EP1500713B1 - Method of making a fine grained cemented carbide - Google Patents
Method of making a fine grained cemented carbide Download PDFInfo
- Publication number
- EP1500713B1 EP1500713B1 EP04014482A EP04014482A EP1500713B1 EP 1500713 B1 EP1500713 B1 EP 1500713B1 EP 04014482 A EP04014482 A EP 04014482A EP 04014482 A EP04014482 A EP 04014482A EP 1500713 B1 EP1500713 B1 EP 1500713B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- nitrogen
- sintering
- temperature
- furnace
- inserts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 83
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 41
- 238000005245 sintering Methods 0.000 claims abstract description 39
- 239000012298 atmosphere Substances 0.000 claims abstract description 13
- 239000011148 porous material Substances 0.000 claims abstract description 10
- 238000003801 milling Methods 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 26
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 20
- 229910009043 WC-Co Inorganic materials 0.000 claims description 14
- 230000001681 protective effect Effects 0.000 claims description 14
- 229910052786 argon Inorganic materials 0.000 claims description 10
- 239000003966 growth inhibitor Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 150000004767 nitrides Chemical class 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 150000001247 metal acetylides Chemical class 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 abstract description 13
- 230000002159 abnormal effect Effects 0.000 abstract description 12
- 239000010941 cobalt Substances 0.000 abstract description 4
- 229910017052 cobalt Inorganic materials 0.000 abstract description 4
- 238000001000 micrograph Methods 0.000 description 17
- 238000009826 distribution Methods 0.000 description 14
- 239000011230 binding agent Substances 0.000 description 12
- 238000001816 cooling Methods 0.000 description 12
- 238000005520 cutting process Methods 0.000 description 12
- 229910045601 alloy Inorganic materials 0.000 description 10
- 239000000956 alloy Substances 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229910003470 tongbaite Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 229910052721 tungsten Inorganic materials 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- 239000011651 chromium Substances 0.000 description 4
- 238000009770 conventional sintering Methods 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- UDKYUQZDRMRDOR-UHFFFAOYSA-N tungsten Chemical compound [W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W][W] UDKYUQZDRMRDOR-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/05—Mixtures of metal powder with non-metallic powder
- C22C1/051—Making hard metals based on borides, carbides, nitrides, oxides or silicides; Preparation of the powder mixture used as the starting material therefor
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/08—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F2005/001—Cutting tools, earth boring or grinding tool other than table ware
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
Definitions
- the present invention relates to a method of making a fine grained cemented carbide. By performing the sintering at least partly in a nitrogen-containing atmosphere, a grain refined cemented carbide structure has been obtained.
- Cemented carbide inserts with a grain refined structure are today used to a great extent for machining of steel, stainless steels and heat resistant alloys in applications with high demands on both toughness and wear resistance. Another important application is in microdrills for the machining of printed circuit board so called PCB-drills.
- Common grain growth inhibitors include vanadium, chromium, tantalum, niobium and/or titanium or compounds involving these. When added, generally as carbides, they limit grain growth during sintering, but they also have undesirable side effects such as unfavorably affecting the toughness behaviour. Additions of vanadium or chromium are particularly detrimental and have to be kept on a very low level in order to limit their negative influence on the sintering behaviour. Both vanadium and chromium reduce the sintering activity often resulting in an uneven binder phase distribution and toughness reducing defects in the sintered structure. Large additions are also known to result in precipitation of embrittling phases in the WC/Co grain boundaries. According to WO 99/13120 , the amount of grain growth inhibitors can be reduced if a carbon content of the cemented carbide close to eta-phase formation is chosen.
- tungsten carbonitride can be produced by high pressure nitrogen treatment of a mixture of tungsten and graphite powder. The process is described in JP-A-03-208811 and JP-A-11-35327 and it is claimed that the resulting tungsten carbonitride powder can be used as a raw material for manufacturing of super hard alloys.
- JP-A-11-152535 discloses a process to manufacture fine grained tungsten carbonitride - cobalt hard alloys using tungsten carbonitride as a raw material.
- JP-A-10-324942 and JP-A-10-324943 disclose methods to produce ultra-fine grained cemented carbide by adding the grain growth inhibitors as nitrides. In order to avoid pore formation by denitrification of the nitrides sintering is performed in a nitrogen atmosphere.
- US 4,548,786 discloses a method of making a cobalt cemented carbide insert by powder metallurgy process, milling, pressing and sintering comprising contacting the carbide with nitrogen gas, at e.g. a pressure of 600 Torr and a temperature of 450 °C, after dewaxing during its sintering process of manufacture.
- the whole sintering process is performed in nitrogen.
- the nitrogen is after pore closure replaced by a protective atmosphere of e.g. argon or vacuum.
- the resulting sintered body is characterised by a grain refined structure, reduced grain size and less abnormal grains, in combination with an improved binder phase distribution compared to sintering according to normal practices with a nitrogen content of more than 0.03 weight-%, preferably more than 0.05 weight-%.
- the cobalt content for these alloys should be in the range 4 to 15 weight-%, preferably 5 to 12 weight-%.
- the average number of abnormal grains can be determined using inserts etched for 2 minutes at room temperature in Murakamis regent, examining the etched surface with optical microscope at 1500X, counting the number of abnormal grains on ten micrographs, taken randomly from the surface, and calculating the average number of abnormal grains per micrograph. Each micrograph corresponds to a surface area of 8360 ⁇ m 2 .
- the average number of abnormal grains per micrograph, having a maximum length in any direction >15 ⁇ m is ⁇ 1.0, preferably ⁇ 0.7.
- the average number of abnormal grains per micrograph, having a maximum length in any direction >20 ⁇ m is ⁇ 0.5.
- the average number of abnormal grains per micrograph, having a maximum length in any direction >5 ⁇ m, is ⁇ 0.15.
- the beneficial effect of nitrogen alloying has to be combined with an addition of conventional grain growth inhibitors Cr and/or V, either as pure metals or compounds thereof except the nitrides thereof, preferably compounds free of nitrogen, most preferably carbides.
- the process of the invention works on pure WC-Co alloys as well as on WC-Co alloys containing grain growth inhibitors. But the most significant improvement regarding grain growth control has been seen for straight WC-Co alloys with a sintered average grain size of ⁇ 1.5 ⁇ m, preferably ⁇ 1 ⁇ m but larger than 0.5 ⁇ m where no further grain growth inhibitors are necessary.
- the furnace was evacuated and refilled with a protective atmosphere of 10 mbar Argon and kept at 1370 °C for 30 minutes followed by increased Ar pressure 40 mbar and a temperature increase up to the final sintering temperature 1410 °C where the temperature was kept for an additional hour before cooling and opening of the furnace.
- the structure in the cutting inserts consisted of comparably fine and uniform tungsten carbide grain size in combination with a good binder phase distribution, Fig. 1.
- Example 2 (reference example to Example 1)
- Pressed inserts from Example 1 were sintered in H 2 up to 450 °C for dewaxing, further in vacuum to 1370 °C, then filled with a protective gas of 10 mbar of Ar and kept at 1370 °C for 30 minutes followed by an increased Ar pressure of 40 mbar and a temperature increase up to the final sintering temperature 1410 °C where the temperature was kept for an additional hour before cooling and opening of the furnace.
- the structure in the cutting inserts consisted of a comparably less fine and uniform tungsten carbide grain size in combination with a acceptable binder phase distribution, Fig. 2.
- Pressed inserts from Example 1 were sintered in H 2 up to 450°C for dewaxing.
- the furnace was evacuated and refilled with nitrogen up to a pressure of 0.8 atm. The temperature was kept constant at 450 °C during the nitrogen filling procedure. After completed filling, the temperature was increased to 1370 °C with a speed of 15 °C/min, keeping the nitrogen pressure constant.
- the furnace was evacuated and refilled with a protective atmosphere of 10 mbar Argon. The actual sintering was limited to a 30 min hold at 1370 °C followed by cooling and opening of the furnace.
- the structure in the cutting inserts consisted of comparably fine and uniform tungsten carbide grain size in combination with an acceptable binder phase distribution, Fig. 3.
- Example 4 (reference example to Example 3)
- Pressed inserts from Example 1 were sintered in H 2 up to 450°C for dewaxing, further in vacuum to 1370 °C.
- the furnace was filled with a protective atmosphere of 10 mbar Argon. The actual sintering was limited to a 30 min hold at 1370 °C followed by cooling and opening of the furnace.
- the structure in the cutting inserts consisted of a comparably less fine and uniform tungsten carbide grain size in combination with an unacceptable binder phase distribution, Fig. 4.
- the structure in the cutting inserts consisted of comparably fine and uniform tungsten carbide grain size in combination with a good binder phase distribution, Fig. 5.
- Example 6 (reference example to Example 5)
- Pressed inserts from Example 5 were sintered in H 2 up to 450°C for dewaxing, further in vacuum to 1370 °C.
- the furnace was filled with a protective atmosphere of 10 mbar Argon. The actual sintering was limited to a 30 min hold at 1370 °C followed by cooling and opening of the furnace.
- the structure in the cutting inserts consisted of a comparably less fine and uniform tungsten carbide grain size in combination with an unacceptable binder phase distribution, Fig. 6.
- the furnace was evacuated and refilled with a protective atmosphere of 10 mbar Argon and kept at 1370 °C for 30 minutes followed by an increased Ar pressure of 40 mbar and a temperature increase up to the final sintering temperature 1410 °C where the temperature was kept for an additional hour before cooling and opening of the furnace.
- the structure in the cutting inserts consisted of compared to the reference in example 8 finer large tungsten carbide grains in combination with a good binder phase distribution, Fig. 7.
- Example 8 (reference example to Example 7)
- Pressed inserts from Example 7 were sintered in H 2 up to 450°C for dewaxing, further in vacuum to 1370 °C, then filled with an protective gas of 10 mbar of Ar and kept at 1370 °C for 30 minutes followed by an increased Ar pressure of 40 mbar and a temperature increase up to the final sintering temperature 1410 °C where the temperature was kept for an additional hour before cooling and opening of the furnace.
- the structure in the cutting inserts consisted of large grains and a non-uniform tungsten carbide grain size in combination with an acceptable binder phase distribution, Fig. 8.
- Inserts from Example 7 and 8 were etched for 2 minutes at room temperature in Murakamis regent and examined under optical microscope at 1500X. Ten micrographs were taken. In all ten micrographs, WC grains having a length in any direction >15 ⁇ m were detected and the maximum length for each such grain was measured. An average number of abnormal grains per micrograph, corresponding to a surface area of 8360 ⁇ m 2 , was calculated by dividing the number of grains by 10.
- the furnace was evacuated and refilled with a protective atmosphere of 10 mbar Argon and kept at 1370 °C for 30 minutes followed by an increased Ar pressure of 40 mbar and a temperature increase up to the final sintering temperature of 1410 °C where the temperature was kept for an additional hour before cooling and opening of the furnace.
- the structure in the cutting inserts consisted of a uniform submicron tungsten carbide grain size and in combination with an almost absence of large grains and a uniform Co distribution, Fig. 9.
- Example 11 (reference example to Example 10)
- Pressed inserts from Example 10 were sintered in H 2 up to 450°C for dewaxing, further in vacuum to 1370 °C, then filled with a protective gas of 10 mbar of Ar and kept at 1370 °C for 30 minutes followed by an increased Ar pressure of 40 mbar and a temperature increase up to the final sintering temperature 1410 °C where the temperature was kept for an additional hour before cooling and opening of the furnace.
- the structure in the cutting inserts consisted of a less uniform submicron tungsten carbide grain size and in combination with some large WC grains, Fig. 10.
- Example 10 and 11 Inserts from Example 10 and 11 were etched for 2 minutes at room temperature in Murakamis regent and examined under optical microscope at 1500X. Ten micrographs were taken. In all ten micrographs, WC grains having a length in any direction >5 ⁇ m were detected and the maximum length for each such grain was measured. An average number of abnormal grains per micrograph, corresponding to a surface area of 8360 ⁇ m 2 , was calculated by dividing the number of grains by 10. Result: Average number of grains with max. length >5 ⁇ m Example 10 (invention) 0-0.1 Example 11 (reference) 0.25-0.4
- the furnace was evacuated and refilled with a protective atmosphere of 10 mbar Argon and kept at 1370 °C for 30 minutes followed by an increased Ar pressure of 40 mbar and a temperature increase up to the final sintering temperature of 1410 °C where the temperature was kept for an additional hour before cooling and opening of the furnace.
- the structure in the cutting inserts consisted of a uniform submicron tungsten carbide grain size and in combination with an almost absence of large grains and a uniform Co distribution, Fig. 11.
- Example 14 (reference example to Example 13)
- Pressed inserts from Example 13 were sintered in H 2 up to 450 °C for dewaxing, further in vacuum to 1370 °C, then filled with a protective gas of 10 mbar of Ar and kept at 1370 °C for 30 minutes followed by an increased Ar pressure of 40 mbar and a temperature increase up to the final sintering temperature 1410 °C where the temperature was kept for an additional hour before cooling and opening of the furnace.
- the structure in the cutting inserts consisted of a less uniform submicron tungsten carbide grain size and in combination with some large WC grains, Fig. 12.
- Example 13 and 14 Inserts from Example 13 and 14 were etched for 2 minutes at room temperature in Murakamis regent and examined under optical microscope at 1500X. Ten micrographs were taken. In all ten micrographs, WC grains having a length in any direction >5 ⁇ m were detected and the maximum length for each such grain was measured. An average per micrograph was calculated by dividing the number of grains by 10. An average number of abnormal grains per micrograph, corresponding to a surface area of 8360 ⁇ m 2 , was calculated by dividing the number of grains by 10. Result: Average number of grains with max. length >5 ⁇ m Example 13 (invention) 0-0.1 Example 14 (reference) 0.2-0.4
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Powder Metallurgy (AREA)
- Carbon And Carbon Compounds (AREA)
- Materials For Medical Uses (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE0302131 | 2003-07-25 | ||
SE0302131A SE0302131D0 (sv) | 2003-07-25 | 2003-07-25 | Method of making a fine grained cemented carbide |
SE0302835 | 2003-10-28 | ||
SE0302835A SE527173C2 (sv) | 2003-07-25 | 2003-10-28 | Sätt att tillverka en finkorning hårdmetall |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1500713A1 EP1500713A1 (en) | 2005-01-26 |
EP1500713B1 true EP1500713B1 (en) | 2007-08-15 |
Family
ID=29552453
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04014482A Expired - Lifetime EP1500713B1 (en) | 2003-07-25 | 2004-06-21 | Method of making a fine grained cemented carbide |
Country Status (8)
Country | Link |
---|---|
US (2) | US20050025657A1 (sv) |
EP (1) | EP1500713B1 (sv) |
JP (1) | JP2005042201A (sv) |
KR (1) | KR101202225B1 (sv) |
AT (1) | ATE370257T1 (sv) |
DE (1) | DE602004008166T2 (sv) |
IL (1) | IL162686A (sv) |
SE (1) | SE527173C2 (sv) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8283058B2 (en) | 2007-06-01 | 2012-10-09 | Sandvik Intellectual Property Ab | Fine grained cemented carbide cutting tool insert |
US8455116B2 (en) | 2007-06-01 | 2013-06-04 | Sandvik Intellectual Property Ab | Coated cemented carbide cutting tool insert |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101151386B (zh) | 2005-03-28 | 2010-05-19 | 京瓷株式会社 | 超硬合金及切削工具 |
SE530516C2 (sv) | 2006-06-15 | 2008-06-24 | Sandvik Intellectual Property | Belagt hårdmetallskär, metod att tillverka detta samt dess användning vid fräsning av gjutjärn |
SE530861C2 (sv) | 2006-12-15 | 2008-09-30 | Sandvik Intellectual Property | Belagd hårdmetallpinnfräs för medel- och finbearbetning av härdade stål och förfarande för dess framställning |
SE0700800L (sv) * | 2006-12-15 | 2008-06-16 | Sandvik Intellectual Property | Belagt skärverktyg |
SE0701449L (sv) | 2007-06-01 | 2008-12-02 | Sandvik Intellectual Property | Finkornig hårdmetall med förfinad struktur |
SE0701760L (sv) * | 2007-06-01 | 2008-12-02 | Sandvik Intellectual Property | Hårdmetallskär för avstickning, spårstickning och gängning |
SE531971C2 (sv) * | 2007-08-24 | 2009-09-15 | Seco Tools Ab | Belagt skärverktyg för allmän svarvning i varmhållfast superlegeringar (HRSA) |
DE102012018067A1 (de) * | 2012-09-13 | 2014-03-13 | Tutec Gmbh | Hexagonales WC-Pulver, Verfahren zu dessen Herstellung sowie Verwendung dieses Pulvers |
US10308558B2 (en) * | 2013-05-31 | 2019-06-04 | Sandvik Intellectual Property Ab | Process of manufacturing cemented carbide and a product obtained thereof |
RU2015156229A (ru) * | 2013-05-31 | 2017-07-06 | Сандвик Интеллекчуал Проперти Аб | Новый способ получения цементированного карбида и получаемый при его помощи продукт |
CN105899706A (zh) * | 2013-12-27 | 2016-08-24 | 山特维克知识产权股份有限公司 | 耐蚀性二联钢合金,由其制成的物体和制造该合金的方法 |
CN113322389A (zh) * | 2021-06-01 | 2021-08-31 | 株洲硬质合金集团有限公司 | 一种耐磨损耐腐蚀超细硬质合金的烧结方法 |
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-
2003
- 2003-10-28 SE SE0302835A patent/SE527173C2/sv not_active IP Right Cessation
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2004
- 2004-06-21 AT AT04014482T patent/ATE370257T1/de active
- 2004-06-21 EP EP04014482A patent/EP1500713B1/en not_active Expired - Lifetime
- 2004-06-21 DE DE602004008166T patent/DE602004008166T2/de not_active Expired - Lifetime
- 2004-06-22 IL IL162686A patent/IL162686A/en not_active IP Right Cessation
- 2004-06-23 US US10/873,234 patent/US20050025657A1/en not_active Abandoned
- 2004-07-13 KR KR1020040054227A patent/KR101202225B1/ko active IP Right Grant
- 2004-07-26 JP JP2004217547A patent/JP2005042201A/ja active Pending
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8283058B2 (en) | 2007-06-01 | 2012-10-09 | Sandvik Intellectual Property Ab | Fine grained cemented carbide cutting tool insert |
US8455116B2 (en) | 2007-06-01 | 2013-06-04 | Sandvik Intellectual Property Ab | Coated cemented carbide cutting tool insert |
Also Published As
Publication number | Publication date |
---|---|
DE602004008166D1 (de) | 2007-09-27 |
SE0302835L (sv) | 2005-01-26 |
IL162686A0 (en) | 2005-11-20 |
US20060029511A1 (en) | 2006-02-09 |
KR20050013077A (ko) | 2005-02-02 |
IL162686A (en) | 2007-10-31 |
DE602004008166T2 (de) | 2008-04-30 |
SE0302835D0 (sv) | 2003-10-28 |
ATE370257T1 (de) | 2007-09-15 |
EP1500713A1 (en) | 2005-01-26 |
JP2005042201A (ja) | 2005-02-17 |
US20050025657A1 (en) | 2005-02-03 |
KR101202225B1 (ko) | 2012-11-16 |
SE527173C2 (sv) | 2006-01-17 |
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