AU673684B2 - Method for the manufacture of an antrifriction agent and antifriction agent - Google Patents

Method for the manufacture of an antrifriction agent and antifriction agent Download PDF

Info

Publication number
AU673684B2
AU673684B2 AU47652/93A AU4765293A AU673684B2 AU 673684 B2 AU673684 B2 AU 673684B2 AU 47652/93 A AU47652/93 A AU 47652/93A AU 4765293 A AU4765293 A AU 4765293A AU 673684 B2 AU673684 B2 AU 673684B2
Authority
AU
Australia
Prior art keywords
parts
weight
document
liquid medium
international
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU47652/93A
Other versions
AU4765293A (en
Inventor
Georg Shpenkov
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Przedsiebiorstwo Wdrozeniowo-Produkcyjno-Handlowe "panther" Spolka Z O O
Original Assignee
PRZED WDROZENIOWO PROD HANDLOW
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PRZED WDROZENIOWO PROD HANDLOW filed Critical PRZED WDROZENIOWO PROD HANDLOW
Publication of AU4765293A publication Critical patent/AU4765293A/en
Application granted granted Critical
Publication of AU673684B2 publication Critical patent/AU673684B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/04—Metals; Alloys
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/10—Metal oxides, hydroxides, carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
    • C10M129/40—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M133/12—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to a carbon atom of a six-membered aromatic ring
    • C10M133/14—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to a carbon atom of a six-membered aromatic ring containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/02—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic oxygen-containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/06—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic nitrogen-containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1208—Inorganic compounds elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/05—Metals; Alloys
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/062—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups bound to the aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/10—Groups 5 or 15
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/12—Groups 6 or 16
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/14—Group 7
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/16—Groups 8, 9, or 10
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Metallurgy (AREA)
  • Lubricants (AREA)
  • Enzymes And Modification Thereof (AREA)

Description

APPLN. ID 47652/93 PCT NUMBER PCT/PL93/00014 1111111111 I lllllll Illllllllllii AU9347652 OPI DATE 15/03/94 r AOJP DATE 09/06/94 INTERNAT1 International Patent Classification 5 141/02, 141/06 CION 10/02, 10/10, 10/12 10/16, 30/06 141/02, 125:04, 129:Jn) (CIOM 141/06, 125:04, 129:4' 133:14) (11) International Publication Number: (43) International P-blication Date: WO 94/04638 3 March 1994 (03.03.94) Sobieskiego 258, 43-300 (21) International Application Number: (22) International Filing Date: Priority data: P.295708 21 Augus PCT/PL93 0014 18 Atjst 1993 (18.I 8.93) (74)Agent: RYGIEL, Andrzej; ul.
Bielsko-Biala (PL).
t 1992 (21.08.92) (81) Designated States: AT, AU, BR, CA, CH, CZ, DE, DK, ES, GB, HU, JP, KR, NO, PT, RU, SE, SK, US.
Published With international search report.
Before the expiration of the time limit for amending the claims and to be republished in the event of the receipt of amendments.
(71 Applicant (for all designated States except US): PRZED- SIEBIORSTWO WDROZENIOWO-PRODUKCYJ- NO-HANDLOWE "PANTHER" SPOLKA Z 0. 0.
[PL/PL], ul. Asnyka 4/8J, .3-300 Bielsko-Biala (PL).
(72) Inventor; and Inventor/Applicant (for US only) SHPENKOV, Georg [BY/PL]; ul. Lwowska 6/64, 41-200 Sosnowiec (PL).
893 i:, I'~:s r iJII i, (54) Title: METHOD FOR THE MANUFACTURE OF AN ANTRIFRICTION AGENT AND ANTIFRICTION AGENT (57) Abstract The subject of the invention is the method of the antifriction agent manufacture and the antifriction agent itself. The method of the antifriction agent manufacture is based on, that to the necessary quantity of particles of colloidal dispel son of copper or vanadium or chromium or cobalt jr nickel or their oxides or their combinations a liquid medium, at the best low viscosity oil, and a surface active agent, at the best oleic acid, and a liquid medium, at the best aminobenzoic acid, are added and mixed thoroughly, keeping to proper proportions. The antifriction agent contains IxlO- 2 to 2.2xl0- 4 atoms or ions of the pure metal, 0.5x10-2 to 1.1xl0-4 of surface active agent (at the best oelic acid) and advantageously 2.75x10- 6 to 2.5x 0- 4 of aminobenzoic acid.
1 METHOD FOR MANUFACTURE OF AN ANTIFRICTION AGENT AND ANTIFRICTION AGENT This invention relates to an antifriction agent and to a method of manufacturing the antifriction agent and in particular to those made on a base of the particles of colloidal dispersion of copper or vanadium or chromium or cobalt or nickel or their oxides or their combinations.
There are known additions to lubricating media, mostly containing powders of tin(Su), copper(Cu), lead(Pb), zinc(Zn) or other metals, which improve the characteristics and which have an influence on the performance of plastic :or liquid lubricants, thereby reducing friction and wear of co-acting parts and at the same time raising their :.i1 electrical conductivity.
15 There are also known additions to fuels which have antismoke properties, decreasing the level of noxious substances in exhaust gases, especially in compressionignition engines. Also there is known an addition to fuels which contains iron oxides thoroughly mixed with fuel. The 20 optimum contents of iron oxides in fuel is 0.01 to 0.1% of the fuel's weight, which reduces the formation of soot by 21%. However, the anti-smoke properties of this addition are poor and there is a disadvantage of a lack of antislide properties, which limits its broad application.
From Polish Patent 167710 there is a known method of producing an addition, especially to a lubricating media, cutting fluids or fuels which includes a colloidal dispersion of copper or vanadium or chromium or cobalt or nickel or their oxides or their combinations. According to this patent to the particles of the colloidal dispersion of copper or vanadium or chromium or cobalt or nickel or their oxides or their combinations a liquid medium is added, SstaflaerJkeep/spoci/47652.93.PANTHER 5.9 I 7 2
S
S
S..
S preferably a low viscosity oil, so that per every two parts by weight of colloidal particles of pure metal there is one part by weight of the liquid medium. Then, the ingredients are mixed. After that, a surface active agent is added, preferably oleic acid, so that per every two parts by weight of colloidal particles of pure metal there is one part by weight to the liquid medium and 0.8 to 1.5 parts by weight of surface active agent. Then the ingredients are mixed. Then the liquid medium is added to obtain such a proportion in which per two parts by weight of colloidal dispersion of pure metal particles there are one to two parts by weight of surface active agent.
The object of the present invention is the development of the method of manufacturing the antifriction agent and the antifriction agent itself, which increases the service life of co-acting parts.
The invention provides a method of manufacturing an antifriction agent in the form of a colloidal dispersion of copper, vanadium, chromium, cobalt, nickel or oxides 20 thereof including combinations thereof, comprising the steps of: mixing particles of copper, vanadium, chromium, cobalt, nickel, oxides thereof or combinations thereof with a liquid medium to form a colloidal dispersion having 2 parts by weight of metal or metal oxides to 1 to 2 parts by weight liquid medium; adding from 0.8 to 1.5 parts by weight of a stabilising surface active agent to the colloidal dispersion formed in paragraph to form a colloidal dispersion having 2 parts by weight of metal or metal oxide, 1 to 2 parts by weight liquid medium, and 0.8 to 1.5 parts by weight of surface active agent; arA e staff/aen/keJspe L47652.93,PANTHEA 5,9 K1 S3 adding further liquid medium to the colloidal dispersion formed in paragraph to form a colloidal dispersion having 2 parts by weight metal or metal oxide, 2 to 47 parts by weight liquid medium, and 0.8 to 1.5 parts by weight surface active agent.
Preferably the liquid medium comprises a low viscosity oil.
Preferably the stabilising surface active agent is oleic acid.
Preferably, together with the further liquid medium, aminobenzoic acid is added so that a ratio is obtained whereby per two parts by weight of colloidal particles of pure metal there is 2.0 to 47 parts by weight of the liquid medium, 0.8 to 1.5 parts by weight of surface active agent 15 and 2.5x10 2 to 5.0x10 2 parts by weight of the aminobenzoic acid.
A preferred embodiment of the invention will be described with reference to the following example.
EXAMPLE
20 Prepare a solution of 34.5 g of sodium hydroxide in 600 ml of water and filtrate it. Prepare a solution of 100 g of blue vitriol in 400 ml of water and filtrate it as well.
Warmed up to the temperature of 70 0 C, the solution of blue vitriol is added to the solution of sodium hydroxide and the achieved mixture is mixed for from 1 to 15 minutes and then poured into water to get the volume from 2 1 to 4 1.
The obtained mixture is subjected to the decantation until all the SO 4 ions are separated, given, the separated water should not become turbid in the next 2 hours after adding barium chloride. Add the liquid medium to the obtained cupric oxide deposit, preferably low viscosity oil, so that stateaonlkee/sped476593PANTHER 5.9 4 per two parts by weight of cupric oxide there is one part by weight of the liquid medium. Mix the ingredients thoroughly, then add to the mixture the surface agent preferably oleic acid, to reach the proportion in which per two parts by weight of cupric oxide there is 1.5 parts by weight of the liquid medium and 0.9 parts by weight of surface active agent.
Such a mixture is filled up with the liquid medium, not interrupting mixing, until per two parts by weight of cupric oxide there is 20 parts by weight of the liquid medium and 0.9 parts by weight of surface active agent.
On obtaining the intimate mixture, the liquid medium is added, preferably aminobenzoic acid, until a ratio is obtained, where per two parts by weight of colloidal particles of pure metal there is 2.0 to 47 parts by weight of liquid medium and 2.5x10 2 to 5.0x10 2 parts by weight of aminobenzoic acid.
The antifriction agent, made according to the above preferred method, which is comprised of the mixture of the 20 particles of colloidal dispersion of copper can then be added to lubricating media, cutting fluids and fuels.
So obtained antifriction agent when added to transmission, hydraulic or engine fluids improves tribological characteristics and performance of the lubricated equipment by repairing micro/macro surface defects of the mating parts, and the presence of the aminobenzoic acid causes a favourable phenomena of very good, stable and uniform dispersion of particles in the agent.
The antifriction agent can be added, for example in quantities of 0.84% to 1% by volume, to all kinds of metalworking, cutting and cooling/lubricating mineral and staHfaen/keep/speci4765293.PANTHER 5.9
C.V
5 synthetic fluids used in machining of metals to extend life of tools and improving surface finish of the machined parts.
The advantage of the antifriction agent is that it forms a non-oxidising layer on working surfaces which are continuously being regenerated due to transfer of active particles contained in the antifriction agent onto these surfaces thus smoothing surface imperfections of the working surfaces.
o0 *ee o ••e ease ft 0 I I 4istaWaenihoepspel476593.PANTHER 5.9 1

Claims (6)

1. A method of manufacturing an antifriction agent in the form of a colloidal dispersion of copper, vanadium, chromium, cobalt, nickel or oxides thereof including combinations thereof, comprising the steps of: mixing particles of copper, vanadium, chromium, cobalt, nickel, oxides thereof or combinations thereof with a liquid medium to form a colloidal dispersion having 2 parts by weight of metal or metal oxides to 1 to 2 parts by weight liquid medium; adding from 0.8 to 1.5 parts by weight of a stabilising surface active agent to the colloidal i: dispersion formed in paragraph to form a colloidal dispersion having 2 parts by weight of metal or metal oxide, 1 to 2 parts by weight liquid medium, and 0.8 to 1.5 parts by weight of surface active agent; and adding further liquid medium to the colloidal S 20 dispersion formed in paragraph to form a colloidal dispersion having 2 parts by weight metal or metal oxide, 2 to 47 parts by weight liquid medium, and 0.8 to 1.5 parts by weight surface active agent.
2. The method according to claim 1 wherein the liquid medium comprises a low viscosity oil.
3. The method according to claim 1 or claim 2 wherein the stabilising surface active agent is oleic acid.
4. The method according to any one of claims 1 to 3 further comprising adding aminobenzoic acid to the dispersion to form a colloidal dispersion of two parts by weight of metal or metal oxide, 2.0 to 47 parts by weight statlaen/keep/speci4765293.PANTHER 5.9 7 of the liquid medium, 0.8 to 1.5 parts by weight of surface active agent and 2.5x10 2 to 5.0x10 2 parts by weight of the aminobenzoic acid.
A method of manufacturing antifriction agents substantially as hereinbefore described with reference to the example in the specification.
6. An antifriction agent substantially as hereinbefore described with reference to the example in the specification. Dated this 5th day of September 1996 PRZEDSIEBIORSTWO WDROZENIOWO-PRODUKCYJNO-HANDLOWE "PANTHER" SPOLKA Z 0. 0. By its Patent Attorneys: GRIFFITH HACK Fellows Institute of Patent Attorneys of Australia. a 0 a *9 a a. A t a 1 r a nin stanlaenfdeeospec4765Z-93,PANTHSR 5.9 INTERNATIONAL SEARCH REPORT International application No. PCT/PL 93/00014 A.ASSIFICATION OF SUBIEET MATTER IPC 5 C10M141/02 C10M141/06 //C1ON1O/02,C1ON1O/10,ClON1O/12, C1ON1O/16,C1ON3O/06,(C1OM141/02,125:04,129:40),(C10M141/06, 125:04,129:40,133:14) According to International Patent Classiflcatioi (IPC' or to both natiornal classfication and IPC B. FIELDS SEARCHED Minimum documnentation searched (clazificatrscyv. Followed by classification symbols) IPC 5 C1OM Documentation searched other thein miunimumn docu-t, to the ,s that such documents are inclulcd in the fields searched Electronic data basc consulted during the international tine of dAL/. tiase and, where practical, search terms used) C. DOCUMENTS CONSIDERED TO BE RELEVANT Category Citation of document, with indication, where appropriate, of the relevant psasages Relevant to claim No. A DE,A,40 17 914 (PEISSI W) 5 December 1991 1,2 see claim 1 A DATABASE WPI 1,2 Week 9207, Derwent Publications Ltd., London, GB; AN 92-055111 SU,A,1 635 904 (KHOKHLOV) 15 March 1991 see abstract A DATABASE WPI 1,2 Week 8722, Derwent Publications Ltd., London, GB; AN 87-153291 JP,A,62 089 794 (TAIHO KOGYO KK) 24 April 1987 see abstract I] Further documents are listed in the continuation of box C. rvIPatent family members are listed in annex. Special categories of cited documents: -T later document published after the international riling date document defining the general state of the art which isno tor i rit 9ead t pincinflic ort the unelyn the considered to be of particular relevance itvedntiondesadtepicpeo udryn h earlier document but published on or after the international 'X document of particuilar relevance; the claimed invention filing date cannot be conidered novel or cantnot be considered to document which may throw doubts on paority claim(s) or involve an inventive step when the document is taken alone whtich is cited to establish the publication date of another document of particular relevance; the claimed invention citation or other special reason (as specified) cannot be considered to involve an inventive step when the document referring to an oral disclosure, use, exhibition or docuiment is combined with one or more other such docu- other means ments, such combination being obvious to A person skilled document published pnior to the international filing date but in the art. later thani the priority date claimed W document member of the same patent family Date of the actis~d completion of the Iriternatior, ;earch Date of mailing of the international search report 26 November 1993 27, 12 93 N~ame and mailing address of the ISA Authorized officer European Patent Office, P.B. 581 Patentlatan 2 NL 2280 HV Rijswijk Tel. 31.70) 340-2040, Tx. 31 651 po nl,Hig n ,K Fax 31.70) 340.3016 ig na K Form PCT/lSA1110 (secondt sheet) (July 1992) INTERNATIONAL SEARCH REPORT Informnfor on patent fanuly members international application No. PCT/PL 93/00014 Patent documemnt Pbcaion Patent family datie cited in search report daemember(s)I DE-A-4017914 05-12-91 NONE 'arm PCT/ISA/210 (patent family annex) (July 1992)
AU47652/93A 1992-08-21 1993-08-18 Method for the manufacture of an antrifriction agent and antifriction agent Ceased AU673684B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
PL295708 1992-08-21
PL92295708A PL170502B1 (en) 1992-08-21 1992-08-21 Method of obtaining an antifriction agent and antifriction agent as such
PCT/PL1993/000014 WO1994004638A1 (en) 1992-08-21 1993-08-18 Method for the manufacture of an antrifriction agent and antifriction agent

Publications (2)

Publication Number Publication Date
AU4765293A AU4765293A (en) 1994-03-15
AU673684B2 true AU673684B2 (en) 1996-11-21

Family

ID=20058355

Family Applications (1)

Application Number Title Priority Date Filing Date
AU47652/93A Ceased AU673684B2 (en) 1992-08-21 1993-08-18 Method for the manufacture of an antrifriction agent and antifriction agent

Country Status (11)

Country Link
JP (1) JPH07507092A (en)
KR (1) KR100271189B1 (en)
AU (1) AU673684B2 (en)
CA (1) CA2121779A1 (en)
CZ (1) CZ121394A3 (en)
DE (1) DE4394035T1 (en)
DK (1) DK45694A (en)
HU (1) HUT67935A (en)
PL (1) PL170502B1 (en)
SK (1) SK58894A3 (en)
WO (1) WO1994004638A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8741821B2 (en) 2007-01-03 2014-06-03 Afton Chemical Corporation Nanoparticle additives and lubricant formulations containing the nanoparticle additives
US8333945B2 (en) 2011-02-17 2012-12-18 Afton Chemical Corporation Nanoparticle additives and lubricant formulations containing the nanoparticle additives

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4017914A1 (en) * 1990-06-02 1991-12-05 Peissig Werner Addn. of oleic acid and copper powder to air intake in I.C. engine - to obtain improved friction coupling and environmental effects

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6289794A (en) * 1986-10-08 1987-04-24 Taihoo Kogyo Kk Production of fuel additive
SU1635904A3 (en) * 1989-05-15 1991-03-15 Л.А.Хохлов, Л.Г.Кошелев, Ю.Ю.Белоус, А.М.Романюха, И.Н.За ц и В.П.Барабан Antifriction additive to lubrication oils

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4017914A1 (en) * 1990-06-02 1991-12-05 Peissig Werner Addn. of oleic acid and copper powder to air intake in I.C. engine - to obtain improved friction coupling and environmental effects

Also Published As

Publication number Publication date
PL170502B1 (en) 1996-12-31
DK45694A (en) 1994-06-13
WO1994004638A1 (en) 1994-03-03
KR100271189B1 (en) 2000-12-01
DE4394035T1 (en) 1994-11-10
AU4765293A (en) 1994-03-15
HUT67935A (en) 1995-05-29
SK58894A3 (en) 1994-09-07
HU9401532D0 (en) 1994-09-28
CZ121394A3 (en) 1994-11-16
JPH07507092A (en) 1995-08-03
PL295708A1 (en) 1994-03-07
CA2121779A1 (en) 1994-03-03

Similar Documents

Publication Publication Date Title
AU673684B2 (en) Method for the manufacture of an antrifriction agent and antifriction agent
KR20080032200A (en) Fuel and lubricant additives and methods for improving fuel economy and vehicle emissions
US4204968A (en) Lubricant additive
US5173202A (en) Lubricant coating material: its characteristics and method of manufacture
CN110408454B (en) Additive for improving engine power
JPH05171169A (en) Lubricant
EP0291511B1 (en) Lubricant additive mixture of antimony thioantimonate and antimony trioxide
US6245721B1 (en) Lubrication additive composition
CN108517238A (en) Protein modification redox graphene water lubrication additive, its preparation method and application
US4927549A (en) Lubricant of lubricating oil basis for lubricating rotating and/or sliding surfaces and process for preparing same
EP1539904A1 (en) A method for producing a solution having lubricating properties intended to be used as an additive to a liquid
US5397485A (en) Power restoring lubricant compositions
US2758085A (en) Method for incorporating oil-insoluble, solid addition agents in mineral oils
US2742427A (en) Lubricating oil containing dispersed magnesium
JP3956399B2 (en) High performance lubricant
HU185805B (en) Lubricant compesition
US5723419A (en) Engine treatment composition
CN112877118A (en) Lubricating oil capable of remarkably reducing engine noise and preparation method thereof
RU2054456C1 (en) Antifriction additive
RU2246531C2 (en) Composition for improving of friction assembly endurance
AU671854B2 (en) Chemical metal and oil treating composition and process
EP0195674B1 (en) Extreme pressure additive for use in metal lubrication
RU2385898C1 (en) Antiwear agent composition
WO2021250307A1 (en) Use of organometallic salt compositions in marine lubricants
RU2139319C1 (en) Plating lubricant concentrate for internal combustion engines

Legal Events

Date Code Title Description
MK14 Patent ceased section 143(a) (annual fees not paid) or expired