EP1509628A1 - Method for refining concentrate containing precious metals - Google Patents
Method for refining concentrate containing precious metalsInfo
- Publication number
- EP1509628A1 EP1509628A1 EP03730239A EP03730239A EP1509628A1 EP 1509628 A1 EP1509628 A1 EP 1509628A1 EP 03730239 A EP03730239 A EP 03730239A EP 03730239 A EP03730239 A EP 03730239A EP 1509628 A1 EP1509628 A1 EP 1509628A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- matte
- smelting furnace
- suspension smelting
- created
- conducted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 45
- 239000010970 precious metal Substances 0.000 title claims abstract description 37
- 239000012141 concentrate Substances 0.000 title claims abstract description 34
- 238000007670 refining Methods 0.000 title claims abstract description 12
- 238000003723 Smelting Methods 0.000 claims abstract description 55
- 239000000725 suspension Substances 0.000 claims abstract description 49
- 239000002893 slag Substances 0.000 claims abstract description 27
- 239000000463 material Substances 0.000 claims abstract description 7
- 238000002844 melting Methods 0.000 claims abstract description 6
- 230000008018 melting Effects 0.000 claims abstract description 6
- 230000004907 flux Effects 0.000 claims abstract description 5
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 4
- 239000003500 flue dust Substances 0.000 claims abstract description 4
- 239000012495 reaction gas Substances 0.000 claims abstract description 4
- 239000002699 waste material Substances 0.000 claims abstract description 4
- 238000002386 leaching Methods 0.000 claims description 12
- 238000009854 hydrometallurgy Methods 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 32
- 229910052759 nickel Inorganic materials 0.000 description 15
- 230000008569 process Effects 0.000 description 15
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 13
- 239000007789 gas Substances 0.000 description 10
- 239000010949 copper Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
- 229910052802 copper Inorganic materials 0.000 description 7
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 4
- 229910052763 palladium Inorganic materials 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 229910000365 copper sulfate Inorganic materials 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 239000013067 intermediate product Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000002918 waste heat Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical class Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000009853 pyrometallurgy Methods 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/02—Obtaining nickel or cobalt by dry processes
- C22B23/025—Obtaining nickel or cobalt by dry processes with formation of a matte or by matte refining or converting into nickel or cobalt, e.g. by the Oxford process
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/02—Obtaining noble metals by dry processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- the invention relates to a method for refining precious metal concentrate defined in the preamble of claim 1.
- a supension smelting furnace there is used a supension smelting furnace; the matte created in said furnace is conducted into hydrometallurgical treatment, and the slag is reduced in an electric furnace.
- the metallicized matte created in the electric furnace is either fed back into the suspension smelting furnace or to hydrometallurgical treatment together or separately with the matte from the suspension smelting furnace.
- precious metals Au, Ag, Pt, Pd, Rh and Ir are in the wolrld produced by using various different manufacturing methods.
- Gold is produced either directly, by making use of the special features of gold, or as a side product in traditional copper production.
- the majority of world's platinum and a remarkable share of palladium is produced by using primary electric furnaces.
- the majority of world's palladium production is mainly based on nickel side production from ores by means of the suspension technique, where the obtained intermediate product is nickel concentrate.
- An essential step in both processes is the use of a converter as part of the process.
- the use of a converter in the processes is harmful, as sulfur dioxide emissions and intermediate products caused by the transportation of melts are increased.
- Mattes obtained in the above described ways are further treated in hydrometallurgic plants. There are several different hydrometallurgical processes for the further refining of matte obtained from smelting, when precious metals should be recovered as side products.
- the Finnish patent application 890 395 describes a manufacturing method and arrangement for producing high-grade nickel matte. According to said method, high-grade nickel matte is directly produced in a suspension smelting furnace.
- At least the slag from the suspension smelting furnace is reduced in an electric furnace, where the electric furnace slag and the metallicized matte are formed, so that at least part of the metallicized matte is returned as feed to the suspension smelting furnace.
- the object of the present invention is to bring forth a new type of method for refining precious metal concentrate, so that the precious metals are advantageously recovered by making use of the suspension smelting process.
- Another object of the invention is to realize a refining process for a concentrate, the value of which lies in the precious metals contained therein, and where the nickel and/or copper only represent a side product in value.
- the method according to the invention for refining precious metal concentrate has several advantages.
- the invention relates to a method for refining precious metal concentrate, and according to said method, at least the treated precious metal concentrate, the reaction gas, the slag forming agent, i.e. flux, and the flue dust are together fed into the reaction shaft of a suspension smelting furnace, so that in the suspension smelting furnace, there are created separate phases, matte and slag.
- the slag created in the suspension smelting furnace is conducted to an electric furnace, where metallicized matte and waste slag are formed, whereafter the matte from the suspension smelting furnace is conducted to hydrometallurgical treatment, and the slag conducted into the electric furnace is processed together with a reducing agent and possibly an agent that lowers the melting point or improves fluidity, and the created metallicized matte is conducted either to hydrometallurgical treatment or back into the suspension smelting furnace.
- a suspension smelting furnace such as a flash smelting furnace.
- the method according to the invention for refining precious metal concentrate can also be utilized so that part of the supplied precious metal concentrate is replaced by sulfide concentrate.
- the process according to the invention essentially differs from said publications (FI patent 890,395 and FI patent 94538), because the raw material used in the process is precious metal concentrate and not nickel concentrate, wherefore high-grade nickel matte is not created.
- the matte obtained from a suspension smelting furnace and the metallicized matte obtained from an electric furnace are granulated prior to the hydrometallurgical treatment.
- the matte from a suspension smelting furnace and the metallicized matte from an electric furnace are processed either in the same hydrometallurgical process or in different processes.
- the matte from the suspension smelting furnace is leached at least in one step.
- the desired components of the concentrate are recovered.
- the metallicized matte from the electric furnace is leached at least in one step in the hydrometallurgical process.
- the leaching of the matte takes place in sulfate atmosphere.
- the leaching takes place in chloride atmosphere.
- precious metals are recovered from the leach residue.
- the ferrous precipitate created in the hydrometallurgical treatment of matte and metallicized matte is conducted to a suspension smelting furnace.
- the energy contained by the raw material such as the oxidizing heat contained by iron and sulfur
- the matte phase is separated from slag in two steps, both in the suspension smelting furnace and in the electric furnace, the recovery of precious metals is remarkably increased when compared to processing in a primary electric furnace.
- the amount of created exhaust gases is remarkably smaller than when using only a primary electric furnace in the treatment of the concentrate.
- dust losses are reduced.
- a relatively smaller quantity of gas facilitates the recovery and manufacturing of sulfur dioxide either into pure sulfur dioxide or into sulfuric acid. Now the necessary investments related to the gas and sulfur dioxide are smaller than in a process based on a corresponding primary electric furnace fulfilling the ecological requirements.
- the elimination of the use of converters results in the same advantages described above as the fact that primary electric furnaces are not used anymore.
- FIG. 1 illustrates a suspension smelting furnace 1 to be used in the method according to the invention, such as a flash smelting furnace.
- a suspension smelting furnace 1 In the top part of the furnace reaction shaft 3 there is fed precious metal concentrate 9, oxidizing reaction gas 10, slag-forming agent, i.e. flux 11 and flue dust 12 obtained from the cooling of exhaust gases from the waste heat boiler 6.
- oxidizing reaction gas 10 slag-forming agent, i.e. flux 11 and flue dust 12 obtained from the cooling of exhaust gases from the waste heat boiler 6.
- iron precipitate created in the hydrometallurgic units 15 and 16 in the treatment of the matte.
- the ingredients fed into the reaction shaft 3 react with each other, and on the bottom of the settler 4, there is formed a matte layer 8 and on top of it a slag layer 7.
- the gases created in the suspension smelting furnace are removed through the uptake shaft 5 into a waste heat boiler 6, wherefrom the created flue dusts 12 are recirculated back into the suspension smelting furnace, and the exhaust gases 18 are conducted for further processing.
- a remarkable share of the concentrate 9 are precious metals that are accumulated in the settler, mainly in the matte phase 8.
- the matte 8 is subjected to granulation 17, and it is conducted into hydrometallurgical further processing 15, where the matte is leached, in which case the precious metals are leached last.
- the slag 7 created in the suspension smelting furnace is conducted into an electric furnace 2, in which, apart from oxidized slag and reducing agent, there also is fed, if necessary, a sulfurous or other material for lowering the melting point or for improving the fluidity in order to adjust the melting point of the matte to be created.
- a sulfurous or other material for lowering the melting point or for improving the fluidity in order to adjust the melting point of the matte to be created.
- metallicized matte 14 and slag 13 In the electric furnace, as a result from the reduction process, there is created metallicized matte 14 and slag 13. Without a sulfur addition, the sulfur content of the metallicized matte may remain very low, and respectively the melting point and viscosity may remain high.
- the precious metals are mainly transferred into a matte phase 14, which is further conducted, according to the invention, either to hydrometallurgical treatment 16, together with the matte from the suspension smelting furnace or separately.
- Another alternative is to recirculate the metallicized matte 14 or part thereof back into the suspension smelting furnace 1.
- the matte Prior to the hydrometallurgical treatment 16 of the metallicized matte 14, the matte is subjected to granulation 19.
- the slag 13 created in the electric furnace 2 is waste slag, i.e. it is discarded.
- the precious metals are recovered in a hydrometallurgical process.
- precious metals are mainly trasferred to the matte phase, from which they are recovered in a hydrometallurgical process.
- Both the matte 8 from the suspension smelting furnace and the metallicized matte 14 from the electric furnace are leached either in the same leaching line or separately. The leaching steps are dependent on the contents of the precious metal concentrate to be treated.
- the leaching is carried out in a sulfate atmosphere, i.e. the solution at some stage contains sulfate.
- the cobalt and nickel possibly contained in the concentrate are leached in the first selective pressure leaching step as sulfate.
- the first selective pressure leaching step there also is leached iron that can at the same time be precipitated as iron hydroxide.
- Nickel is recovered as salt, or it is turned into metal in the electrolysis.
- copper is leached as copper sulfate, which can be separated as such or turned into metallic copper in the electrolysis. Copper sulfate can also be crystallized and fed back into the suspension smelting furnace after drying.
- the sulfate balance of the solution can be affected.
- the precious metals are left in the leach residue.
- the precious metal content of the leach residue is increased for instance by means of a strong sulfuric acid and sulfur dioxide treatment.
- the created concentrated precipitate is a good raw material for various precious metal refineries.
- the leaching is carried out in a chloride atmosphere, in which case there is used chloride gas in the leaching, and in the solution, there are created cobalt, nickel, copper and iron chlorides.
- the method according to the invention was applied for the precious metal concentrate mentioned above, so that part of said concentrate was replaced by nickel concentrate.
- the iron precipitate created in the hydrometallurgic unit was recirculated back into the suspension smelting furnace.
- the abbreviation PGM means precious metals.
- the gas created in a suspension smelting furnace contains more than 10% sulfur dioxide, and is thus suitable for the production of sulfuric acid.
- the exhaust gases from the electric furnace are nearly free of sulfur dioxide, and consequently do not strain the environment.
- the method described above also functions without nickel and even so that a large part of the copper is replaced by iron, if the source material does not contain a sufficient amount of copper.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI20020835A FI114808B (sv) | 2002-05-03 | 2002-05-03 | Förfarande för förädling av ädelmetallsslig |
| FI20020835 | 2002-05-03 | ||
| PCT/FI2003/000343 WO2003093516A1 (en) | 2002-05-03 | 2003-05-02 | Method for refining concentrate containing precious metals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1509628A1 true EP1509628A1 (en) | 2005-03-02 |
Family
ID=8563870
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP03730239A Withdrawn EP1509628A1 (en) | 2002-05-03 | 2003-05-02 | Method for refining concentrate containing precious metals |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US20050217422A1 (sv) |
| EP (1) | EP1509628A1 (sv) |
| JP (1) | JP2005524768A (sv) |
| KR (1) | KR20040099476A (sv) |
| CN (1) | CN1650037A (sv) |
| AU (1) | AU2003240873A1 (sv) |
| BR (1) | BR0309679A (sv) |
| CA (1) | CA2484416A1 (sv) |
| EA (1) | EA006620B1 (sv) |
| FI (1) | FI114808B (sv) |
| MX (1) | MXPA04010718A (sv) |
| PL (1) | PL372600A1 (sv) |
| RS (1) | RS95504A (sv) |
| WO (1) | WO2003093516A1 (sv) |
| ZA (1) | ZA200408570B (sv) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI115638B (sv) * | 2002-12-05 | 2005-06-15 | Outokumpu Oy | Förfarande för att behandla slagg |
| FI119774B (sv) * | 2007-06-20 | 2009-03-13 | Outotec Oyj | Förfarande för behandling av kobolthaltigt kopparkoncentrat |
| FI120157B (sv) * | 2007-12-17 | 2009-07-15 | Outotec Oyj | Förfarande för förädling av kopparslig |
| JP5609121B2 (ja) * | 2010-01-21 | 2014-10-22 | 新日鐵住金株式会社 | 銅鉄スクラップ中の白金を回収するための白金の溶銅相への濃化方法 |
| FI20110278A0 (sv) * | 2011-08-29 | 2011-08-29 | Outotec Oyj | Förfarande för utvinning av metaller ur sulfidkoncentrat |
| CN102605191B (zh) * | 2012-04-16 | 2013-12-25 | 阳谷祥光铜业有限公司 | 一种铜精矿直接生产粗铜的方法 |
| FI124028B (sv) | 2012-06-13 | 2014-02-14 | Outotec Oyj | Förfarande och arrangemang för förädling av kopparkoncentrat |
| RU2531333C2 (ru) * | 2012-06-25 | 2014-10-20 | Радик Расулович Ахметов | Способ извлечения металлов платиновой группы из отработанных автомобильных катализаторов |
| CN104451195B (zh) * | 2014-11-21 | 2016-05-18 | 邱江波 | 红土镍矿的闪速熔炼方法 |
| CN104561519A (zh) * | 2014-12-03 | 2015-04-29 | 金川集团股份有限公司 | 一种高镁贵金属精矿的处理方法 |
| RU2614293C2 (ru) * | 2015-06-04 | 2017-03-24 | Общество с ограниченной ответственностью "Институт Гипроникель" | Способ переработки низкоавтогенного сырья в печах взвешенной плавки |
| US11155894B2 (en) * | 2016-04-28 | 2021-10-26 | Eldorado Gold Corporation | Method for reducing arsenic content in arsenic-bearing gold material |
| CN107119195B (zh) * | 2017-04-27 | 2019-01-04 | 山东河西黄金集团有限公司 | 基于高S高Fe金矿与含铜废料直接熔炼回收金和铜的方法 |
| US10662500B2 (en) | 2018-01-24 | 2020-05-26 | Heraeus Deutschland GmbH & Co. KG | Process for the recovery of precious metal from petrochemical process residues |
| CN112359227B (zh) * | 2020-11-12 | 2022-05-20 | 中国恩菲工程技术有限公司 | 从火法炼镍过程中提钴的方法 |
| CN115433838A (zh) * | 2022-08-15 | 2022-12-06 | 金川镍钴研究设计院有限责任公司 | 一种火法处理尼尔森精矿富集贵金属的方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5149119A (en) * | 1974-10-28 | 1976-04-28 | Nippon Mining Co | Doseirenniokeru rendanrosogyoho |
| SE444578B (sv) * | 1980-12-01 | 1986-04-21 | Boliden Ab | Forfarande for utvinning av metallinnehall ur komplexa sulfidiska metallravaror |
| SE453200B (sv) * | 1984-09-28 | 1988-01-18 | Boliden Ab | Forfarande for utvinning av edelmetaller ur silverrika, halogenhaltiga material |
| FI84368B (fi) * | 1989-01-27 | 1991-08-15 | Outokumpu Osakeyhtioe | Foerfarande och anlaeggning foer framstaellning av nickelfinsten. |
| FI94538C (sv) * | 1992-06-18 | 1999-11-09 | Outokumpu Harjavalta Metals Oy | Förfarande för framställning av finkornig nickelsten och metalliserad sten |
| AP538A (en) * | 1992-06-26 | 1996-09-18 | Intec Pty Ltd | Production of metal from minerals |
| FI98073C (sv) * | 1995-08-14 | 1997-04-10 | Outokumpu Eng Oy | Förfarande för hydrometallurgisk återvinning av nickel ur två olika typer av nickelsten |
-
2002
- 2002-05-03 FI FI20020835A patent/FI114808B/sv not_active IP Right Cessation
-
2003
- 2003-05-02 BR BR0309679-3A patent/BR0309679A/pt not_active IP Right Cessation
- 2003-05-02 WO PCT/FI2003/000343 patent/WO2003093516A1/en not_active Application Discontinuation
- 2003-05-02 AU AU2003240873A patent/AU2003240873A1/en not_active Abandoned
- 2003-05-02 PL PL03372600A patent/PL372600A1/xx not_active Application Discontinuation
- 2003-05-02 EA EA200401237A patent/EA006620B1/ru not_active IP Right Cessation
- 2003-05-02 KR KR10-2004-7017730A patent/KR20040099476A/ko not_active Application Discontinuation
- 2003-05-02 CN CNA038100134A patent/CN1650037A/zh active Pending
- 2003-05-02 MX MXPA04010718A patent/MXPA04010718A/es unknown
- 2003-05-02 RS YUP-955/04A patent/RS95504A/sr unknown
- 2003-05-02 CA CA002484416A patent/CA2484416A1/en not_active Abandoned
- 2003-05-02 EP EP03730239A patent/EP1509628A1/en not_active Withdrawn
- 2003-05-02 JP JP2004501650A patent/JP2005524768A/ja not_active Abandoned
- 2003-05-02 US US10/513,164 patent/US20050217422A1/en not_active Abandoned
-
2004
- 2004-10-22 ZA ZA200408570A patent/ZA200408570B/xx unknown
Non-Patent Citations (1)
| Title |
|---|
| See references of WO03093516A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| US20050217422A1 (en) | 2005-10-06 |
| EA006620B1 (ru) | 2006-02-24 |
| BR0309679A (pt) | 2005-03-01 |
| EA200401237A1 (ru) | 2005-06-30 |
| WO2003093516A1 (en) | 2003-11-13 |
| PL372600A1 (en) | 2005-07-25 |
| KR20040099476A (ko) | 2004-11-26 |
| FI20020835A (sv) | 2003-11-04 |
| RS95504A (en) | 2007-02-05 |
| FI114808B (sv) | 2004-12-31 |
| FI20020835A0 (sv) | 2002-05-03 |
| CN1650037A (zh) | 2005-08-03 |
| JP2005524768A (ja) | 2005-08-18 |
| MXPA04010718A (es) | 2005-03-07 |
| AU2003240873A1 (en) | 2003-11-17 |
| ZA200408570B (en) | 2005-04-22 |
| CA2484416A1 (en) | 2003-11-13 |
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