EP1275273A1 - Dispositif electrique presentant un polymere conducteur ctp - Google Patents
Dispositif electrique presentant un polymere conducteur ctpInfo
- Publication number
- EP1275273A1 EP1275273A1 EP01917935A EP01917935A EP1275273A1 EP 1275273 A1 EP1275273 A1 EP 1275273A1 EP 01917935 A EP01917935 A EP 01917935A EP 01917935 A EP01917935 A EP 01917935A EP 1275273 A1 EP1275273 A1 EP 1275273A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- conductive polymer
- electrical device
- ptc
- electrodes
- electroless
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920001940 conductive polymer Polymers 0.000 title claims abstract description 44
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 36
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000011889 copper foil Substances 0.000 claims abstract description 26
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 18
- 230000003746 surface roughness Effects 0.000 claims description 9
- 238000007747 plating Methods 0.000 abstract description 16
- 239000000126 substance Substances 0.000 abstract description 10
- 238000000034 method Methods 0.000 description 21
- 229910052751 metal Inorganic materials 0.000 description 17
- 239000002184 metal Substances 0.000 description 17
- 229910052802 copper Inorganic materials 0.000 description 9
- 239000010949 copper Substances 0.000 description 9
- 238000009713 electroplating Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 5
- -1 polypropylene Polymers 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 238000007772 electroless plating Methods 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 238000005554 pickling Methods 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 230000001235 sensitizing effect Effects 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000011231 conductive filler Substances 0.000 description 3
- 238000005238 degreasing Methods 0.000 description 3
- 238000004070 electrodeposition Methods 0.000 description 3
- 229920000620 organic polymer Polymers 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 241000430525 Aurinia saxatilis Species 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 208000006558 Dental Calculus Diseases 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
- H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
- H05B3/146—Conductive polymers, e.g. polyethylene, thermoplastics
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/02—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having positive temperature coefficient
- H01C7/027—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having positive temperature coefficient consisting of conducting or semi-conducting material dispersed in a non-conductive organic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C1/00—Details
- H01C1/14—Terminals or tapping points or electrodes specially adapted for resistors; Arrangements of terminals or tapping points or electrodes on resistors
- H01C1/1406—Terminals or electrodes formed on resistive elements having positive temperature coefficient
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/02—Heaters using heating elements having a positive temperature coefficient
Definitions
- the present invention relates to an electrical device having a positive temperature coefficient (PTC) conductive polymer, and more particularly to an electrical device having PTC conductive polymer, which is made by combining electrodes in which electroless nickel plating is formed on an electrolytic copper foil, with PTC conductive polymer, so ensuring improved PTC characteristics and good chemical and mechanical binding capacity between the electrodes and the PTC conductive polymer.
- PTC positive temperature coefficient
- the conductive polymer shows PTC characteristics that conductive fillers are dispersed on organic polymer.
- PTC means a characteristic that electrical resistance rapidly increases at a relatively narrow temperature range due to increase of temperature.
- High molecular substances having PTC characteristics are generally used in a constant- temperature wire, a protection device for blocking over current, a circuit protection element, a heater and so on.
- Such conductive polymer is mechanically chemically combined with at least one electrode in an electrical device.
- a metal plate is generally used as the electrode combined with the conductive polymer.
- Such metal plate acts a role of connecting the conductive polymer to an external electrode and should not deteriorate the PTC characteristics of the conductive polymer. For such a reason, the conductive polymer should have good binding capacity to ensure electrical and mechanical combination with the metal plate.
- the binding capacity between the metal plate and the conductive polymer generally has two characteristics: mechanical binding capacity and chemical binding capacity.
- mechanical binding capacity a process of increasing surface roughness of the metal plate is required to restrain separation of the metal plate and the conductive polymer.
- metal plates show significantly different binding capacities to the polymer depending on their kinds, which are originated from difference of chemical binding capacities between the metal and the polymer.
- the chemical binding capacity increases in order of copper, iron, nickel, aluminum, zinc and so on. Therefore, the metal plate to be combined with polymer might be processed by scaling, surface-treatment using brass or zinc, or adhesive application using silane group.
- the electroplating is a representative method to increase surface roughness of the metal plate for restraining separation of the metal plate and the conductive polymer.
- a copper plating foil used in a printed circuit boards (hereinafter, referred to as PCB) and a metal plate used in an electrical device having PTC characteristics are manufactured using such method.
- the copper plating foil for the PCB is made to have 10 to 150 ⁇ m
- a copper foil is laminated on a base plate and then given heat and pressure thereto.
- the copper foil should have chemical resistance, such as against an acid, and resistance against discoloration of the board after etching after being attached to the base plate, and is required not to rust after etching.
- a surface of the copper foil for the PCB may be coated by a layer containing zinc, indium, brass or the like (Japanese Patent Publication No. 51-35711), or use an electrodeposited copper layer having two layers (Japanese Patent Publication No. 53-39376).
- the copper-zinc layer may be formed by electrolyzing one surface of the copper foil in a copper-zinc electrolytic bath containing copper ion, zinc ion, tartar acid and alkali with the cathode and then treating chromate on the cupper foil (U.S. Patent No. 5,304,428).
- the conventional electrode made by electrolytic plating or electrodeposition shows uneven thickness, which causes the electrode to be separated from the PTC polymer. Therefore, inventors of the present invention have endeavored to solve such problems and developed an electrode with even thickness by executing electroless plating to the electrolytic cupper foil used for the PCB.
- An object of the present invention is to provide an electrical device, which is made by combining metal electrodes, in which electroless nickel plating with even thickness is formed on an electrolytic copper foil, with PTC conductive polymer, so ensuring improved PTC characteristics and good chemical and mechanical binding capacity between the electrodes and the PTC conductive polymer.
- the present invention provides an electrical device having Positive Temperature Coefficient (PTC) conductive polymer, which includes electrodes having electroless-plated nickel layers at both sides of an electrolytic copper foil, and PTC conductive polymer welded between the electrodes, wherein the electroless-plated nickel has even thickness to ensure sufficient binding capacity to the PTC conductive polymer.
- PTC Positive Temperature Coefficient
- the electrolytic copper foil has surface roughness
- the electroless-plated nickel layer has a
- FIG. 1 is a surface photograph of an electrolytic copper foil used in the present invention
- FIG. 2 is a surface photograph of a specimen that the electrolytic copper foil is electroless nickel-plated of l ⁇ m in thickness;
- FIG. 3 shows an electrical device according to the present invention.
- FIG. 4 is a resistance-temperature graph of the electrical devices according to first to third embodiments of the present invention.
- the present invention suggests an electrical device including conductive polymer with PTC (Positive Temperature Coefficient) characteristics and electroless-plated metal electrodes.
- the PTC conductive polymer is welded between the electrodes in a sandwich type.
- the conductive polymer with PTC characteristics may be obtained by mixing conductive filler, cross-linking agent, antioxidant, etc. to organic polymer.
- the organic polymer can be one of polyethylene or ethylene-acrylic acid copolymer, ethylene-ethyl aciylate copolymer, ethylene-vinyl acetate copolymer and ethylene-butyl aciylate copolymer. Among them, polyethylene is most preferred.
- the conductive filler powder nickel, gold dust, powder copper, silvered powder copper, metal-alloy powder, carbon black, carbon powder or carbon graphite can be used. Among them, carbon black is most preferred.
- the metal electrode is made by electroless-plating a metal, which has good chemical binding capacity to the PTC conductive polymer, on the electrolytic copper foil having good mechanical binding capacity.
- the surface roughness Rz of the electrolytic copper foil is set to be l-20 ⁇ m through electrolytic plating in its manufacturing process.
- the electrolytic copper foil can be commercially acquired from LG Industry Co., which is specially used in this invention.
- the electrolytic copper foil is electroless-plated with nickel.
- the electroless nickel-plating procedure includes a degreasing process, a pickling process, an actuating and sensitizing treatment, an electroless nickel-plating process and a rinsing process.
- FIG. 2 a specimen, which is electroless-plated with nickel of l ⁇ m in thickness, is shown in FIG. 2. Seeing FIG. 2, it can be easily known that the surface roughness and shape of the specimen have no significant difference.
- the metal electrodes 2, in which the nickel is electroless-plated on the copper, are welded at both side of the PTC conductive polymer 1 to make the electrical device. This is well shown in FIG. 3.
- Polyethylene and carbon black are mixed to make PTC conductive polymer.
- electroless nickel-plating layer of l ⁇ m in thickness is formed on the electrolytic copper foil through a degreasing process, a pickling process, an actuating and sensitizing treatment, an electroless nickel-plating process and a rinsing process, to make electrodes.
- the electrodes are welded to both sides of the PTC conductive polymer in a sandwich type, so making the PTC electrical device as shown in FIG. 3.
- Embodiment 2 Polyethylene and carbon black are mixed to make PTC conductive polymer.
- An electrolytic copper foil having a surface roughness of 5 to
- nickel-plating layer of lO ⁇ m in thickness is formed on the electrolytic copper foil through a degreasing process, a pickling process, an actuating and sensitizing treatment, an electroless nickel-plating process and a rinsing process, to make electrodes.
- the electrodes are welded to both sides of the PTC conductive polymer in a sandwich type, so making the PTC electrical device as shown in FIG. 3.
- An electrical device is prepared in a similar method to the Embodiment 1. However, the actuating and sensitizing treatment is excluded from the electroless-plating procedure, and the electroless nickel-plating process is executed just after the pickling process. And then, chromium is coated on the electroless nickel-plating layer through substitution plating in a chromium bath. Comparative Example
- FIG. 4 Resistance changes depending on temperature of the electrical devices according to the embodiments 1 to 3 are shown in FIG. 4.
- the electrical devices of the present invention show no significant difference in resistance-temperature characteristics, compared with an electrical device using a conventional electrolytic copper foil. It means that the electrical device of the present invention not only strengthens binding capacity between the PTC conductive polymer and the electrodes but also maintains its resistance-temperature characteristics as much as the electrical device using the conventional electrolytic copper foil.
- the electrical device using copper electrodes of the comparative example shows significant difference in its resistance value before and after the humidity test. But, a resistance value of the electrical device using the electroless nickel plating according to the embodiment 1 does not decrease more than 10m ⁇ after the humidity
- the electrical device of the present invention gives more improved PTC characteristics and better binding capacity between the PTC conductive polymer and the electrodes than the conventional electrical device employing electrolytic plating or electrodeposition.
- the electroless plating employed in the present invention has an advantage that it may plate an object having uneven surfaces more uniformly than the electrolytic plating or the electrodeposition. Therefore, the electrical device of the present invention employing the electrodes, in which nickel is electroless-plated on the electrolytic copper foil, gives the advantages of better mechanical and chemical binding capacity to the PTC conductive polymer and more improved PTC characteristics.
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Chemically Coating (AREA)
- Thermistors And Varistors (AREA)
- Electroplating Methods And Accessories (AREA)
- Resistance Heating (AREA)
Abstract
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR2000018453 | 2000-04-08 | ||
KR1020000018453A KR100330919B1 (ko) | 2000-04-08 | 2000-04-08 | 피티씨 전도성 폴리머를 포함하는 전기장치 |
PCT/KR2001/000523 WO2001078453A1 (fr) | 2000-04-08 | 2001-03-30 | Dispositif electrique presentant un polymere conducteur ctp |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1275273A1 true EP1275273A1 (fr) | 2003-01-15 |
EP1275273A4 EP1275273A4 (fr) | 2007-11-28 |
Family
ID=19662812
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01917935A Withdrawn EP1275273A4 (fr) | 2000-04-08 | 2001-03-30 | Dispositif electrique presentant un polymere conducteur ctp |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP1275273A4 (fr) |
JP (1) | JP3833538B2 (fr) |
KR (1) | KR100330919B1 (fr) |
CN (1) | CN1210994C (fr) |
AU (1) | AU2001244810A1 (fr) |
TW (1) | TW480496B (fr) |
WO (1) | WO2001078453A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6965293B2 (en) | 2000-04-08 | 2005-11-15 | Lg Cable, Ltd. | Electrical device having PTC conductive polymer |
EP1327995A3 (fr) * | 2002-01-11 | 2005-10-12 | Shipley Co. L.L.C. | Structure à résistance |
JP4942333B2 (ja) * | 2005-11-29 | 2012-05-30 | 住友金属鉱山株式会社 | ニッケル粉およびその製造方法、ならびに該ニッケル粉を用いたポリマーptc素子 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0952591A1 (fr) * | 1996-09-20 | 1999-10-27 | Matsushita Electric Industrial Co., Ltd. | Thermistance a coefficient de temperature positif |
EP0955643A1 (fr) * | 1996-12-26 | 1999-11-10 | Matsushita Electric Industrial Co., Ltd | Thermistance ctp et son procede de fabrication |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4689475A (en) * | 1985-10-15 | 1987-08-25 | Raychem Corporation | Electrical devices containing conductive polymers |
JPH01236601A (ja) * | 1988-03-17 | 1989-09-21 | Matsushita Electric Ind Co Ltd | セラミック電子部品 |
JPH01236602A (ja) * | 1988-03-17 | 1989-09-21 | Matsushita Electric Ind Co Ltd | 正特性サーミスタ |
JPH05343201A (ja) * | 1992-06-11 | 1993-12-24 | Tdk Corp | Ptcサーミスタ |
DE69513656T2 (de) * | 1994-06-08 | 2000-07-13 | Raychem Corp., Menlo Park | Leitfähige polymere enthaltende elektrische vorrichtungen |
-
2000
- 2000-04-08 KR KR1020000018453A patent/KR100330919B1/ko not_active IP Right Cessation
-
2001
- 2001-03-30 JP JP2001575773A patent/JP3833538B2/ja not_active Expired - Fee Related
- 2001-03-30 WO PCT/KR2001/000523 patent/WO2001078453A1/fr active Application Filing
- 2001-03-30 AU AU2001244810A patent/AU2001244810A1/en not_active Abandoned
- 2001-03-30 CN CNB018066844A patent/CN1210994C/zh not_active Expired - Fee Related
- 2001-03-30 EP EP01917935A patent/EP1275273A4/fr not_active Withdrawn
- 2001-04-02 TW TW090107842A patent/TW480496B/zh not_active IP Right Cessation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0952591A1 (fr) * | 1996-09-20 | 1999-10-27 | Matsushita Electric Industrial Co., Ltd. | Thermistance a coefficient de temperature positif |
EP0955643A1 (fr) * | 1996-12-26 | 1999-11-10 | Matsushita Electric Industrial Co., Ltd | Thermistance ctp et son procede de fabrication |
Non-Patent Citations (1)
Title |
---|
See also references of WO0178453A1 * |
Also Published As
Publication number | Publication date |
---|---|
EP1275273A4 (fr) | 2007-11-28 |
CN1418451A (zh) | 2003-05-14 |
CN1210994C (zh) | 2005-07-13 |
WO2001078453A1 (fr) | 2001-10-18 |
JP3833538B2 (ja) | 2006-10-11 |
KR20010090933A (ko) | 2001-10-22 |
KR100330919B1 (ko) | 2002-04-03 |
TW480496B (en) | 2002-03-21 |
AU2001244810A1 (en) | 2001-10-23 |
JP2003530718A (ja) | 2003-10-14 |
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