EP1618336A1 - Porenbrenner mit siliziumkarbid-porenkörper - Google Patents
Porenbrenner mit siliziumkarbid-porenkörperInfo
- Publication number
- EP1618336A1 EP1618336A1 EP04727529A EP04727529A EP1618336A1 EP 1618336 A1 EP1618336 A1 EP 1618336A1 EP 04727529 A EP04727529 A EP 04727529A EP 04727529 A EP04727529 A EP 04727529A EP 1618336 A1 EP1618336 A1 EP 1618336A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- burner
- pore
- fabric
- pore burner
- porous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 229910010271 silicon carbide Inorganic materials 0.000 title claims abstract description 12
- 239000011148 porous material Substances 0.000 claims abstract description 55
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003546 flue gas Substances 0.000 claims abstract description 16
- 238000002485 combustion reaction Methods 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 5
- 239000004744 fabric Substances 0.000 claims description 23
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 3
- 239000004753 textile Substances 0.000 abstract 3
- 239000000463 material Substances 0.000 description 7
- 239000000919 ceramic Substances 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 241000208202 Linaceae Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000112 cooling gas Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000006262 metallic foam Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000005475 siliconizing Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C99/00—Subject-matter not provided for in other groups of this subclass
- F23C99/006—Flameless combustion stabilised within a bed of porous heat-resistant material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
- F23D14/12—Radiant burners
- F23D14/14—Radiant burners using screens or perforated plates
- F23D14/145—Radiant burners using screens or perforated plates combustion being stabilised at a screen or a perforated plate
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2203/00—Gaseous fuel burners
- F23D2203/10—Flame diffusing means
- F23D2203/104—Grids, e.g. honeycomb grids
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2212/00—Burner material specifications
- F23D2212/10—Burner material specifications ceramic
- F23D2212/105—Particles
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2900/00—Special features of, or arrangements for burners using fluid fuels or solid fuels suspended in a carrier gas
- F23D2900/14—Special features of gas burners
- F23D2900/14582—Special features of gas burners with outlets consisting of layers of spherical particles
Definitions
- the invention relates to a pore burner for burning a fuel-air mixture to produce a hot flue gas, comprising a housing in which a pore material made of porous, high-temperature resistant silicon carbide (SiC) for a
- Incineration is provided.
- Such a pore burner is used, for example, to apply a hot flue gas stream to a steam superheater.
- the steam generated in the steam superheater has high temperatures and is under high pressure.
- the energy stored in the steam can then be used in the form of mechanical or electrical energy, e.g. B. by relaxation in an expansion machine for driving a generator.
- the hotter the steam and the higher the pressure the better the efficiency of such machines. Accordingly, it is necessary for the flue gas stream to have the highest possible temperatures. Typical temperatures are between 850 ° C and 1400 ° C.
- the pore burners for generating a hot flue gas flow differ in particular from a pure radiant burner, in which only the radiant heat of the burner is used and the flue gas formed as a by-product via one
- Chimney or an exhaust pipe is withdrawn.
- radiant burners are, for example, artificial log fires or radiant burners for drying paintwork.
- the radiant heat of a pore burner can also be used, the essential one However, part of the energy transferred to the steam generator comes from the flue gas.
- a pore burner for burning a Brermstofr7O-ddationsschgemiscb.es is known.
- the pore burner is filled with spherical fillers.
- the size of the resulting pores is determined by the size of the packing.
- the known pore burner is designed so that an excessively high temperature in the reaction space is avoided by an additional cooling gas.
- a pore burner which contains porous material which has spatially connected cavities which are formed by a packing made of heat-resistant wire, foil or sheet material. A defined flame zone forms in these cavities. The material is not suitable for high temperatures.
- the object is achieved in that the pore body comprises siliconized carbon fabric which has an orderly, regular structure.
- the invention is based on the knowledge that the properties of a pore burner can be influenced if the pore structure can be produced in a targeted manner. It is not possible to weave the hard and brittle silicon carbide material. However, by siliconizing a suitably shaped carbon fabric, it is possible to create a correspondingly designed fabric structure made of SiC.
- the siliconized fabric is inexpensive to manufacture. It withstands mechanical and thermal loads very well.
- the mesh size and flat shape of the fabric can be individually adjusted, as can its size and outline, so that when using such materials as pore bodies for pore burners, an optimization of the burner properties is possible.
- the silicon carbide fabric has a shape that deviates from a flat surface. A plurality of pieces of tissue can then be stacked on top of one another. In this way, a three-dimensional arrangement with which the pore burner can be filled is created without additional spacers or the like.
- the fabric can be wave-shaped. However, other shapes are also possible, such as a profile that is sawtooth-shaped or box-shaped. In order to obtain a small pore size, on the one hand the tissue parameters can be kept small and on the other hand the waveform can be composed of a large number of small waves.
- the fabric can consist of completely siliconized fibers. For some applications, however, it can also make sense for the fabric to be partially silicided and to contain a core of pure carbon.
- the ordered structures are designed in such a way that zones of different porosity form.
- the porous body of the burner can be formed in two or more zones of different pore sizes. The inlet-side part of the porous body then has a smaller one
- Pore size than the outlet-side pore body is greater than the outlet-side pore body.
- the flame forms in the large-pore zone, while the fuel-air mixture takes place in the fine-pore zone and is preheated. This leads to a particularly low pollutant content in the flue gas when conventional fuels such as natural gas, gasoline or the like are burned.
- the pore size can be selected by the
- Tissue and its arrangement such as. B. stacking, be designed particularly well.
- the fine-pored part is made of conventional pore-forming materials, while the coarse-pored part consists of siliconized carbon fabric.
- the material of the fine-pored part is preferably poorly conductive, so that heat transfer from the combustion zone to the premixing zone is avoided. This prevents the flames from kicking back.
- the axes of curvature of the waves of a piece of tissue can lie in one plane and the pieces of tissue can be arranged one above the other in such a way that the projections of the wave normals on such a plane defined by the axes of curvature are perpendicular to one another.
- the wave normals then preferably each form an angle of approximately 45 ° to the direction of flow of the flue gas.
- a wave normal is the vertical on a wave front. It lies in the plane defined by the axes of curvature.
- the pore structure is formed from stacked wavy SiC mats. The individual levels are rotated at an angle of approximately 90 ° to each other. This arrangement is particularly favorable for the combustion behavior of the burner.
- the structure flowed through in this way is referred to as a static mixer.
- the fuel and the combustion air are mixed together in such a way that the fuel is particularly low-pollutant and completely burned.
- the housing of the burner is preferably provided with an insulating layer. This prevents undesired convective heat transfer through the housing into the periphery of the burner.
- the housing wall can be flowed through by a cooling medium, which is either discharged into the environment separately or mixed with the hot flue gas in the outlet area of the burner.
- Figure 1 is a schematic representation of a pore burner
- FIG. 3 is a section through a schematically illustrated pore burner
- Figure 4 is a section along the line A-A in Figure 3 and shows the outlet of a
- a pore burner 10 is shown schematically.
- the pore burner consists of a housing 12 into which a fuel gas-air mixture is introduced.
- the direction of flow of the inflowing gas is shown by the arrows 14.
- a multiplicity of fabric pieces 16 are stacked on top of one another in the housing 12.
- the pores are smaller in a first zone 18 and the pores are larger in a second zone 20.
- the porous material of the first zone 18 is not shown.
- the flue gas is used to heat a steam generator. It is possible to arrange the steam generator within the radiation field of the pore burner 10, so that not only the heat transferred by the flue gas, but also the radiation heat is used.
- the tissue gap 16 are shown again in detail in FIG. 2. They consist of an essentially rectangular, net-like fabric. A large number of these fabric pieces 16 are layered one on top of the other. Each piece of fabric 16 is bent in a wave shape around an axis of curvature 37. The fabric pieces are layered on top of one another in such a way that the mountains 24 and valleys 26 of the curvatures always lie alternately offset by 90 degrees. This can be seen in FIG. 3. For example, the fabric piece 30 lies on the fabric piece 28 offset by 90 degrees.
- the pore burner is completely filled with the tissue pieces 16. This creates a pore structure that allows particularly good, even flame development.
- the pore burner is completely filled with the tissue pieces 16. This creates a pore structure that allows particularly good, even flame development.
- the fuel / air mixture flows through the porous body parallel to the planes of the individual tissue layers and in the direction of the bisector 34 of the angle of rotation between the wave normals 35 and the wave normals 39 of the layers.
- the pore burner 10 has a rectangular cross section and is therefore also filled with rectangular tissue pieces 16. If the pore burner 10 has a differently shaped cross section, the shape of the fabric pieces is of course also adapted accordingly.
- the housing 12 of the porer burner is flowed through by a coolant.
- the cooling air is fed separately into a cooling duct 38 (FIG. 4) of the housing 12 and is mixed with the flue gas at the outlet 40.
- the pore size is smaller in zone 18 (FIG. 1) and larger in zone 20.
- the fabric pieces are made of silicon carbide. Silicon carbide is a carbide ceramic material and cannot be woven as such. A carbon fabric is therefore used to produce such fabrics, which is brought into the appropriate shape and then siliconized. Various processes are suitable for siliciding. At the
- Liquid siliconization processes molten silicon infiltrates a porous substrate made of carbon fiber reinforced carbon (C / C) and reacts with the carbon of the matrix directly to SiC.
- C / C carbon fiber reinforced carbon
- the siliconized fabric pieces 16 are stiff after this process and can be used in the burner without further change in shape.
- the material is resistant to high temperatures.
- the manufacturing process for flat SiC structures is inexpensive compared to sponge-like ceramic bodies, and the mechanical and thermal load-bearing capacity is significantly higher than that of ceramic sponges.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Gas Burners (AREA)
- Ceramic Products (AREA)
- Woven Fabrics (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10317857 | 2003-04-18 | ||
| DE102004006824A DE102004006824B4 (de) | 2003-04-18 | 2004-02-11 | Porenbrenner mit Siliziumkarbid-Porenkörper |
| PCT/EP2004/003968 WO2004092646A1 (de) | 2003-04-16 | 2004-04-15 | Porenbrenner mit siliziumkarbid-porenkörper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1618336A1 true EP1618336A1 (de) | 2006-01-25 |
| EP1618336B1 EP1618336B1 (de) | 2011-06-29 |
Family
ID=33300846
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP04727529A Expired - Lifetime EP1618336B1 (de) | 2003-04-18 | 2004-04-15 | Porenbrenner mit siliziumkarbid-porenkörper |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20060035190A1 (de) |
| EP (1) | EP1618336B1 (de) |
| JP (1) | JP2006523815A (de) |
| WO (1) | WO2004092646A1 (de) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005044494B3 (de) * | 2005-09-16 | 2007-03-08 | Wenzel, Lothar | Vorrichtung zur Beseitigung von schädlichen Bestandteilen aus Abgasen von Brennkraftmaschinen |
| US8357327B2 (en) | 2006-05-16 | 2013-01-22 | Sms Siemag Aktiengesellschaft | Heating device for preheating a liquid-metal transfer container |
| TWI450439B (zh) | 2009-10-22 | 2014-08-21 | Atomic Energy Council | 應用於高溫燃料電池之多孔性介質燃燒器 |
| CN102287819B (zh) * | 2011-07-01 | 2012-12-12 | 中国计量学院 | 一种燃用低热值气体燃料的多孔介质燃烧器 |
| US10571124B2 (en) | 2013-02-14 | 2020-02-25 | Clearsign Combustion Corporation | Selectable dilution low NOx burner |
| CA2892229A1 (en) | 2013-02-14 | 2014-08-21 | Clearsign Combustion Corporation | Startup method and mechanism for a burner having a perforated flame holder |
| EP3017098B1 (de) * | 2013-07-02 | 2019-06-05 | Bekaert Combustion Technology B.V. | Gasvormischbrenner |
| DE102014216430A1 (de) * | 2014-08-19 | 2016-02-25 | Schunk Kohlenstofftechnik Gmbh | Porenkörper, insbesondere zur Verwendung als Verbrennungszone eines Porenbrenners, sowie Porenbrenner mit einem derartigen Porenkörper |
| EP3426980B1 (de) * | 2016-03-10 | 2022-03-02 | Solaronics | Hochintensiver gasbefeuerter infrarotstrahler und betriebsverfahren dafür |
| KR101688894B1 (ko) * | 2016-08-08 | 2016-12-23 | 주식회사 지엔티엔에스 | 고온 연소촉매를 이용한 버너 |
| CN110425536B (zh) * | 2019-08-06 | 2020-11-10 | 东北大学 | 一种角型多孔介质燃烧器 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3155142A (en) * | 1961-02-13 | 1964-11-03 | Minnesota Mining & Mfg | Radiant gas burner |
| US3726633A (en) * | 1970-11-30 | 1973-04-10 | Thermo Electron Corp | Low pollutant-high thermal efficiency burner |
| JPS62216981A (ja) * | 1986-03-15 | 1987-09-24 | イビデン株式会社 | 炭化珪素質複合材料の製造方法 |
| US5633081A (en) * | 1986-03-24 | 1997-05-27 | Ensci Inc. | Coated porous substrates |
| US4895513A (en) * | 1987-08-06 | 1990-01-23 | Br Laboratories, Inc. | Heat resistant combustion element |
| US5026273A (en) * | 1988-07-15 | 1991-06-25 | W. R. Grace & Co.-Conn. | High temperature combuster |
| US5346389A (en) * | 1989-02-24 | 1994-09-13 | W. R. Grace & Co.-Conn. | Combustion apparatus for high-temperature environment |
| DE19625118A1 (de) * | 1995-06-22 | 1997-01-02 | Vaillant Joh Gmbh & Co | Vollvormischender atmosphärischer Strahlungsbrenner |
| US5720933A (en) * | 1996-03-11 | 1998-02-24 | Srinivasan; Makuteswara | Process for preparing ceramic fibers |
| DE19621638C2 (de) * | 1996-05-30 | 2002-06-27 | Fraunhofer Ges Forschung | Offenzellige Schaumkeramik mit hoher Festigkeit und Verfahren zu deren Herstellung |
| US5989013A (en) * | 1997-01-28 | 1999-11-23 | Alliedsignal Composites Inc. | Reverberatory screen for a radiant burner |
| US5890886A (en) * | 1997-07-21 | 1999-04-06 | Sulzer Chemtech Ag | Burner for heating systems |
| JP3466103B2 (ja) * | 1999-03-16 | 2003-11-10 | 松下電器産業株式会社 | 触媒燃焼装置 |
| DE10114903A1 (de) * | 2001-03-26 | 2002-10-17 | Invent Gmbh Entwicklung Neuer Technologien | Brenner für ein Gas/Luft-Gemisch |
-
2004
- 2004-04-15 WO PCT/EP2004/003968 patent/WO2004092646A1/de not_active Ceased
- 2004-04-15 EP EP04727529A patent/EP1618336B1/de not_active Expired - Lifetime
- 2004-04-15 JP JP2006505129A patent/JP2006523815A/ja active Pending
-
2005
- 2005-10-17 US US11/252,344 patent/US20060035190A1/en not_active Abandoned
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2004092646A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006523815A (ja) | 2006-10-19 |
| US20060035190A1 (en) | 2006-02-16 |
| WO2004092646A1 (de) | 2004-10-28 |
| EP1618336B1 (de) | 2011-06-29 |
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