EP1341937A1 - Procede de production d'un feuillard a chaud en acier presentant une teneur elevee en maganese - Google Patents

Procede de production d'un feuillard a chaud en acier presentant une teneur elevee en maganese

Info

Publication number
EP1341937A1
EP1341937A1 EP01991793A EP01991793A EP1341937A1 EP 1341937 A1 EP1341937 A1 EP 1341937A1 EP 01991793 A EP01991793 A EP 01991793A EP 01991793 A EP01991793 A EP 01991793A EP 1341937 A1 EP1341937 A1 EP 1341937A1
Authority
EP
European Patent Office
Prior art keywords
strip
hot
hot strip
steel
rolling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP01991793A
Other languages
German (de)
English (en)
Other versions
EP1341937B1 (fr
Inventor
Bernhard Dr.-Ing. Engl
Dieter Prof. Dr.-Ing. Senk
Johann Wilhelm Dr. Schmitz
Andreas Dipl.-Ing. Offergeld
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp Steel Europe AG
Original Assignee
ThyssenKrupp Stahl AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7666209&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1341937(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by ThyssenKrupp Stahl AG filed Critical ThyssenKrupp Stahl AG
Publication of EP1341937A1 publication Critical patent/EP1341937A1/fr
Application granted granted Critical
Publication of EP1341937B1 publication Critical patent/EP1341937B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/021Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular fabrication or treatment of ingot or slab
    • C21D8/0215Rapid solidification; Thin strip casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/001Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/06Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
    • B22D11/0622Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars formed by two casting wheels
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/46Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
    • B21B1/463Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting in a continuous process, i.e. the cast not being cut before rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B3/00Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
    • B21B3/02Rolling special iron alloys, e.g. stainless steel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B9/00Measures for carrying out rolling operations under special conditions, e.g. in vacuum or inert atmosphere to prevent oxidation of work; Special measures for removing fumes from rolling mills

Definitions

  • the invention relates to a method for producing a hot strip from a steel having a high manganese content of more than 12 to 30% by weight. Steels of this type are characterized by their particularly high strength.
  • a problem in the production and processing of steels which have such high manganese contents is that they have a solidification behavior which differs from the conventional steels intended for deep-drawing applications, such as IF or low-carbon steels. This shows that steels of the type in question which are cast in conventional slab casting have poor forming behavior.
  • steels which, in addition to other alloying elements, contain 7% to 27% Mn, can be produced by thin strip casting as a strip close to the end and processed into hot strip.
  • the material obtained in this way is particularly suitable for use in the field of automobile body construction.
  • the object of the invention is to provide a method which enables the production of steel strips enables that have a good forming behavior despite a high manganese content.
  • This object is achieved by a method for producing a hot strip having TWIN and TRIP properties from a steel containing more than 12 to 30% by weight of manganese, in which a melt in a two-roll casting machine is close to the final dimensions of a preliminary strip with a Thickness of up to 6 mm is cast, which is continuously processed into hot strip after the casting by rolling it to the final thickness of the hot strip in a single hot pass.
  • high manganese steel is cast into a raw material, the dimensions of which approximate the final dimensions of the hot strip.
  • a thin material is produced in the casting process that an essentially uniform solidification is ensured over its entire cross section.
  • the hot strip produced from the primary material has TRIP ("Transformation-Induced-Plasticity") and TWIP ("Twinning-Induced-Plasticity”) properties and accordingly has good formability, which it combines with the high strength in a special way suitable for use in body construction.
  • the thickness of the material produced should be as small as possible.
  • the solidification process can be specifically controlled in a simple manner in the case of a thin cast preliminary product.
  • the rate of solidification has a direct influence on the level and distribution of micro segregations. These in turn influence the grain growth and the state of the precipitates occurring during the solidification, such as MnS, A1N and Ti (C, N).
  • the fundamentals can be set which decisively influence the further processability and the properties of use of the end product.
  • the steel is cast according to the invention in a two-roll casting machine.
  • This type of casting machine which is known per se, makes it possible to produce particularly thin pre-material, which closely approximates the final dimension of the hot strip, and whose solidification behavior, in particular its solidification speed and uniformity, leads to an optimal casting structure and, consequently, to an optimized formability.
  • the further processing of the primary material into hot strip comprises a controlled cooling immediately following the casting. This enables the primary material emerging from the casting mold to be specifically cooled in such a way that a structure which is optimized for further processing is obtained. As a rule, cooling will take place at a higher cooling rate than cooling in air.
  • the mean initial rolling temperature at which the starting material enters the roll stand can be between 1100 ° C and 750 ° C.
  • the properties of the hot-rolled strip can also be influenced in a targeted manner by cooling the rolled hot strip in a controlled manner after the hot rolling.
  • process the hot strip obtained in accordance with the invention “inline”, for example into a cold strip. In many cases it will possibly be with regard to the following
  • Processing steps or properties of the hot strip to be set are expedient if the strip is coiled into a coil in the course of further processing.
  • the primary material By further processing the primary material into hot strip at least in sections under a protective gas atmosphere, oxidation of the strip surface and the associated excessive scale formation can be avoided.
  • the primary material is kept under the protective gas atmosphere at least up to its entry into the roll stand.
  • Steels used according to the invention can contain up to 3.5% by weight, in particular up to 3% by weight, of silicon in addition to further alloying elements. In addition, they can have up to 3.5% by weight, in particular up to 3% by weight, of aluminum. In steels of the type processed according to the invention, iron and aluminum or iron and silicon form intermetallic phases which occur below the thermoforming temperature and are stable up to room temperature.
  • FIG. 1 shows the structure of a device for producing a hot strip in a schematic side view, Diagram the temperature profile over the processing time of the pre-strip and hot strip in a device according to FIG. 1,
  • Image 1 an enlarged section through the
  • the figure shows schematically the structure of a device 1 for producing a hot strip W, which comprises a casting device 2, a first cooling section 3, a roll stand 4, a second cooling section 5 and a reel device 6.
  • a melt S contained in a tundish 7 of a composition explained below in detail is converted into a preliminary strip V in the casting gap 10 formed between two casting rolls 8, 9 cast.
  • the cast pre-strip V leaves the casting gap 10 in a continuous conveying process with a thickness that can be varied between less than 1 mm and 6 mm.
  • the sliver V On its way to the rolling stand 4, the sliver V is cooled in a controlled manner in the first cooling section 3 below the outlet of the casting gap 10 and closely adjacent to it, using a cooling medium applied to its surfaces.
  • the conveyor section covered by the thin strip V between the exit of the casting gap 10 and the roll stand 4 is surrounded by a housing 11 in which a protective gas atmosphere is maintained. In this way, contact of the belt surface with the oxygen in the ambient air is avoided.
  • the thin strip V runs into the rolling stand 4 with a rolling start temperature AT and is rolled in one pass to its final thickness.
  • the hot strip W is again brought to the reel temperature HT in a controlled manner with a suitable cooling medium, with which it is finally in the reel device
  • the attached diagram shows the roll starting temperature AT, the roll end temperature ET and the reel temperature HT over the processing time after casting in the range that can be set depending on the composition and the desired properties of the hot strip to be produced on a device constructed according to the figure , Appropriate temperature control along a predetermined limit curve with subsequent isothermal holding, rolling and quenching allows the fine-grained structure of the hot strip to freeze after it leaves the rolling stand, so that the good performance properties of the hot strip are retained after hot rolling. Especially when the temperature profile of the pre and hot strip approximates the lower limit curve shown in the diagram, this effect can be achieved.
  • the melt S cast in the exemplary embodiment had an Mn content of 20% by weight, a C content of 0.003% by weight, a sulfur content of 0.007% by weight and an Si content of 3%. 0% by weight, an Al content of 3.0% by weight and the balance iron.
  • Figure 1 shows an enlarged section through the edge area
  • Figure 2 shows an enlarged section in the same way through the central area of a hot strip produced from this steel in the device shown in the figure. It can be seen that the strip has a dendritic structure which consists of austenite and a presumably carbon-containing second phase. Towards the core of the tape there is a clear fine-tuning of the structure.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Metal Rolling (AREA)
  • Continuous Casting (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
  • Heat Treatment Of Steel (AREA)
EP01991793A 2000-12-06 2001-12-06 Procede de production d'un feuillard a chaud en acier presentant une teneur elevee en maganese Expired - Lifetime EP1341937B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10060948 2000-12-06
DE10060948A DE10060948C2 (de) 2000-12-06 2000-12-06 Verfahren zum Erzeugen eines Warmbandes aus einem einen hohen Mangan-Gehalt aufweisenden Stahl
PCT/EP2001/014306 WO2002046480A1 (fr) 2000-12-06 2001-12-06 Procede de production d'un feuillard a chaud en acier presentant une teneur elevee en maganese

Publications (2)

Publication Number Publication Date
EP1341937A1 true EP1341937A1 (fr) 2003-09-10
EP1341937B1 EP1341937B1 (fr) 2004-05-19

Family

ID=7666209

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01991793A Expired - Lifetime EP1341937B1 (fr) 2000-12-06 2001-12-06 Procede de production d'un feuillard a chaud en acier presentant une teneur elevee en maganese

Country Status (11)

Country Link
US (2) US20040074628A1 (fr)
EP (1) EP1341937B1 (fr)
JP (1) JP3836793B2 (fr)
CN (1) CN1236076C (fr)
AT (1) ATE267269T1 (fr)
AU (1) AU2002231664A1 (fr)
CZ (1) CZ304928B6 (fr)
DE (2) DE10060948C2 (fr)
ES (1) ES2221659T3 (fr)
PL (1) PL196538B1 (fr)
WO (1) WO2002046480A1 (fr)

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Publication number Priority date Publication date Assignee Title
JP2004050220A (ja) 2002-07-18 2004-02-19 Ishikawajima Harima Heavy Ind Co Ltd 帯板製造設備
DE10259230B4 (de) * 2002-12-17 2005-04-14 Thyssenkrupp Stahl Ag Verfahren zum Herstellen eines Stahlprodukts
DE102004054444B3 (de) * 2004-08-10 2006-01-19 Daimlerchrysler Ag Verfahren zur Herstellung von Stahlbauteilen mit höchster Festigkeit und Plastizität
WO2006048034A1 (fr) * 2004-11-03 2006-05-11 Thyssenkrupp Steel Ag Bande ou tole d'acier extremement resistante a proprietes twip et procede de fabrication de ladite bande a l'aide de la 'coulee directe de bandes'
FR2878257B1 (fr) * 2004-11-24 2007-01-12 Usinor Sa Procede de fabrication de toles d'acier austenitique, fer-carbone-manganese a tres hautes caracteristiques de resistance et d'allongement, et excellente homogeneite
DE102005052774A1 (de) * 2004-12-21 2006-06-29 Salzgitter Flachstahl Gmbh Verfahren zum Erzeugen von Warmbändern aus Leichtbaustahl
DE102005010243A1 (de) * 2005-03-05 2006-09-07 Sms Demag Ag Verfahren und Anlage zur Herstellung eines Leichtbaustahls mit einem hohen Mangan-Gehalt
JP4555183B2 (ja) * 2005-07-15 2010-09-29 株式会社神戸製鋼所 成形用アルミニウム合金板の製造方法および成形用アルミニウム合金の連続鋳造装置
DE102007059007A1 (de) 2007-12-06 2009-06-18 Salzgitter Flachstahl Gmbh Verfahren zum Erzeugen eines Warmbandes und aus einem Triplex-Leichtbaustahl hergestelltes Warmband
DE102007059006A1 (de) 2007-12-06 2009-06-10 Salzgitter Flachstahl Gmbh Verfahren zum Erzeugen eines Warmbandes und aus einem ferritischen Stahl hergestelltes Warmband
DE102008005158A1 (de) 2008-01-18 2009-07-23 Robert Bosch Gmbh Bauelement, insbesondere eine Kraftfahrzeugkomponente, aus einem höherfesten austenitischen Stahl mit TRIP-, TWIP- und/oder SIP-Effekt
WO2010102595A1 (fr) 2009-03-11 2010-09-16 Salzgitter Flachstahl Gmbh Procédé de production d'un feuillard à chaud et feuillard à chaud produit à partir d'acier ferritique
DE102009030324A1 (de) * 2009-06-24 2011-01-05 Voestalpine Stahl Gmbh Manganstahl und Verfahren zur Herstellung desselben
US10001228B2 (en) * 2011-06-17 2018-06-19 National Oilwell Varco Denmark I/S Unbonded flexible pipe
KR102079847B1 (ko) * 2013-07-10 2020-02-20 티센크루프 스틸 유럽 악티엔게젤샤프트 철-기반 형상 기억 합금으로부터 평강 제품을 제조하기 위한 방법
CN106583454A (zh) * 2016-12-30 2017-04-26 宁波大学 一种无料头双金属层复合实心轴的连铸—楔横轧成形方法
CN106734203A (zh) * 2016-12-30 2017-05-31 宁波大学 一种无料头双金属层复合空心轴的连铸—楔横轧成形方法
CN108655354B (zh) * 2018-06-07 2019-12-27 东北大学 一种高强塑积中锰钢薄带的短流程制备方法
CN110899644A (zh) * 2018-09-14 2020-03-24 宝山钢铁股份有限公司 一种超薄热轧带钢的生产方法

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Also Published As

Publication number Publication date
JP3836793B2 (ja) 2006-10-25
CN1466633A (zh) 2004-01-07
JP2004515362A (ja) 2004-05-27
CN1236076C (zh) 2006-01-11
WO2002046480A1 (fr) 2002-06-13
US20040074628A1 (en) 2004-04-22
EP1341937B1 (fr) 2004-05-19
ES2221659T3 (es) 2005-01-01
DE10060948A1 (de) 2002-06-27
DE50102363D1 (de) 2004-06-24
US20070199631A1 (en) 2007-08-30
CZ20031558A3 (cs) 2004-02-18
ATE267269T1 (de) 2004-06-15
PL196538B1 (pl) 2008-01-31
CZ304928B6 (cs) 2015-01-28
DE10060948C2 (de) 2003-07-31
PL362508A1 (en) 2004-11-02
AU2002231664A1 (en) 2002-06-18

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