EP1520915A2 - Verfahren und Apparatur zum teilweisen Beschichten von Oberflächen eines Werkstückes - Google Patents

Verfahren und Apparatur zum teilweisen Beschichten von Oberflächen eines Werkstückes Download PDF

Info

Publication number
EP1520915A2
EP1520915A2 EP04021494A EP04021494A EP1520915A2 EP 1520915 A2 EP1520915 A2 EP 1520915A2 EP 04021494 A EP04021494 A EP 04021494A EP 04021494 A EP04021494 A EP 04021494A EP 1520915 A2 EP1520915 A2 EP 1520915A2
Authority
EP
European Patent Office
Prior art keywords
work
plating
hanger
shield member
piston
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP04021494A
Other languages
English (en)
French (fr)
Other versions
EP1520915A3 (de
Inventor
Wataru Nippon Platec Co. Ltd. Oikawa
Akira Nippon Platec Co. Ltd. Takumi
Tomoyoshi Nippon Platec Co. Ltd. Zenbayashi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Platec Co Ltd
Original Assignee
Nippon Platec Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2003324977A external-priority patent/JP3915762B2/ja
Application filed by Nippon Platec Co Ltd filed Critical Nippon Platec Co Ltd
Publication of EP1520915A2 publication Critical patent/EP1520915A2/de
Publication of EP1520915A3 publication Critical patent/EP1520915A3/de
Withdrawn legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/02—Electroplating of selected surface areas
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00—Electroplating characterised by the article coated
    • C25D7/04—Tubes; Rings; Hollow bodies
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/02—Electroplating of selected surface areas
    • C25D5/022—Electroplating of selected surface areas using masking means
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/16—Electroplating with layers of varying thickness

Definitions

  • This invention relates to a method and an apparatus for partially plating work surfaces, suitable for use in depositing a metallic coating selectively on a specified part of work surfaces to impart thereto particular properties, for example, improved properties as a sliding surface, enhanced resistance to abrasive wear and so forth, while preventing deposition of a metallic coating on other parts of the work surfaces.
  • a piston in addition to sliding surfaces areas to be held in sliding contact with inner surfaces of a cylinder, a piston usually has a surface area or areas on which a seal member is to be fitted on.
  • an annular groove is provided around the circumferential surface of the piston at one or a plural number of positions in the axial direction. The annular groove is so arranged as to retain a seal member therein.
  • seal fitting portions which contain up and down surface irregularities due to existence of seal fitting grooves, can result in deposition of a coating of non-uniform thickness and unstable surface conditions as a result of changes in current density from one part to another. Therefore, seal fitting portions of a piston need precision machining to maintain certain surface accuracy. Taking these factors into consideration, in plating exterior surfaces of a piston for the purpose of improving its resistance to abrasive wear, it is desirable to limit the plating to the sliding surfaces areas, excluding the seal fitting areas and other surface areas from treatments.
  • Preparatory treatments in a plating process usually include degreasing, pickling, alkali etching, acid activation, and zinc replacement, each followed by a rinsing treatment to wash treated surfaces with water. Therefore, in addition to a plating bath, a work is successively immersed in treating baths for the above-mentioned preparatory treatments.
  • a masking tape is bonded on a work before prior to the preparatory treatments, that is to say, a work is immersed in each treating bath in a masked state in the multiple preparatory treatment stage. This means that the masking tape is also immersed in various treating baths along with the work and each time wetted with a treating liquid in each treatment.
  • Each preparatory treatment is followed by a rinsing treatment to wash off a deposited treating liquid from the masking tape.
  • a treating liquid tends to remain and linger in corner portions around raised marginal edges of a masking tape, and in some cases the rinsing treatment fails to completely wash off the lingering treating liquid from the corner portions.
  • a drying mark of a remained treating liquid comes out at the boundaries between the masked and unmasked surface areas of the work in a drying stage subsequent to a plating stage.
  • drying marks i.e., streaks of impurity or contaminant substances, which appears at the boundaries of partially plate surface areas not only impair the appearance of a product but also give rise to a structural problem such as development of corrosion.
  • a method for partially plating work surfaces which comprises the steps of: placing a shield member around and in small gap relation with a non-plating surface area of a work connected to a cathode; immersing the work in a plating bath with an anode located on the outer side of the shield member; conducting current between the anode and cathode to deposit a metallic coating selectively on a specific work surface area or areas uncovered by the shield member.
  • an apparatus for partially plating work surfaces which comprises: a plating bath; a hanger adapted to hold a work in an immersed position in the plating bath and to electrically connect the work to a cathode of a power supply; and a tubular shield member provided on the support means in such a way as to circumvent the work, in non-contacting small gap relation with a non-plating surface of the work to cover the non-plating surface from an anode plate in the plating bath.
  • a metallic coating is deposited on the side of the cathode. At this time, a coating of uniform thickness is formed in case current density between the anode and cathode is constant. If a shielding object is placed between the anode and the cathode, current takes a by-pass route around the shielding object. In a case where the cathode is partly covered by a shielding object, the current density in a cathode portion which confront the shielding object distinctively differs from that of a cathode portion which directly confronts the anode.
  • the shielding object is located closer to the cathode, no current flows to some part of the cathode. If the shielding object is placed face to face and in small gap relation with the cathode, for example, leaving a gap space of several millimeters therebetween, the thickness of a deposited coating gradually continuously decreases from and inward of a boundary of a shielded area covered by the shielding object, and no coating is deposited past certain marginal portions of the shielded area.
  • a shield member is set around a work in small gap relation with the latter, in such a way as to expose work surface areas to be plated while covering non-plating surface areas of the work with the shield member.
  • the shield member is set in non-contacting state relative to the work. Therefore, when an assembly of the work and the shield member is dipped in a treating bath in various pretreatment stages of a plating process, a treating solution or liquid can be urged to flow down and back into a treating bath through the small gaps between the work and the shield member.
  • the treating solution can be completely removed by immersing the assembly of the work and shield member in a rinsing bath. It follows that work surfaces can be cleaned completely free of impurities and contaminants before the work is introduced into a plating bath.
  • a cathode In a plating solution of a plating bath, as a cathode the work is located face to face with an anode. As a result of current conduction between the anode and the cathode, a metallic coating is deposited on work surfaces. Since part of the work is covered by the shield member which is set in small gap relation with the work, a transitional zone of a certain width is formed between an exposed plating work surface and a shielded non-plating work surface, namely, at the boundaries of a shielded work surface. In the transitional zone, the thickness of the deposited coating decreases continuously from a plated surface area toward and inward of a shield surface area.
  • the shape of the shield member is determined in relation with the shape of plating or non-plating work surfaces. For example, in a case where a plating work surface and a non-plating work surface are separated by a horizontal or vertical boundary line, the shield member is located face to face with a non-plating surface area. In a case where a coating is to be deposited on a limited surface area which is surrounded by non-plating work surfaces, an opening is provided in the shield member at a confronting position relative to the plating surface area.
  • the gap space between a work and a shield member wider becomes the transitional zone at the boundaries of a shielded surface area, encompassing even those surface areas on which no coating should be deposited.
  • the gap width is of an extremely small value, say, smaller than 1mm, the transitional zone becomes substantially as narrow as a line.
  • higher skills are required in setting the shield member exactly in an aligned position relative to the work, and it becomes difficult to mount and dismantle the work on and from a work support or mounter member. Nevertheless, for high precision partial plating, it may become necessary to diminish the gap width between a work and a shield member.
  • the shield member is maintained out of contact with work surfaces.
  • part of the shield member may be in contact with a work surface in a case where treating solutions in pretreatment stages can be completely removed from the contacting work surface by rinsing the work in water.
  • the transitional zone in partial plating becomes two wide if the gap width between a work and a shield member is wider than 5mm. Therefore, the gap width between a work and a shield member should be smaller than 5mm, and preferably between 2mm and 5mm.
  • a shield member In the course of a partial plating process, a shield member is used in a plating stage alone. Therefore, if desired, a shield member may be preset in a predetermined position within a plating bath where it can cover a predetermined part of work surfaces when a work is introduced into the plating bath.
  • a shield member in an actual plating process, it is the general practice to prepare a work by a multiple pretreatment and to immerse the work in a plating bath immediately after completion of pretreatments. For this purpose, a work is supported on a hanger, which is transferred by a transport means to introduce the work successively into treating baths in a multiple pretreatment stage.
  • a work which is supported on a hanger is prepared in a plural number of pretreatment baths before introduction into a plating bath, and, after the plating bath, sent to a post-treatment stage for post-treatments including rinsing in a water bath.
  • the treating solution of the bath should be drained off the hanger and off the work and the shield member as well, because otherwise the treating solution would be carried away with the hanger and the work to contaminate treating solutions in the succeeding treating baths and a plating solution in the plating bath.
  • some measures should be taken to urge draining of a treating solution drain each time when the hanger and work are lifted up from a treating bath, for preventing the hanger from carrying out a treating solution from a treating bath and bringing it to a succeeding treating bath.
  • the shield member may be fixedly provided on a hanger, or alternatively it may be detachably set on a hanger if desired. Any way, a work is set at a predetermined position on a hanger to let the shield member function as a masking member to a satisfactory degree. After plating, the plated work is dismantled from the hanger and a fresh work is set on the hanger. At the time of mounting a work on a hanger and dismantling a plated work from a hanger, there is no need for bonding a masking tape on a work surface or peeling off a masking tape from a plated work.
  • a work is supported on and carried by a hanger through the entire line of the plating process, from an initial step of a multiple pretreatment stage to the end of a post-treatment stage.
  • work contact points are provided on the side of a hanger. As soon as the hanger is introduced into a plating bath, these contact points are connected to the cathode of a power supply. That is to say, the contact points are connected to the cathode only when the hanger is immersed in a plating bath. Therefore, the hanger is made of a conducting material, and desirably provided with a rod-like conductive member which is extended out of the plating bath and connected to the cathode of a power supply.
  • the work contacting points may be provided on hooks or the like which also function as work holder means.
  • the shield member may be of a conductive material as long as it is electrically insulated from the current-carrying hanger. However, it is desirable that the shield member is made of an electrically insulating material.
  • a work to be employed for partial plating may be almost any shape.
  • a metallic coating can be deposited on a specific surface area of a work which is in the shape of a flat plate, a square rod, a circular or elliptical column or cylinder, a tube or the like.
  • the irregular surface portion can be utilized as a border of a plating surface area.
  • both work and shield member are removably supported on a hanger.
  • both a work and a shield member are removed from a hanger, and a fresh work is set on the hanger, making adjustments for alignment with a shield member.
  • a work and a shield member on a hanger can be brought into alignment with each by adjusting positions relative to each other or relative to the hanger.
  • a shield member which is separable into right and left parts may be provided on a hanger in such a way that the two separable parts are initially put in open positions and, after setting a work in position, the two parts are closed toward each other and around the work to cover a non-plating surface area or areas of the work completely.
  • a plating specimen P was prepared as shown in Fig. 1, setting a shield member S on a flat metal plate W (e.g., a flat aluminum plate) to be plated, in face to face relation with a plating surface of the metal plate W.
  • the shield member S was made of an electrically insulating material, and formed in a plate-like shape having a predetermined width (larger than 30mm) and a uniform thickness.
  • One end of the shield member S was fixed to the metal plate W, and lifted off the metal plate W by a vertical riser wall, for example, setting the shield member S at a space of 20mm from the metal plate W.
  • the spacing between the metal plate W and the shield member S was gradually narrowed down toward the other end of the shield member S which was also fixed to the metal plate W.
  • the spacing between the shield plate S and the metal plate W is indicated by a graduated scale from 20mm to 0mm. Graduations in the longitudinal direction indicate distances from outer to inner side of the shield plate S at intervals of 5mm.
  • the metal plate W of the plating specimen P was connected to the cathode and the plating specimen P was positioned face to face with the anode to start plating.
  • deposition rate varies across the shielded area depending upon the spacing between the shield member S and the metal plate P to be plated.
  • curve A plotting deposition rates at 20mm spacing positions, approximately 20% higher deposition took place even at a position 20mm inward of the boundary of the shield member S as compared with depositions in unshielded areas.
  • curve B plotting deposition rates at 15mm spacing positions, deposition took place only at a rate of several per cent at a position 20mm inward of the boundary of the shield member S.
  • curve C plotting deposition rates at 10mm spacing positions, deposition did not reach a 20mm inner position on the shielded area.
  • partial plating is possible by the use of the non-contacting shield member S as long as the width of spacing between the shield member S and the metal plate W is smaller than 5mm. It is more preferable to use the shield member with a spacing of approximately 2.5mm and to deposit a coating of approximately 1.5 ⁇ m. Across a transition zone which is approximately as wide as 10mm, the coating thickness gradually and continuously decreases from a plated area to a non-plated area.
  • the partial plating of the present invention is applied to a piston 1 of an automobile reciprocating engine to plate only sliding surface areas of the piston.
  • the present invention is not limited to a work of this sort.
  • the piston 1 is generally in the shape of a lidded round tube, including a piston crown 2, a skirt portion 3, and a boss portion 4 to which a piston pin (not shown) is to be connected.
  • a piston pin (not shown) is to be connected.
  • Formed around the outer periphery of the piston crown 2 are a plural number of annular piston ring grooves 5 in series in the axial direction. A piston ring is fitted in each one of these piston ring grooves 5.
  • a connecting rod which is connected to the piston pin on the boss portion 4 is moved up and down.
  • the piston rings which are fitted in the piston ring grooves 5 and the skirt portion 3 are held in sliding contact with the cylinder. Namely, as far as the main body of the piston 1 is concerned, it is only the skirt portion 3 that is held in sliding contact with the cylinder. More precisely, in order to reduce sliding resistance, sliding surfaces 3a on the skirt portion 3 are limited to certain angular or segmental sections on the opposite sides of the boss portion 4 as shown in Fig. 4.
  • the body of the piston 1 itself is made of aluminum or an aluminum alloy, and an iron coating (or an iron-chromium alloy coating) is plated on the sliding surfaces 3a on the skirt portion 3 of the piston 1 to enhance the resistance to abrasive wear.
  • the partial plating excludes the boss portion 4 which will receive a piston pin, as well as the piston crown 2 which is formed with piston ring grooves 5, for maintaining the finish accuracy of these piston portions with complicate shapes. That is to say, the partial plating is limited to the sliding surfaces 3a.
  • non-plating surface areas need to be masked.
  • a hanger 10 as shown in Figs. 5 to 8 can be employed for partially plating the piston 1.
  • the hanger 10 has a generally L-shaped hanger body proper 11.
  • a hook portion 12 which, in addition to functions as a hook, serves as a power supply contact point.
  • the hook portion 12 is hooked on a rod member 30 (Fig. 9) of a transfer means, which is adapted to repeat an operation of feeding the hanger 10 pitch by pitch in the forward direction and an operation of lifting the hanger 10 up and down to deliver same successively to pretreatment baths, plating bath and post-treatment baths.
  • the hanger body 11 is composed of a vertical hanger rod portion 11a and a mounter rod portion 11b which is formed by bending a lower end portion of the vertical hanger rod portion 11a approximately through 90 degrees.
  • piston ring grooves are provided on the piston crown 2, various solutions in treating baths as well as plating solution can be carried out by the piston 1.
  • arrangements may be made such that the hanger body 11 is tilted to a certain degree when the hook portion 12 is hooked on the transfer rod 30. Otherwise, the angle between the vertical hanger rod portion 11a and the mounter rod portion 11b may be adjusted in such a way as to tilt the piston 1 on the mounter rod portion 11b to a suitable degree.
  • the hanger body 11 is made of a conducting metal, and encased in an insulating tube 13.
  • a support post 14 Erected on the mounter rod portion 11b of the hanger body 11 is a support post 14 to be abutted against the lower side of the piston crown 2.
  • the support post 14 is constituted by a rod member of an electrically insulating material, and serves to sustain the load of the piston 1.
  • four L-shaped angular electrode rods 15 are provided on the mounter rod portion 11b, in laterally projected positions on the front and rear sides of the support post 14. Base ends of these electrode rods 15 are connected to the hanger body 11 in an electrically conductive state. Except tip end portions, the electrode rods 15 are encased in an insulating tube 13. Tip end portions of the electrode rods 15 are exposed and provided with arcuately curved spring electrodes 15a.
  • each one of the four spring electrodes 15a is biased to abut against an inner surface of the skirt portion 3 in transitional regions from an arcuate segmental section with the sliding surface 3a to a boss portion 4.
  • the electrodes 15a are abutted on the outer peripheral side of the piston 1, it is desirable to bring the respective electrodes 15a into abutting engagement with the piston 1 at the positions marked with " ⁇ " in Fig. 6.
  • the spring electrodes 15a are pressed against the inner surface of the piston 1 in such a way as to hold the piston 1 stably at a predetermined position.
  • a shield member 20 is attached to the outer periphery of the insulating tube 13 encasing the vertical hanger rod portion 11a of the hanger body 11.
  • the shield member 20 is composed of upper and lower tubular enclosures 21 and 22.
  • the upper tube 21 is fitted in the lower tube 22 to a predetermined extent, and fixed in that position by the use of an adhesive or the like.
  • the shield member 20 is separable into the upper tube 21 and the lower tube 22 and provided with openings 23 at opposite lateral sides to expose the sliding surfaces 3a on the skirt portion 3.
  • the shield member 20 is not necessarily required to be a split type.
  • the shield member 20 may be constituted by a single tubular structure which is provided with openings at opposite lateral sides similarly to the opening 23.
  • T-shaped connecting arm 24 is extended out from the outer periphery of the shield member 20, and a clamp plate 25 is fixed to the outer end of the connecting arm 24 by a plural number of screws 26 in such a way as to firmly grip the insulating tube 13 of the hanger body 11 therebetween.
  • the shield member 20 may be of any material because it is electrically insulated from the hanger body 11 by the insulating tube 13. However, it is desirable that the shield member 20 is a synthetic resin molding.
  • the piston 1 is hooked on a hanger transfer rod 30 of the transfer means which is adapted to lift the piston 1 up and down in combination with pitch by pitch forward feed actions.
  • the hanger transfer rod 30 is preferred to be of a square shape in cross-section.
  • iron is plated on the sliding surfaces 3a of the piston 1 in a plating bath 31 as shown in Fig. 10.
  • the plating bath 31 is filled with an electrolyte, and anode plates 32 are immersed in the bath.
  • the square hanger transfer rod 30 is located between the anode plates 32.
  • the anode plates 32 are connected to the anode of a direct-current power supply 33.
  • the cathode is electrically connected to the hook 12 of the hanger 10 when the hanger transfer rod 30 is located over the plating bath 31.
  • the piston 1 By current conduction between the anode plates 32 and the hanger transfer rod 30, an iron coating is deposited only on the sliding surfaces 3a on the skirt portion 3 of the piston as a result of partial plating.
  • the piston 1 may be held in a still state, but it may be oscillated in vertical or lateral directions to complete the plating more efficiently.
  • the work is passed through post-treatment stages including rinsing, tin plating, rinsing and drying.
  • the post-treatments include tin plating of iron plated surfaces to put the sliding surfaces 3a in more fit conditions relative to the cylinder.
  • the post-treatments may not be necessarily required to include tin plating.
  • the piston 1 is set on and carried by the hanger 10 from the start of the pretreatments till the end of post-treatments. That is to say, the piston 1 is set on the hanger 10 before starting pretreatments, and removed from the hanger 10 after the post-treatments.
  • the shield member 20 which is assembled with the hanger 10 is open on the top side. Therefore, the piston 1 can be placed in position within the shield through the open top side of the latter. After completing a plating process, the piston 1 can be removed from the hanger 10 simply by lifting it up through the open top end of the shield member 20. Namely, the hanger 10 is arranged to leave the top side of the shield member in an open state for the purpose of facilitating mounting and dismantling of the piston 1 onto and from the hanger 10.
  • the piston 1 can be mounted onto and dismantled from the hanger 10 in an extremely facilitated manner. Besides, since there is no need for bonding a masking tape on non-plating portions of the piston 1 in a preparatory stage of the plating process as discussed in detail hereinlater, time and labor can be saved to a significant degree.
  • the piston 1 When the piston 1 is set in position on the hanger 10, it is retained in a non-contacting state relative to the inner surface of the shield member 20 which is assembled with the hanger 10, and its outer periphery is substantially uniformly spaced from the shield member 20. Since the shield member 20 is provided fixedly on the hanger 10, the piston 1 should always be in the same positional relations with the shield member 20 when set on the hanger 10.
  • the support post 14 is abutted against the lower side of the piston crown 2, while the spring electrodes 15a are resiliently abutted against the inner side of the skirt portion 3 of the piston 1 at four separate points.
  • the piston 1 is automatically oriented into a concentric aligned position relative to the shield member 20 as soon as it is placed on the hanger 10. Namely, the piston 1 is almost uniformly spaced from the shield member 20 all around its outer periphery. Besides, the piston 1 can always be set in the same direction relative to the shield member 20 and the hanger 10. Therefore, the sliding surfaces 3a on the skirt portion 3 of the piston 1 are always positioned face to face with the openings 23 in the shield member 20. That is to say, only the sliding surfaces 3a of the piston 1 are exposed through the openings 23, while the piston crown 2 and boss portion 4 of the piston 1 are covered in the shield member 20.
  • the hanger 10, with the piston 1 set in position in the above-described manner, is immersed in the plating bath 31, whereupon current conduction takes place between the anode plates 32 and the rod 30.
  • current-carrying contact points are established between the hook 12 of the hanger 10 and the hanger body 11 and between each one of the electrodes 15a on the electrodes rods 15 and the piston 1.
  • a metallic coating is deposited on outer surfaces of the piston 1. More specifically, a metallic coating of uniform thickness is deposited exclusively on the sliding surfaces 3a of the piston 1 alone.
  • the entire body of the piston 1 is immersed in the electrolyte in the plating bath 31.
  • the current density becomes higher at an edgy portion which exists in the transitional portion from the sliding surface 3a to the boss portion 4.
  • the sliding surfaces 3a alone that are allowed to directly face an anode plate 32, and other portions of the piston 1 are intervened and covered by the shield member 20.
  • the deposition continuously decreases in a transitional zone of about 10mm which intervenes a plated area and a non-plated area.
  • the width of the transitional zone can be minimized by further narrowing the spacing between the piston and the shield member 20.
  • the shield member 20 in order to prevent current concentration at edgy portions between the sliding surface 3a and the boss portion 4 and at lower end portions of the sliding surface 3a and to distribute current uniformly over the entire sliding surfaces 3a, it is desirable to overlap side and lower portions of the shield member 20 partly by several millimeters on the sliding surfaces 3a to have substantially uniform current distribution over the entire sliding surfaces 3a.
  • the extent of overlapping of the shield member 20 is determined suitably in consideration of shapes of the transitional portion from the sliding surface 3a to the boss portion 4 and of the lower end portion of the sliding surface 3a, that is to say, taking into account whether or not these portions contain edges or, in other words, whether or not these portions are rounded off.
  • the exterior surfaces of a work, the piston 1 in this case are in a completely exposed state without contacting any other member, so that a treating solutions which are used in a pretreatment stage, for example, a treating solution in an acid or alkali treatment stage can be completely removed in a subsequent rinsing stage. Therefore, all of retreating solutions are removed completely form the work before introducing same into the plating bath 31 to undergo partial plating. It follows that the partially plated piston 1 is very satisfactory in appearance because it is free of deposition of impurities which would give rise to problems like corrosion.
  • Figs. 11 through 17 Shown in Figs. 11 through 17 is a second embodiment of the present invention.
  • those component parts which are same as or equivalent with the counterparts in the foregoing first embodiment are simply designated by the same reference numerals or characters to avoid repetitions of the same explanations.
  • the second embodiment arrangements are made so that a work in the form of a piston 1 as well as a shield member 60 is removably set on a hanger 40.
  • the piston 1 and the shield member 60 are set on the hanger in an inclined state, for example, with an inclination angle of 15 to 30 degrees relative to the hanger 40.
  • the hanger 40 is largely constituted by a vertical hanger bar member 42 and a mounter member 43 which is connected to a lower end portion of the vertical hanger bar member 42.
  • the mounter member 43 is provided with support strips 43a and 43b which are crossed at the lower end of the vertical hanger bar member 42.
  • the vertical hanger bar member 42 is provided with a hook portion 42a at its top end, and the hook portion 42a is hooked on a hanger transfer rod of a transfer means, by which the work is fed pitch by pitch in the forward direction and lifted up and down at predetermined positions although not shown in the drawings.
  • a support post 44 is erected at the intersection of the support strips 43a and 43b.
  • a piston receptacle member 45 Provided at the top end of the support post 44 are a piston receptacle member 45, and a pair of piston retainer springs 46 which are provided opposingly at the opposite ends of the piston receptacle strip 45.
  • the opposite ends of the piston receptacle strip 45 are bent at right angles, that is to say, are turned upward for abutting engagement with inner end face of the piston crown 2 of the piston 1.
  • Each one of the piston holder springs 46 is constituted by a leaf spring which is extended obliquely downward away from an upper end portion of the support post 44 over a predetermined length, then bent obliquely inward toward the support post 44 and finally bent obliquely outward away from the support post 44, providing a shoulder portion 46a and an outwardly turned distal end portion 46b.
  • the most projected shoulder portions 46a of the retainer springs 46 which serve as spring force exerting portions are pressed against inner surfaces of the skirt portion 3 of the piston 1.
  • the outwardly turned end portions 46b function as an escape to avert the lower end of the piston 1.
  • positioning/ support pins 47 are erected on front and rear end portions of the support strip 43a which are extended in forward and rearward directions.
  • pedestal pins 48 are erected on opposite end portions of the support strip 43b which is extended in the transverse direction of the hanger.
  • the shield member 60 is removably supported on the mounter member 43 of the hanger 40 by these support pins 47 and pedestal pins 48.
  • gripper leaf springs 49 are attached on opposite end portions of the support strip 43b thereby to clamp the outer periphery of the shield member 60 from outside.
  • gripper leaf springs 49 which rise upward from the support strip 43b are bent in the inward direction and then in the outward direction to provide angularly bent clamp portions 49a which are projected inward or toward each other for abutting engagement with the outer periphery of the shield member 60. Above the clamp portion 49a, each gripper leaf spring 49 is bent outward. Thus, the inwardly projected clamp portions 49a serve to clamp the outer periphery of the shield member 60 from opposite sides. Further, outwardly bent upper end portions 49b of the gripper leaf springs 49 serve as guide surfaces for the shield member 60, urging the latter into position inward of the gripper leaf springs 49.
  • the shield member 60 is provided with a shield body 63 in the form of a stepped tube having an upper small diameter section 61 and a lower large diameter section 62.
  • a pair of flanges 64 are projected radially outward from at radially opposite positions which are spaced from each other by 180 degrees.
  • a positioning hole 65 is bored in each one of these flanges 64 to receive a head portion of a support pin 47 which is provided on the part of the hanger 40.
  • the inside diameter of the small diameter section 61 of the shield member 60 is slightly larger than the outside diameter of the piston crown 2 of the piston 1, more specifically, there is a diametrical differential of less than 2.5mm between the small diameter portion 61 of the shield member 60 and the piston crown 2.
  • the inside diameter of the large diameter section 62 is sufficiently larger than the outside diameter of the skirt portion 3, more specifically, there is a diametrical differential larger than 20mm between the large diameter portion 62 and the skirt portion 3.
  • Openings 66 each with a predetermined angle range in the radial direction are provided in the shield member 60 at 90 degrees positions on the opposite sides of the flanges 64.
  • each opening 66 ranges from a lower end portion of the small diameter section 61 to an intermediate portion of the large diameter section 62.
  • the openings 66 are formed to have an angular range of approximately 45 degrees around the outer periphery of the large diameter section 62 of the shield member 60.
  • each support pin 17 serves as positioning means for the shield member 60 and at the same time as support means for supporting the shield member 60 in cooperation with the pedestal pins 48.
  • each support pin 17 is provided with a round-headed rod portion 47a which is projected upward from a pedestal portion 47b, and a screw portion 47c which is projected downward from the pedestal portion 47b.
  • the screw portion 47c is threaded into a female screw shaft 47d which is fixedly provided on the support strip 43a.
  • a height adjustor ring 50 Interposed between the screw portion 47c and the female screw shaft 47d is a height adjustor ring 50.
  • each one of the pedestal pins 48 is provided with a flat-topped pedestal portion 48a, which is threaded into a female screw shaft 48b.
  • a height adjustor ring 51 is interposed between the pedestal portion 48a and the female screw shaft 48b, so that the height or the position of the top end face of the pedestal portion 48a can be raised or lowered by adjusting the degree of tightening of the pedestal portion 48a relative to the female screw shaft 48b.
  • the shield member 60 can be supported on the hanger 40 in a stabilized state, and possibilities of positional deviations of the shield member 60 can be precluded by employing a minimum value for the diametrical differential between the support pin 47 and the positioning hole 65.
  • the gripper leaf springs 49 are provided in opposing positions on the hanger 40.
  • the shield member 60 As the shield member 60 is set in position on the hanger 40, the inwardly projecting clamp portions 49a of the gripper leaf springs 49 are pushed apart from each other by the shield member 60 and then brought into abutting engagement with the outer periphery of the large diameter section 62 of the shield member 60. Thus, the shield member 60 is fixedly gripped in position on the hanger 40 by the action of the gripper leaf springs 49.
  • the mounter member 43 of the hanger 40 is tilted through a certain angle, preferably, through an angle of from 15 to 30 degrees relative to the vertical hanger bar 42. Accordingly, the piston 1 which is supported on the hanger 40 as well as the shield member 60 which is set on the hanger 40 in such a way as to cover in the piston 1 is held in a tilted state. Therefore, when the vertical hanger bar 42 of the hanger 40 is lowered vertically into the plating bath 31 as shown in Fig. 17, the piston 1 and the shield member 60 are tilted forward along the opposing surfaces of the anode plates 32. At this time, each opening 66 in the shield member 60 is faced toward an anode plate 32.
  • the hanger 40 itself is made of a conductive metal and encased in an insulating cover. However, the insulating cover is stripped off at the hook portion 42a which serves as a contact point for power supply to the piston 1, at the most projected shoulder portions 46a of the piston holder leaf springs 46 which are held in contact with the piston 1, and at top end faces 45a of the upwardly bent end portions of the piston receptacle strip 45 which also function as current conducting contact points.
  • the hanger 40 as well as the piston 1 and the shield member 60 which are mounted on the hanger 40 are set in a tilted posture in such a way as to exclude flat horizontal surfaces. Therefore, when the hanger 40 is lifted up after immersion in a plating bath or other treating bath, the plating or treating solution is urged to flow down along tilted surfaces and smoothly get back to the plating or treating bath. Accordingly, before coming to an end of an uplifting stroke, the plating or treating solution is substantially completely drained off the piston 1, the shield member 60 and the hanger 40, including dipped surface portions on the top end of the piston 1. As a result, it becomes possible to reduce the consumption of the plating and treating solutions which are carried out from the respective baths with the hanger 40, that is to say, it becomes possible to prevent contamination of a succeeding bath by a solution of a preceding bath.
  • the piston 1 and the shield member 60 which is placed partially around the piston 1 in small gap relation with the latter can be separately and independently set on and off the hanger 40.
  • the support post 44 is provided on the hanger 40 for mounting a piston 1 thereon.
  • the piston holder leaf springs 46 are received in the inner cavity of the piston 1, and the most projected portions 46a of the leaf springs 46 are resiliently deformed by lower marginal end portions of the skirt portion 3 of the piston 1. That is to say, the two piston holder leaf springs 46 which are provided in radially opposing positions are flexed toward each other as the piston 1 is put on the support post 44.
  • the piston 1 is retained in position on the support post 44 by gripping actions of the piston holder leaf springs 46 as soon as an inner surface of the piston crown portion 2 is set on the piston receptacle strip member 45 at the top end of the support post 44.
  • the shield member 60 is set on the hanger 40 in such a way as to circumvent the piston 1 in small gap relation therewith as described above.
  • the lower end of the shield member 60 gets into the space between the inwardly bent clamp portions 49a of the paired gripper leaf springs 49 via the outwardly bent upper end portions 49b, spreading apart the inwardly bent clamp portions 49a.
  • the support pins 47 are placed in the positioning holes 55 in the flange portions 54 of the shield member 60.
  • the shield member 60 is oriented to its position on the hanger 40, and, as the support pins 47 are fully inserted in the positioning holes 55, the lower end of the shield member 60 is set on the top end surfaces of the pedestal portions 47b of the support pins 47 and the pedestal portions 48a of the pedestal pins 48 and at the same time gripped by the inwardly bent clamp portions 49a of the gripper leaf springs 49.
  • the shield member 60 is fixedly retained in position on the mounter member 43 of the hanger 40.
  • the shield member 60 Upon completing a plating process, firstly the shield member 60 is dismantled from the hanger 40. After removing the shield member 60, the partially plated piston 1 can be easily picked up from the hanger 40, with no possibilities of collision against any other member of the hanger 40.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating Methods And Accessories (AREA)
EP04021494A 2003-09-17 2004-09-09 Verfahren und Apparatur zum teilweisen Beschichten von Oberflächen eines Werkstückes Withdrawn EP1520915A3 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2003324977A JP3915762B2 (ja) 2002-11-28 2003-09-17 部分メッキ装置
JP2003324977 2003-09-17

Publications (2)

Publication Number Publication Date
EP1520915A2 true EP1520915A2 (de) 2005-04-06
EP1520915A3 EP1520915A3 (de) 2006-11-02

Family

ID=34270087

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04021494A Withdrawn EP1520915A3 (de) 2003-09-17 2004-09-09 Verfahren und Apparatur zum teilweisen Beschichten von Oberflächen eines Werkstückes

Country Status (4)

Country Link
US (1) US7402231B2 (de)
EP (1) EP1520915A3 (de)
KR (1) KR100706069B1 (de)
CN (1) CN100378252C (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006042049A1 (de) * 2006-09-05 2008-03-06 Mahle International Gmbh Vorrichtung zum galvanischen Beschichten eines Kolbens

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100715023B1 (ko) * 2005-04-22 2007-05-09 임경락 차량용 피스톤 부분표면처리장치
US8057644B2 (en) * 2005-07-26 2011-11-15 Federal-Mogul World Wide, Inc. Process and apparatus for plating articles
DE102005041404A1 (de) * 2005-09-01 2007-03-08 Mahle International Gmbh Vorrichtung zum Haltern eines Kolbens in einer Anlage zum Beschichten von Kolben
CN101368284B (zh) * 2007-08-15 2010-10-06 富葵精密组件(深圳)有限公司 电镀装置
FR2944717B1 (fr) * 2009-04-27 2012-08-17 Peugeot Citroen Automobiles Sa Procede de metallisation partielle d'une piece en matiere plastique, en particulier d'un masque de feu d'eclairage et/ou de signalisation de vehicule.
DE102010047906B4 (de) * 2010-10-11 2014-09-11 MTU Aero Engines AG Verfahren zur elektrochemischen partiellen Beschichtung eines Bauteils sowie Vorrichtung
CN101967639A (zh) * 2010-10-25 2011-02-09 成都雷思特电子科技有限责任公司 微波毫米波铝合金结构件表面混合处理方法
EP2691976A4 (de) * 2011-03-29 2014-09-17 Natcore Technology Inc Verfahren zur steuerung der dicke einer siliciumoxidschicht
US20140339077A1 (en) * 2012-01-11 2014-11-20 Honda Motor Co., Ltd. Plating device
US9371927B1 (en) * 2013-05-31 2016-06-21 Marathon Valve LLC Pressure relief valve
DE102014226058A1 (de) 2014-12-16 2016-06-16 Federal-Mogul Nürnberg GmbH Aufnahme für einen Kolben eines Verbrennungsmotors zur Bearbeitung des Kolbens
CN105568333B (zh) * 2015-12-31 2018-10-16 中国电子科技集团公司第十八研究所 一种铜导电翅片局部镀银装置
SG11202001662SA (en) * 2017-09-07 2020-03-30 Acm Res Shanghai Inc Plating chuck
TWI791785B (zh) * 2019-03-06 2023-02-11 大陸商盛美半導體設備（上海）股份有限公司 電鍍夾盤
KR102134170B1 (ko) * 2020-03-04 2020-07-16 브이앤씨테크 주식회사 환형 구조물의 도금용 랙
US11453954B2 (en) 2020-10-07 2022-09-27 Honeywell International Inc. Masking and sealing system for multi-step surface treatment
CN112251782A (zh) * 2020-10-30 2021-01-22 深圳市宏钢机械设备有限公司 一种局部电镀金的方法、装置和产品
CN113463153B (zh) * 2021-07-02 2023-04-25 宁波奉化金盛镀业有限公司 一种表面电镀工艺
KR102428851B1 (ko) * 2022-05-18 2022-08-04 손규태 부스바의 전기도금장치

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1115265A (en) * 1964-12-19 1968-05-29 Electro Finish Plating rack
JPH07180084A (ja) * 1993-12-21 1995-07-18 Nkk Corp 鍍金遮蔽装置
DE19722983A1 (de) * 1996-08-09 1998-02-12 Atotech Deutschland Gmbh Verfahren zur elektrochemischen Behandlung von stabförmigem Behandlungsgut und Vorrichtung zur Durchführung des Verfahrens
DE19932785C1 (de) * 1999-07-14 2000-11-16 Atotech Deutschland Gmbh Verfahren und Vorrichtung zum präzisen Justieren von Abschirmmasken bei der elektrochemischen Behandlung von stabförmigem Behandlungsgut

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2362228A (en) * 1941-06-12 1944-11-07 Bell Telephone Labor Inc Method of forming contacts on metal oxide-metal rectifiers
JPS6044062B2 (ja) 1982-02-26 1985-10-01 株式会社クボタ 遠心鋳造管用中子の塗型装置
JPS6324267A (ja) 1986-07-16 1988-02-01 Canon Inc 現像装置
CN87107696A (zh) 1987-06-13 1988-07-27 北京开关厂 屏蔽法局部镀银
JPH01149464A (ja) 1987-12-04 1989-06-12 Nec Corp 半導体装置
US4904365A (en) * 1988-02-29 1990-02-27 Trinity Industrial Corporation Electrodeposition coating facility
US5368719A (en) * 1993-05-12 1994-11-29 Hughes Aircraft Company Method for direct plating of iron on aluminum
US5486281A (en) * 1993-10-15 1996-01-23 United Technologies Corporation Method for CBN tipping of HPC integrally bladed rotors
JP3492457B2 (ja) 1995-12-20 2004-02-03 今村 弘 ワーク取付用ハンガー
JP3342394B2 (ja) 1998-03-26 2002-11-05 松下電工株式会社 電気メッキ用治具
JP3586420B2 (ja) 2000-03-21 2004-11-10 株式会社杉浦製作所 袋状ワークのめっき方法及びめっきライン

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1115265A (en) * 1964-12-19 1968-05-29 Electro Finish Plating rack
JPH07180084A (ja) * 1993-12-21 1995-07-18 Nkk Corp 鍍金遮蔽装置
DE19722983A1 (de) * 1996-08-09 1998-02-12 Atotech Deutschland Gmbh Verfahren zur elektrochemischen Behandlung von stabförmigem Behandlungsgut und Vorrichtung zur Durchführung des Verfahrens
DE19932785C1 (de) * 1999-07-14 2000-11-16 Atotech Deutschland Gmbh Verfahren und Vorrichtung zum präzisen Justieren von Abschirmmasken bei der elektrochemischen Behandlung von stabförmigem Behandlungsgut

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 1995, no. 10, 30 November 1995 (1995-11-30) & JP 07 180084 A (NKK CORP; others: 01), 18 July 1995 (1995-07-18) *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006042049A1 (de) * 2006-09-05 2008-03-06 Mahle International Gmbh Vorrichtung zum galvanischen Beschichten eines Kolbens
US7964069B2 (en) 2006-09-05 2011-06-21 Mahle International Gmbh Device for galvanic coating of a piston

Also Published As

Publication number Publication date
CN100378252C (zh) 2008-04-02
KR20050028797A (ko) 2005-03-23
CN1609282A (zh) 2005-04-27
US20050056541A1 (en) 2005-03-17
EP1520915A3 (de) 2006-11-02
US7402231B2 (en) 2008-07-22
KR100706069B1 (ko) 2007-04-11

Similar Documents

Publication Publication Date Title
US7402231B2 (en) Method and apparatus for partially plating work surfaces
US6409903B1 (en) Multi-step potentiostatic/galvanostatic plating control
US3065153A (en) Electroplating method and apparatus
JP4748037B2 (ja) メッキ用ハンガー、ワークの部分メッキ装置及び方法並びにピストン
KR101587819B1 (ko) 전기화학적 프로세서용 컨택 링
US7560014B2 (en) Method for airfoil electroplating
JP3915762B2 (ja) 部分メッキ装置
US4294670A (en) Precision electroplating of metal objects
JP2002523625A (ja) 棒状被処理物の部分的な電気化学的処理用装置
US5364523A (en) Method of electroplating half sliding bearings
US3616287A (en) Method for hard-chrome plating large metallic surfaces
GB1406081A (en) Method for electrolytic deposition
US4659447A (en) Apparatus and installation for producing an electrolytic metallic deposit of constant thickness
KR101776782B1 (ko) 원통형 피도금체 도금을 위한 도금전극 유닛을 갖는 도금장치
US3445351A (en) Process for plating metals
US3751354A (en) Electroplating cell including magnetic means to couple concave workpieces to a plating rack
JPH01162798A (ja) 電気めっき用コンダクターロールの付着金属除去装置
KR20030062501A (ko) 다수의 전원장치를 구비하는 도금장치 및 그를 이용한도금방법
JP2023108343A (ja) ロッドの製造方法
KR200430588Y1 (ko) 균일 도금을 위한 차폐유도판
JPH0488192A (ja) 部分めっき装置
JPH10204611A (ja) 鉄系物品の浸硫処理法
EP1081252A1 (de) Verbessertes selektives Plattierungsverfahren
KR101786712B1 (ko) 아노다이징 소재 공급 시스템
KR20050063446A (ko) 균일한 도금층 형성방법

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL HR LT LV MK

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL HR LT LV MK

17P Request for examination filed

Effective date: 20070502

AKX Designation fees paid

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR

17Q First examination report despatched

Effective date: 20100805

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20140401