EP1699755B1 - Process for preparing fluorochemical monoisocyanates - Google Patents
Process for preparing fluorochemical monoisocyanates Download PDFInfo
- Publication number
- EP1699755B1 EP1699755B1 EP04813986A EP04813986A EP1699755B1 EP 1699755 B1 EP1699755 B1 EP 1699755B1 EP 04813986 A EP04813986 A EP 04813986A EP 04813986 A EP04813986 A EP 04813986A EP 1699755 B1 EP1699755 B1 EP 1699755B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mdi
- fluorochemical
- reaction
- heptane
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
- 0 *C=NN(c1ccc(*)cc1)c1ccc(*)cc1 Chemical compound *C=NN(c1ccc(*)cc1)c1ccc(*)cc1 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/36—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of amides of sulfonic acids
- C07C303/40—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of amides of sulfonic acids by reactions not involving the formation of sulfonamide groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C311/01—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms
- C07C311/02—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C311/09—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton the carbon skeleton being further substituted by at least two halogen atoms
Definitions
- This invention relates to a process for selectively preparing fluorochemical monoisocyanates.
- these resins comprise long chain pendant perfluorinated groups (for example, 8 carbon atoms or greater) because long chains readily align parallel to adjacent pendant groups attached to acrylic backbone units, and thus maximize water- and oil-repellency.
- long chain perfluorinated group-containing compounds such as, for example, perfluorooctyl containing compounds ( U.S. Patent No. 4,540,497 ) may bioaccumulate in living organisms (see, for example, U.S. Patent No. 5,688,884 (Baker et al. )).
- the present invention provides a process for preparing fluorochemical monoisocyanates that have short chain perfluorinated groups, which are thought to be less toxic and less bioaccumulative than longer chain perfluorinated groups (see, for example, WO 01/30873 ). These fluorochemical monoisocyanates can be reacted with acrylates, and then polymerized, to provide polymers having oil- and water-repellency properties.
- the process of the invention can be used to selectively prepare fluorochemical monoisocyanates in purities greater than 85% without any further purification. Furthermore, the process can be carried out using a substantially smaller excess of diisocyanate than other known processes (see, for example, U.S. Patent No. 5,446,118 (Shen et al. ), and U.S. Patent App. No. US 2001/0005738 A1 (Bruchmann et al. )).
- the process of the invention therefore meets the need in the art for an economical process for preparing starting compounds useful in the preparation of less bioaccumulative polymerizable water- and oil-repellent acrylic resins.
- this invention also provides fluorochemical isocyanate compositions prepared by the process of the invention wherein said composition comprises greater than 85% monoisocyanate.
- Fluorochemical alcohols that are useful starting compounds include C 2 F 5 SO 2 NCH 3 (CH 2 ) 2 OH, C 2 F 5 SO 2 NCH 3 (CH 2 ) 3 OH, C 2 F 5 SO 2 NCH 3 (CH 2 ) 4 OH, C 3 F 7 SO 2 NCH 3 (CH 2 ) 2 OH, C 3 F 7 SO 2 NCH 3 (CH 2 ) 3 OH, C 3 F 7 SO 2 NCH 3 (CH 2 ) 4 OH, C 4 F 9 SO 2 NCH 3 (CH 2 ) 2 OH, C 4 F 9 SO 2 NCH 3 (CH 2 ) 3 OH, C 4 F 9 SO 2 NCH 3 (CH 2 ) 4 OH, C 5 F 11 SO 2 NCH 3 (CH 2 ) 2 OH, C 5 F 11 SO 2 NCH 3 (CH 2 ) 3 OH, C 5 F 11 SO 2 NCH 3 (CH 2 ) 4 OH, and mixtures thereof.
- Preferred fluorochemical alcohols include, for example, C 2 F 5 SO 2 NCH 3 (CH 2 ) 2 OH, C 4 F 9 SO 2 NCH 3 (CH 2 ) 2 OH, C 4 F 9 SO 2 NCH 3 (CH 2 ) 4 OH, and mixtures thereof. More preferred fluorochemical alcohols include, for example, C 4 F 9 SO 2 NCH 3 (CH 2 ) 2 OH, C 4 F 9 SO 2 NCH 3 (CH 2 ) 4 OH, and mixtures thereof.
- a most preferred fluorochemical alcohol is C 4 F 9 SO 2 NCH 3 (CH 2 ) 2 OH.
- Useful fluorochemical alcohols can be purchased from 3M (St. Paul, MN), or can be prepared essentially as described in U.S. Patent Nos. 2,803,656 (Ahlbrecht et al. ) and 6,664,345 (Savu et al. ).
- the above-described fluorochemical alcohols can be reacted with 4,4'-diphenylmethane diisocyanate in a solvent to form the corresponding monoisocyanates.
- 4,4'-Diphenylmethane diisocyanate is commonly known as "methylene diisocyanate" or "MDI".
- MDI is commercially available as Isonate TM 125M from the Dow Chemical Company (Midland, MI), and as Mondur TM M from Bayer Polymers (Pittsburgh, PA).
- the process of the invention can be carried out with a molar ratio of fluorochemical alcohol:MDI from 1:1 to 1:2.5.
- the molar ratio of fluorochemical alcohol:MDI is from 1:1 to 1:2. More preferably, the molar ratio is from 1:1.1 to 1:1.5.
- the process of the invention can be carried out in a solvent in which the resulting monoisocyanate is not soluble (that is, the solvent is one in which the monoisocyanate partitions out of so that it no longer participates in the reaction).
- the solvent is a nonpolar solvent. More preferably, it is a nonpolar non-aromatic hydrocarbon or halogenated solvent.
- solvents include cyclohexane, n-heptane, hexanes, n-hexane, pentane, n-decane, i-octane, octane, methyl nonafluoroisobutyl ether, methyl nonafluorobutyl ether, petroleum ether, and the like, and mixtures thereof.
- a mixture of methyl nonafluoroisobutyl ether and methyl nonafluorobutyl ether is available as HFE-7100 Novec TM Engineered Fluid from 3M (St. Paul, MN).
- Preferred solvents include, for example, methyl nonafluoroisobutyl ether, methyl nonafluorobutyl ether, petroleum ether, n-heptane, and the like.
- the solvent has a Hildebrand solubility parameter ( ⁇ ) of less than 8.3 (cal/cm 3 ) 1/2 (about 17 MPa 1/2 ) and a hydrogen bonding index of less than about 4.
- ⁇ Hildebrand solubility parameter
- the hydrogen bonding index is a numerical value that indicates the strength of the hydrogen bonding that occurs in a solvent. Hydrogen bonding values range from -18 to +15. For example, n-heptane has a hydrogen bonding value of about 2.2, and water has a hydrogen bonding value of about 16.2 ( Principles of Polymer Systems, 2nd edition, McGraw-Hill Book Company, New York (1982 )).
- the reaction can be carried out by combining the fluorochemical alcohol and MDI in the solvent.
- the fluorochemical alcohol is added to MDI, which is in the solvent, over time.
- the fluorochemical alcohol can first be dissolved in a solvent such as, for example, toluene, and then added to the MDI in solution.
- the reaction mixture is agitated.
- the reaction can generally be carried out at a temperature between about 25oC and about 70oC (preferably, between about 25oC and about 50oC).
- the reaction can be carried out in the presence of a catalyst.
- a catalyst include bases (for example, tertiary amines, alkoxides, and carboxylates), metal salts and chelates, organometallic compounds, acids, and urethanes.
- the catalyst is an organotin compound (for example, dibutyltin dilaurate (DBTDL)) or a tertiary amine (for example, diazobicyclo[2.2.2]octane (DABCO)), or a combination thereof. More preferably, the catalyst is DBTDL.
- the reaction product can be filtered out and dried.
- the reaction product typically comprises greater than about 85% of the desired fluorochemical monoisocyanate (preferably, greater than about 90%; more preferably, greater than about 95%).
- Preferred fluorochemical monoisocyanates that can be prepared using the process of the invention include, for example: and More preferred fluorochemical monoisocyanates prepared using the process of the invention include, for example: and
- Fluorochemical monoisocyanates prepared using the process of the invention can be useful starting compounds in processes for preparing fluorinated acrylic polymers with water- and oil-repellency properties.
- fluorochemical monoisocyanates prepared using the process of the invention can be reacted with active hydrogen-containing compounds, materials, or surfaces bearing hydroxyl, primary or secondary amines, or thiol groups.
- the monomer produced by reacting a fluorochemical monoisocyanate prepared by the process of the invention with a hydroxy alkyl acrylate such as hydroxy ethyl acrylate, for example, can be polymerized (alone or with comonomers) to provide polymers that have useful water- and oil-repellency properties.
- the resulting slurry was heated for 6 hr at 136oC, treated with 15 g of CH 2 Cl 2 , and heated for an additional 20 hr at 136oC.
- the resulting mixture was then washed with water, extracted with CH 2 Cl 2 , stripped to 237.8 g, and distilled (1-plate) to yield a 75.1 g main cut at 110-130oC/0.2-0.3 mTorr.
- the resulting material, C 4 F 9 SO 2 NCH 3 C 4 H 8 acetate was dissolved in 50 mL ethanol and treated with 5.0 g 50% NaOH diluted with 20 mL water with agitation. After 24 hr, infrared spectroscopy (IR) showed no acetate remaining.
- the product was extracted with CH 2 Cl 2 to yield 65.7 g C 4 F 9 SO 2 NCH 3 C 4 H 8 OH, a pale tan liquid.
- C 4 F 9 SO 2 N(CH 3 ) (CH 2 ) 11 OH was prepared using a procedure similar to that described above for preparing C 4 F 9 SO 2 N (CH 3 ) (CH 2 ) 4 OH. 175.9 g C 4 F 9 SO 2 NHCH 3 and 121.4 g 25% NaOCH 3 were reacted to produce a solution of C 4 F 9 SO 2 NNaCH 3 in about 100 mL diglyme. This solution was treated with 141 g 11-bromoundecanol (available from Aldrich) and heated at 100oC for 20 hr to form a heavy precipitate.
- C 2 F 5 SO 2 N(CH 3 )CH 2 CH 2 OH can be prepared essentially as described in Example 1 Part A and Example 2 Part A of U.S. Patent No. 6,664,354 (Savu et al. ) with the exception that an equimolar amount of C 2 F 5 SO 2 F is substituted for C 4 F 9 SO 2 F.
- C 2 F 5 SO 2 N(CH 3 )CH 2 CH 2 OH was prepared from C 2 F 5 SO 2 F by reaction with monomethylamine in MTBE, followed by stripping of the solvent, acidification with 19% sulfuric acid, then water washing and distillation at 5.5 mm at a head temperature of 69°C to give C 2 F 5 SO 2 N(CH 3 )H.
- the C 2 F 5 SO 2 N(CH 3 )H was then reacted with 3 equivalents of ethylene carbonate and 0.08 equivalents K 2 CO 3 neat at 110oC overnight.
- the product was isolated by successive washes with water, 3% sulfuric acid and water, followed by distillation at 0.5 mm at a head temperature of 98oC.
- Example 1 Reaction of C 4 F 9 SO 2 N(CH 3 ) (CH 2 ) 4 OH with MDI: 1.0:1.5
- Example 4 was prepared by essentially following the procedure described for Example 3, with the exception that the molar ratio of MeFBSE:MDI was 1:1.2.
- Example 5 was prepared by essentially following the procedure described for Example 3, with the exception that the molar ratio of MeFBSE:MDI was 1:1.3.
- Example 6 was prepared by essentially following the procedure described for Example 3, with the exception that the molar ratio of MeFBSE:MDI was 1:1.4.
- Example 7 was prepared by essentially following the procedure described for Example 3, with the exception that the molar ratio of MeFBSE:MDI was 1:1.5.
- Example 8 was prepared by essentially following the procedure described for Example 3, with the exception that the molar ratio of MeFBSE:MDI was 1:2.
- Example 9 was prepared by essentially following the procedure described for Example 3, with the exception that the molar ratio of MeFBSE:MDI was 1.0:2.5
- Example 11 was prepared essentially following the procedure described in Example 5, except substituting 400 ml of petroleum ether for the heptane. The product immediately precipitated as MeFBSE was added. The MeFBSE was added over a 1 hour period. The product was isolated after a 1.5 hour hold period, and rinsed once with warm petroleum ether, then dried with nitrogen. The yield was 82 g.
- Example 12 was prepared essentially following the procedure described in Example 5, except substituting 300 ml of HFE-7100 for heptane.
- the MDI was not soluble to any large extent in this solvent.
- the product immediately precipitated.
- the product was rinsed with warm heptane of equal volume, and dried by nitrogen stream.
- the reaction was allowed to cool overnight to room temperature and the heptane layer was decanted off. Then, heptane (65 g) was added to the reaction, which was heated to 70oC. After stirring, the heptane layer was decanted off, leaving 52 g of a thick whitish solid.
- Comparative Example C-5 was prepared essentially following the procedure described in Example 5, except substituting 300 ml of MTBE for heptane. Much of the product does not precipitate in the MTBE. The solid was rinsed once with an equivalent volume of warm heptane.
- Residue in the flask was rinsed out with an additional 300 g of dry heptane.
- the recovered solid was dried in a vacuum oven at 45°C, using a drying tower of CaCl 2 . This solid partially melted during the drying process. The yield was approximately 160 g.
- reaction contents were filtered after an additional 2 hours of stirring at 55°C, and then rinsed with an equivalent volume of warm heptane.
- the resulting solid was transferred to an Erlenmeyer flask and heated with another volume of heptane, then filtered, under a nitrogen atmosphere. Additional heptane was used for rinsing.
- the solid was dried in a vacuum oven at 45°C overnight. About 135 g of a light, powdery solid was recovered.
- the sample solutions were each analyzed by high performance liquid chromatography (HPLC) under the following chromatographic conditions: Instrument: Agilent 1100 HPLC Column: Merck Purospher RP18e, 5 ⁇ m, 125 x 3 mm Solvent A: Water Solvent B: Acetonitrile Gradient: 40% B to 100% B in 15 minutes and hold 100% B for 10 minutes Flow Rate: 0.5 mL/min Injection: 2 ⁇ L Detector: UV at 254 nm The methanolized samples were further analyzed by liquid chromatography-mass spectrometry (LC-MS) in positive electrospray ionization in order to identify the major components that were observed in the HPLC chromatograms.
- LC-MS liquid chromatography-mass spectrometry
- UV Area (%) Data is reported in Table 1 as UV Area (%) of the desired monoisocyanate product.
- Table 1. UV Area (%) of Monoisocyanate
- Example UV Area (%) 1 89.12 C-1 20.12 2 85.89 C-2 61.60 3 93.18 C-3 78.53 4 95.34 C-4 65.09 5 94.69 C-5 14.69 6 94.23 C-6 82.37 7 92.88 C-7 70.95 8 94.22 C-8 19.66 9 85.37 C-9 83.98 10 93.94 C-10 66.70 11 96.50 C-11 15.31 12 90.04 C-12 69.59 C-13 54.14 C-14 40.63
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyurethanes Or Polyureas (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/751,142 US7081545B2 (en) | 2003-12-31 | 2003-12-31 | Process for preparing fluorochemical monoisocyanates |
PCT/US2004/041743 WO2005065164A2 (en) | 2003-12-31 | 2004-12-14 | Process for preparing fluorochemical monoisocyanates |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1699755A2 EP1699755A2 (en) | 2006-09-13 |
EP1699755A4 EP1699755A4 (en) | 2007-11-07 |
EP1699755B1 true EP1699755B1 (en) | 2011-09-21 |
Family
ID=34701272
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04813986A Not-in-force EP1699755B1 (en) | 2003-12-31 | 2004-12-14 | Process for preparing fluorochemical monoisocyanates |
Country Status (8)
Country | Link |
---|---|
US (2) | US7081545B2 (ko) |
EP (1) | EP1699755B1 (ko) |
JP (1) | JP4965264B2 (ko) |
KR (1) | KR20060107836A (ko) |
CN (1) | CN100471834C (ko) |
AT (1) | ATE525348T1 (ko) |
CA (1) | CA2552000A1 (ko) |
WO (1) | WO2005065164A2 (ko) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1709089B1 (en) * | 2003-12-31 | 2008-03-05 | 3M Innovative Properties Company | Water-and oil-repellent fluoroacrylates |
US7345123B2 (en) * | 2004-12-28 | 2008-03-18 | 3M Innovative Properties Company | Fluoroacrylate-multifunctional acrylate copolymer compositions |
US7253241B2 (en) | 2004-12-28 | 2007-08-07 | 3M Innovative Properties Company | Fluorochemical containing low adhesion backsize |
US7291688B2 (en) * | 2004-12-28 | 2007-11-06 | 3M Innovative Properties Company | Fluoroacrylate-mercaptofunctional copolymers |
US20060142530A1 (en) * | 2004-12-28 | 2006-06-29 | Moore George G | Water- and oil-repellent fluorourethanes and fluoroureas |
US7411020B2 (en) | 2004-12-28 | 2008-08-12 | 3M Innovative Properties Company | Water-based release coating containing fluorochemical |
KR20080033306A (ko) * | 2005-06-29 | 2008-04-16 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 올리고머형 플루오로아크릴레이트로부터 유도된 폴리우레탄 |
US7279210B2 (en) * | 2005-09-07 | 2007-10-09 | 3M Innovative Properties Company | Curable compositions, methods of making and using the same, and articles therefrom |
US7560166B2 (en) * | 2005-12-28 | 2009-07-14 | 3M Innovative Properties Company | Adhesive article, composite article, and methods of making the same |
US7981988B2 (en) * | 2006-05-25 | 2011-07-19 | 3M Innovative Properties Company | Ultraviolet radiation-polymerizable compositions |
US20080075951A1 (en) * | 2006-09-27 | 2008-03-27 | 3M Innovative Properties Company | Fluoroacrylates and hardcoat compositions including the same |
US8530054B2 (en) * | 2006-09-27 | 2013-09-10 | 3M Innovative Properties Company | Solar control multilayer film |
WO2008083272A1 (en) * | 2006-12-29 | 2008-07-10 | 3M Innovative Properties Company | Stain and fouling resistant polyurea and polyurethane coatings |
WO2011005396A1 (en) | 2009-06-12 | 2011-01-13 | 3M Innovative Properties Company | Fluorinated aromatic bis(acyl)-containing compounds and polyesters prepared therefrom |
US8975436B2 (en) | 2009-12-22 | 2015-03-10 | 3M Innovative Properties Company | Fluorinated arylene-containing compounds, methods, and polymers prepared therefrom |
CN104927024A (zh) * | 2014-03-20 | 2015-09-23 | 江南大学 | 一种氟改性光固化聚氨酯丙烯酸酯树脂的制备方法及其作为光固化涂层疏水填料的应用 |
Family Cites Families (31)
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US2803656A (en) * | 1956-01-23 | 1957-08-20 | Minnesota Mining & Mfg | Fluorocarbonsulfonamidoalkanols and sulfates thereof |
US3776805A (en) * | 1971-09-07 | 1973-12-04 | Minnesota Mining & Mfg | Solar control products |
US4321404A (en) * | 1980-05-20 | 1982-03-23 | Minnesota Mining And Manufacturing Company | Compositions for providing abherent coatings |
US4540497A (en) * | 1982-11-09 | 1985-09-10 | Minnesota Mining And Manufacturing Company | Fluoroaliphatic radical-containing, substituted guanidines and fibrous substrates treated therewith |
US4668726A (en) * | 1984-03-30 | 1987-05-26 | Minnesota Mining And Manufacturing Company | Cationic and non-ionic fluorochemicals and fibrous substrates treated therewith |
US4566981A (en) * | 1984-03-30 | 1986-01-28 | Minnesota Mining And Manufacturing Company | Fluorochemicals and fibrous substrates treated therewith: compositions of cationic and non-ionic fluorochemicals |
DE3521762A1 (de) * | 1985-06-19 | 1987-01-02 | Bayer Ag | Ionisch modifizierte pur-streichpasten und ihre verwendung |
FR2588555B1 (fr) * | 1985-10-16 | 1987-12-11 | Atochem | Monomeres acryliques fluores, polymeres en derivant et leur application au traitement hydrofuge et oleofuge de substrats divers |
FR2590895B1 (fr) * | 1985-12-03 | 1988-01-15 | Atochem | Monomeres acryliques fluores, polymeres en derivant et leur application comme agents hydrophobes et oleophobes |
US5144056A (en) * | 1985-12-03 | 1992-09-01 | Atochem | Fluorinated acrylic monomers as hydrophobic and oleophobic agents |
CA2048232A1 (en) * | 1990-09-05 | 1992-03-06 | Jerry W. Williams | Energy curable pressure-sensitive compositions |
JPH0689462A (ja) | 1992-09-07 | 1994-03-29 | Three Bond Co Ltd | 光ディスク |
TW312700B (ko) * | 1994-05-17 | 1997-08-11 | Sony Co Ltd | |
US5446118A (en) * | 1994-08-11 | 1995-08-29 | W. L. Gore & Associates, Inc. | Fluorinated acrylic monomers containing urethane groups and their polymers |
US6017603A (en) * | 1995-04-28 | 2000-01-25 | Nippon Kayaku Kabushiki Kaisha | Ultraviolet-curing adhesive composition and article |
US5688884A (en) * | 1995-08-31 | 1997-11-18 | E. I. Du Pont De Nemours And Company | Polymerization process |
DE19541174C2 (de) * | 1995-11-04 | 1998-11-26 | Spraying Systems Deutschland G | Hochleistungsstrahldüse |
JPH09291258A (ja) * | 1996-04-26 | 1997-11-11 | Lintec Corp | 粘着剤組成物およびこれを用いた粘着シート |
JP3835857B2 (ja) | 1996-06-18 | 2006-10-18 | 日本化薬株式会社 | 光ディスク用接着剤組成物、硬化物、物品及び接着方法 |
JPH1025453A (ja) | 1996-07-08 | 1998-01-27 | Nippon Kayaku Co Ltd | 陰極線管用接着剤及びその硬化物 |
JP3911728B2 (ja) | 1996-08-07 | 2007-05-09 | 住友化学株式会社 | ディジタルビデオディスクの保護コート兼接着用樹脂組成物 |
JPH10140090A (ja) | 1996-11-08 | 1998-05-26 | Daicel U C B Kk | 陰極線管用接着剤およびその硬化物 |
WO1998036325A1 (en) | 1997-02-13 | 1998-08-20 | Dsm N.V. | Photocurable resin composition |
TW430672B (en) * | 1997-07-03 | 2001-04-21 | Sumitomo Chemical Co | A photo-curing resin composition for DVD |
US5959775A (en) * | 1997-12-23 | 1999-09-28 | 3M Innovative Properties Company | Urethane/acrylate bead bond for retroreflective articles |
US6180200B1 (en) * | 1998-06-01 | 2001-01-30 | Dsm N. V. | Cationic and hybrid radiation curable pressure sensitive adhesives for bonding of optical discs |
DE60042561D1 (de) * | 1999-10-27 | 2009-08-27 | 3M Innovative Properties Co | Fluorochemische sulfonamide tenside |
DE19962272A1 (de) * | 1999-12-23 | 2001-06-28 | Basf Ag | Isocyanatgruppen aufweisende Bausteine sowie ihre Verwendung zur Funktionalisierung oder Modifizierung von Verbindungen oder Oberflächen |
EP1142912A1 (en) | 2000-04-05 | 2001-10-10 | Dsm N.V. | Radiation curable compositions |
US6949297B2 (en) * | 2001-11-02 | 2005-09-27 | 3M Innovative Properties Company | Hybrid adhesives, articles, and methods |
EP1709089B1 (en) * | 2003-12-31 | 2008-03-05 | 3M Innovative Properties Company | Water-and oil-repellent fluoroacrylates |
-
2003
- 2003-12-31 US US10/751,142 patent/US7081545B2/en not_active Expired - Fee Related
-
2004
- 2004-12-14 WO PCT/US2004/041743 patent/WO2005065164A2/en active Application Filing
- 2004-12-14 AT AT04813986T patent/ATE525348T1/de not_active IP Right Cessation
- 2004-12-14 EP EP04813986A patent/EP1699755B1/en not_active Not-in-force
- 2004-12-14 CA CA002552000A patent/CA2552000A1/en not_active Abandoned
- 2004-12-14 CN CNB2004800396658A patent/CN100471834C/zh not_active Expired - Fee Related
- 2004-12-14 JP JP2006547104A patent/JP4965264B2/ja not_active Expired - Fee Related
- 2004-12-14 KR KR1020067013191A patent/KR20060107836A/ko not_active Application Discontinuation
-
2006
- 2006-07-12 US US11/457,037 patent/US7361782B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US20060247460A1 (en) | 2006-11-02 |
EP1699755A2 (en) | 2006-09-13 |
US7081545B2 (en) | 2006-07-25 |
WO2005065164A3 (en) | 2005-09-09 |
EP1699755A4 (en) | 2007-11-07 |
JP4965264B2 (ja) | 2012-07-04 |
US20050143595A1 (en) | 2005-06-30 |
CN1902164A (zh) | 2007-01-24 |
CN100471834C (zh) | 2009-03-25 |
CA2552000A1 (en) | 2005-07-21 |
JP2007517033A (ja) | 2007-06-28 |
KR20060107836A (ko) | 2006-10-16 |
WO2005065164A2 (en) | 2005-07-21 |
US7361782B2 (en) | 2008-04-22 |
ATE525348T1 (de) | 2011-10-15 |
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