EP1353045A2 - Hubventil - Google Patents
Hubventil Download PDFInfo
- Publication number
- EP1353045A2 EP1353045A2 EP03007678A EP03007678A EP1353045A2 EP 1353045 A2 EP1353045 A2 EP 1353045A2 EP 03007678 A EP03007678 A EP 03007678A EP 03007678 A EP03007678 A EP 03007678A EP 1353045 A2 EP1353045 A2 EP 1353045A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat
- valve
- poppet valve
- front face
- poppet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01L—CYCLICALLY OPERATING VALVES FOR MACHINES OR ENGINES
- F01L3/00—Lift-valve, i.e. cut-off apparatus with closure members having at least a component of their opening and closing motion perpendicular to the closing faces; Parts or accessories thereof
- F01L3/02—Selecting particular materials for valve-members or valve-seats; Valve-members or valve-seats composed of two or more materials
- F01L3/04—Coated valve members or valve-seats
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01L—CYCLICALLY OPERATING VALVES FOR MACHINES OR ENGINES
- F01L3/00—Lift-valve, i.e. cut-off apparatus with closure members having at least a component of their opening and closing motion perpendicular to the closing faces; Parts or accessories thereof
- F01L3/02—Selecting particular materials for valve-members or valve-seats; Valve-members or valve-seats composed of two or more materials
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
Definitions
- the present invention relates to a poppet valve which is capable of reducing thermal load in a valve head.
- An intake valve is heated on a front face of a valve head which faces a cylinder at approximately 100 % and cooled at a rear portion of the valve head so that heat may be left into intake air and at the same time left from a valve stem and a valve face into a cylinder head through a valve guide and a valve seat.
- An exhaust valve is heated at a front face and a rear portion at approximately 7:3. Heat is thereby transferred from a valve stem and a valve face into the cylinder head through the valve guide and the valve seat.
- Temperature of the intake and exhaust valves during operation is determined by the balance between heating and cooling.
- the valve head increases in temperature, depending on operating conditions, causing an increase in thermal load since cooling is generally less than heating.
- Poppet valves are generally made of martensite heat-resistant steel, mainly for intake valves, and austenite heat-resistant steel for exhaust valves.
- Heat-resistant steels are relatively expensive thereby limiting potential decreases in the manufacturing cost of poppet valves.
- Intake valves having relatively low thermal load are made of Al alloy thereby lightening a valve-operating mechanism to improve engine performance.
- there are disadvantages in high-temperature strength thereby making practical use impossible.
- Fig. 1 illustrates the first embodiment of a poppet valve used as an exhaust valve according to the present invention.
- the poppet valve 1 consists of a valve stem 2 and a valve head 3 made of austenite heat-resistant steel.
- the valve head 3 consists of a front face 3b opposite a cylinder (not shown) and a rear portion 3c in an exhaust port. The whole surface of the valve head 3 except a valve face 3a is covered with a film 4 made of heat-resistant heat-insulating material.
- the heat-insulating material includes ceramic oxides such as alumina, cordierite, zirconia, zircon and titanium oxide; ceramic carbides such as silicon carbide; ceramic nitrides such as silicon niride; aluminum silicate; chromium oxide; WC-Co alloy; WC-Ni-W-Cr 3 C 2 alloy and Cr 3 C 2 -Ni-Cr alloy.
- the film 4 may be made using gas flame or arc spraying, plasma spraying, explosion spraying, sputtering or ion plating.
- the film 4 may have thickness of 0.1 to 2.0 mm to insulate heat and decrease weight.
- the heat-insulating material as above may be sprayed after the surface on which the film is formed is made rough by using shot blasting or mechanical working.
- a film 4 that consists of multiple layers having different contents of heat-insulating material may be formed.
- the first layer 4a is a highly adhesive binding layer made from the same material as the valve. Heat-insulating materials are increased in conjunction with the increase in layers.
- An outermost layer 4b is made only of heat-insulating material. The surface of the film may be sprayed without making a rough surface. In the case of intake valves, the film 4 on the rear portion 3c may be omitted.
- Fig. 4 illustrates the second embodiment of the present invention, in which a thin convex heat-shielding plate 7 made of heat-insulating material, as described above, or heat-resistant material such as heat-resistant steel is mounted to a front face 6a of a valve head 6 of a martensite heat-resistant steel poppet valve 5 to form a heat-insulating space 8 between the plate 7 and the front face 6.
- a thin convex heat-shielding plate 7 made of heat-insulating material, as described above, or heat-resistant material such as heat-resistant steel is mounted to a front face 6a of a valve head 6 of a martensite heat-resistant steel poppet valve 5 to form a heat-insulating space 8 between the plate 7 and the front face 6.
- an L-sectioned mounting portion 7a is formed on the circumferential end, and is engaged in an annular groove 9 on the circumferential end of the front face 6a. Then, the circumferential end of the front face 6a is plastically reconfigured inwards.
- the circumferential end of the heat-shielding plate 7 may be welded to the front face 6a.
- the convex heat-shielding plate 7 provides sufficient bending strength against pressure and decreases concave deformation.
- Fig. 5 illustrates the third embodiment of a poppet valve according to the present invention in which a heat-shielding plate 10, made of the same material as the above, has multiple reinforcement ribs 11 on the upper surface.
- a mounting portion 10a formed in the upper circumferential end is fixed to the circumferential end of a front face by the above caulking method to form a heat-insulating space 8 against the front face 6a.
- Fig. 6 illustrates the fourth embodiment of a poppet valve according to the present invention in which a front face 6a of a poppet valve 5 is convex.
- a concave heat-shielding plate 12 having multiple reinforcement ribs 11 on the upper surface is fixed to the circumferential end of the front face 6a using an L-shaped mounting portion 12a on the circumferential end of the plate 12 by the above caulking method.
- the heat-insulating space 8 is formed between the front face 6a and the heat-shielding plate 12 while the upper ends of the reinforcement ribs 11 are engaged on the front face 6a.
- the reinforcement rib may be formed as grid, concentric circle, vortex, parallel plate, corrugated plate, incomplete circle, arc and protrusion.
- the reinforcement rib may be provided on the front face 6a.
- the reinforcement rib as described above, may be provided in the embodiment in Fig. 4.
- the film may be formed on the rear portion 6b similar to the first embodiment in case of exhaust valves.
- a light heat-insulating filler such as glass wool and rock wool or a heat-insulating gas such as Ar may be enclosed under ordinary or high pressure. Space 8 may be vacuous.
- the front face 3b and the rear portion 3c subjected to a high-temperature combustion or exhaust gas are covered with the film 4 made of heat-insulating material.
- the heat-shielding plates 7,10,12 are mounted to the front face 6a to form a heat-insulating space 8.
- Heat into the valve head 3,6 decreases, and generally dissipates through a valve seat or a valve guide thereby decreasing valve temperature during operation and improving durability. Heat into the valve head 3,6 decreases the heat loss rate and increases thermal efficiency thereby improving engine performance such as output and fuel efficiency.
- valve Furthermore, a decrease in thermal load enables the valve to be made of low-cost material such as carbon steel or mechanical structural steel.
- the present invention allows for poppet valves to be made of lightweight metals such as Al, Mg and Ti alloys which were heretofore difficult in use thereby reducing the inertia mass of a valve-operating mechanism to decrease mechanical loss such as friction so as to achieve double improvement in engine performance with decreased heat loss.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Lift Valve (AREA)
- Cylinder Crankcases Of Internal Combustion Engines (AREA)
- Coating By Spraying Or Casting (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002109861A JP2003307105A (ja) | 2002-04-12 | 2002-04-12 | エンジンバルブ |
JP2002109861 | 2002-04-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1353045A2 true EP1353045A2 (de) | 2003-10-15 |
EP1353045A3 EP1353045A3 (de) | 2004-03-10 |
Family
ID=28449972
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03007678A Withdrawn EP1353045A3 (de) | 2002-04-12 | 2003-04-03 | Hubventil |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1353045A3 (de) |
JP (1) | JP2003307105A (de) |
KR (1) | KR20030081165A (de) |
CN (1) | CN1451850A (de) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006097264A1 (de) * | 2005-03-18 | 2006-09-21 | Man B & W Diesel Aktiengesellschaft | Gaswechselventil mit korrosionsschutzschicht |
DE102006053550A1 (de) * | 2006-11-14 | 2008-05-15 | Man Diesel Se | Brennkraftmaschine sowie Gaswechselventil einer Brennkraftmaschine |
DE102006061128A1 (de) * | 2006-12-22 | 2008-06-26 | Mahle International Gmbh | Gaswechselventil eines Verbrennungsmotors |
EP1746179A3 (de) * | 2005-06-22 | 2009-09-30 | Yamaha Hatsudoki Kabushiki Kaisha | Titanteil für eine Brennkraftmaschine |
US20100077983A1 (en) * | 2008-10-01 | 2010-04-01 | Aisan Kogyo Kabushiki Kaisha | Engine valves |
EP2182183A1 (de) * | 2008-10-31 | 2010-05-05 | Mahle International GmbH | Beweglicher, heißen Gasen ausgesetzter Verschlusskörper eines Ventiles |
US8376721B2 (en) | 2006-11-01 | 2013-02-19 | Borgwarner Inc. | Turbine heat shield assembly |
DE102013213268A1 (de) * | 2013-07-05 | 2015-01-08 | Mahle International Gmbh | Gebautes Hohlventil |
WO2015182248A1 (en) * | 2014-05-30 | 2015-12-03 | Toyota Jidosha Kabushiki Kaisha | Supercharged internal combustion engine |
DE102014219917A1 (de) * | 2014-10-01 | 2016-04-07 | Mahle International Gmbh | Wirbelstromventil |
EP3106634A4 (de) * | 2014-02-12 | 2017-11-29 | Nittan Valve Co., Ltd. | Kegelventil |
WO2019086244A1 (en) * | 2017-10-30 | 2019-05-09 | Eaton Intelligent Power Limited | Poppet valve |
DE102018118791A1 (de) * | 2018-08-02 | 2020-02-06 | Federal-Mogul Valvetrain Gmbh | Tellerventil mit einer Hochtemperatur-Beschichtung |
US10731538B2 (en) | 2017-12-19 | 2020-08-04 | Toyota Jidosha Kabushiki Kaisha | Internal combustion engine |
US11767774B2 (en) | 2017-10-30 | 2023-09-26 | Eaton Intelligent Power Limited | Poppet valve |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013170555A (ja) * | 2012-02-23 | 2013-09-02 | Mazda Motor Corp | 断熱構造体及びその製造方法 |
US9441287B2 (en) | 2012-10-31 | 2016-09-13 | Fukuda Metal Foil & Powder Co., Ltd. | Ni-Cr-Co-based alloy having high-temperature corrosion resistance, and poppet valve surface-modified with the same |
CN104995377B (zh) * | 2013-02-15 | 2018-01-02 | 丰田自动车株式会社 | 提升阀 |
JP6109945B2 (ja) * | 2013-09-11 | 2017-04-05 | 日鍛バルブ株式会社 | エンジンバルブ及びエンジンバルブの製造方法 |
MX2016009708A (es) * | 2014-02-10 | 2016-11-08 | Nittan Valva | Valvula de asiento hueca. |
KR101566743B1 (ko) | 2014-04-18 | 2015-11-06 | 현대자동차 주식회사 | 엔진용 배기 밸브 |
KR101575328B1 (ko) | 2014-04-29 | 2015-12-07 | 현대자동차 주식회사 | 엔진용 흡기 밸브 |
JP6609124B2 (ja) * | 2015-06-23 | 2019-11-20 | イビデン株式会社 | エンジンバルブ及びその製造方法 |
JP6832204B2 (ja) * | 2017-03-27 | 2021-02-24 | 三菱重工業株式会社 | 弁装置、タービンハウジング、排気タービン過給機及びエンジン |
KR102285017B1 (ko) | 2018-03-20 | 2021-08-04 | 니탄 밸브 가부시키가이샤 | 배기용 중공 포핏 밸브 |
JP7190506B2 (ja) | 2018-11-12 | 2022-12-15 | 株式会社Nittan | エンジンのポペットバルブの製造方法 |
EP4129525A4 (de) | 2020-03-30 | 2023-06-14 | Nittan Corporation | Verfahren zur herstellung eines motortellerventils |
JP2022113437A (ja) * | 2021-01-25 | 2022-08-04 | フジオーゼックス株式会社 | 中空エンジンバルブ |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB618607A (en) * | 1946-06-04 | 1949-02-24 | William Thomas Davies | Improvements in or relating to the production of corrosion resistant coatings on poppet valves for internal-combustion engines |
DE3150708A1 (de) * | 1981-12-22 | 1983-07-07 | Gesenkschmiede Schneider Gmbh, 7080 Aalen | "tellerventil als auslassventil fuer hochbelastbare motore" |
US4530322A (en) * | 1980-10-31 | 1985-07-23 | Nippon Kokan Kabushiki Kaisha | Exhaust valve for diesel engine and production thereof |
CH658101A5 (en) * | 1982-04-07 | 1986-10-15 | I K Technology A S | Valve for diesel engines |
US5543029A (en) * | 1994-04-29 | 1996-08-06 | Fuji Oozx Inc. | Properties of the surface of a titanium alloy engine valve |
-
2002
- 2002-04-12 JP JP2002109861A patent/JP2003307105A/ja active Pending
-
2003
- 2003-04-03 EP EP03007678A patent/EP1353045A3/de not_active Withdrawn
- 2003-04-09 CN CN03109541A patent/CN1451850A/zh active Pending
- 2003-04-11 KR KR10-2003-0022948A patent/KR20030081165A/ko not_active Application Discontinuation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB618607A (en) * | 1946-06-04 | 1949-02-24 | William Thomas Davies | Improvements in or relating to the production of corrosion resistant coatings on poppet valves for internal-combustion engines |
US4530322A (en) * | 1980-10-31 | 1985-07-23 | Nippon Kokan Kabushiki Kaisha | Exhaust valve for diesel engine and production thereof |
DE3150708A1 (de) * | 1981-12-22 | 1983-07-07 | Gesenkschmiede Schneider Gmbh, 7080 Aalen | "tellerventil als auslassventil fuer hochbelastbare motore" |
CH658101A5 (en) * | 1982-04-07 | 1986-10-15 | I K Technology A S | Valve for diesel engines |
US5543029A (en) * | 1994-04-29 | 1996-08-06 | Fuji Oozx Inc. | Properties of the surface of a titanium alloy engine valve |
Cited By (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006097264A1 (de) * | 2005-03-18 | 2006-09-21 | Man B & W Diesel Aktiengesellschaft | Gaswechselventil mit korrosionsschutzschicht |
EP1746179A3 (de) * | 2005-06-22 | 2009-09-30 | Yamaha Hatsudoki Kabushiki Kaisha | Titanteil für eine Brennkraftmaschine |
US7794846B2 (en) | 2005-06-22 | 2010-09-14 | Yamaha Hatsudoki Kabushiki Kaisha | Titanium part for internal combustion engine |
US8376721B2 (en) | 2006-11-01 | 2013-02-19 | Borgwarner Inc. | Turbine heat shield assembly |
DE102006053550A1 (de) * | 2006-11-14 | 2008-05-15 | Man Diesel Se | Brennkraftmaschine sowie Gaswechselventil einer Brennkraftmaschine |
DE102006061128A1 (de) * | 2006-12-22 | 2008-06-26 | Mahle International Gmbh | Gaswechselventil eines Verbrennungsmotors |
DE102006061128B4 (de) * | 2006-12-22 | 2015-06-11 | Mahle International Gmbh | Gaswechselventil eines Verbrennungsmotors |
US20100077983A1 (en) * | 2008-10-01 | 2010-04-01 | Aisan Kogyo Kabushiki Kaisha | Engine valves |
DE102009042545B4 (de) * | 2008-10-01 | 2013-01-17 | Aisan Kogyo K.K. | Motorventile |
US8726873B2 (en) | 2008-10-31 | 2014-05-20 | Mahle International Gmbh | Moveable valve sealing body exposed to hot gases |
DE102008054266A1 (de) * | 2008-10-31 | 2010-05-06 | Mahle International Gmbh | Beweglicher, heißen Gasen ausgesetzter Verschlusskörper eines Ventiles |
EP2182183A1 (de) * | 2008-10-31 | 2010-05-05 | Mahle International GmbH | Beweglicher, heißen Gasen ausgesetzter Verschlusskörper eines Ventiles |
DE102013213268A1 (de) * | 2013-07-05 | 2015-01-08 | Mahle International Gmbh | Gebautes Hohlventil |
EP3106634A4 (de) * | 2014-02-12 | 2017-11-29 | Nittan Valve Co., Ltd. | Kegelventil |
WO2015182248A1 (en) * | 2014-05-30 | 2015-12-03 | Toyota Jidosha Kabushiki Kaisha | Supercharged internal combustion engine |
CN106414984A (zh) * | 2014-05-30 | 2017-02-15 | 丰田自动车株式会社 | 增压式内燃发动机 |
CN106414984B (zh) * | 2014-05-30 | 2018-09-28 | 丰田自动车株式会社 | 增压式内燃发动机 |
DE102014219917A1 (de) * | 2014-10-01 | 2016-04-07 | Mahle International Gmbh | Wirbelstromventil |
WO2019086244A1 (en) * | 2017-10-30 | 2019-05-09 | Eaton Intelligent Power Limited | Poppet valve |
US11767774B2 (en) | 2017-10-30 | 2023-09-26 | Eaton Intelligent Power Limited | Poppet valve |
US10731538B2 (en) | 2017-12-19 | 2020-08-04 | Toyota Jidosha Kabushiki Kaisha | Internal combustion engine |
DE102018118791A1 (de) * | 2018-08-02 | 2020-02-06 | Federal-Mogul Valvetrain Gmbh | Tellerventil mit einer Hochtemperatur-Beschichtung |
Also Published As
Publication number | Publication date |
---|---|
JP2003307105A (ja) | 2003-10-31 |
CN1451850A (zh) | 2003-10-29 |
KR20030081165A (ko) | 2003-10-17 |
EP1353045A3 (de) | 2004-03-10 |
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