EP1605182A1 - Unruh-Spiralfeder-Oszillator mit Temperaturkompensation - Google Patents
Unruh-Spiralfeder-Oszillator mit Temperaturkompensation Download PDFInfo
- Publication number
- EP1605182A1 EP1605182A1 EP04405355A EP04405355A EP1605182A1 EP 1605182 A1 EP1605182 A1 EP 1605182A1 EP 04405355 A EP04405355 A EP 04405355A EP 04405355 A EP04405355 A EP 04405355A EP 1605182 A1 EP1605182 A1 EP 1605182A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- spiral
- balance
- mechanical oscillator
- oscillator according
- angle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010453 quartz Substances 0.000 claims abstract description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000000758 substrate Substances 0.000 claims abstract description 11
- 229910000831 Steel Inorganic materials 0.000 claims description 6
- 230000007547 defect Effects 0.000 claims description 6
- 239000010959 steel Substances 0.000 claims description 6
- 229910001369 Brass Inorganic materials 0.000 claims description 5
- 239000010951 brass Substances 0.000 claims description 5
- 230000000737 periodic effect Effects 0.000 claims 1
- 238000000034 method Methods 0.000 description 9
- 239000013078 crystal Substances 0.000 description 6
- 230000010355 oscillation Effects 0.000 description 5
- 229910001374 Invar Inorganic materials 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 229910000646 Glucydur Inorganic materials 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 241001080024 Telles Species 0.000 description 2
- 241000897276 Termes Species 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 230000003416 augmentation Effects 0.000 description 2
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 229910000952 Be alloy Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000010339 dilation Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B17/00—Mechanisms for stabilising frequency
- G04B17/04—Oscillators acting by spring tension
- G04B17/06—Oscillators with hairsprings, e.g. balance
- G04B17/066—Manufacture of the spiral spring
Definitions
- the present invention relates to mechanical oscillators in general and concerns, more particularly, oscillators mechanical watches which comprise a set consisting of a spiral and a balance, compensated in temperature.
- the pendulum must also be compensated heat; what can be achieved, for example, by using a "glucydur” type alloy (alloy of copper and beryllium, also called “glucinium”) or other alloys having a very low coefficient of thermal expansion.
- glucydur alloy of copper and beryllium, also called “glucinium”
- This method is also complicated and no more than the others more traditional methods, does not allow to get rid of others isochronism defects such as those due, for example, to various friction in the oscillator, an imbalance of the balance, a offset of the center of mass of the spiral etc.
- the present invention aims to overcome the disadvantages previous techniques by proposing a hairspring, for oscillator timepiece, whose behavior with respect to variations thermal is such that it allows to maintain the balance-spiral assembly as little as possible of the said variations thermal. More specifically, the spiral of the invention is no only self-compensated but it can be realized in such a way also compensate for the heat drifts of the balance.
- Another object of the invention is to be able to compensate also isochronism defects inherent in the construction the balance-spring.
- the spiral of the invention is made in a crystalline quartz substrate whose cut is chosen so that the whole, constituted by the balance spring and the pendulum, is compensated thermally.
- the shape of the spiral is chosen to compensate for the defects of anisochronism of the balance-spiral assembly.
- the thermal behavior of the quartz spiral springs is essentially related to the inclination of the section with respect to the optical axis Z of the quartz crystal.
- the plane of the hairspring can be identified by a double rotation ZY / ⁇ / ⁇ (notation according to the IEEE standards), where ⁇ is the longitude and ⁇ the colatitude (inclination of the axis of the hairspring relative to to the optical axis Z of the crystal).
- the rigidities of the crystals usually have a nearby thermal inversion point 0 ° K with a negative curvature. They stiffen at low temperature. Their first temperature coefficient at temperature ambient temperature, ie 25 ° C, is therefore generally negative with a negative curvature. It varies from a few tens to a few hundreds of ppm / ° C. Quartz is one of the few crystals allowing, at room temperature, to cancel the first coefficient thermal rigidity by means of the cut, that is to say the orientation of the structure, and even, to make it positive a few tens of ppm / ° C.
- the quartz spiral does not require a pendulum compensated glucydur type. It compensates for the drift thermal of most low-end current balances in stainless steel and, even, to make it, in some ways, more favorable than that of the 32 kHz quartz tuning fork.
- FIGS. 3a to 3.c show the level lines of the graphs of FIG. 2. Considering, in particular, FIG.
- the spirals made in a plate of this type will have maximum elastic symmetry, namely a symmetry with respect to the X plane and a symmetry with respect to the axis of the spiral (Z axis after rotation). These spirals will therefore be better balanced elastically than those made in a double rotation plate and without having a limitation of their heat compensation capacity. It should be noted that the simple rotation can also be performed around the Y axis.
- Figures 5.a to 5.b show the variation, as a function of the angle ⁇ , of the thermal coefficients ⁇ , ⁇ and ⁇ of the stiffness, respectively, for a hairspring having a single rotation cut X / ⁇ .
- the thermal drift of the pendulum depends on the material in which it is made.
- common stainless steels have a thermal coefficient of expansion varying typically between 10 and 15 ppm / ° C, whereas for brass the value of this coefficient is 17 ppm / ° C.
- Figure 6 shows some examples of achievable thermal compensation, for different balance materials, with X / ⁇ single-turn cutting spirals .
- the curves C1 to C3 show the thermal drifts of the frequency of oscillators comprising steel rockers of different types, while the curve C4 corresponds to that of an oscillator with a brass balance.
- the quartz hairspring also makes it possible to compensate for isochronism defects of the oscillator.
- One of the main sources of anisochronism is the variation in the amplitude of the oscillations of the pendulum.
- the variation of the anisochronism can be of the order of several ppm / degree of angle, typically 2 ppm / degree of angle with a typical angle variation of ⁇ 25%.
- a known method to compensate for anisochronism is to act on the curvature of the end of the hairspring near the peak P. This method requires an adjustment step by specially trained persons; which is not optimal in terms of industrialization.
- it is proposed to act on the local stiffness of the turn by modulating the width of its section.
- the modulation has the effect of reinforcing the inertia and the local rigidity of the coil in the opposite sector to the peak.
- the width modulation function of the section is, for example, of the type k .cos ( ⁇ m - ⁇ ), where k is a coefficient of proportionality, ⁇ represents the polar angle in the section considered and ⁇ m the value from the polar angle to the peak.
- k a coefficient of proportionality
- ⁇ represents the polar angle in the section considered
- ⁇ m the value from the polar angle to the peak.
- the anisochronism compensation is about 1 ppm / degree of angle.
- Figure 7 shows a spiral having such a modulation of the width of its section.
- the modulation of the width of the section of the turns may be accompanied by a modulation of the pitch between the turns so that the interval between them at rest remains constant. This last modulation, not shown, avoids sticking between turns during large amplitudes of oscillation.
- the spiral described above may be manufactured by any means known to those skilled in the art for the machining of quartz, such as wet attack means (chemical etching) or dry (plasma attack).
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Piezo-Electric Or Mechanical Vibrators, Or Delay Or Filter Circuits (AREA)
- Oscillators With Electromechanical Resonators (AREA)
- Inductance-Capacitance Distribution Constants And Capacitance-Resistance Oscillators (AREA)
- Springs (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Electric Clocks (AREA)
- Percussion Or Vibration Massage (AREA)
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT04405355T ATE470086T1 (de) | 2004-06-08 | 2004-06-08 | Unruh-spiralfeder-oszillator mit temperaturkompensation |
EP04405355A EP1605182B8 (de) | 2004-06-08 | 2004-06-08 | Unruh-Spiralfeder-Oszillator mit Temperaturkompensation |
DE602004027471T DE602004027471D1 (de) | 2004-06-08 | 2004-06-08 | Unruh-Spiralfeder-Oszillator mit Temperaturkompensation |
US11/628,831 US7682068B2 (en) | 2004-06-08 | 2005-06-02 | Temperature-compensated balance wheel/hairspring oscillator |
PCT/EP2005/052520 WO2005124184A1 (fr) | 2004-06-08 | 2005-06-02 | Oscillateur balancier-spiral compense en temperature |
CNB2005800233744A CN100564927C (zh) | 2004-06-08 | 2005-06-02 | 带温度补偿的摆轮/游丝振荡器 |
JP2007526416A JP2008501967A (ja) | 2004-06-08 | 2005-06-02 | 温度補償天輪/ヒゲゼンマイ発振器 |
HK07111842.0A HK1106570A1 (en) | 2004-06-08 | 2007-11-01 | Temperature compensated balance-spiral oscillator |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04405355A EP1605182B8 (de) | 2004-06-08 | 2004-06-08 | Unruh-Spiralfeder-Oszillator mit Temperaturkompensation |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1605182A1 true EP1605182A1 (de) | 2005-12-14 |
EP1605182B1 EP1605182B1 (de) | 2010-06-02 |
EP1605182B8 EP1605182B8 (de) | 2010-07-14 |
Family
ID=34932141
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04405355A Expired - Lifetime EP1605182B8 (de) | 2004-06-08 | 2004-06-08 | Unruh-Spiralfeder-Oszillator mit Temperaturkompensation |
Country Status (8)
Country | Link |
---|---|
US (1) | US7682068B2 (de) |
EP (1) | EP1605182B8 (de) |
JP (1) | JP2008501967A (de) |
CN (1) | CN100564927C (de) |
AT (1) | ATE470086T1 (de) |
DE (1) | DE602004027471D1 (de) |
HK (1) | HK1106570A1 (de) |
WO (1) | WO2005124184A1 (de) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2154583A1 (de) * | 2008-07-29 | 2010-02-17 | Rolex Sa | Spiralfeder für Unruh-Spiralfeder |
CH701846A1 (fr) * | 2009-09-21 | 2011-03-31 | Rolex Sa | Spiral plat pour balancier d'horlogerie et ensemble balancier-spiral. |
CH706087A1 (fr) * | 2012-02-01 | 2013-08-15 | Piguet & Co Horlogerie | Spiral plat pour organe régulateur d'un mouvement d'horlogerie. |
EP2703909A1 (de) * | 2012-09-04 | 2014-03-05 | The Swatch Group Research and Development Ltd. | Gepaarter Spiralunruh-Schwinger |
EP2717103A1 (de) * | 2012-10-04 | 2014-04-09 | The Swatch Group Research and Development Ltd. | Leuchtende Spiralfeder |
CN105738034A (zh) * | 2014-12-12 | 2016-07-06 | 天津海鸥表业集团有限公司 | 激光校正摆轮重心偏移的平衡测量方法及测量切削装置 |
EP3056948B1 (de) | 2015-02-17 | 2019-02-20 | Master Dynamic Limited | Siliciumspiralfeder |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1818736A1 (de) * | 2006-02-09 | 2007-08-15 | The Swatch Group Research and Development Ltd. | Stossfeste Spiralrolle |
EP2184653A1 (de) * | 2008-11-06 | 2010-05-12 | Montres Breguet S.A. | Spiralfeder mit Endkurvenerhöhung aus mikro-bearbeitbarem Material |
DE202010018420U1 (de) * | 2009-02-06 | 2016-06-22 | Damasko Gmbh | Mechanisches Schwingsystem für eine Uhr und Unruhfeder für eine Uhr |
US10324419B2 (en) | 2009-02-06 | 2019-06-18 | Domasko GmbH | Mechanical oscillating system for a clock and functional element for a clock |
EP2284629A1 (de) * | 2009-08-13 | 2011-02-16 | ETA SA Manufacture Horlogère Suisse | Thermokompensierter mechanischer Resonator |
EP2337221A1 (de) * | 2009-12-15 | 2011-06-22 | The Swatch Group Research and Development Ltd. | Thermokompensierter Resonator mindestens ersten und zweiten Grades |
GB201001897D0 (en) * | 2010-02-05 | 2010-03-24 | Levingston Gideon | Non magnetic mateial additives and processes for controling the thermoelastic modulus and spring stiffness within springs for precision instruments |
US8777195B2 (en) * | 2011-09-23 | 2014-07-15 | Adicep Technologies, Inc. | Non-linear torsion spring assembly |
EP2590325A1 (de) * | 2011-11-04 | 2013-05-08 | The Swatch Group Research and Development Ltd. | Thermokompensierter Resonator aus Keramik |
EP2597536A1 (de) * | 2011-11-25 | 2013-05-29 | CSEM Centre Suisse d'Electronique et de Microtechnique SA - Recherche et Développement | Verbesserte Spiralfeder, und Herstellungsverfahren dieser Spiralfeder |
US9188956B2 (en) * | 2012-12-28 | 2015-11-17 | Seiko Instruments Inc. | Balance, timepiece movement, timepiece and manufacturing method of balance |
DE102013106505B8 (de) * | 2013-06-21 | 2014-08-21 | Damasko Uhrenmanufaktur KG | Schwingsystem für mechanische Uhrwerke |
WO2014203086A1 (de) | 2013-06-21 | 2014-12-24 | Damasko Uhrenmanufaktur KG | Schwingsystem für mechanische uhrwerke, spiralfeder und verfahren zu deren herstellung |
DE102013110090A1 (de) * | 2013-09-13 | 2015-03-19 | Damasko Uhrenmanufaktur KG | Schwingsystem für mechanische Uhrwerke |
EP3159746B1 (de) * | 2015-10-19 | 2018-06-06 | Rolex Sa | Hochdotierte siliziumfeder für uhr |
EP3214506B1 (de) * | 2016-03-04 | 2019-01-30 | ETA SA Manufacture Horlogère Suisse | Kompakte spiralfeder mit konstantem doppelquerschnitt |
WO2017163148A1 (fr) * | 2016-03-23 | 2017-09-28 | Patek Philippe Sa Geneve | Oscillateur balancier-spiral pour piece d'horlogerie |
TWI796444B (zh) * | 2018-03-20 | 2023-03-21 | 瑞士商百達翡麗日內瓦股份有限公司 | 用於製造精確剛度之時計熱補償游絲的方法 |
EP3667433B1 (de) * | 2018-12-12 | 2023-02-01 | Nivarox-FAR S.A. | Spiralfeder und ihr herstellungsverfahren |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US209642A (en) * | 1878-11-05 | Improvement in balance-springs for time-keepers | ||
EP0732635A1 (de) * | 1995-03-17 | 1996-09-18 | C.S.E.M. Centre Suisse D'electronique Et De Microtechnique Sa | Mikromechanischer Teil und Verfahren zur dessen Herstellung |
US20030011119A1 (en) * | 2000-02-07 | 2003-01-16 | Masato Imai | Quartz coil spring and method of producing the same |
EP1422436A1 (de) * | 2002-11-25 | 2004-05-26 | CSEM Centre Suisse d'Electronique et de Microtechnique SA | Spiraluhrwerkfeder und Verfahren zu deren Herstellung |
Family Cites Families (8)
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CH1060869A4 (de) * | 1969-07-11 | 1971-06-30 | ||
JPH06117470A (ja) * | 1992-10-07 | 1994-04-26 | Yokogawa Electric Corp | 渦巻きバネ及び指示電気計器 |
EP0886195B1 (de) * | 1997-06-20 | 2002-02-13 | Montres Rolex Sa | Selbstkompensierende Spiralfeder für mechanische Uhrwerkunruhspiralfederoszillator und Verfahren zu deren Herstellung |
US6536472B2 (en) * | 2001-05-07 | 2003-03-25 | Fisher Controls International, Inc. | High performance fluid control valve |
EP1302821A3 (de) * | 2001-10-10 | 2010-05-05 | Franck Muller-Watchland SA | Spiralfeder für Zeitmessgerät |
JP2004007420A (ja) * | 2002-03-26 | 2004-01-08 | Seiko Epson Corp | 圧電振動片、圧電振動子および圧電デバイス |
EP1445670A1 (de) * | 2003-02-06 | 2004-08-11 | ETA SA Manufacture Horlogère Suisse | Spiralfeder der Resonatorunruh und Fabrikationsmethode |
DE60333191D1 (de) * | 2003-09-26 | 2010-08-12 | Asulab Sa | Spiralfeder-Unruh-Resonator mit Thermokompensation |
-
2004
- 2004-06-08 EP EP04405355A patent/EP1605182B8/de not_active Expired - Lifetime
- 2004-06-08 AT AT04405355T patent/ATE470086T1/de not_active IP Right Cessation
- 2004-06-08 DE DE602004027471T patent/DE602004027471D1/de not_active Expired - Lifetime
-
2005
- 2005-06-02 JP JP2007526416A patent/JP2008501967A/ja active Pending
- 2005-06-02 CN CNB2005800233744A patent/CN100564927C/zh active Active
- 2005-06-02 WO PCT/EP2005/052520 patent/WO2005124184A1/fr active Application Filing
- 2005-06-02 US US11/628,831 patent/US7682068B2/en active Active
-
2007
- 2007-11-01 HK HK07111842.0A patent/HK1106570A1/xx unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US209642A (en) * | 1878-11-05 | Improvement in balance-springs for time-keepers | ||
EP0732635A1 (de) * | 1995-03-17 | 1996-09-18 | C.S.E.M. Centre Suisse D'electronique Et De Microtechnique Sa | Mikromechanischer Teil und Verfahren zur dessen Herstellung |
US20030011119A1 (en) * | 2000-02-07 | 2003-01-16 | Masato Imai | Quartz coil spring and method of producing the same |
EP1422436A1 (de) * | 2002-11-25 | 2004-05-26 | CSEM Centre Suisse d'Electronique et de Microtechnique SA | Spiraluhrwerkfeder und Verfahren zu deren Herstellung |
Non-Patent Citations (1)
Title |
---|
ANONYMOUS: ""Good" Fundamental Material Constants for Chrystalline Quartz", INTERNET ARTICLE, 11 August 2003 (2003-08-11), XP002311434, Retrieved from the Internet <URL:http://web.archive.org/web/20030811155745/www.sawyerresearch.com/Misc/Qtz_Constants.pdf> [retrieved on 20041220] * |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2154583A1 (de) * | 2008-07-29 | 2010-02-17 | Rolex Sa | Spiralfeder für Unruh-Spiralfeder |
EP2523053A1 (de) * | 2008-07-29 | 2012-11-14 | Rolex S.A. | Spiralfeder für Unruh-Spiralfeder |
CH701846A1 (fr) * | 2009-09-21 | 2011-03-31 | Rolex Sa | Spiral plat pour balancier d'horlogerie et ensemble balancier-spiral. |
US8348497B2 (en) | 2009-09-21 | 2013-01-08 | Rolex S.A. | Flat balance spring for horological balance and balance wheel/balance spring assembly |
CH706087A1 (fr) * | 2012-02-01 | 2013-08-15 | Piguet & Co Horlogerie | Spiral plat pour organe régulateur d'un mouvement d'horlogerie. |
EP2703910A3 (de) * | 2012-09-04 | 2014-05-14 | The Swatch Group Research and Development Ltd. | Gepaarter Spiralunruh-Schwinger |
EP2703909A1 (de) * | 2012-09-04 | 2014-03-05 | The Swatch Group Research and Development Ltd. | Gepaarter Spiralunruh-Schwinger |
US9030920B2 (en) | 2012-09-04 | 2015-05-12 | The Swatch Group Research And Development Ltd. | Resonator with matched balance spring and balance |
EP2717103A1 (de) * | 2012-10-04 | 2014-04-09 | The Swatch Group Research and Development Ltd. | Leuchtende Spiralfeder |
WO2014053336A1 (fr) * | 2012-10-04 | 2014-04-10 | The Swatch Group Research And Development Ltd | Spiral lumineux |
CN104704431A (zh) * | 2012-10-04 | 2015-06-10 | 斯沃奇集团研究和开发有限公司 | 发光游丝 |
US9188958B2 (en) | 2012-10-04 | 2015-11-17 | The Swatch Group Research And Development Ltd | Illuminated balance spring |
JP2015534071A (ja) * | 2012-10-04 | 2015-11-26 | ザ・スウォッチ・グループ・リサーチ・アンド・ディベロップメント・リミテッド | 照明されるバランスばね |
RU2596097C1 (ru) * | 2012-10-04 | 2016-08-27 | Те Свотч Груп Рисерч Энд Дивелопмент Лтд | Подсвечиваемая балансирная пружина |
CN105738034A (zh) * | 2014-12-12 | 2016-07-06 | 天津海鸥表业集团有限公司 | 激光校正摆轮重心偏移的平衡测量方法及测量切削装置 |
CN105738034B (zh) * | 2014-12-12 | 2018-05-22 | 天津海鸥表业集团有限公司 | 激光校正摆轮重心偏移的平衡测量方法及测量切削装置 |
EP3056948B1 (de) | 2015-02-17 | 2019-02-20 | Master Dynamic Limited | Siliciumspiralfeder |
Also Published As
Publication number | Publication date |
---|---|
EP1605182B8 (de) | 2010-07-14 |
JP2008501967A (ja) | 2008-01-24 |
ATE470086T1 (de) | 2010-06-15 |
HK1106570A1 (en) | 2008-03-14 |
DE602004027471D1 (de) | 2010-07-15 |
US20080008050A1 (en) | 2008-01-10 |
EP1605182B1 (de) | 2010-06-02 |
WO2005124184A1 (fr) | 2005-12-29 |
CN100564927C (zh) | 2009-12-02 |
US7682068B2 (en) | 2010-03-23 |
CN1985103A (zh) | 2007-06-20 |
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