EP1539904A1 - Procede de production d'une solution dotee de proprietes lubrifiantes destinee servir comme additif a un liquide - Google Patents

Procede de production d'une solution dotee de proprietes lubrifiantes destinee servir comme additif a un liquide

Info

Publication number
EP1539904A1
EP1539904A1 EP03794394A EP03794394A EP1539904A1 EP 1539904 A1 EP1539904 A1 EP 1539904A1 EP 03794394 A EP03794394 A EP 03794394A EP 03794394 A EP03794394 A EP 03794394A EP 1539904 A1 EP1539904 A1 EP 1539904A1
Authority
EP
European Patent Office
Prior art keywords
solution
boric
additive
liquid
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP03794394A
Other languages
German (de)
English (en)
Inventor
Mats Selin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ECURITY AB
Original Assignee
ECURITY AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from SE0202659A external-priority patent/SE0202659D0/xx
Application filed by ECURITY AB filed Critical ECURITY AB
Publication of EP1539904A1 publication Critical patent/EP1539904A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/26—Compounds containing silicon or boron, e.g. silica, sand
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/02—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic oxygen-containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C10L1/125—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1291—Silicon and boron containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

Definitions

  • the present invention refers to a method for producing a solution having lubrication properties intended to be used as an additive to a liquid preferably a liquid fuel or a lubricant and a solution made according to said method, which when blended gives the liquid friction-reducing, lubricating and corrosion ihibiting characteristics.
  • boron can establish a complex ligand bond to other metals. This occurs after an exposure over time, from hours to days.
  • the boron compounds in question are aligned to two dimensional pallets, that slides on each other, which causes a reduced friction.
  • boron acts as a corrosion ihibitor for metals as the boric acid bonds to a thin layer on the underlying metal surface and prevents oxidation due to the electro negativity, which makes boron an effective reduction substance that prevents corrosion of exposed surfaces.
  • oil is blended with a high concentration of boric acid, and the blend is diluted at a ratio of approximately 10% to different lubricating oils.
  • boric acid can be used as an additive to fuels to accomplish a friction reducing effect.
  • the method is to mix boric acid in a base oil or a concentrate based on a diesel fuel.
  • the particle size of the boric compound normally in the range of 0.5 to 20 micron, is made by "jet-milling", a method in doing so.
  • an additive, diesel addi- tive as example, made by this method over time has a limited stability.
  • the boric acid particles are aggregating and are falling out and gathered on the bottom of the container. This happens within a period of months or less. This could lead to severe consequences for any engine, as example a diesel engine. Even when the boric acid particles are mixed in a base oil and thereafter eventually are diluted in fuel or the like, the same risk exists.
  • the object of the present invention is to eliminate the disadvantages as mentioned above, and to make an additive to a fluid or liquid, preferably a liquid fuel or a lubricant, which can be dissolved in the liquid and give the liquid friction reducing, lubricating and corrosion restraining effect.
  • a fluid or liquid preferably a liquid fuel or a lubricant, which can be dissolved in the liquid and give the liquid friction reducing, lubricating and corrosion restraining effect.
  • the composition consisting lubricant and the solution should have a concentration of boric compounds of around 400 ppm/4%.
  • the invention also incorporates a solution as such made as an additive by dissolving a boric compound, a boric acid and/or bortrioxide.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Lubricants (AREA)

Abstract

L'invention concerne un procédé permettant de produire une solution possédant des propriétés lubrifiantes que l'on peut utiliser de préférence comme additif à un concentré mélangé à un liquide, par exemple un carburant liquide. Un composé borique, par exemple l'acide borique et/ou le bore-trioxyde, est dissout dans un solvant, les ions de borate étant alors dans une phase homogène avec le solvant, lequel en tant que solution dans des conditions stables présente une teneur élevée de borate grâce à la contre-action des liaisons d'hydrogène à l'électronégativité du composé borique et à sa tendance à se lier de manière covalente. Ladite solution est utilisée comme additif au liquide effectif, lequel se dote ainsi de caractéristiques qui réduisent le frottement, qui sont lubrifiantes et qui inhibent la corrosion.
EP03794394A 2002-09-09 2003-09-08 Procede de production d'une solution dotee de proprietes lubrifiantes destinee servir comme additif a un liquide Withdrawn EP1539904A1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
SE0202659A SE0202659D0 (sv) 2002-09-09 2002-09-09 Smörjmedel och smörjmedelsadditiv
SE0202659 2002-09-09
SE0302070A SE524898C3 (sv) 2002-09-09 2003-07-14 Förfarande för framställning av en lösning med smörjande egenskaper avsedd att användas såsom tillsats till en vätska, användning av lösningen och lösningen
SE0302070 2003-07-14
PCT/SE2003/001366 WO2004022676A1 (fr) 2002-09-09 2003-09-08 Procédé de production d'une solution dotée de propriétés lubrifiantes destinée à servir comme additif à un liquide

Publications (1)

Publication Number Publication Date
EP1539904A1 true EP1539904A1 (fr) 2005-06-15

Family

ID=27767292

Family Applications (1)

Application Number Title Priority Date Filing Date
EP03794394A Withdrawn EP1539904A1 (fr) 2002-09-09 2003-09-08 Procede de production d'une solution dotee de proprietes lubrifiantes destinee servir comme additif a un liquide

Country Status (7)

Country Link
US (1) US20060100111A1 (fr)
EP (1) EP1539904A1 (fr)
JP (1) JP2005538209A (fr)
AU (1) AU2003261686A1 (fr)
BR (1) BR0314167A (fr)
SE (1) SE524898C3 (fr)
WO (1) WO2004022676A1 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005083042A1 (fr) * 2004-03-02 2005-09-09 Mats Selin Additif pour carburant de moteur deux temps a proprietes lubrifiantes permettant de remplacer le carburant et l'huile moteur deux temps classiques
US7494959B2 (en) * 2005-08-10 2009-02-24 Advanced Lubrication Technology Inc. Multi-phase lubricant compositions containing emulsified boric acid
US7419515B2 (en) * 2005-08-10 2008-09-02 Advanced Lubrication Technology, Inc. Multi-phase distillate fuel compositions and concentrates containing emulsified boric acid
CN100526444C (zh) * 2005-12-20 2009-08-12 中国科学院兰州化学物理研究所 硼酸盐超细颗粒润滑添加剂的制备方法
JP6042208B2 (ja) * 2009-05-08 2016-12-14 トリボロン・インターナショナル・アーベー 安定なホウ素溶液を製造するための方法
RU2405030C1 (ru) * 2009-07-16 2010-11-27 Владимир Николаевич Наумов Водорастворимое смазочное средство для обработки конвейерных лент
US9212329B2 (en) * 2012-03-15 2015-12-15 William E. Olliges Use of hexylene glycol fuel additive containing boric oxide
US20190119589A1 (en) * 2016-04-08 2019-04-25 Triboron International Ab Oil-replacement additive for reducing emissions from two-stroke engines
EP3532575A4 (fr) * 2016-10-27 2020-07-01 Triboron International AB Procédés de prévention de la prolifération microbienne et de la corrosion influencée par les microorganismes dans un combustible biodégradable et/ou renouvelable, un fluide hydraulique et/ou un lubrifiant

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4440656A (en) * 1981-11-23 1984-04-03 Mobil Oil Corporation Borated alkoxylated alcohols and lubricants and liquid fuels containing same
US4524004A (en) * 1983-10-28 1985-06-18 Mobil Oil Corporation Borated N-hydrocarbyl-hydrocarbylene diamines as multifunctional lubricant/fuel additives and compositions thereof
GB2149810B (en) * 1983-11-15 1987-04-08 Shell Int Research Borated basic metal salt and oil composition containing it
US4557844A (en) * 1984-01-30 1985-12-10 Mobil Oil Corporation Aminated boron- and phosphorus-containing compounds and lubricant or fuel compositions containing same
US4741848A (en) * 1986-03-13 1988-05-03 The Lubrizol Corporation Boron-containing compositions, and lubricants and fuels containing same
US5033415A (en) * 1987-06-22 1991-07-23 Mobil Oil Corporation Friction reducing additives and compositions thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2004022676A1 *

Also Published As

Publication number Publication date
SE524898C2 (sv) 2004-10-19
AU2003261686A1 (en) 2004-03-29
US20060100111A1 (en) 2006-05-11
SE524898C3 (sv) 2005-06-01
SE0302070L (sv) 2004-03-10
JP2005538209A (ja) 2005-12-15
BR0314167A (pt) 2005-07-19
WO2004022676A1 (fr) 2004-03-18
SE0302070D0 (sv) 2003-07-14

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