Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
  • B01J2/24—Obtaining flakes by scraping a solid layer from a surface
• • C—CHEMISTRY; METALLURGY
  • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F11/00—Treatment of sludge; Devices therefor
  • C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
  • C02F11/13—Treatment of sludge; Devices therefor by de-watering, drying or thickening by heating
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F26—DRYING
  • F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
  • F26B17/00—Machines or apparatus for drying materials in loose, plastic, or fluidised form, e.g. granules, staple fibres, with progressive movement
  • F26B17/001—Machines or apparatus for drying materials in loose, plastic, or fluidised form, e.g. granules, staple fibres, with progressive movement the material moving down superimposed floors
  • F26B17/003—Machines or apparatus for drying materials in loose, plastic, or fluidised form, e.g. granules, staple fibres, with progressive movement the material moving down superimposed floors with fixed floors provided with scrapers
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F26—DRYING
  • F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
  • F26B21/00—Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects
  • F26B21/14—Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects using gases or vapours other than air or steam, e.g. inert gases
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F26—DRYING
  • F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
  • F26B2200/00—Drying processes and machines for solid materials characterised by the specific requirements of the drying good
  • F26B2200/18—Sludges, e.g. sewage, waste, industrial processes, cooling towers

Definitions

• the present invention relates to an apparatus and a process for the indirect heat drying and simultaneous pelletization, e.g. obtained from a waste water treatment process.
• the sludge is thermally dried and processed to obtain substantially pathogene free low dust containing pellets, substantially uniform in particle size and uniform in moisture content. Thereafter the pellets are suitable for use as a fertilizer, an additive to a fertilizer, a fuel, etc.
• Waste water treatment creates sewage sludge in large amounts.
• Raw sewage received in waste water treatment facilities is treated by various known methods which generate the sludge. Thereafter, a problem remains in how to treat and dispose of the sludge in an environmentally safe, energy efficient and economical way.
• Sludge is presently disposed of in many ways, such as by direct land application of the sludge, composting the sludge, land filling the sludge, ocean filling the sludge, and drying and incinerating the sludge.
• Municipal sludge for instance is mostly a liquid containing 2-6% total solids. It typically contains inorganic and organic matter, nutrients such as nitrogen, phosphorous and potassium and traces of various metals. It may also contain pathogens, and, in some instances, constituents such as heavy metals and hazardous organics, depending upon the source of the raw sewage that has been treated.
• the sludge is treated to increase its solid content.
• the sludge can be dewatered by gravity, by mechanically dewatering the sludge, and by thermal treatment of the sludge.
• the water content of sludge includes intracellular water, capillar water, colloidal water and free water. Free water can generally be separated from the sludge by gravity.
• the capillar and colloidal water can be removed from the sludge, usually after chemical conditioning, by mechanical means such as centrifuges, belt presses, vacuum filters and the like.
• Intracellular water on the other hand, generally needs to be removed by breaking the cell structure down by thermal treatment.
• the sludge product obtained is 2-6% total solids.
• the solids content is increased by mechanical dewatering of the sludge to 15-30% total solids.
• the liquid sludge is thermally dried, a product of 80-98% total solids is obtained.
• the volume of the sludge decreases as the sludge is processed to increase its solids content.
• the type of dewatering process that is selected for a particular waste treatment plant is based upon several considerations.
• the thermal treatment of sludge has the advantage of the greatest reduction in sludge volume (up to 98%), and also destroys or inactivates pathogenic organisms, rendering the sludge sterile.
• the thermal treatment of sludge requires special drying equipment and an energy source for generating the heat needed in drying the sludge.
• Sludge is a solid-liquid waste mixture having a total solid concentration that may range from as low as 10% til more than 50% dry solid content for some industrial sludges. Generally, sludge can flow and can be pumped.
• Another aspect of this problem is that with the volume of sludges from the domestic and industrial increasing, the land available for such sludge disposal and public tolerance of environmental pollution is decreasing. This situation has severely constrained the choice of acceptable disposal practices.
• US 5,628,913 discloses a method and an apparatus where pellets can be formed directly, while preventing the formation of aggregates.
• the latter document discloses however the use of an extruder through which the dried sludge is urged to a nozzle having an orifice. It is clear that separate pelletizing means are provided in order to obtain said pellets.
• An object of the present invention is to overcome the deficiencies of the known sludge treatment systems by using a dryer-pelletizer for sludge that has been dewatered mechanically to dry the sludge by condutive indirect drying and simultaneously pelletization of the dried product inside the dryer-pelletizer so that it is acceptable for use as a fertilizer in pellet form.
• the pellets do not contain any living organisms, viruses or pathogens so that the risk of contaminating the land, which is present in the direct application of sludge that has not been heat treated, is avoided. Further, as a result of simultaneously pelletizing the dried product to form pellets of a size that can be handled like existing fertilizer pellets, no additional pellet forming apparatus is required that would increase the cost of the system.
• a further object of the present invention is to provide non-polluting, odorless process of sludge by an indirect heat method with simultaneous pelletization of the sludge in a multi-stage dryer-pelletizer.
• Yet a further object of the present invention is to provide a thermal sludge treatment process and apparatus that is safe and wherein only a negligible volume of odourous uncondensables is produced.
• the apparatus is air tight and the inside of the dryer-pelletizer and pellet recirculation system is processed at an oxygen content far below the ignition limits of the dried sludge, by means of inertization by the water vapors generated by the drying process.
• the inertization of gaseous medium inside the embodiment is done by injection and evaporation of water to displace the air by inert water vapor.
• Yet another object of the invention is to inertisate the pellet recirculation system to eliminate the risk of: pellet glowing and burning, CO and dust explosions, by displacing O 2 by water vapors coming from the drying process.
• To achieve this inertization part of the water vapor flow generated in the dryer-pelletizer are extracted in front of the condenser and reinjected in the pellet recirculation system at the farest end to flow back into the dryer-pelletizer.
• Yet a further object of the present invention is the place of the coater right in front off and on top of the dryer-pelletizer to achieve a monogeneous and not sticky mixture of died fines coated with a thin layer of wet sludge, together having a moisture content of between 60 to 70% solids.
• the dryer-pelletizer feed is preferably kept at a moisture content of between 60 to 70% solids so that a difficult to handle, glue-like sludge phase inside the dryer-pelletizer is avoided.
• the dried fines are mixed with the dewatered sludge to provide central dry nuclei that are coated by the dewatered sludge and dried to build up the nuclei layer by layer to form the pellets of a desired size, preferably 2-4 millimeters. Pellets are built up layer by layer, and are therefore dried from the inside out. It is further preferable that a supply of dried fines are maintained for start-up of the process after the indirect heat dryer has been shut down for a period of time.
• Yet another object to the invention is to guarantee the pearl process, of adding layer by layer of wet sludge to a basis of dried sludge pellets and roll it gently over the heated plates while drying to over 90% dry solid content and killing infectious organisms, although the number of scrapers and scraper arms, to gently roll and pelletise the sludge, can vary with a factor of 1 to 100 between the small and the large embodiments.
• part of the scrapers are mounted to push the drying pellets stream up instead of stream down like the other scrapers.
• the angle of the scrapers is adjustable and adjusted in a way that the residence time in the embodiment, the collision energy between scrapers and drying pellets, and the number of collisions of a drying pellet with the scrapers can be kept the same independent of the size and drying capacity of the embodiment and independent of the number of scrapers of the embodiment.
• Yet another object of the present invention is to control the pellet size by a pellet separation hopper.
• the pellet separation hopper In the pellet separation hopper the larger fraction of pellets is separated from the fines.
• the hopper has an pellet input and two pellet outputs. At the input, the pellets are entered with a certain horizontal speed. The first exit in horizontal direction is filled up with the fines which are recirculated into the coater in front of the dryer-pelletizer. The second exit in the horizontal direction is always kept empty and only the sufficient large pellets will get to this exit and represent the end product of the system.
• the larger pellets are separated because of their higher kinetic energy and the fact that larger pieces roll easier down hill over a slope of pellets. The sizing of the pellets is a result of this horizontal speed and the dimensions of the pellet slope.
• the separation hopper is made with adjustable plates to change the dimensions of the hopper which means changing of the shape, length and/or the angle of the pellet slope.
• This hopper can be placed as well at the bottom of the dryer- pelletizer as on top of it.
• the bottom scrapers of the dryer-pelletizer will be responsible for the horizontal speed to enter the pellet separation hopper.
• the horizontal speed can be given by a pellet transport device, preferably a bucket elevator or a disk chain conveyor.
• Yet another object of the present invention is to provide an easily operable process whereby no dust is produced and working at a minimum temperature is possible, to result in high quality pellets which are round-shaped and dust-free.
• the speed of the scrapers is limited to a maximum and the pellet separation hopper is sized to lead the little amount of dust together with the undersized pellets back to the coater.
• Yet another object of the present invention is to provide for the small capacity embodiments an apparatus with dimensions such that it can be handled over public roads.
• the small embodiments are built in a container sized frame of 20ft, 30ft or 40ft depending of the evaporation capacity of the embodiment.
• sludge denotes any product containing both solid and liquid matter, in which the liquid matter can be evaporated by heating up the sludge.
• pellet herein used denotes rounded marble like particles with an average diameter between 0.5mm and 15mm.
• dryer-pelletizer denotes an apparatus in which the wet sludge is dried and simultaneously pelletized.
• inert atmosphere, inert gas denotes means in this field of invention a gas or atmosphere which has no significant exothermal reaction with no sludge, pellets and dust.
• the term "scraper” herein used denotes a downwardly positioned element which forces the coated sludge and pellets to roll down stream or up stream on the horizontal hot plates of the dryer-pelletizer.
• the present invention relates to a process, also referred to as "the pearl process", and to an apparatus to dry and pelletize sludge, with a dry solid content of less than 40%, typically about 25%, in a one step process with respect of the safety of the process and quality of the end product.
• the sludge is dried in a conductive and indirect heating apparatus to simultaneously dry and pelletize the sludge.
• the dried product is classified to separate the undersized fraction from the pellets.
• the end product are pellets with a dry solid content of more than 80%, preferably about 93%, which are then cooled and stored for subsequent use as fertilizer, fuel, etc.
• the too fine pellet fraction is added to and mixed again with liquid sludge before it is input to the drying and pelletizing device.
• the apparatus and pellet recirculation system are air tight and kept under a water vapor blanket coming from the drying process.
• the escape of malodorous gases is prevented by keeping the internal of the drying and pellet recirculating system below atmospheric pressure.
• the water vapor generated during the drying of the sludge is preferably condensated in a direct condenser and the uncondensables are preferably deodorized in a high temperature combustion zone, a bio filter or an activated carbon filter.
• the present invention relates to a process for converting a substantial wet sludge into dried pellets comprising:
• the invention further relates to an apparatus for the treatment of sludge into pellets, comprising: input means for the sludge on top of the apparatus, - pellet exit means at a bottom plate of the apparatus,
• the present invention relates a process and method for treating a sludge by transforming it into dried pellets comprising: rolling the wet sludge over one or more hot plates for conductive indirect drying and simultaneously pelletization of the sludge, while keeping the process under an inert atmosphere, inert for explosions and combustion of the pellets, dust and sludge.
• This inert atmosphere is achieved by using the evaporated vapors as an inert low oxygen containing blanket inside the dryer-pelletizer and pellet recirculation system.
• the sludge is first coated, in a coater, around dry nuclei, preferably existing of recirculated dried too fine pellets, to facilitate the formation of pellets while drying in the dryer-pelletizer.
• dried sludge is recirculated several times as fines separated in the separation hopper, building up the pellets layer by layer to a predetermined size, before it is separated off as an on-size pellet in the separation hopper.
• the invention provides therefore a method for the continuous drying of sludge comprising: coating of recirculated sludge pellets with a dry solid content of about 80-99% with sludge to be dried, introducing said coated sludge pellets into a dryer-pelletizer at a slightly negative pressure with the exclusion of air, such that the oxygen content in the dryer is lower than 5% by volume, bringing said coated pellets into contact with the outside surfaces of a plurality of hollow and heated annular plates, displacing the coated pellets on each plate inwardly or outwardly and counter stream such that these coated pellets stay sufficiently long and with the right pellet layer thickness on the plate to obtain a sufficient residence time in the dryer-pelletizer to dry and gently form a round pellet shape while passing onto the next lower plate for treatment on the plates in cascade, evaporizing the liquid contained in said coated pellets, separating the sufficiently sized dried sludge pellet fraction from the not sufficiently sized dried sludge pellets fraction in the separation hopper, and recirculating
• the combination of coating and drying and recirculation provides for an excellent mode of operation wherein the sludge is dried efficiently and high quality pellets are resulting therefrom.
• Pellets produced according to the present invention can be delivered at a time suitable to agriculture or for other applications, since they are capable of being stored.
• the invention further relates to an apparatus for the treatment of sludge comprising coater for the coating of recirculated sludge pellets with a dry solid content of about 80-99% with sludge to be dried and drying means for drying the coated sludge pellets, whereby the drying means comprise a plurality of vertically spaced-apart horizontal annular plates, an upright shaft, upper inlet means and lower outlet means, the shaft having at least one radial arm disposed above each plate for entraining a multiplicity of scrapers for enabling the movement of the coated pellets on each plate inwardly or outwardly such that these coated pellets can pass onto the next lower plate for treatment on the plates in cascade, and heating means for heating the plates, whereby the coater are situated near the upper inlet of the drying means. All kept under a low oxygen containing blanket of vapors from the drying process to avoid explosions and fire.
• the apparatus and the process for indirect heat drying and simultaneous pelletization of a liquid waste sludge is shown in figure 1 and the dryer-pelletizer itself in figure 2a and figure 2b.
• the system is fully integrated to provide an odorless, highly energy efficient process for treating liquid sludge wherein the escape of malodorous gases and the risk of self-ignition of the pellets and dust explosion is minimized, and sterile dry pellets are produced as a fertilizer, fuel, etc.
• the drying and pelletizing section receives the dewatered sludge stored in silo 10 in a coater 2 as it is transported 6 from the silo 10 to the coater 2.
• the dewatered sludge is mixed with fines obtained from the dry product classifying separation hopper 14, and the mixture is input to dryer-pelletizer 3.
• the moisture content of the mixture entering S2 the dryer-pelletizer 3 is between 60 and 70% solids in order to avoid a difficult to handle, glue-like sludge phase inside the dryer-pelletizer 3.
• each particle of the fines represents a central dry nucleus 38 that is built up layer by layer with the dewatered sludge 34 and dried to form the pellets and other dried material of various sizes.
• the layering process is repeated over and over until the product exits P2 the dryer-pelletizer 3. Therefore, the dried product exiting the dryer-pelletizer 3 will be in various shapes and sizes, and will include the pellets that are the desired end product of the process.
• each of the pellets is formed from a dry core, the resultant pellets have a structural stability that withstands subsequent material handling steps without crumbling.
• the sufficiently sized pellets are separated from the fines in the pellet separation hopper 14 and cooled down in a fluidized bed cooler 22, while the fines are recirculated 15. According to the present invention there has now been provided a process, a method and an apparatus that would fulfill the inventive object in an excellent manner.
• figure 1 schematically illustrates an apparatus for carrying out the process and method in accordance with the present invention
• figure 2a and 2b schematically illustrates a preferred embodiment of the conductive and indirect heated plate-type dryer-pelletizer means used in the. present invention
• figure 3 schematically illustrates a preferred embodiment of the coater used in the present invention
• figure 4 schematically illustrates a preferred embodiment of a separation hopper used in the method and apparatus of the present invention
• figure 5 schematically illustrates the preferred dimensioning with the accompanying frame for housing an apparatus according to the present invention
• figure 6 exemplifies schematically a coated sludge pellet.
• FIG. 1 discloses schematically a preferred embodiment of a process and an apparatus according to the present invention.
• Said apparatus 1 comprises four main components, being a sludge coater 2, drying-pelletizing means 3, pellet recirculation means 4 and pellet separation means 14.
• the sludge to be dried may be optionally mechanically dewatered 5 whereby sludge is obtained of 15 til 50% dry solid content.
• the sludge originating for example from a wastewater treatment plant is further transported to the coater 2 by means of a sludge transport system 6, preferably a sludge pump or horizontal and vertical screw conveyors.
• the dewatered sludge can be stored in a buffer silo 10 for a short time.
• the fraction of recirculated dry sludge pellets fines (P1) are intermixed with an incoming fraction of dewatered sludge (S1).
• the coated pellets 35 with the wet sludge are fed (S2) into the drying means 3.
• a dosing hopper 11 is provided for dosing the fraction dewatered sludge
• the coated pellets fraction is entered (S2) in the drying means 3 on a spiral dividing plate 49 or centrally entered on a dividing cone 47.
• Dryer-pelletizer means 3 which is producing dry round-shaped pellets in a continuous energy efficient drying and simultaneous pelletization operation.
• the characteristics of the obtained pellets are an average diameter of about 1 -4 mm and their specific hardness, due to the formation of a pellet layer by layer depending on the number of recirculation cycli.
• the obtained pellets are suitable for agricultural use, as an auxiliary fuel, etc. Possible agricultural uses are the use as a slow-release fertilizer or soil conditioner.
• the energy for the drying means 3 is preferably supplied by a heat carrier 37 as there is the thermal oil system 12 heat.
• the dried pellets leaving P2 the drying means 3 at a temperature of about 80-110°C are transported upwards in transporting means 4 and/or 15, preferably a bucket elevator or disc chain elevator.
• a not sufficient sized fraction of the dried pellets are recirculated 15 to the coater 2 via a separation hopper 14.
• the separation hopper 14 (see also figure 4) is in general a hopper having one inlet 16 and two separate outlets 17, 18.
• a first part 19 of the separation hopper 14 is substantially full and a second part 20 is substantially empty. Due to the right combination of horizontal kinetic energy of the pellets, the gravitational forces, an inclination surface 21 , length and width within the separation hopper 14 the sufficiently sized pellet fraction (P3) falls through the exit 18 out of the drying system.
• the size of the pellets can be changed from sufficiently sized if bigger than 0,5 mm till sufficiently sized if bigger than 10 mm.
• the fines fraction (P1) which leaves the separation hopper 14 via exit 17 is recycled and sent back to the coater 2 and the drying means 3.
• the separation hopper 14 is able to make a classification of the on-size dried product fractions. Indeed, the larger particles tend to come out of the system while the smaller ones remain.
• the pellet separation hopper 14 followed by the pellet dosing means 15, can be placed as well at the exit of the dryer-pelletizer means 3 as right in front of the pellet coater 2.
• the sufficiently sized pellet fraction (P3) is optionally cooled preferably in a vibrating fluid bed cooler 22 up to approximately a temperature of 30-50°C and transferred to a pellet storage 50.
• Part of the vapors extracted from the dryer-pelletizer 3 are recirculated 52 to the pellet recirculation system 4 and/or 15.
• the energy from the rest of the vapors is recovered in a condensor 51 and preferably used to heat the liquid sludge prior to digestion.
• the non-condensables (V3) are preferable injected into a burner for a complete thermal destruction, treated in the deodorisation unit of the waste water treatment plant or for the smaller embodiments treated in a biofilter or activated carbon filter.
• the apparatus according to this preferred embodiment is designed for a continuous operation (24 hours a day, 7 days a week) and is controlled automatically from a (not shown) central dispatch, where all data is stored in a central databank.
• a central dispatch where all data is stored in a central databank.
• the smaller embodiments can also be operated 16 hours a day, 5 days a week.
• the preferably mechanically dewatered sludge needs to be dried further from approximately 15% till 50% dry solid content up to more than 90% dry solid content.
• the drying system is essentially an conductive indirect contact dryer-pelletizer 3 having 1 up to 25 plates.
• the diameter of the plates 31 and 33 is preferably from 2 m to over 7,5 m, for example 2000 mm, 3800 mm, 5200 mm, 6200 mm or 7200 mm. When a container-sized device figure 5 would be envisaged, a smaller diameter of 2000 mm is preferred.
• thermal oil as a heating medium is used to optimize heat transfer rate.
• the preferably mechanically dewatered sludge is transported 6 and dosed into the coater 2 where it is thoroughly mixed and coated around the recirculated dry sludge pellet fraction of fines (P1).
• the coated pellets fall via the sludge inlet 25 in the upper section of the drying means 3 and are evenly spread by the spiral dividing plate 49 by the ranking mechanism 28 or by the top cone 47 and the raking mechanism 28 on the upper plate 27.
• the multiplicity of scrapers 48 enable the movement of the coated pellets 35 on each plate 31 and 33 inwardly or outwardly, depending on the angle and position of the scrapers 48 on their radial arm 32. Through this engagement the pellets 35 move to a next plate 31 or 33 for further drying.
• the speed of rotation, the position of the scrapers 48 are important features which can control the residence time of the coated pellets 35 in the dryer-pelletizer 3, the pellet layer thickness on the plates 31 and 33 and the speed and efficiency of drying.
• the necessary energy for the drying process is transferred by thermal oil 37 which circulates through the hollow plates 31 and 33 at a temperature range of about 150-300°C, and more preferably 230-260°C.
• the oil is heated by any burner, preferably a biological and natural gas burner or heated by fluegases of an incineration process.
• a substantial amount of energy can be recovered from the dryer-pelletizer exhaust.
• the vapors leaving the dryer-pelletizer 3 at a temperature of about 100-160°C, more preferably at about 115-130°C are preferably condensed in a direct condensor 51.
• the vaporized liquid is withdrawn via the ID fan (V3) from the housing and led to the hollow heat exchange means, condensed, giving up its latent heat energy, and vaporizing the liquid in wet material.
• the heat released by said condensation heats water from 50-60°C.
• each coated pellet 35 is being recirculated for an average of 4-20 times and provides for a dry solid content of more than 90%. Care is taken that in the dryer-pelletizer means 3 the oxygen content is lower than 5% by volume, preferably lower than 2%. This aspect minimizes fire and explosion risk.
• the obtained dust-free granules have a dry solid content of more than 90% and a chosen average diameter of 0,5 till 10 mm.
• FIG. 5 For the container sized type of the apparatus a preferred embodiment of the invention is depicted in figure 5 whereby a frame 39 is provided around the complete apparatus having the outside dimensions suitable for public road transport.
• the pellet separation hopper 14 in this embodiment is integrated in the bottom of the drying means 3 which provides for a more simple construction and a further guarantee for providing a safe atmosphere for the storage of the hot pellets.
• shaft 29 driving means are integrated at the top of the dryer-pelletizer 3 which further simplifies the construction.
• adjustable blades or scrapers 48 are preferred to control the residence time.
• Frame 39 consists essentially of container-sized interlinked horizontal and vertical beams including standard container corners.
• Four stamps 43 are attached on a floor element 44.
• a separate container 45 can be provided for housing of for example the burner unit and control panels.
• the coater 2 wherein sludge S1 and pellet fines P2 are intermixed such that the dried pellet fines are coated with a wet sludge forming the outer layer 34 of said pellet by means of a horizontal shaft 41 carry blades or scrapers 42. Along the horizontal shaft 41 several material engaging blades 42 are provided which each have a separate axe 43. Rotation of the shaft 41 provides for an efficient coating of the pellets 35.

Landscapes

• Engineering & Computer Science (AREA)
• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Mechanical Engineering (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Life Sciences & Earth Sciences (AREA)
• Hydrology & Water Resources (AREA)
• Environmental & Geological Engineering (AREA)
• Water Supply & Treatment (AREA)
• General Engineering & Computer Science (AREA)
• Treatment Of Sludge (AREA)
• Glanulating (AREA)

Priority Applications (1)

Applications Claiming Priority (4)

Publications (1)

Family

ID=8175815

Family Applications (1)

Country Status (4)

Families Citing this family (9)

Family Cites Families (6)

• 2001
  • 2001-09-21 AU AU2001293831A patent/AU2001293831A1/en not_active Abandoned
  • 2001-09-21 JP JP2002528605A patent/JP2004508930A/ja active Pending
  • 2001-09-21 WO PCT/EP2001/010951 patent/WO2002024585A1/en active Application Filing
  • 2001-09-21 EP EP01974278A patent/EP1324954A1/en not_active Withdrawn

Non-Patent Citations (1)

Also Published As

Similar Documents

Legal Events