EP1581680A4 - FABRIC WITH FLOATING YARNS HAVING INTERNAL LINKING ELEMENTS - Google Patents

FABRIC WITH FLOATING YARNS HAVING INTERNAL LINKING ELEMENTS

Info

Publication number
EP1581680A4
EP1581680A4 EP03781391A EP03781391A EP1581680A4 EP 1581680 A4 EP1581680 A4 EP 1581680A4 EP 03781391 A EP03781391 A EP 03781391A EP 03781391 A EP03781391 A EP 03781391A EP 1581680 A4 EP1581680 A4 EP 1581680A4
Authority
EP
European Patent Office
Prior art keywords
yarn
yarns
fibers
woven fabric
fabric according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP03781391A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1581680A2 (en
Inventor
William O Boyd Jr
John L Tucker Jr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Milliken and Co
Original Assignee
Milliken and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/298,475 external-priority patent/US20040097152A1/en
Priority claimed from US10/298,476 external-priority patent/US20040097150A1/en
Priority claimed from US10/319,097 external-priority patent/US20040116020A1/en
Priority claimed from US10/454,416 external-priority patent/US20040097148A1/en
Application filed by Milliken and Co filed Critical Milliken and Co
Publication of EP1581680A2 publication Critical patent/EP1581680A2/en
Publication of EP1581680A4 publication Critical patent/EP1581680A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • D03D13/004Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft with weave pattern being non-standard or providing special effects
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • D03D1/0035Protective fabrics
    • D03D1/0041Cut or abrasion resistant
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D11/00Double or multi-ply fabrics not otherwise provided for
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D11/00Double or multi-ply fabrics not otherwise provided for
    • D03D11/02Fabrics formed with pockets, tubes, loops, folds, tucks or flaps
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D27/00Woven pile fabrics
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/10Patterned fabrics or articles
    • D04B1/12Patterned fabrics or articles characterised by thread material
    • D04B1/126Patterned fabrics or articles characterised by thread material with colour pattern, e.g. intarsia fabrics
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24Viscose
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00Protein-based fibres, e.g. animal fibres
    • D10B2211/01Natural animal fibres, e.g. keratin fibres
    • D10B2211/02Wool
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2403/00Details of fabric structure established in the fabric forming process
    • D10B2403/01Surface features
    • D10B2403/011Dissimilar front and back faces
    • D10B2403/0112One smooth surface, e.g. laminated or coated
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2403/00Details of fabric structure established in the fabric forming process
    • D10B2403/02Cross-sectional features
    • D10B2403/023Fabric with at least two, predominantly unlinked, knitted or woven plies interlaced with each other at spaced locations or linked to a common internal co-extensive yarn system

Definitions

  • the present invention relates to fabrics having internal connecting elements to help stabilize the fabric construction.
  • Fig. 1 is an enlarged cross sectional view of a fabric with floating yarns ' incorporating the present invention.
  • Fig. 2 is an enlarged partial view of a needle for use in the present invention.
  • the fabric 10 is a woven fabric having a first side 101 and a second side 102.
  • the fabric 100 is formed of a first set of yarns, or warp yarns 110, and a second set of yarns, or fill yarns 120 interlaced to form the fabric 100.
  • the warp yarns 110 form warp yarn first side floats 106 on the first side 101 of the fabric 100, and warp yarn second side floats 107 on the second side 102 of the fabric 100.
  • the fill yarns 120 form fill yarn first side floats 108 on the first side 101 of the fabric 100, and fill yarn second side floats 109 on the second side 102 of the fabric 100.
  • the warp yarns 110 comprise warp yarn fibers 111 which form a warp yarn main body 112.
  • the main body of a yarn shall mean the group of fibers of a yarn that are oriented in substantially the same direction as the yarn itself.
  • the fill yarns 120 also are comprised of fill yarn fibers 121 which form a fill yarn main body 122.
  • Warp yarn connecting elements 113 are formed by portions of the warp yarn fibers 111 projecting into the fill yarn main body 122 and/or between the fill yarn main body 122 of more than one fill yarns 120.
  • fill yarn connecting elements 123 are formed by a portion of fill yarn fibers 121 projecting into the warp yarn main body 112 and/or between the warp yarn body 112 of more than one warp yarns 110.
  • the warp yarn connecting elements 113 are secured to the fill yarn 120 by the fill yarn fibers 121 of the fill yarn main body 122.
  • the fill yarn connecting elements 123 are secured by the warp yarn fibers 111 of the warp yarn main body 112.
  • the warp yarn connecting elements 113 provide extra securement of the warp yarns 110 in the fabric 100 above the preexisting securement provided by the interlacing of the warp yarns 110 and the fill yarns 120.
  • the fill yarn connecting elements 123 provide extra securement of the fill yarns 120 in the fabric 100 in addition to the securement provided by the interlacing of the warp yarns 110 with the fill yarns 120.
  • These types of connections contrast with connections formed between yarns by the entanglement of fibers extending generally outward and at least partially radially from one yarn with the fibers extending in a direction generally outward and at least partially radially from another yarn, as experienced with many of the hydroentangled methods of treating a fabric.
  • the connecting elements (warp yarn connecting elements 113 and fill yam connecting elements 123) exist in the yarns as they float in the fabric. Therefore, the connecting elements assist to secure the warp yarn first side floats 106 and the fill yarn first side floats 108 on the first side 101 of the fabric 100, and also to secure the warp yarn second side floats 107 and the fill yarns second side floats 109 to the second side 102 of the fabric 100.
  • the fabric 100 is a fabric having floats, such as a basket weave, twill weave, satin weave, or any other style of weaving which creates a pattern in which at least one of the yarns from a set of yarns extends over three or more yarns from the other set of yarns.
  • weave patterns suitable for the fabric 100 include basket weave, twill weave, sateen weave, fabrics woven by the dobby process which creates floats, fabrics formed by the jackard process which creates floats, or any other similar fabric in which a floating yarn is created.
  • the fabric 100 can have yarns which float from 3 to 20 of the yarns in the other set of the yarns. In a preferred embodiment, the fabric 100 will have yarns which float from 3 to 9 of the yarns in the other set.
  • the yarns forming the fabric 100 have a yarn size from about 100 denier to about 1200 denier. In one preferred embodiment, the yarn forming the fabric 100 has a yarn size from about 150 denier to about 750 denier. In one preferred embodiment, the fibers forming the warp yarn fibers 111 and the fill yarn fibers comprise filament fibers, thereby forming multi-filament yarns. In another embodiment, the fibers forming the warp yarn fibers 111 and the fill yarn fibers 121 are staple fibers such that the warp yarns 110 and the fill yarns 120 are spun yarns. In yet another embodiment, the warp yarn 110 can comprise spun yarns, and the blister yarn 120 can comprise filament yarns.
  • the present invention will work with yarns of combined filament and staple fiber.
  • the combined filament and stable fiber yarns can be used in the warp yarns 110, and/or the fill yarns 120 as a substitute for either the filament yarns and/or the spun yarns in the above combinations.
  • the fibers of the filament and/or spun yarns in the present invention can be formed from natural or manufactured material.
  • natural materials can include materials of animals, vegetable, or mineral origin which are used as fibers.
  • Manufactured materials can include polymers synthesized from chemical compounds, modified natural materials and minerals, and the like.
  • the yarns that float in the fabric 100 have a total of from about .1 connections per yarn-millimeter to about 5 connections per yarn-millimeter. In a preferred embodiment, the yarns in the area of a float contain a total of from about .4 connections per yarn-millimeter to about 2 connections per yarn-millimeter.
  • the fibers of the yarn are the source of connections, different yarns will have different availability of fibers for the connection, and different needs for the amount of connections based on the fiber content of the yarn.
  • a measurement of filament-distance is a length of yarn having filament(s) multiplied by the number of filament in that yarn bundle. Therefore, it is helpful to understand the number of total connections (total of both connections originated from a particular yarn and the connections secured by that particular yarn) per filament distance of the yarns for the area of a yarn floating in the fabric 100.
  • the yarn in the area of a yarn that is floating, the yarn will have at least about 0.01 connections per filament-inch to about 0.5 connections per filament-inch.
  • the yarn in the area of a float will have from about .04 connections per filament-inch to about 0.2 connections per filament-inch.
  • the fabric to be further processed is formed and then subjected to the needling process.
  • the fabric can be formed by standard weaving techniques, jacquard weaving, dobby weaving, or any other form by which yarns are forced to float in the weave pattern over other yarns of the fabric.
  • the formed fabric to be processed is fed into a needling machine that needles the fabric by the insertion of the bed of needles into fabric. Typically, the needle machine inserts the needles into the fabric, and withdraws the needles, at a direction generally perpendicular to the surface of the fabric.
  • Backing plates provide support to the fabric on the opposite side of the needle bed, and has openings to allow the needles to pass completely through the fabric.
  • the needles can be inserted and withdrawn from either side of the fabric, or both sides of the fabric. By inserting the needles from only one side, connections will only be generated by the portion of the yarns on the side of the fabric in which the needles are inserted. If more needle insertions per square area are required than can be provided by a single insertion of the bed of needles, then the bed of needles can be inserted more than once in a particular are of the fabric, or multiple beds of needles can be used to be inserted into the same area.
  • the needle machine inserts the needles into the fabric in a manner which produces little or no relative motion between the beds of needles and the fabric in a linear direction (the machine direction) as the fabric moves into, through, and exits the needling machine.
  • the relative linear motion between the needle bed and the fabric can be accomplished by moving the needle beds with the direction of travel of the fabric as the needles are inserted into the fabric and removed from the fabric.
  • a back coating can be applied to the fabric by various known methods, such as knife coating, foam coating, combination, spray coating, or other similar methods.
  • the needle 200 has a pointed end 210 and notches 220 along the length of the needle.
  • the pointed end is shown.
  • the 210 of the needle 200 facilitates the passage of the needle 200 through the yarns of the fabric.
  • the notches 220 of the needle 200 pick up or (hook) fibers of the yarn as the needle 200 passes through the yarns of the fabric.
  • the fibers previously hooked by the notches 220 of the needle 200 are moved into the main body of the adjacent yarns of the fabric. Movement of fibers by the needle 200 will stretch or pull the fibers from the originating yarns.
  • the fiber will follow the notch 220 of the needle 200 until the free end of the fiber passes through the notch 220 or the needle 200 reaches the end of its travel, and the fiber is deposited into the adjacent yarn.
  • the fiber will pass into the adjacent yarn until the needle 200 reaches the end of its travel, or the tension in the fiber causes the fiber to come free from the notch 220 or the fiber breaks.
  • the portion of the fiber that follows the needle and becomes free from the needle, or breaks, will deposit that portion of the fiber into the adjacent yarn.
  • the result is a positive movement of a portion of the fibers and/or filaments of the yarn directly into the main body of adjacent yarns, and/or secured between the main body of two adjacent yarns, creating an anchor directly by the main body of the adjacent yarns.
  • the fiber and/or filament secured by the adjacent yarn forms a connection between the yarns of the fabric.
  • hydroentanglement force fibers external to the main body of a yarn to entangle with fibers external to the main body of another yarn, providing a less direct connection between the components.
  • hydroentanglement has a limited ability to provide stability to a filament yarn because there are no, or few, free ends of the filaments that can be broken free from the main body of the yarn to entangle with the filaments from other yarns.
  • a fabric was woven with a pattern of warp yarns floating over 5 fill yarns and fill yarns floating over 5 warp yarns.
  • the fabric was woven from 2/300/136 56T polyester filament yarns. The fabric was then subjected to a needling process to form connections between the yarns of the fabric.
  • Needle Loom (Dilo manufacturing company) was used to needle the fabric with a needling motion that had little to no relative motion in the machine direction between the fabric and the needle bed.
  • the needle beds contained Groz-Beckert F222 needles, which are a triangular needle having six notches (2 per corner edge of the needle).
  • the needle beds were inserted into both sides of the fabric sufficient times that about 300 needle insertions were made per square centimeter of the fabric. The insertion of the needles was to a depth that four of the notches in the needles engaged the fabric.
  • EXAMPLE 2 A fabric was formed of the same yarns from Example 1 , except for in a pattern having warp yarns floating over 4 fill yarns, and fill yarns floating over 4 warp yarns. The fabric was then subjected to the same needling process as in Example 1 using the same needling equipment and needles. The needle bed was inserted into both sides of the fabric sufficient times that about 300 needle insertions were made per centimeter of the fabric, with the needles being inserted to a depth where four of the notches engaged the fabric. It was found that the process resulted in about 1.16 connections per yarn-millimeter in the area of the yarns that floated in the fabric, and about 0.108 connections per filament-inch in the same area.
  • EXAMPLE 3 A fabric was formed from the same yarns as in Example 1 , except for with a pattern having warp yarns floating over 3 fill yarns, and fill yarns floating over 3 warp yarns. The fabric was then subjected to the same needling process as in Example 1 using the same needling equipment and needles. The fabric was needled into both sides of the fabric sufficient times that about 300 needle insertions were made per square centimeter of the fabric, with the needles being inserted to a depth where four of the notches engaged the fabric. The process resulted in about 1.88 connections per yarn-millimeter in the floating area of the yarns, and about .175 connections per filament-inches in the same area.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Woven Fabrics (AREA)
  • Knitting Of Fabric (AREA)
  • Treatment Of Fiber Materials (AREA)
EP03781391A 2002-11-15 2003-10-24 FABRIC WITH FLOATING YARNS HAVING INTERNAL LINKING ELEMENTS Withdrawn EP1581680A4 (en)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US10/298,475 US20040097152A1 (en) 2002-11-15 2002-11-15 Composite fabrics with internal connecting elements
US298476 2002-11-15
US298475 2002-11-15
US10/298,476 US20040097150A1 (en) 2002-11-15 2002-11-15 Blister fabrics with internal connecting elements
US319097 2002-12-13
US10/319,097 US20040116020A1 (en) 2002-12-13 2002-12-13 Fabric with floating yarn having internal connecting elements
US10/454,416 US20040097148A1 (en) 2002-11-15 2003-06-04 Blister fabrics with internal connecting elements
US454416 2003-06-04
PCT/US2003/033844 WO2004046446A2 (en) 2002-11-15 2003-10-24 Fabric with floating yarn having internal connecting elements

Publications (2)

Publication Number Publication Date
EP1581680A2 EP1581680A2 (en) 2005-10-05
EP1581680A4 true EP1581680A4 (en) 2007-04-04

Family

ID=32330029

Family Applications (2)

Application Number Title Priority Date Filing Date
EP03781391A Withdrawn EP1581680A4 (en) 2002-11-15 2003-10-24 FABRIC WITH FLOATING YARNS HAVING INTERNAL LINKING ELEMENTS
EP03779253A Expired - Lifetime EP1583856B1 (en) 2002-11-15 2003-10-24 Blister fabrics with internal connecting elements

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP03779253A Expired - Lifetime EP1583856B1 (en) 2002-11-15 2003-10-24 Blister fabrics with internal connecting elements

Country Status (10)

Country Link
EP (2) EP1581680A4 (es)
JP (1) JP4599589B2 (es)
KR (2) KR20050086561A (es)
CN (2) CN1711379B (es)
AU (2) AU2003284934A1 (es)
BR (2) BR0316356A (es)
CA (2) CA2505388A1 (es)
HK (1) HK1086229A1 (es)
MX (2) MXPA05005077A (es)
WO (2) WO2004046446A2 (es)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007105278A1 (ja) * 2006-03-10 2007-09-20 Fujitsu Limited 光スイッチ及び光パケットバッファ
CN107142588B (zh) * 2017-06-21 2018-09-11 江苏工程职业技术学院 一种多层双面起泡功能性面料及其生产工艺
US20190216149A1 (en) * 2018-01-12 2019-07-18 Nike, Inc. Woven Trim Piece
CN109667023B (zh) * 2018-12-19 2020-11-06 江苏工程职业技术学院 一种功能性起泡色织面料的设计方法及其生产工艺
CN110079912B (zh) * 2019-03-30 2021-10-26 浙江超仕达特纺有限公司 一种环保高强淤泥围栏滤布

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US2991537A (en) * 1954-03-10 1961-07-11 Du Pont Method of making felt-like fabric
JPS51105477A (es) * 1975-03-13 1976-09-18 Fuji Fibre Glass Co Ltd
FR2408001A1 (fr) * 1977-11-04 1979-06-01 Amyot Louis Procede pour la realisation d'un article textile
GB2077786A (en) * 1980-06-06 1981-12-23 Antonini Massimiliano A mat and similar fabrics made of textile fibres, treated for improved adherence, for use in plastic material structures
GB2095300A (en) * 1981-03-23 1982-09-29 Textiltech Forsch Textile material having a fibrous appearance
JPS6328971A (ja) * 1986-07-14 1988-02-06 株式会社 カナメ 繊維編織物
EP0266238A1 (fr) * 1986-10-01 1988-05-04 Institut Textile De France Tissu enduit
JPH04174758A (ja) * 1990-10-29 1992-06-22 Nippon Felt Kogyo Kk 嵩高ファブリック及びその製造方法
US5143771A (en) * 1989-05-19 1992-09-01 Establissements Les Fils D'auguste Chomarat Et Cie Textile reinforcement which can be used to make various composites and method for its manufacture
WO2001000412A1 (en) * 1999-06-25 2001-01-04 Milliken & Company Napped fabric and process

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JPH08337953A (ja) * 1995-06-09 1996-12-24 Hori Sadao 繊維シート
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US2991537A (en) * 1954-03-10 1961-07-11 Du Pont Method of making felt-like fabric
JPS51105477A (es) * 1975-03-13 1976-09-18 Fuji Fibre Glass Co Ltd
FR2408001A1 (fr) * 1977-11-04 1979-06-01 Amyot Louis Procede pour la realisation d'un article textile
GB2077786A (en) * 1980-06-06 1981-12-23 Antonini Massimiliano A mat and similar fabrics made of textile fibres, treated for improved adherence, for use in plastic material structures
GB2095300A (en) * 1981-03-23 1982-09-29 Textiltech Forsch Textile material having a fibrous appearance
JPS6328971A (ja) * 1986-07-14 1988-02-06 株式会社 カナメ 繊維編織物
EP0266238A1 (fr) * 1986-10-01 1988-05-04 Institut Textile De France Tissu enduit
US5143771A (en) * 1989-05-19 1992-09-01 Establissements Les Fils D'auguste Chomarat Et Cie Textile reinforcement which can be used to make various composites and method for its manufacture
JPH04174758A (ja) * 1990-10-29 1992-06-22 Nippon Felt Kogyo Kk 嵩高ファブリック及びその製造方法
WO2001000412A1 (en) * 1999-06-25 2001-01-04 Milliken & Company Napped fabric and process

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Also Published As

Publication number Publication date
KR20050086568A (ko) 2005-08-30
JP2006506557A (ja) 2006-02-23
BR0316354A (pt) 2005-09-27
EP1583856A4 (en) 2007-03-28
CN1711379B (zh) 2010-12-22
MXPA05005077A (es) 2005-07-01
CN1711168A (zh) 2005-12-21
JP4599589B2 (ja) 2010-12-15
EP1583856B1 (en) 2010-12-08
CN1296198C (zh) 2007-01-24
AU2003287211A8 (en) 2004-06-15
AU2003284934A1 (en) 2004-06-15
EP1581680A2 (en) 2005-10-05
WO2004046437A1 (en) 2004-06-03
WO2004046446A2 (en) 2004-06-03
MXPA05005075A (es) 2005-07-01
CA2505391A1 (en) 2004-06-03
CA2505388A1 (en) 2004-06-03
AU2003287211A1 (en) 2004-06-15
WO2004046446A3 (en) 2004-12-16
HK1086229A1 (en) 2006-09-15
BR0316356A (pt) 2005-09-27
KR20050086561A (ko) 2005-08-30
KR100752857B1 (ko) 2007-08-29
CN1711379A (zh) 2005-12-21
EP1583856A1 (en) 2005-10-12

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