EP1739208A4 - Électrode pour la génération d'hydrogène, processus pour la produire et méthode d'électrolyse avec elle - Google Patents

Électrode pour la génération d'hydrogène, processus pour la produire et méthode d'électrolyse avec elle

Info

Publication number
EP1739208A4
EP1739208A4 EP04821906A EP04821906A EP1739208A4 EP 1739208 A4 EP1739208 A4 EP 1739208A4 EP 04821906 A EP04821906 A EP 04821906A EP 04821906 A EP04821906 A EP 04821906A EP 1739208 A4 EP1739208 A4 EP 1739208A4
Authority
EP
European Patent Office
Prior art keywords
electrode
hydrogen generation
platinum
electrolysis
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP04821906A
Other languages
German (de)
English (en)
Japanese (ja)
Other versions
EP1739208A1 (fr
EP1739208B1 (fr
Inventor
Yoshinori Shirakura
Akinori Shimono
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tosoh Corp
Original Assignee
Tosoh Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tosoh Corp filed Critical Tosoh Corp
Publication of EP1739208A1 publication Critical patent/EP1739208A1/fr
Publication of EP1739208A4 publication Critical patent/EP1739208A4/fr
Application granted granted Critical
Publication of EP1739208B1 publication Critical patent/EP1739208B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C25B11/097—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds comprising two or more noble metals or noble metal alloys
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

Une électrode pour la génération de l'hydrogène, qui possède un surpotentiel d'hydrogène suffisamment bas et est exempte de toute influence d'empoisonnement par les ions de fer, mais également exempte de toute augmentation du surpotentiel d'hydrogène ou d'abandon de matériau transporté lors de l'opération ou au démarrage ou à l'arrêt, et qui excelle en durabilité ; un processus pour produire l'électrode de génération d'hydrogène ; une méthode d'électrolyse dans laquelle l'électrode pour la génération d'hydrogène sert d'électrode négative. Une électrode est utilisée pour la génération de l'hydrogène, composée d'un matériau de base conducteur et, transporté dessus, un alliage de platine composé de platine et d'un métal sélectionné dans le groupe composé de nickel, de cobalt, de cuivre, d'argent et de fer ou d'un matériau amorphe de d'un élément de métal de transition et de platine. Cette électrode peut être obtenue par la réalisation d'un revêtement avec une solution d'un composé de métal choisi dans le groupe constitué de nickel, de cobalt, de cuivre, d'argent et de fer et une solution de composé de platine capable de former un complexe aminé, de les sécher et de réaliser une pyrolyse de 200 à 700° C, suivi en option par un traitement de réduction.
EP04821906.7A 2004-04-23 2004-10-25 Électrode pour la génération d'hydrogène, processus pour la produire et méthode d'électrolyse avec elle Expired - Fee Related EP1739208B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2004128129 2004-04-23
PCT/JP2004/015797 WO2005103337A1 (fr) 2004-04-23 2004-10-25 Électrode pour la génération d'hydrogène, processus pour la produire et méthode d'électrolyse avec elle

Publications (3)

Publication Number Publication Date
EP1739208A1 EP1739208A1 (fr) 2007-01-03
EP1739208A4 true EP1739208A4 (fr) 2007-06-27
EP1739208B1 EP1739208B1 (fr) 2018-08-15

Family

ID=35197014

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04821906.7A Expired - Fee Related EP1739208B1 (fr) 2004-04-23 2004-10-25 Électrode pour la génération d'hydrogène, processus pour la produire et méthode d'électrolyse avec elle

Country Status (4)

Country Link
US (1) US8343329B2 (fr)
EP (1) EP1739208B1 (fr)
CN (1) CN1938453B (fr)
WO (1) WO2005103337A1 (fr)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104037430A (zh) * 2006-03-29 2014-09-10 株式会社科特拉 燃料电池用导电性碳载体、燃料电池用电极催化剂以及具备该电极催化剂的固体高分子型燃料电池
DE102008007605A1 (de) 2008-02-04 2009-08-06 Uhde Gmbh Modifiziertes Nickel
DE102009006403A1 (de) * 2009-01-28 2010-08-05 Süd-Chemie AG Vanadiumfreier Diesel-Oxidationskatalysator und Verfahren zu dessen Herstellung
JP2011032507A (ja) * 2009-07-30 2011-02-17 Sanyo Electric Co Ltd 電解用電極材料、電解用電極及びその製造方法
JP5693215B2 (ja) 2010-12-28 2015-04-01 東ソー株式会社 イオン交換膜法電解槽
AU2013278446B2 (en) 2012-06-18 2016-12-22 Asahi Kasei Kabushiki Kaisha Bipolar alkaline water electrolysis unit and electrolytic cell
US10189085B2 (en) 2013-11-28 2019-01-29 Lg Chem, Ltd. Hollow metal particles, electrode catalyst including same, electrochemical battery including the electrode catalyst, and method of manufacturing hollow metal particles
CN104047018A (zh) * 2014-06-20 2014-09-17 深圳市好美水科技开发有限公司 一种富氢电解的方法
CN104233366B (zh) * 2014-09-16 2017-01-25 武汉轻工大学 一种铱铜氧化物合金阴极催化剂的制备方法
JP6837342B2 (ja) * 2017-02-02 2021-03-03 田中貴金属工業株式会社 水素発生用電極およびその製造方法
WO2018151228A1 (fr) * 2017-02-15 2018-08-23 旭化成株式会社 Électrode négative, son procédé de fabrication, cellule électrolytique l'utilisant et procédé de production d'hydrogène
US11142836B2 (en) 2018-11-29 2021-10-12 Industrial Technology Research Institute Catalyst material and method for manufacturing the same
US10900133B2 (en) 2018-11-30 2021-01-26 Industrial Technology Research Institute Nitride catalyst and method for manufacturing the same
US10914011B2 (en) 2018-11-30 2021-02-09 Industrial Technology Research Institute Membrane electrode assembly and method for hydrogen evolution by electrolysis
US10914012B2 (en) 2018-11-30 2021-02-09 Industrial Technology Research Institute Membrane electrode assembly and method for hydrogen evolution by electrolysis
WO2021053865A1 (fr) * 2019-09-18 2021-03-25 株式会社島津製作所 Analyseur d'ions

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2185347A (en) * 1986-01-13 1987-07-15 Engelhard Nippon Platinum alloy electrocatalyst
DE10007448A1 (de) * 1999-02-24 2000-08-31 Permelec Electrode Ltd Aktivierte Kathode und Verfahren zu ihrer Herstellung

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6013074B2 (ja) 1978-02-20 1985-04-04 クロリンエンジニアズ株式会社 電解用陰極及びその製造法
JPS5948872B2 (ja) * 1978-02-20 1984-11-29 クロリンエンジニアズ株式会社 電解用陰極及びその製造法
SE440240B (sv) 1980-04-22 1985-07-22 Johnson Matthey Co Ltd Katod for anvendning i en reaktion, vid vilken vetgas utvecklas vid katoden, sett att tillverka katoden samt elektrolyscell innefattande katoden
JPS5925985A (ja) 1982-08-03 1984-02-10 Asahi Glass Co Ltd 水電解用高耐久性低過電圧陰極及びその製造法
US4572770A (en) 1983-05-31 1986-02-25 The Dow Chemical Company Preparation and use of electrodes in the electrolysis of alkali halides
AU580002B2 (en) 1983-05-31 1988-12-22 Dow Chemical Company, The Preparation and use of electrodes
US4584085A (en) 1983-05-31 1986-04-22 The Dow Chemical Company Preparation and use of electrodes
US4760041A (en) 1983-05-31 1988-07-26 The Dow Chemical Company Preparation and use of electrodes
JPS6017085A (ja) 1983-07-11 1985-01-28 Hodogaya Chem Co Ltd 耐腐食性活性陰極
EP0136794B1 (fr) 1983-08-22 1990-05-02 Imperial Chemical Industries Plc Traitement des cathodes pour leur utilisation dans les cellules electrolytiques
JPS6056082A (ja) 1983-09-07 1985-04-01 Toyo Soda Mfg Co Ltd 塩化アルカリ水溶液の電解方法
GB8617325D0 (en) 1986-07-16 1986-08-20 Johnson Matthey Plc Poison-resistant cathodes
JPH0633492B2 (ja) 1987-06-29 1994-05-02 ペルメレック電極株式会社 電解用陰極及びその製造方法
EP0769576B1 (fr) 1995-10-18 2000-09-20 Tosoh Corporation Cathode présentant une basse surtension à l'hydrogène et son procédé de fabrication
JP3358465B2 (ja) 1995-10-18 2002-12-16 東ソー株式会社 低水素過電圧陰極およびその製造方法
JPH09206597A (ja) 1996-01-30 1997-08-12 Aqueous Res:Kk 白金−鉄合金電極触媒及び燃料電池
JP3319370B2 (ja) 1996-12-17 2002-08-26 東ソー株式会社 低水素過電圧陰極とその製造方法
EP1626108A1 (fr) 1996-12-17 2006-02-15 Tosoh Corporation Cathode présentant une faible surtension d'hydrogène et son procédé de fabrication
CA2269643C (fr) * 1998-04-23 2009-02-17 N.E. Chemcat Corporation Electrocatalyseur, electrodes, assemblage membrane-electrode et piles a combustible de polymere solide utilisant cet electrocatalyseur
TW200304503A (en) * 2002-03-20 2003-10-01 Asahi Chemical Ind Electrode for generation of hydrogen
US7566388B2 (en) * 2002-12-17 2009-07-28 Asahi Kasei Chemicals Corporation Electrode catalyst for oxygen reduction and gas diffusion electrode
US7485390B2 (en) * 2003-02-12 2009-02-03 Symyx Technologies, Inc. Combinatorial methods for preparing electrocatalysts
US7311946B2 (en) * 2003-05-02 2007-12-25 Air Products And Chemicals, Inc. Methods for depositing metal films on diffusion barrier layers by CVD or ALD processes
US7700521B2 (en) * 2003-08-18 2010-04-20 Symyx Solutions, Inc. Platinum-copper fuel cell catalyst

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2185347A (en) * 1986-01-13 1987-07-15 Engelhard Nippon Platinum alloy electrocatalyst
DE10007448A1 (de) * 1999-02-24 2000-08-31 Permelec Electrode Ltd Aktivierte Kathode und Verfahren zu ihrer Herstellung

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO2005103337A1 *

Also Published As

Publication number Publication date
EP1739208A1 (fr) 2007-01-03
CN1938453B (zh) 2010-10-20
US8343329B2 (en) 2013-01-01
EP1739208B1 (fr) 2018-08-15
WO2005103337A1 (fr) 2005-11-03
US20080029396A1 (en) 2008-02-07
CN1938453A (zh) 2007-03-28

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