield member be made of a metal having a higher metting point than that of refractory metal in the furnace or is made of a ceramic having a higher melting point than that of the refractory metal. Furthermore, it is especially preferable that the metal or ceramic comprising the shield member be maintained at a temperature not greater than the melting point of the refractory metal. Molybdenum or tantalum is preferable as such a metal, and calcia, yttria or a complex of calcia and yttria is preferable as such a ceramic.
  • the inventors discovered that a reaction of titanium vapor or impurities with the furnace wall or the ceiling wall can be greatly reduced and contamination of impurities into melting metal pool can be further suppressed by separating and recovering the titanium vapor or impurities once evaporated from the melting metal pool at a cooling portion (hereinafter referred to as a "condensation tube") additionally arranged downstream of the evacuation unit for exhaust gas in the apparatus.
  • a cooling portion hereinafter referred to as a "condensation tube”
  • the purity of the molten titanium in the hearth or water-cooled mold can be further improved, and as a result, the purity of the ingot can be maintained at an extremely high level.
  • the invention as described below has been completed in view of such knowledge.
  • the condensation tube of the refractory metal vapor be arranged downstream of the evacuation unit for exhaust gas. It should be noted that the condensation tube can be arranged incorporated with the electron-beam furnace, or it can be arranged separately from the apparatus.
  • the inventors discovered that maintenance operation time of the furnace can be extremely reduced and the furnace availability can be greatly increased by predisposing a removable lining on the inner surface of the electron-beam furnace and by replacing the lining with adhering or deposited material after melting.
  • the electron-beam furnace for refractory metal of the present invention is consisted of a feeder unit for raw materials, a furnace wall connected with the a feeder unit for raw materials, and a ceiling wall; the apparatus has a melting unit for raw materials including at least a hearth, a water-cooled mold, an electron gun, and an evacuation unit for exhaust gas connected with the melting unit for raw material; and the apparatus further has a removable lining attached on the inner surface of the electron-beam furnace.
  • the lining consists of a ceiling lining, a side wall lining and a bottom lining. It is preferable that each lining be attachable and detachable separately.
  • the present invention provides a method for production of a refractory metal ingot in which melting is performed by using the electron-beam furnace having the above-described construction.
  • additional contamination of impurities can be reduced during melting of refractory metal such as titanium by keeping at least the surface of the furnace wall or ceiling wall in the apparatus in appropriate condition.
  • the impurities once evaporated from the melting metal pool and deposited on the ceiling wall, are effectively prevented from again being brought into the melting pool by the arrangement of shield members or a condensation tube.
  • the quality of ingot can be maintained at an extremely pure level.
  • the lining with deposited metal may be immediately removed and replaced with a newly prepared lining so that the furnace can be reused quickly again in the present invention after the melting of metal is completed, the metal has cooled and is pulled out as an ingot since the lining is removable. In this way, the furnace can be greatly improved. Furthermore, since the frequency for washing operations inside the furnace is reduced, the service life reduction of the furnace by corrosion can be effectively avoided.
  • Fig. 1 is a side view diagram showing the first embodiment 10a of a preferred electron-beam furnace of the present invention.
  • a portion of a feeder unit for raw materials means the left region from the hearth 11 and a portion of melting unit of raw material means the region from the left edge of the hearth 11 to the base of the outlet nozzle unit for exhaust gas 14 and a portion of the evacuation unit for exhaust gas means the right region from the base of the outlet nozzle unit for exhaust gas 14 in Fig. 1 .
  • the furnace wall 15 and the dome-shaped ceiling wall 16 are connected each other, and plural fin-shaped members 17 are arranged on the ceiling wall 16. It is preferable that the furnace wall 15, the ceiling wall 16, and the fin-shaped member 17 be made of titanium or stainless steel. It should be noted that the reason why the ceiling wall 16 is dome-shaped, is that the plural fin-shaped members 17 can be easily arranged on the ceiling wall 16.
  • titanium material 18 as a raw material is fed through the feeder unit for raw materials to the hearth 11, and this is melted by the electron gun 13.
  • melted titanium in the hearth 11 is flown into the water-cooled mold 12, and while controlling the temperature by the electron gun 13, ingot 19 is formed and pulled downward by an ingot pulling means, which is not shown.
  • titanium or impurities are evaporated and moved upward from the melted titanium pool in the hearth 11 or the water-cooled mold 12, a part of the evaporated titanium or impurities is exhausted to the outside through the outlet nozzle unit for exhaust gas 14, and most of the evaporated titanium or impurities reaches the furnace wall 15 and the ceiling wall 16 and then condenses.
  • the condensed deposits may fall off and fall downward by their own weights.
  • the plural fin-shaped members 17 consisting of the present invention are attached on the ceiling wall 16, the fin-shaped member 17 reveals a function as a tray for holding the condensed titanium or impurities, and the falling thereof into the melting metal pool in the hearth 11 or the water-cooled mold 12 can be effectively avoided. It should be noted that the falling of titanium or impurities held on the fin-shaped member 17 can be avoided more effectively by adding a bent shape at the free edge of the fin-shaped member 17 as shown in Fig. 1 .
  • the electron-beam furnace 10a of the first embodiment can effectively avoid additional contamination of impurities by the linings on the furnace wall 15 and the ceiling wall 16, and furthermore, quality deterioration of ingots due to the falling of titanium or impurities can be effectively suppressed by arranging plural fin-shaped members 17 on the ceiling wall 16.
  • Fig. 2 is a side view diagram showing the second embodiment 10b of a preferred electron-beam furnace of the present invention.
  • the basic structure of the furnace of Fig. 2 is similar to that of Fig. 1 . Therefore, also in the second embodiment, a portion of a feeder unit for raw materials means the left region from the hearth 11 and a portion of a melting unit for raw material means the region from the left edge of the hearth 11 to the base of the exhaust nozzle 14, and a portion of a evacuation unit for exhaust gas means the right region from the base of the outlet nozzle unit for exhaust gas 14 in Fig. 1 .
  • shield member 20 is additionally arranged at the furnace wall 15, and the shield member 20 is positioning below the ceiling wall 16.
  • the shield member 20 is arranged to interfere an evaporation path of titanium or impurities from the melting metal pool in the hearth 11 or water-cooled mold 12 to the ceiling wall 16. It is preferable that the shield member 20 have an inverted-cone shape with an opening through which electron beam 13a passes at its central part; however, another shape may be employed.
  • the shield member 20 is an inverted-cone shape which extending from the furnace wall 15 to a central and upper portion of the apparatus in lateral view in the present embodiment, and even if the impurities or the like fall from the fin-shaped member 17 downward, this structure enables the impurities or the like to be trapped on the shield member 20 and to be prevented from falling below the shield member 20.
  • the shield member 20 be made of a material having a melting point higher than that of titanium, such as Mo or Ta. It is preferable that the temperature of the shield member 20 be maintained from 1000 to 1600°C, and more desirably from 1300 to 1600°C. However, the temperature is desirably maintained below the melting point of titanium since the member may react with evaporated titanium and may form alloys, deteriorating the strength of the ingot if the temperature reaches the melting point of titanium.
  • the temperature of the shield member 20 can be maintained within the above-mentioned range by irradiating electron beam 13a or by providing a heater. By maintaining the temperature within the range, deposition of titanium vapor evaporated from the hearth 11 or the water-cooled mold 12 can be restrained on the lower surface of the shield member 20. By the above-mentioned functions, falling and contamination of solid impurities can be reduced, which may cause generation of LDI or HDI, into the hearth 11 or water-cooled mold 12. Therefore, deterioration of the quality of the titanium ingot can be effectively avoided.
  • the shield member 20 has a function of capturing titanium or impurities leaving from the lower surface of the fin-shaped member 17 because of their own weights.
  • the shield member 20 can be made of calcia, yttria, or a complex ceramic thereof. Also in this case, it is preferable that the temperature of the shield member 20 be maintained from 1000 to 1600°C, and more desirably from 1300 to 1600°C. Furthermore, in the case in which the shield member 20 is made of the above-mentioned ceramic, the shield member 20 is desirably maintained within the above-mentioned temperature range with additional heater. Condensation and deposition of the titanium vapor can be reduced by keeping the temperature of the shield member 20 within the high temperature range, and as a result, contamination of impurities into the ingot can be effectively reduced.
  • the titanium vapor reaching the shield member maintained within the temperature range is partially condensed on the surface of the shield member 20, and most of the titanium vapor existing in the gas phase flows downward in an oblique direction along the inner surface of the shield member 20, and it is exhausted to the outside the furnace, which is not shown.
  • Fig. 3 is a side view diagram showing the third embodiment 10c of a preferable electron-beam furnace of the present invention.
  • the embodiment has a structure in which vapor of titanium or impurities from the melting titanium pool in the hearth 11 or water-cooled mold 12 are guided to a condensation tube 21 which is additionally and separately arranged at the furnace 10 downstream of the outlet nozzle unit of the exhaust gas 14 while the vapor is being maintained at a high temperature and in which the vapor of titanium or impurities is cooled to be separated in the condensation tube 21 and recovered.
  • a portion of a feeder unit for raw materials means the left region from the hearth 11 and a portion of the melting unit for raw materials means the region from the left edge of the hearth 11 to a left side of a tapered portion having a tapered shape consisting of the furnace wall 15 and the ceiling wall 16, and a portion of outlet nozzle unit for an exhaust gas means the region of the tapered part in Fig. 3 .
  • a heating plate 23 with a corrosion resistance is arranged not only on the ceiling wall 16 but also on the inner surface of the side wall 15. It is preferable that the heating plate 23 be maintained at a high temperature so that the titanium vapor evaporated from the melting metal pool is difficult to be condensed on the heating plate 23. Specifically, it is preferable that the temperature be in a range of 1000 to 1600°C, and it is important that it be maintained so as not to reach the melting point of titanium. Most of the above-mentioned titanium vapor and impurities can be guided to the t condensation tube 21 by maintaining the high temperature without condensing on the heating plate 23.
  • the impurities or the like are not transported in the hearth 11 or water-cooled mold 12, and they are separated and recovered as adhering material 24 or deposited material 25 in the condensation tube 21.
  • the heating plate 23 is made of molybdenum or tantalum, which are durable in the above-mentioned high temperature range.
  • recovery of titanium vapor and impurities can be improved more efficiently by arranging another condensation tube, which is not shown, in the downstream of the condensation tube 21.
  • the amount of metallic powder or dust reaching the evacuation unit 26 arranged in the downstream of the condensation tube 21 can be reduced by such a structure of the apparatus, which contribute to the prolongation of the service life of the evacuation unit 26.
  • Fig. 4 is a side view diagram showing the fourth embodiment 10d of a preferred electron-beam furnace of the present invention.
  • Fig. 4 is a conceptual diagram showing the electron-beam furnace 10d in which the apparatus is described from a vertical direction of the viewpoint of Figs. 1 to 3 , and the hearth 11 and the feeder unit for raw materials are located behind the face.
  • a removable ceiling lining 31 is arranged on the inner wall of the ceiling wall 16.
  • a removable side wall lining 32 is arranged on the inner surface of the furnace wall 15, and a removable bottom lining 34 is arranged on the inner surface of the bottom wall.
  • the structure of fin-shaped member 17 shown in Fig. 1 can be applied to the ceiling lining 31.
  • the above-mentioned fin-shaped members be provided.
  • the fin-shaped member desirably has a structure extending horizontally from the ceiling wall. Furthermore, the top edge part of the fin-shaped member is desirably bent upward. By such a structure, falling of adhering material is effectively reduced.
  • a network structure of the metal is considered to be preferable as a ceiling lining. If the ceiling lining has a network structure, the deposited material hangs in concave portions, and it is more difficult for the deposited material to fall downwardly, compared to the case of a ceiling wall having a planar structure.
  • Material for the network structure can be made of stainless steel; however, titanium can be used if contamination of the final product must be inhibited severely. Falling of deposited material adhered and accumulated on the ceiling lining can be effectively reduced by such a structure and arrangement.
  • the ceiling lining have a structure such that it can be attached and detached from the ceiling wall relatively easily.
  • bolting or an attachment structure is preferable like hooking.
  • a side wall lining is used by attaching on the inner wall part of the apparatus, and the side wall lining also desirably has a structure easily attached and removed, similar to the case of the ceiling wall. Specifically, bolting or an attachment structure using a hook is preferable.
  • Material of the side wall lining is desirably made of a metal, especially stainless steel having superior corrosion resistance. Furthermore, titanium is more desirable as a side wall lining in case that contamination by impurities is inhibited extremely. It should be noted that synthetic resin with a heat resistance can be applied as a part of sidewall material in case that radiation heat from the hearth or the mold is relatively low and the temperature does not increase so high. The synthetic resin is appropriate for a treatment of water-washing and drying since the synthetic resin has a superior corrosion-resistant.
  • a condensed material received in the groove 33 be engaged and arranged at the lower edge of the side wall lining as shown in Fig. 4 .
  • the condensed material is effectively captured by arranging such a groove 33 for receiving condensed material, if the condensed material falls from the surface of the side wall lining.
  • the condensed material can be purified and be reused as a titanium raw material.
  • the side wall lining can be constructed as a metallic planar structure; however, similar to the case of the ceiling lining, it can have a network structure. Falling of the adhering material can be effectively avoided by making the side wall lining of a net structure.
  • a bottom lining is attached on the bottom part of the electron-beam furnace 10d, and it desirably has a structure covering the bottom portion of the furnace as much as possible.
  • the condensed material in attaching or removing of the ceiling lining or side wall lining can be effectively recovered by this structure.
  • the bottom lining can be made of metal; however, it can also be made of a synthetic resin with a heat resistance.
  • a lining fitted to the shape of the bottom part of the electron-beam furnace 10d can be obtained by making the bottom lining using such a synthetic resin.
  • FRP is an appropriate construction material as the bottom lining of the present invention since it is light and has high strength.
  • the bottom portion of the furnace includes a mold, and its affixing members or the like therefore have complicated shapes due to the concave and convex parts. Therefore, first of all, it is desirable to take a bottom portion to arrange a bottom lining which can accommodate such a complicated bottom part, and synthetic resin is cast into the mold to obtain the bottom lining. By constructing the bottom lining in this way, a bottom lining closely attached to the bottom part of the furnace can be constructed.
  • the ceiling portion After completion of the installation of the linings, the ceiling portion is engaged to the main body and the pressure inside the furnace is reduced. After confirming that the pressure inside has achieved a certain degree in vacuum, an electron beam is irradiated into the hearth and a stub held in the water-cooled mold to begin the melting operation mentioned above.
  • the next melting process can be started by merely disassembling the electron-beam furnace 10d, removing the linings, and attaching new linings which have been prepared.
  • adhering material deposited on the ceiling or inner wall of the furnace has been removed manually, and this operation required about 5 to 7 days, and this was the main cause of the poor rate of the furnace availability.
  • the maintenance time required after completion of melting and production of an ingot can be greatly reduced, and as a result, productivity of the furnace can be extremely improved.
  • productivity of the furnace can be extremely improved.
  • the frequency of washing the inside of the furnace can be reduced, reducing the service life of the furnace by corrosion can also be prevented effectively.
  • Example 2 Melting process was conducted in conditions similar to that of Example 2, except that the linings of the present invention were not attached. After finishing the melting process, the furnace was disassembled, and the inside thereof was cleaned, washed with water, and dried. Next, the furnace was assembled to prepare for the next melting process. The time required for the process was six days.
  • Example 2 and Comparative Example 2 by the electron-beam furnace for metals and the melting method using the apparatus of the present invention, the effect that the time required for maintenance of the furnace after the melting process can be greatly reduced has been confirmed.
  • the present invention is useful for production of titanium ingots for aviation in which incorporation of LDI is desired to be reduced to a very high degree, and the present invention can greatly improve the utilization rate of furnaces.

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Claims (11)

  1. Elektronenstrahlofen zum Schmelzen von hochschmelzendem Metall, umfassend:
    eine Beschickereinheit für Rohmaterialien (18);
    eine Schmelzeinheit (11) für Rohmaterialien, die mit der Beschickereinheit für Rohmaterialen verbunden ist und aus einer Ofenwand (15) und einer Deckenwand (16) konstruiert ist und wenigstens einen Herd (11), eine wassergekühlte Form (12) und eine Elektronenstrahlkanone (13) enthält,
    eine Auslassdüseneinheit (14) für Abgas, die mit der Schmelzeinheit für Rohmaterialien verbunden ist,
    dadurch gekennzeichnet, dass wenigstens die Ofenwand (15) und/oder die Deckenwand (16) mit Titan oder rostfreiem Stahl ausgekleidet ist, wobei eine Vielzahl rippenförmiger Elemente (17), die aus Titan oder rostfreiem Stahl gefertigt sind, an der Deckenwand (16) angeordnet ist.
  2. Elektronenstrahlofen nach Anspruch 1, wobei ein Abschirmungselement (20) an der Ofenwand (15) angeordnet ist, so dass sich in dem von der Seite betrachteten Ofen das Abschirmungselement (20) von der Ofenwand (15) in Richtung zur Mitte und nach oben erstreckt.
  3. Elektronenstrahlofen nach Anspruch 2, wobei das Abschirmungselement (20) aus Metallen gefertigt ist, die einen höheren Schmelzpunkt aufweisen als denjenigen des hochschmelzenden Metalls im Ofen, oder aus Keramik gefertigt ist, das einen höheren Schmelzpunkt aufweist als denjenigen des hochschmelzenden Metalls im Ofen.
  4. Elektronenstrahlofen nach Anspruch 3, wobei das Metall des Abschirmungselements (20) Molybdän oder Tantal ist.
  5. Elektronenstrahlofen nach Anspruch 3, wobei die Keramik des Abschirmungselements (20) Kalziumoxid, Yttriumoxid oder ein Komplex hiervon ist.
  6. Elektronenstrahlofen nach irgendeinem der Ansprüche 1 bis 5, wobei eine Kondensationsröhre (21) für den Metalldampf des hochschmelzenden Metalls in der Auslaufstrecke der Auslassdüseneinheit (14) für das Abgas angeordnet ist.
  7. Elektronenstrahlofen zum Schmelzen von hochschmelzendem Metall, umfassend:
    eine Beschickereinheit für Rohmaterialien (18);
    eine Schmelzeinheit (11) für Rohmaterialien, die mit der Beschickereinheit für Rohmaterialen verbunden ist und aus einer Ofenwand (15) und einer Deckenwand (16) konstruiert ist und wenigstens einen Herd (11), eine wassergekühlte Form (12) und eine Elektronenstrahlkanone (13) enthält,
    eine Auslassdüseneinheit (14) für Abgas, die mit der Schmelzeinheit für Rohmaterialien verbunden ist,
    wobei eine entnehmbare Auskleidung an einer Innenfläche des Elektronenstrahlofens angeordnet ist, dadurch gekennzeichnet, dass
    die Auskleidung aus einer Deckenauskleidung (31), einer Seitenwandauskleidung (32) und einer Bodenauskleidung (34) besteht, wobei jede Auskleidung separat aus dem Ofen entnehmbar ist.
  8. Elektronenstrahlofen nach Anspruch 7, wobei die Deckenauskleidung (31) aus Metall gefertigt ist und die Seitenwandauskleidung (32) und die Bodenauskleidung (34) aus Metall oder Kunstharz gefertigt sind.
  9. Elektronenstrahlofen nach Anspruch 8, wobei das Metall der Deckenauskleidung (31) ein Kohlenstoffstahl, ein rostfreier Stahl oder ein Titanmaterial ist.
  10. Elektronenstrahlofen nach irgendeinem der Ansprüche 7 bis 9, wobei die Deckenauskleidung (31) eine Plattenstruktur oder eine Netzstruktur aufweist.
  11. Verfahren zur Herstellung eines hochschmelzenden Metallrohblocks (19) die Schritte umfassend:
    Zuführen von Rohmaterial (18) in den Herd (11) des Elektronenstrahlofens nach irgendeinem der Ansprüche 7 bis 10,
    Schmelzen des Rohmaterials (18) mittels der Elektronenstrahlkanone (13), während vom Rohmaterial (18) ausgedampfte Verunreinigungen an den Auskleidungen aufgefangen werden, die die Deckenauskleidung (31), die Seitenwandauskleidung (32) und die Bodenauskleidung (34) umfassen, wobei jede Auskleidung separat aus dem Ofen entnehmbar ist, und
    Erhalten des Metallrohblocks (19) durch Abkühlen geschmolzenen Rohmaterials in der wassergekühlten Form.
EP06712160A 2005-01-25 2006-01-23 Vorrichtung zum schmelzen von metall mittels elektronenstrahlen und verfahren zur herstellung hochschmelzender metallgussblöcke mit dieser vorrichtung Active EP1845325B1 (de)

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JP2005016396A JP4443430B2 (ja) 2005-01-25 2005-01-25 電子ビーム溶解装置
JP2005363412A JP4860253B2 (ja) 2005-12-16 2005-12-16 金属の電子ビーム溶解装置およびこの装置を用いた金属の溶解方法
PCT/JP2006/300944 WO2006080269A1 (ja) 2005-01-25 2006-01-23 金属の電子ビーム溶解装置およびこの装置を用いた高融点金属インゴットの製造方法

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JP5871320B2 (ja) * 2012-07-24 2016-03-01 東邦チタニウム株式会社 電子ビーム溶解炉およびこれを用いた電子ビーム溶解炉の運転方法
RU2499065C1 (ru) * 2012-10-12 2013-11-20 Закрытое Акционерное Общество "Уральские Инновационные Технологии" (ЗАО "УРАЛИНТЕХ") Способ рафинирования сплавов на основе тантала
CN103966458A (zh) * 2013-02-04 2014-08-06 青海聚能钛业有限公司 单电子枪冷床熔炼炉
CN106868455B (zh) * 2017-03-17 2019-04-23 武汉华星光电技术有限公司 蒸镀坩埚及蒸镀装置
FR3082853B1 (fr) 2018-06-26 2020-09-04 Safran Aircraft Engines Procede de fabrication de lingots en compose metallique a base de titane
CN112410575B (zh) * 2020-11-13 2023-01-24 西安诺博尔稀贵金属材料股份有限公司 一种用于双枪双进料系统电子束熔炼炉的磁屏蔽系统
CN113249586B (zh) * 2021-03-22 2023-02-28 洛阳双瑞精铸钛业有限公司 一种用于eb炉熔炼钛合金的双层式冷凝罩
CN113249587B (zh) * 2021-03-22 2022-10-18 洛阳双瑞精铸钛业有限公司 一种用于eb炉熔炼钛合金的组合式冷凝罩

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EP1845325A4 (de) 2008-12-24
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EP1845325A1 (de) 2007-10-17
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