Classifications

• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
  • C21D9/02—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for springs
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
  • C21D1/18—Hardening; Quenching with or without subsequent tempering
  • C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
  • C21D1/20—Isothermal quenching, e.g. bainitic hardening
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
  • C21D1/18—Hardening; Quenching with or without subsequent tempering
  • C21D1/25—Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
  • C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
  • C21D8/065—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/30—Ferrous alloys, e.g. steel alloys containing chromium with cobalt
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
  • C21D1/18—Hardening; Quenching with or without subsequent tempering
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D2211/00—Microstructure comprising significant phases
  • C21D2211/008—Martensite
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
  • C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
  • C21D9/525—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length for wire, for rods

Definitions

• the present invention relates to a spring steel wire having a tempered martensitic structure brought about by quenching-tempering, to a method of manufacturing the spring steel wire in a well-suited efficient manner, and to a spring manufactured from the steel wire. More particularly, the present invention relates to a high toughness spring steel wire having a high strength with excellent fatigue properties that is advantageously applicable to engine valve springs or those springs used for transmission interior parts, etc. of automobiles.
• Patent document 1 Japanese Patent Publication No. 2842579
• springs such as engine valve springs or springs for transmission parts have been increasingly required to have better mechanical or physical properties in recent years, so that further improvement has come to be demanded in spring steel wires and springs worked from the steel wire.
• spring steel wires and springs manufactured therefrom be provided with fatigue properties and toughness in better balance than ever.
• springs worked from steel wires are typically subjected to heat treatment (nitriding treatment) at elevated temperatures (specifically, around 420-480°C).
• the patent document 1 discloses a technique that aims at improving the toughness of a steel wire by providing it with a C (carbon) content ranging from 0.3% to 0.5% by weight.
• a steel wire with a carbon content as low as less than 0.50% by weight will have a reduced thermal resistance
• a spring worked from such a low carbon content steel wire is subjected to nitriding treatment at elevated temperatures as described above, the resultant spring will have a reduced fatigue strength, so that it may undergo internal breakage when put into practical use.
• the patent document 3 discloses a technique that aims at improving a steel wire in its workability into sprang by decarbonizing its surface purposely during the oil tempering so as to reduce the surface hardness, but this prior art technique is inadequate for the mass production of such a steel wire or spring because it is practically difficult to obtain a uniform decarburized layer in the surface of the steel wire. Moreover, the oxygen concentration must be well controlled when heating the steel wire (during the oil tempering), thus adding to the cost accordingly.
• the proof stress of the material (spring) to a stress exerted inside in its torsional direction i.e., the shear yield stress of the spring is not examined subsequent to the nitriding treatment to which the spring is subjected after worked from the steel wire.
• a principal object of the present invention is to provide a high strength spring steel wire which is excellent not only in fatigue strength but also in toughness. Also, it is another object of the present invention to provide a spring manufactured from the above-described steel wire and a suitable method to manufacture the spring steel wire.
• the present invention provides a spring steel wire, in which its reduction of area after quenching-tempering and its shear yield stress after subjected to heat treatment comparable to nitriding treatment following the above quenching-tempering are limited to specific ranges, respectively.
• the present invention provides a spring steel wire which has a tempered martensitic structure brought about by quenching-tempering.
• the present spring steel wire is characterized by a 40% or higher reduction of area and by a 1,000 MPa or higher shear yield stress after subjected to heat treatment for at least 2 hours at a temperature ranging from 420°C to 480°C.
• the spring steel wire preferably comprises any one of the following chemical formulations 1 through 6:
• the present invention also provides a method of manufacturing the above-described spring steel wire in a well suited manner therefor, as will be described herein below. More specifically, the method of manufacturing the spring steel wire according to the present invention comprises patenting a steel having any one of the chemical formulations (A) through (C) given below, drawing the patented steel into a steel wire, and subjecting the resultant steel wire to quenching-tempering.
• the above-mentioned patenting process comprises an austenization step in which the steel is heated at 900-1,050°C for 60 to 180 seconds, and an isothermal transformation step in which the thus austenized steel is heated at 600-750°C for 20 to 100 seconds.
• the improvement of a spring in its fatigue properties may preferably be addressed in terms of the suppression of its fatigue breakage.
• a repetitive stress is exerted on the spring not only in the tensile and compression directions but also in the shear direction simultaneously.
• the spring undergoes a repetitive slip deformation (plastic deformation) locally or intensively and creates projections and depressions in the surface region to induce cracks leading to breakage, namely resulting in fatigue breakage. Therefore, for suppressing the fatigue breakage of the spring, it will be effective to suppress such a local or concentrated plastic deformation.
• the steel wire is typically subjected to heat treatment such as nitriding treatment after worked into spring to increase its surface hardness and thereby to increase its fatigue limit.
• heat treatment such as nitriding treatment after worked into spring to increase its surface hardness and thereby to increase its fatigue limit.
• mere an increase in fatigue limit of the springs may sometimes be insufficient to allow their practical use, because such springs tend to undergo permanent set in fatigue.
• the present invention provides a spring steel wire having a reduction of area limited to a specific range of 40% or higher.
• the steel wire tends to undergo in-process breakage when worked into spring and its mass productivity could be substantially compromised thereby.
• the reduction of area may decrease a little when subjecting the steel wire to such particular heat treatment comparable to nitriding treatment that is accomplished at a temperature ranging from 420°C to 480°C for at least 2 hours following the quenching-tempering as described previously.
• the steel wire has a 40% or higher reduction of area after quenching-tempering as described above, it can maintain a 35% or higher reduction of area even after the above-described heat treatment, and a spring manufactured from this steel wire can have a high fatigue properties.
• the reduction of area of a spring steel wire and its shear yield stress after subjected to heat treatment comparable to nitriding treatment following the above quenching-tempering are limited to specific ranges, respectively, to provide the spring steel wire and the spring manufactured from the steel wire with a high fatigue strength and high toughness in adequate balance.
• the present invention specifically limits the present steel wire to predetermined optimal chemical compositions and optimal manufacturing conditions, especially patenting conditions.
• the fatigue limit of a spring can be improved by increasing the surface hardness of the spring by subjecting it to the heat treatment such as nitriding treatment or like after it is worked from a steel wire
• an internal hardness of the spring decreases by the heat treatment to sometimes cause the spring to undergo internal breakage in use.
• the steel wire to be worked into a spring contains carbon (C) and silicon (Si) in a quantity (in mass %) falling in a predetermined range in order to improve the thermal resistance of a matrix of the steel wire.
• the steel wire contains a predetermined quantity of chromium (Cr) in order to produce carbide in the structure of the steel wire when it is tempered and to thereby increase the softening resistance of the steel wire.
• the steel wire may contain also a predetermined quantity of molybdenum (Mo), vanadium (V), niobium (Nb), Tungsten (W), or titanium (Ti) to effectively increase the softening resistance.
• Mo molybdenum
• V vanadium
• Nb niobium
• W Tungsten
• Ti titanium
• the inventors have found out that, for improving the shear yield stresses of the steel wire and the spring manufactured therefrom of the present invention, it is effective to provide the steel wire with a 0.02-1.00 mass % cobalt (Co) content or a rather excess manganese (Mn) content (over 0.7 to 1.5 mass %).
• the steel wire of the present invention has Mn and Co contents limited to specific ranges, respectively. The ranges of these contents and the grounds for such limitation will be described in detail herein later.
• the spring steel wire of the present invention is obtained by subjecting a steel having the above-described chemical compositions to the following processes in sequence: steel ingot making ⁇ hot forging ⁇ hot rolling ⁇ patenting ⁇ wire drawing ⁇ quenching-tempering
• a steel rod is subjected, before wire drawing, to patenting under particular conditions to fully austenitize the structure of the steel to thereby dissolve the undissolved carbide and to obtain a homogeneous pearlitic structure through an appropriate isothermal transformation following the austenitization. Insufficient austenitization may cause the reduction of toughness and shear yield stress of the resultant steel wire. Then, for fully austenitizing the steel, it is preferred to heat the steel rod at a temperature of 900-1,050°C for 60 to 180 seconds.
• the heating temperature is lower than 900°C, or if the heating temperature falls in the range of 900-1,050°C but the heating time is shorter than 60 seconds, sufficient austenitization will not be achieved and undissolved carbide will remain. However, if the heating temperature is higher than 1,050°C, or if the heating temperature falls in the range of 900-1,050°C but the heating time is longer than 180 seconds, austenite grains will become coarse, thus tending to produce martensite during the succeeding transformation, so that the drawability of the steel rod will not be secured during the wire drawing process.
• the steel rod For the isothermal transformation of the steel following the austenitization, it is preferred to heat the steel rod at 600-750°C for 20 to 100 seconds. If the heating temperature is higher than 750°C, or if the heating temperature falls in the 600-750°C range but the heating time is longer than 100 seconds, cementite spheroidizes in the structure of the steel, which may degrade the drawability of the steel rod. On the other hand, if the heating temperature is lower than 600°C, or if the heating temperature falls in the 600-750°C range but the heating time is shorter than 20 seconds, the transformation to pearlite will not be completed and martensite will be produced to thereby degrade the drawability.
• the steel wire obtained by drawing the steel rod which is subjected to patenting as above is then subjected to quenching at too low a temperature, undissolved carbide will remain in the structure of the steel wire, which acts to reduce the toughness of the steel wire.
• the quenching temperature is too high, the austenite grains will grow to larger sizes and consequently the fatigue limits of the steel wire and the spring manufactured therefrom will be reduced.
• the quenching temperature be higher than 850°C but lower than 1,050°C.
• the spring steel wire has a tempered martensitic structure. Moreover, if the austenite grains (prior austenite grains) of the steel wire are rendered fine as observed after subjected to the quenching-tempering, such a steel wire and the spring manufactured from the steel wire will become hard to undergo a slip deformation locally or intensively even when a repetitive stress is applied thereto. That is to say, since the shear yield stress of the steel wire or spring can be improved by rendering fine the austenite grains (prior austenite grains), this consequently contributes to improved fatigue properties of the steel wire or spring.
• the average grain size of the austenite grains fall in the range of 3.0-7.0 micrometers.
• the average grain size can be changed by varying the temperature for patenting the steel rod. More specifically, if the austenitization during patenting is effected at a lower temperature, the grain size will tend to become smaller, while if this austenitizing temperature is increased, the grain size tends to increase. With an average grain size smaller than 3.0 micrometers, undissolved carbide will remain due to the lower austenitizing temperature and tend to reduce the toughness of the steel wire. Meanwhile, if the average grain size is larger than 7.0 micrometers, it is difficult to improve the fatigue limit of the steel wire or the spring manufactured therefrom. Now it is to be noted that the average grain size herein is given in measurements taken on steel wires after drawing and then subjected to quenching-tempering.
• Carbon (C) is an important element which determines the strength of steel, and since a carbon content lower than 0.50 mass % of the total steel will not allow a resulting steel wire to have a sufficient strength, while a carbon content exceeding 0.75 mass % will result in reduced toughness, it is preferred that the carbon content ranges from 0.50 mass % to 0.75 mass %.
• Silicon (Si) is used as a deoxidizer when melting and smelting a raw steel. Moreover, Si is solid-dissolved in steel's ferrite to improve the thermal resistance of the steel and has the effect of preventing the hardness reduction inside the steel wire (spring) due to heat treatment such as strain relief annealing or nitriding treatment to which the spring is subjected after worked from the steel wire. It is preferred that the steel have a Si content ranging from 1.80 mass % to 2.70 mass %, because the 1.80 mass % or higher Si content is required to maintain an adequate thermal resistance but the toughness will decrease if the Si content exceeds 2.70 mass %.
• Mn manganese
• the Mn content required for such a deoxidizer has a lower limit of 0.1 mass %.
• Mn has the effect of improving the hardenability of the steel wire to thereby increase its strength and improve the shear yield stress of the steel wire and the spring manufactured therefrom.
• the Mn content preferably has an upper limit of 1.5 mass %.
• the Mn content may fall in a rather lower range of 0.1-0.7 mass %, while it is preferred for a formulation without Co content that the Mn content fall in a rather higher range of over 0.7 to 1.5 mass %.
• a formulation having a rather higher Mn content may contain also Co.
• a small quantity of cobalt (Co) added to a steel acts to improve the shear yield stress of the resultant steel wire and the spring worked from the steel wire. Also, Co is effective for improving the thermal resistance of the steel wire and for the softening prevention of the spring worked from the steel wire and subjected to the tempering and nitriding treatment. Further, Co does not act to reduce the toughness of the steel wire, so long as its content is low. A Co content lower than 0.02 mass % is hard to contribute to any improved shear yield stress for the steel wire or the spring as described above or to any improved thermal resistance for the steel wire.
• the Co content fall in the range of 0.02 mass % to 1.00 mass %.
• Mn content of the steel may fall in a rather low range of 0.1-0.7 mass %, as described above.
• These elements act to produce carbide in the structure of a steel wire when it is tempered and have the effect of tending to increase the softening resistance of the steel wire. If the content of each of molybdenum (Mo), vanadium (V), tungsten (W) or niobium (Nb) is lower than 0.05 mass % of the total steel, the above-described effect will be hard to achieve. Meanwhile, if the Mo content exceeds 0.50 mass %, if the V content exceeds 0.50 mass %, if the W content exceeds 0.15 mass %, or if the Nb content exceeds 0.15 mass %, the resultant steel wire tends to have reduced toughness in either case.
• Mo molybdenum
• V vanadium
• W tungsten
• Nb niobium
• Titanium acts to produce carbide when the steel wire is tempered and has the effect of tending to increase a softening resistance of the steel wire.
• a Ti content lower than 0.01 mass % will not yield the above-mentioned effect, while a Ti content higher than 0.20 mass % will produce a high-melting point non-metallic inclusion TiO in the structure of the steel wire, tending to reduce the toughness of the steel wire.
• the Ti content preferably ranges from 0.01 mass % to 0.20 mass %.
• the spring steel wire of the present invention may have any cross-sectional shape as cut by a plane perpendicular to the longitudinal direction (drawing direction) of the steel wire, including a typical circular shape and other special or peculiar cross-sectional shapes such as an ellipse, a trapezoid, a square, a rectangle, and so on.
• the spring of the present invention may be provided by subjecting the above-described spring.steel wire to any known spring forming process such as coiling. Especially, it is to be noted here that by subjecting the spring worked from the present spring steel wire to heat treatment such as nitriding treatment or like, the resultant spring can have an improved surface hardness and thus an excellent fatigue limit.
• the respective 6.5 mm ⁇ wire rods were patented under several varied patenting conditions, including austenitizing conditions under which the wire rods were heated at varied temperatures for varied retention times, and conditions for isothermal transformation under which the wire rods were heated also at varied temperatures for varied retention times-subsequentiy to the austenization, as shown in Table 2.
• the resultant steel wires (3.0mm ⁇ ) were then subjected to quenching-tempering.
• quenching the conditions shown in Table 3 were used, while the tempering was carried out using a heating temperature of 450-530°C for all wires.
• the reduction of area (RA) and the average grain sizes (average ⁇ grain size) of austenite grains (prior austenite grains) were measured on the respective quench-tempered wires.
• the results are shown in Table 3.
• the wire quenching temperature was varied to change the average grain size of austenite grains (prior austenite grains).
• the average grain size of austenite grains was determined based on the intercept method subject to JIS G 0522.
• shear yield stress and the fatigue properties were measured on those steel wires which were subjected, after the quenching-tempering, to heat treatment (420°C for 2 hours or 480°C for 2 hours) comparable to nitriding treatment.
• the results are shown also in Table 3.
• the shear yield stress of the steel wires which were heat-treated as above was determined from torque- ⁇ curves obtained through twisting tests on samples of 100d in length (d: sample diameter).
• the fatigue limit was evaluated based on a Nakamura-type rotating bending fatigue test.
• the samples No. 1-4, 6, and 8 having a low shear yield stress after the heat treatment comparable to nitriding treatment turned out to have a low fatigue limit.
• the samples No.2 and 4 had also an inferior toughness with a low reduction of area.
• the steel wires of the samples No. 5 and 7 underwent martensite generation in their wire rod structures during patenting and then frequent wire breakage in the succeeding shaving step, and thus the experiment was forced to stop continuing.
• the sample No. 11 since it had a higher V content of the total steel in addition to its low shear yield stress after the heat treatment, it had a lowered reduction of area of the steel wire to thus reduce its fatigue limit.
• the sample No. 12 since it had a higher Ti content in addition to its low shear yield stress after the heat treatment, it underwent a reduction in fatigue limit owing to breakage caused by Ti-based inclusions.
• the sample No. 9 since it had a smaller average grain size of the austenite grains (prior austenite grains) in addition to its low shear yield stress after the heat treatment, it showed also a low reduction of area.
• the sample No. 10 showed a reduction in fatigue limit, because it had a large average grain size of the austenite grains (prior austenite grains) in addition to its low shear yield stress after the heat treatment.
• the spring steel wire of the present invention is excellent both in fatigue properties and in toughness, it is best suited as a material for springs that are used for parts requiring an adequate fatigue strength.

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• Chemical & Material Sciences (AREA)
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• Materials Engineering (AREA)
• Mechanical Engineering (AREA)
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• Organic Chemistry (AREA)
• Thermal Sciences (AREA)
• Crystallography & Structural Chemistry (AREA)
• Physics & Mathematics (AREA)
• Manufacturing & Machinery (AREA)
• Heat Treatment Of Strip Materials And Filament Materials (AREA)
• Heat Treatment Of Steel (AREA)
• Springs (AREA)

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• 2004
  • 2004-02-04 JP JP2004027891A patent/JP4357977B2/ja not_active Expired - Fee Related
• 2005
  • 2005-02-04 US US10/588,287 patent/US20080271824A1/en not_active Abandoned
  • 2005-02-04 WO PCT/JP2005/001703 patent/WO2005075695A1/fr active Application Filing
  • 2005-02-04 EP EP05709768.5A patent/EP1731625B1/fr not_active Not-in-force
  • 2005-02-04 CN CNB2005800039621A patent/CN100449026C/zh not_active Expired - Fee Related
• 2006
  • 2006-08-14 KR KR1020067016315A patent/KR101096888B1/ko active IP Right Grant

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